Molybdate Orange-Low Soluble Lead

Transcription

1 SAFETY DATA SHEET Molybdate Orange-Low Soluble Lead 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name : NL-35, NL-38, NL-38C, NL-39, NR-34 Molybdate Orange NR-37C, NR-38, NRC-36, NS-36, NS-38 Molybdate Orange Nubiterm NK-38 Chemical description : Lead chromate molybdate sulfate red REACH nr. : Relevant identified uses of the substance or mixture and uses advised against Use : Colouring agents, pigments Details of the supplier of the safety data sheet Company identification : NUBIOLA GROUP Gran Via Corts Catalanes Barcelona SPAIN Tel nuproducts.safety@nubiola.com 1.4. Emergency telephone number Phone number : UK National Poisons Emergency Hazards identification 2.1. Classification of the substance or mixture Classification [Regulation (EC) No 1272/2008 (CLP/GHS)] Health hazards Environmental hazards : Carcinogenicity - Category 1B - Danger (CLP : Carc. 1B) H350 Reproductive toxicity - Unborn Child - Category 1A - Danger (CLP : Repr. 1A) H360 Reproductive toxicity - Fertility - Category 2 - Warning (CLP : Repr. 2) H361 Specific Target Organ Toxicity - Repeated exposure - Category 2 - Warning (CLP : STOT RE 2) H373 : Hazardous to the aquatic environment - Acute hazard - Category 1 - Warning (CLP : Aquatic Acute 1) H400 Hazardous to the aquatic environment - Chronic hazard - Category 1 - Warning ( CLP : Aquatic Chronic 1) H410 Classification [67/548/EEC or 1999/45/EC] Classification : Carc. Cat. 2; R45 Repr. Cat. 1; R61-62 R33 N; R Label elements Revised edition no : 2 Page : 1 / 10 Date : 15/11/2012 Supersedes : 8/5/2012

2 2. Hazards identification (continued) SAFETY DATA SHEET Molybdate Orange-Low Soluble Lead Labelling [Regulation (EC) No 1272/2008 (CLP/GHS)] Hazard pictograms Signal word Hazard statements Precautionary statements General Prevention Response Storage Disposal considerations M MÅ : Danger : H350 : May cause cancer. H360Df: May damage the unborn child. Suspected of damaging fertility. H373 : May cause damage to organs through prolonged or repeated exposure. H410 : Very toxic to aquatic life with long lasting effects. : P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. : P273: Avoid release to the environment. P281: Use personal protective equipment as required. : P308+P313: IF exposed or concerned: Get medical advice/attention. P391: Collect spillage. : P405: Store locked up. : P501: Dispose of contents/container to hazardous or special waste collection point, in accordance with local / regional / national or international regulations. Contains : Lead chromate molybdate sulfate red (Pigment Red 104, C.I ) Labelling [67/548/EEC or 1999/45/EC] Symbol(s) Symbol(s) êt ên : T : Toxic N : Dangerous for the environment R Phrase(s) : R45 : May cause cancer. R61 : May cause harm to the unborn child. R33 : Danger of cumulative effects. R62 : Possible risk of impaired fertility. R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S Phrase(s) : S45 : In case of accident or if you feel unwell, seek medical advice immediately ( show the label when possible). S53 : Avoid exposure - obtain special instructions before use. S60 : This material and its container must be disposed of as hazardous waste. S61 : Avoid release to the environment. Refer to special instructions/safety data sheets. Contains : Lead chromate molybdate sulfate red (Pigment Red 104, C.I ) Special labelling : Restricted to professional users. (Substances which appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008) 2.3. Other hazards Other hazards : The substance does not fulfil the criteria to be identified as PBT substance or vpvb Revised edition no : 2 Page : 2 / 10 Date : 15/11/2012 Supersedes : 8/5/2012

3 2. Hazards identification (continued) SAFETY DATA SHEET Molybdate Orange-Low Soluble Lead substance according to Annex XIII of Regulation REACH. 3. Composition/information on ingredients Substance / Mixture Hazardous component(s) Composition : Substance. Lead chromate molybdate sulfate red (Pigment Red 104, C.I ) CAS No : EC No : Index No : REACH Ref. : : This product is hazardous. : Pb (Cr,Mo,S)SO4 Substance name Contents CAS No EC No Index No REACH Ref. Classification Lead chromate molybdate sulfate : Carc. Cat. 2; R45 red (Pigment Red 104, C.I ) Repr. Cat. 1; R61 Repr. Cat. 3; R62 R33 N; R Carc. 1B _ H350 Repr. 1A _ H360D Repr. 2 _ H361f STOT RE 2 _ H373 Aquatic Acute 1 _ H400 Aquatic Chronic 1 _ H410 Contains no other components or impurities which will influence the classification of the product. Full text of R-, H- and EUH-phrases: see section First aid measures 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If you feel unwell, seek medical advice. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if pain, blinking or redness persist. : Induce vomiting (only if the person is conscious). Rinse mouth. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms relating to use : Not expected to present a significant hazard under anticipated conditions of normal use Indication of any immediate medical attention and special treatment needed General information : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical advice/attention. Revised edition no : 2 Page : 3 / 10 Date : 15/11/2012 Supersedes : 8/5/2012

4 5. Fire-fighting measures SAFETY DATA SHEET Molybdate Orange-Low Soluble Lead 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Sand. : Carbon dioxide. Do not use a heavy water stream Special hazards arising from the substance or mixture Hazardous combustion products : Under fire conditions, hazardous fumes will be present Advice for fire-fighters Protection against fire Special procedures : Do not enter fire area without proper protective equipment, including respiratory protection. : Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For emergency responders Special precautions For non-emergency personnel : Equip cleanup crew with proper protection. Ventilate area. : Recover the cleaning water for later disposal. : Evacuate unnecessary personnel Environmental precautions Environmental precautions : Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters Methods and material for containment and cleaning up Clean up methods : Ventilate area. On land, sweep or shovel into suitable containers. Minimize generation of dust Reference to other sections See section 8. Exposure controls/personal protection 7. Handling and storage 7.1. Precautions for safe handling Handling Technical protective measures : Do not handle until all safety precautions have been read and understood. Avoid breathing dust. Contaminated work clothing should not be allowed out of the workplace. Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. : Provide adequate ventilation to minimize dust concentrations. Revised edition no : 2 Page : 4 / 10 Date : 15/11/2012 Supersedes : 8/5/2012

5 7. Handling and storage (continued) SAFETY DATA SHEET Molybdate Orange-Low Soluble Lead 7.2. Conditions for safe storage, including any incompatibilities Storage Storage - away from : Keep only in the original container in a cool, dry, well-ventilated place. Keep container closed when not in use. : Strong acids. Strong bases Specific end use(s) Specific end use(s) : Industrial uses: Uses of substances as such or in preparations at industrial sites. 8. Exposure controls / personal protection 8.1. Control parameters TWA [mg/m³] MAK OEL [mg/m³] : 0.05 mg/m3 (CrO3) (Respirable Dust) 0.10 mg/m3 (Pb) (Respirable Dust) : 0.15 mg/m3 (Directive 98/24/EC) 8.2. Exposure controls Engineering measures Personal protection : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. : ó = : Avoid all unnecessary exposure. General Respiratory protection : Wear respiratory protection: FFP3 (EN 149) Hand protection : Wear protective gloves. (EN 374) Eye protection : Chemical goggles or safety glasses. Others : Do not eat, drink or smoke when using this product. 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state at 20 C : Powder. Colour : Orange. Odour : Odourless. Odour threshold : Not applicable. ph : (10% w/w) [ISO 787-9] Melting point [ C] : > 800 C Decomposition point [ C] : > 400 C Critical temperature [ C] : Not applicable. Auto-ignition temperature [ C] : Not applicable. Flammability (solid, gas) : Not flammable. [UN Test 1] Revised edition no : 2 Page : 5 / 10 Date : 15/11/2012 Supersedes : 8/5/2012

6 SAFETY DATA SHEET Molybdate Orange-Low Soluble Lead 9. Physical and chemical properties (continued) Flash point [ C] Boiling point [ C] Evaporation rate Vapour pressure [20 C] Vapour density Density at 20ºC [g/cm3] Solubility in water Log Pow octanol / water at 20 C Viscosity at 40 C [mm2/s] Explosive properties Explosion limits - upper [%] Explosion limits - lower [%] Oxidising properties : Not flammable. : Not applicable. (Solid) : Not applicable. : Not applicable. (Solid) : Not applicable. (Solid) : g/cm3 [ASTM D ] : Insoluble. : No data available. : Not applicable. (Solid) : Not explosive. : Not applicable. : Not applicable. : Not oxidizing. 10. Stability and reactivity Reactivity Reactivity : Stable under normal conditions Chemical stability Chemical stability : Stable under normal conditions Possibility of hazardous reactions Hazardous reactions : Stable under recommended storage conditions Conditions to avoid Conditions to avoid : Decomposes at temperatures above 400 ºC Incompatible materials Incompatible materials : Strong acids. Strong bases Hazardous decomposition products Hazardous decomposition products : None under normal conditions. 11. Toxicological information Information on toxicological effects Acute toxicity Ingestion : Based on available data, the classification criteria are not met. - LD50 (rat, oral) [mg/kg] : > 5000 mg/kg (bw; male/female) [OECD 401] Revised edition no : 2 Page : 6 / 10 Date : 15/11/2012 Supersedes : 8/5/2012

7 SAFETY DATA SHEET Molybdate Orange-Low Soluble Lead 11. Toxicological information (continued) Dermal : No data available. Inhalation : No data available. Corrosion : Not applicable. Irritation : Based on available data, the classification criteria are not met. Eyes irritation (rabbit) : Non-irritating. (72 h) [OECD 405] Dermal irritation (rabbit) : Non-irritating. (72 h) [OECD 404] Sensitization : No sensitizing potential. Repeated dose toxicity Ingestion (90 d) - LOAEL : 70 mg/kg (bw/day) dogs [OECD 408] Mutagenicity : Bacterial mutation: Positive [AMES Test] Mammalian cells mutation: Positive [OECD 479] Chromosome aberration: Genotoxicity Negative (mouse, female) [Bone narrow micronucleous Test] Carcinogenicity : May cause cancer mg/kg (bw) (implanted pellets, two years) [FDA Guidelines] Reproductive toxicity : May damage the unborn child. Suspected of damaging fertility. Effects on fertility : Testicular degeneration. 70 mg/kg (bw; 90 days; dogs/male) [OECD 409] Effects on development : No data available. Specific target organ toxicity (STOT) : No experimental or epidemiological evidence exists. single exposure Specific target organ toxicity (STOT) : May cause damage to organs through prolonged or repeated exposure. repeated exposure Aspiration hazard : No experimental or epidemiological evidence exists. 12. Ecological information Toxicity Toxicity information : Very toxic to aquatic life with long lasting effects. - EC50 48 h - Daphnia [mg/l] : > 100 mg/l (Daphnia magna) - LC50 96 h - Fish [mg/l] : 2500 mg/l (Leuciscus idus) Persistence - degradability Persistence - degradability : May cause long-term adverse effects in the environment Bioaccumulative potential Bioaccumulative potential : Inorganic substance Mobility in soil Mobility in soil : Not established Results of PBT and vpvb assessment Revised edition no : 2 Page : 7 / 10 Date : 15/11/2012 Supersedes : 8/5/2012

8 12. Ecological information (continued) SAFETY DATA SHEET Molybdate Orange-Low Soluble Lead Results of PBT and vpvb assessment : The substance does not fulfil the criteria to be identified as PBT substance or vpvb substance according to Annex XIII of Regulation REACH Other adverse effects Environmental precautions : Avoid release to the environment. WGK (Germany) :3 13. Disposal considerations Waste treatment methods General Special precautions : Avoid release to the environment. Dispose of contents/container to hazardous or special waste collection point, in accordance with local / regional / national or international regulations. : Hazardous waste due to the heavy metal content. 14. Transport information Land transport (ADR-RID) Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Lead chromate molybdate sulfate red (Pigment Red 104, C.I )) UN N : 3077 H.I. nr :90 ADR - Class :9 Labelling - Transport : 9 : Miscellaneous dangerous substances and articles. ào ADR - Classification code :M7 ADR - Group : III ADR - Packing instructions : P002 R001 LP002 ADR - Limited Quantity : 5 KG ADR - Tunnel code : E : Passage forbidden through tunnels of category E Sea transport (IMDG)» Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Lead chromate molybdate sulfate red (Pigment Red 104, C.I )) UN N : 3077 Revised edition no : 2 Page : 8 / 10 Date : 15/11/2012 Supersedes : 8/5/2012

9 14. Transport information (continued) SAFETY DATA SHEET Molybdate Orange-Low Soluble Lead IMO-IMDG - Class or division IMO-IMDG - Packing group IMO- IMDG - Packing instructions IMO-IMDG - Limited quantities IMO-IMDG - Marine pollution EMS-Nr : 9 : Miscellaneous dangerous substances and articles. : III : P002 LP02 : 5 kg : YES : F-A S-F Air transport (ICAO-IATA) Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Lead chromate molybdate sulfate red (Pigment Red 104, C.I )) UN N : 3077 IATA - Class or division : 9 : Miscellaneous dangerous substances and articles. IATA - Packing group : III IATA - Passenger and Cargo Aircraft : ALLOWED - Passenger and Cargo - Packing : 956 instruction - Passenger and Cargo - Maximum : 400 kg Quantity/Packing IATA - Cargo only : ALLOWED - Cargo only - Packing instruction : Cargo only - Maximum Quantity/ : 400 kg Packing IATA - Limited Quantites ERG-Nr :9L : 30 kg G 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Safety, health and environmental : Ensure all national/local regulations are observed. regulations/legislation specific for the substance or mixture REACH Restrictions - Annex XVII : Caution : product for professional use only. Shall not be placed on the market or used for supply to the general public when the individual concentration in the substance or mixture is equal to or greater than 0,1%. SVHC substance (ECHA: REACH Authorisation - Annex XIV : Substance listed in Annex XIV Chemical Safety Assessment Chemical Safety Assessment : It has been carried out. 16. Other information Revision : Revision - See : * Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of Revised edition no : 2 Page : 9 / 10 Date : 15/11/2012 Supersedes : 8/5/2012

10 16. Other information (continued) SAFETY DATA SHEET Molybdate Orange-Low Soluble Lead Full text of abbreviated R-phrases ( Section 3) Full text of abbreviated H-statements (Section 3) Recommended uses and restrictions Further information substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 : R33 : Danger of cumulative effects. R45 : May cause cancer. R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R61 : May cause harm to the unborn child. R62 : Possible risk of impaired fertility. : H350 : May cause cancer. H360D: May damage the unborn child. H361f : Suspected of damaging fertility. H400 : Very toxic to aquatic life. H410 : Very toxic to aquatic life with long lasting effects. : See product bulletin for detailed information. : For professional use only. The contents and format of this safety data sheet are in accordance with REACH Regulation (EC) No 1907/2006 and Regulation ( EU) No 453/2010. DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. End of document Revised edition no : 2 Page : 10 / 10 Date : 15/11/2012 Supersedes : 8/5/2012

11 ANNEX I 1. EXPOSURE SCENARIOS General remarks For the human health exposure assessment, only the inhalation route is considered because it is the relevant route of exposure for the worker and professional user. Use in consumer products is not supported and thus, no oral risk assessment was performed. Because the inhalation DMEL must not be exceeded and the acute tests did not reveal any effects, the long term exposure scenarios are expected to also cover short term exposure. Hence, no additional assessment of acute exposure was performed. Short description of all exposure scenarios Table 1. Short description of all exposure scenarios with their use descriptors and life cycle stage Life cycle stage covered by ES Number (ES) Short description of exposure scenario Product Category (PC) Manufacture Formulation End use Industrial Professional Consumer Service Life Sector of use (SU) Process category (PROC) Article Category (AC) Environmental release category (ERC) 2 Formulation of pigment products 3 Calendering 4 5 Treatment of articles by dipping and pouring Pelletization, masterbatching 6 Spraying of pigment containing products 7 8 Roller Application, brushing, including hand mixing Powder Coating NA X X X NA X X X NA X X 32 X X X 9a X X 9a X X NA X X 3, 22 3, 22 3, 22 3, 22 3, 22 5, 8a/ b, 9 NA 2 6 NA 5 13 NA 8b, 9, 14 7, 11 3, 22 10, 19 3, 22 5, 7, 9, 5, 8c NA 3 NA NA NA 5, 8c 5, 8c, 8f 5, 8c 1/59

12 Life cycle stage covered by ES Number (ES) Short description of exposure scenario Product Category (PC) Manufacture Formulation Industrial End use Professional Consumer Service Life Sector of use (SU) Process category (PROC) Article Category (AC) Environmental release category (ERC) 11, 14, 24 9 Pigment in articles NA X X 3, 22 NA 1, 2, 4, 10, 11, 13 10a, 11a 1.1. Formulation of Pigment Products Exposure Scenario (ES2) Environmental assessment in Scenario 2 are based on ERC 2 Refinements used were: Measured release to air, sewage and soil: The spercs No. 3, 6, 7 and 10 from CEPE have been considered for the formulation of paints. The sperc with the worst case release factors and emission days have been taken for the calculation. Number of the ES 2 Title of exposure scenario Production of pigment formulations Name of contributing environmental scenario (1) and corresponding ERC Formulation of preparations, ERC 2 Name(s) of contributing worker scenarios and corresponding PROCs Industrial filling (PROCs 8 b, 9); Production of pigment formulations (PROC 5); Packaging (PROCs 8 a/b, 9) Contributing exposure scenario (1) controlling environmental exposure Annual site tonnage Maximum amount used daily at a site 1000 (tonnes/year) 4445 (kg/day) Frequency and duration of use Continuous release. Environment factors and operational conditions Emission days Local freshwater dilution factor 225 (days/year) 10 (default) 2/59

13 Local marine water dilution factor Indoor use. 100 (default) Release fraction to air from process Release fraction to wastewater from process Release fraction to soil from process 0 Technical conditions and measures Type of STP Assumed sewage treatment plant flow Assumed flow of receiving water (m3/d) Local 2000 (m3/d) (m3/d) Contributing exposure scenario (1) controlling worker exposure for PROC 8 b and 9 Name of contributing exposure Industrial filling scenario Product characteristic Physical state of the product Powder Concentration of substance in product 100 % Dustiness High Frequency and duration of use/exposure Duration of exposure < 2.5 Hours/day Frequency of exposure < 240 Days /year Human factors not influenced by risk management Other given operational conditions affecting workers exposure Locality Inside Room volume 350 m 3 Technical conditions and measures at process level (source) to prevent release Wet cleaning of the workplace. Technical conditions and measures to control dispersion from source towards the worker Local exhaust ventilation Yes Effectiveness: 90% Organisational measures to prevent /limit releases, dispersion and exposure Conditions and measures related to personal protection, hygiene and health evaluation Wearing of goggles Yes Wearing of laboratory coat Yes Respiratory protection required Yes Effectiveness: 90% Guidance to DU to evaluate whether he works inside the boundaries set by the ES Not applicable. Contributing exposure scenario (2) controlling worker exposure for PROC 5 Name of contributing exposure scenario Production of pigment formulations Product characteristic Physical state of the product Powder Concentration of substance in product 100 % Dustiness High 3/59

14 Not applicable Frequency and duration of use/exposure Duration of exposure < 3 Hours/day Frequency of exposure < 240 Days /year Human factors not influenced by risk management Other given operational conditions affecting workers exposure Locality Inside Room volume > 1000 m 3 Separation Segregation Segregation Substance not in breathing zone No segregation to work environment No personal enclosure Technical conditions and measures at process level (source) to prevent release Open process Wet cleaning of the workplace. Technical conditions and measures to control dispersion from source towards the worker Local exhaust ventilation Yes Effectiveness: 90% Organisational measures to prevent /limit releases, dispersion and exposure Conditions and measures related to personal protection, hygiene and health evaluation Wearing of goggles Wearing of protective clothing Yes Yes Respiratory protection required Yes Effectiveness: 90% 3. Guidance to DU to evaluate whether he works inside the boundaries set by the ES Not applicable Contributing exposure scenario (3) controlling worker exposure for PROC 8 a/b and 9 Name of contributing exposure Industrial packaging of pigment formulations in dedicated and scenario non-dedicated filling lines. Product characteristic Physical state of the product Suspension Concentration of substance in product 100 % Dustiness Non-dusty Frequency and duration of use/exposure Duration of exposure > 4 Hours/day Frequency of exposure < 240 Days /year Human factors not influenced by risk management Other given operational conditions affecting workers exposure Locality Inside Room volume Not applicable 4/59

15 Technical conditions and measures at process level (source) to prevent release Wet cleaning of the workplace. Technical conditions and measures to control dispersion from source towards the worker Local exhaust ventilation No Organisational measures to prevent /limit releases, dispersion and exposure Conditions and measures related to personal protection, hygiene and health evaluation Wearing of goggles Yes Wearing of laboratory coat Yes Respiratory protection required Guidance to DU to evaluate whether he works inside the boundaries set by the ES Not applicable. No Exposure Estimation (ES2) Table 2. Estimated exposure for the environment, scenario 2 ERC 2 Compartment PEC / TDI Unit Remark STP mg L-1 Freshwater mg L-1 Freshwater sediment mg kgwwt-1 Soil mg kgwwt-1 Marine water mg L-1 Marine water sediment mg kgwwt-1 Total daily intake man via the environment E-06 mg.kgdw-1.d-1 Compartment PEC Unit Remark Air (annual average) E-05 mgc.m-3 Table 3. Estimated exposure for workers / contributing scenario for PROC 8b and 9 Calculation tool used: workplace measurements Route of exposure dose / conc Unit Justification Long-term exposure, systemic, inhalative mg/m Exposure including PPE. Work place measurements with Gravikon VC 25 Table 4. Estimated exposure for workers / contributing scenario for PROC 5 Calculation tool used: work place measurements Route of exposure dose / conc Unit Justification 5/59

16 Long-term exposure, systemic, inhalative mg/m Exposure including PPE. Work place measurements with Gravikon VC 25 Table 5. Estimated exposure for workers / contributing scenario for PROC 8 a/b and 9 Calculation tool used: qualitative assessment Route of exposure dose / conc Unit Justification Long-term exposure, systemic, inhalative << mg/m 3 Exposure to the pigment is expected to be negligible because aerosol formation is not expected and the solid pigment will not evaporate. Therefore, the risk characterization ratio is expected to be below 1 under the conditions of this scenario Calendering Exposure Scenario (ES3) Environmental assessment in Scenario 3 based on ERCs 5. Refinements used were: Measured release to air, sewage and soil: Release factors and emission days for ERC 5 have been used according to the OECD Emission Scenario Document on Plastic Additives (No. 3), chapter 11 Colorants Pigments, Conversion. Number of the ES 3 Title of exposure scenario Calendering Name of contributing environmental Industrial use resulting in inclusion into or onto a matrix, ERC 5 scenario (1) and corresponding ERC Name(s) of contributing worker scenarios and corresponding PROCs Calendering (PROC 6) Contributing exposure scenario (1) controlling environmental exposure Annual site tonnage Maximum amount used daily at a site 1000 (tonnes/year) 4445 (kg/day) Frequency and duration of use Continuous release. Environment factors and operational conditions Emission days Local freshwater dilution factor Local marine water dilution factor 225 (days /year) 10 (default) 100 (default) Indoor use. Measured release to air (kg/d) 0 Measured release to sewage (kg/d) Measured release to soil (kg/d) 0 Technical conditions and measures 6/59

17 Type of STP Assumed sewage treatment plant flow onsite 2000 (m3/d) Assumed flow of receiving water (m3/d) Contributing exposure scenario (1) controlling worker exposure for PROC 6 Name of contributing exposure Calendering scenario Product characteristic (m3/d) Physical state of the product Concentration of substance in product Dustiness Solid 20 % Low Frequency and duration of use/exposure Duration of exposure > 4 Hours/day Frequency of exposure < 240 Days /year Human factors not influenced by risk management Other given operational conditions affecting workers exposure Locality Room volume Inside N/A Technical conditions and measures at process level (source) to prevent release None. Technical conditions and measures to control dispersion from source towards the worker Local exhaust ventilation Yes Effectiveness: 90% Organisational measures to prevent /limit releases, dispersion and exposure Conditions and measures related to personal protection, hygiene and health evaluation Wearing of goggles Wearing of laboratory coat Respiratory protection required Yes Yes No 3. Guidance to DU to evaluate whether he works inside the boundaries set by the ES Not applicable Exposure Estimation (ES3) Table 6. Estimated exposure for the environment, scenario 3 ERC 5 Compartment PEC / TDI Unit Remark STP mg L-1 7/59

18 Freshwater mg L-1 Freshwater sediment mg kgwwt-1 Soil mg kgwwt-1 Marine water mg L-1 Marine water sediment mg kgwwt-1 Total daily intake man via the environment E-06 mg.kgdw-1.d-1 Compartment PEC Unit Remark Air (annual average) E-05 mgc.m-3 Table 7. Estimated exposure for workers / contributing scenario for PROC 6 Calculation tool used: ECETOC TRA Route of exposure dose / conc Unit Justification Long-term exposure, systemic, inhalative mg/m Treatment of Articles by Dipping and Pouring Exposure Scenario (ES4) Environmental assessment in Scenario 4 based on ERCs 5 and 8c. Refinements used were: Measured release to air, sewage and soil: For estimating the industrial and professional use of the substance in coating applications, different scenarios were calculated. These were - considering the industrial use (ERC 5) - spercs 12, 14, 17a/b, 18 from CEPE ansd sperc 1 from ACEA. As a specific tonnage allocation is not possible, the tonnage estimated for use in paints has been divided equally by the number of spercs (5). For the professional use scenario (ERC 8c) no differentiation has been performed and thus and the full production tonnage has been used. For ERC 8c and ERC 8f, the default parameters have been used for the calculation. For all use scenarios all calculations will be reported Number of the ES 4 Title of exposure scenario Treatment of articles by dipping and pouring Name of contributing environmental scenario (1,2) and corresponding ERC Name(s) of contributing worker scenarios and corresponding PROCs Industrial use resulting in inclusion into or onto a matrix, ERC 5 Wide dispersive indoor use resulting in inclusion into or onto a matrix, ERC 8c Treatment of articles by dipping and pouring (PROC 13) Contributing exposure scenario (1) controlling environmental exposure (CEPE 12) Annual site tonnage 200 (tonnes/year) 8/59

19 Maximum amount used daily at a site 548 (kg/day) Frequency and duration of use Continuous release. Environment factors and operational conditions Emission days 365 (days/year) Local freshwater dilution factor 10 (default) Local marine water dilution factor 100 (default) Indoor use. Release fraction to air from process 0 Release fraction to wastewater from process 0.01 Release fraction to soil from process 0 Technical conditions and measures Type of STP Local Assumed sewage treatment plant flow 2000 (m3/d) Assumed flow of receiving water (m3/d) (m3/d) Contributing exposure scenario (1) controlling environmental exposure (CEPE 14) Annual site tonnage 200 (tonnes/year) Maximum amount used daily at a site 548 (kg/day) Frequency and duration of use Continuous release. Environment factors and operational conditions Emission days 365 (days/year) Local freshwater dilution factor 10 (default) Local marine water dilution factor 100 (default) Indoor use. Release fraction to air from process 0 Release fraction to wastewater from process 0.01 Release fraction to soil from process Technical conditions and measures Type of STP Local Assumed sewage treatment plant flow 2000 (m3/d) Assumed flow of receiving water (m3/d) (m3/d) Contributing exposure scenario (1) controlling environmental exposure (CEPE 17a) Annual site tonnage 200 (tonnes/year) Maximum amount used daily at a site 909 (kg/day) Frequency and duration of use Continuous release. Environment factors and operational conditions 9/59

20 Emission days 220 (days/year) Local freshwater dilution factor 10 (default) Local marine water dilution factor 100 (default) Indoor use. Release fraction to air from process Release fraction to wastewater from process 0 Release fraction to soil from process 0 Technical conditions and measures Type of STP Local Assumed sewage treatment plant flow 2000 (m3/d) Assumed flow of receiving water (m3/d) (m3/d) Contributing exposure scenario (1) controlling environmental exposure (CEPE 18) Annual site tonnage 200 (tonnes/year) Maximum amount used daily at a site 889 (kg/day) Frequency and duration of use Continuous release. Environment factors and operational conditions Emission days 225 (days/year) Local freshwater dilution factor 10 (default) Local marine water dilution factor 100 (default) Indoor use. Release fraction to air from process Release fraction to wastewater from process Release fraction to soil from process 0 Technical conditions and measures Type of STP Local Assumed sewage treatment plant flow 2000 (m3/d) Assumed flow of receiving water (m3/d) (m3/d) Contributing exposure scenario (1) controlling environmental exposure (ACEA 1) Annual site tonnage 200 (tonnes/year) Maximum amount used daily at a site 548 (kg/day) Frequency and duration of use Continuous release. Environment factors and operational conditions Emission days 365 (days/year) Local freshwater dilution factor 10 (default) Local marine water dilution factor 100 (default) Indoor use. 10/59

21 Release fraction to air from process Release fraction to wastewater from process 0 Release fraction to soil from process Technical conditions and measures Type of STP Assumed sewage treatment plant flow Assumed flow of receiving water (m3/d) Local 2000 (m3/d) (m3/d) Contributing exposure scenario controlling environmental exposure (ERC 8c) Annual site tonnage Average daily use over a year for wide dispersive use 2000 (tonnes/year) 5480 (kg/day) Frequency and duration of use Continuous release. Environment factors and operational conditions Emission days Local freshwater dilution factor Local marine water dilution factor 365 (days/year) 10 (default) 100 (default) Indoor use. Release fraction to air from process Release fraction to wastewater from process Release fraction to soil from process 0.15 (default) 0.01(default) 0 (default) Technical conditions and measures Type of STP Assumed sewage treatment plant flow municipal / onsite 2000 (m3/d) Assumed flow of receiving water (m3/d) (m3/d) Contributing exposure scenario (1) controlling worker exposure for PROC 13 Name of contributing exposure Treatment of articles by dipping and pouring scenario Product characteristic Physical state of the product Concentration of substance in product Dustiness Solvent suspension 50 % Non-dusty Frequency and duration of use/exposure Duration of exposure > 4 Hours/day Frequency of exposure < 240 Days /year Human factors not influenced by risk management Other given operational conditions affecting workers exposure 11/59

22 Locality Inside Room volume Not applicable Separation Worker is within one meter of source Technical conditions and measures at process level (source) to prevent release None. Technical conditions and measures to control dispersion from source towards the worker Local exhaust ventilation No Organisational measures to prevent /limit releases, dispersion and exposure Conditions and measures related to personal protection, hygiene and health evaluation Wearing of goggles No Wearing of protective clothing Yes Respiratory protection required No Guidance to DU to evaluate whether he works inside the boundaries set by the ES Not applicable Exposure Estimation (ES4) Table 8. Estimated exposure for the environment, scenario 4,6,7,8 ERC 5 (CEPE 12) Compartment PEC / TDI Unit Remark STP E-05 mg L-1 Freshwater mg L-1 Freshwater sediment mg kgwwt-1 Soil mg kgwwt-1 Marine water E-05 mg L-1 Marine water sediment mg kgwwt-1 Total daily intake man via the environment E-06 mg.kgdw-1.d-1 Compartment PEC Unit Remark Air (annual average) E-05 mgc.m-3 Table 9. Estimated exposure for the environment, scenario 4,6,7,8 ERC 5 (CEPE 14) Compartment PEC / TDI Unit Remark STP E-05 mg L-1 12/59

23 Freshwater mg L-1 Freshwater sediment mg kgwwt-1 Soil mg kgwwt-1 Marine water E-05 mg L-1 Marine water sediment mg kgwwt-1 Total daily intake man via the environment E-06 mg.kgdw-1.d-1 Compartment PEC Unit Remark Air (annual average) E-05 mgc.m-3 Table 10. Estimated exposure for the environment, scenario 4,6,7,8 ERC 5 (CEPE 17a) Compartment PEC / TDI Unit Remark STP 0 mg L-1 Freshwater mg L-1 Freshwater sediment mg kgwwt-1 Soil mg kgwwt-1 Marine water E-05 mg L-1 Marine water sediment mg kgwwt-1 Total daily intake man via the environment E-06 mg.kgdw-1.d-1 Compartment PEC Unit Remark Air (annual average) E-05 mgc.m-3 Table 11. Estimated exposure for the environment, scenario 4,6,7,8 ERC 5 (CEPE 18) Compartment PEC / TDI Unit Remark STP 0 mg L-1 Freshwater mg L-1 Freshwater sediment mg kgwwt-1 Soil mg kgwwt-1 Marine water E-05 mg L-1 Marine water sediment mg kgwwt-1 Total daily intake man E-06 mg.kgdw-1.d-1 13/59

24 via the environment Compartment PEC Unit Remark Air (annual average) E-05 mgc.m-3 Table 12. Estimated exposure for the environment, scenario 4,6,7,8 ERC 5 (ACEA 1) Compartment PEC / TDI Unit Remark STP 0 mg L-1 Freshwater mg L-1 Freshwater sediment mg kgwwt-1 Soil mg kgwwt-1 Marine water E-05 mg L-1 Marine water sediment mg kgwwt-1 Total daily intake man via the environment E-06 mg.kgdw-1.d-1 Compartment PEC Unit Remark Air (annual average) E-05 mgc.m-3 Table 13. Estimated exposure for the environment, scenario 4,6,7,8 ERC 8c Compartment PEC / TDI Unit Remark STP mg L-1 Freshwater mg L-1 Freshwater sediment mg kgwwt-1 Soil mg kgwwt-1 Marine water E-05 mg L-1 Marine water sediment mg kgwwt-1 Total daily intake man via the environment E-06 mg.kgdw-1.d-1 Compartment PEC Unit Remark Air (annual average) E-05 mgc.m-3 14/59

25 Table 14. Estimated exposure for workers / contributing scenario for PROC 13 Calculation tool used: Advanced REACh Tool Route of exposure dose / conc Unit Justification Long-term exposure, systemic, inhalative << mg/m 3 Exposure to the pigment is expected to be negligible because aerosol formation is not expected and the solid pigment will not evaporate. Therefore, the risk characterization ratio is expected to be below 1 under the conditions of this scenario Pelletization, Masterbatching Exposure Scenario (ES5) Number of the ES 5 Title of exposure scenario Pelletization, Masterbatching Name of contributing environmental scenario (1) and corresponding ERC Name(s) of contributing worker scenarios and corresponding PROCs Formulation in articles, ERC 3 Contributing exposure scenario (1) controlling environmental exposure Annual site tonnage Maximum amount used daily at a site Frequency and duration of use Continuous release. Environment factors and operational conditions Emission days Local freshwater dilution factor Local marine water dilution factor Indoor use. Release fraction to air from process Release fraction to wastewater from process Release fraction to soil from process Technical conditions and measures Type of STP Assumed sewage treatment plant flow Assumed flow of receiving water (m3/d) Pelletization, Masterbatching (PROC 14), Industrial packaging of pigments in dedicated filling lines (PROC 8b, 9) 1000 (tonnes/year) (kg/day) 100 (days/year) 10 (default) 100 (default) 0.3 (default) 0.02 (default) 0.1(default) Local 2000 (m3/d) (m3/d) Contributing exposure scenario (1) controlling worker exposure for PROC 8b and 9 Name of contributing exposure Industrial packaging of pigments in dedicated filling lines. scenario Product characteristic 15/59

26 Physical state of the product Concentration of substance in product Dustiness Powder 100 % High Frequency and duration of use/exposure Duration of exposure < 2.5 Hours/day Frequency of exposure < 240 Days /year Human factors not influenced by risk management Other given operational conditions affecting workers exposure Locality Inside Room volume 350 m 3 Technical conditions and measures at process level (source) to prevent release Wet cleaning of the workplace. Technical conditions and measures to control dispersion from source towards the worker Local exhaust ventilation Yes Effectiveness: 90% Organisational measures to prevent /limit releases, dispersion and exposure Conditions and measures related to personal protection, hygiene and health evaluation Wearing of goggles Yes Wearing of laboratory coat Yes Respiratory protection required Yes Effectiveness: 90% Guidance to DU to evaluate whether he works inside the boundaries set by the ES Not applicable. Contributing exposure scenario (2) controlling worker exposure for PROC 14 Name of contributing exposure Tabletting/compression/extrusion/pelletization, masterbatching scenario Product characteristic Physical state of the product Concentration of substance in product Dustiness Powder 100 % High Not applicable Frequency and duration of use/exposure Duration of exposure < 3 Hours/day Frequency of exposure < 240 Days /year Human factors not influenced by risk management Other given operational conditions affecting workers exposure Locality Inside Room volume > 1000 m 3 Separation Substance not in breathing zone 16/59

27 Segregation No segregation to work environment Segregation No personal enclosure Technical conditions and measures at process level (source) to prevent release Open process Wet cleaning of the workplace. Technical conditions and measures to control dispersion from source towards the worker Local exhaust ventilation Yes Effectiveness: 90%. Organisational measures to prevent /limit releases, dispersion and exposure Conditions and measures related to personal protection, hygiene and health evaluation Wearing of goggles Yes Wearing of protective clothing Yes Respiratory protection required Yes Effectiveness: 90% Guidance to DU to evaluate whether he works inside the boundaries set by the ES Not applicable Exposure Estimation (ES5) Table 15. Estimated exposure for the environment, scenario 5 ERC 3 Compartment PEC / TDI Unit Remark STP mg L-1 Freshwater mg L-1 Freshwater sediment mg kgwwt-1 Soil mg kgwwt-1 Marine water mg L-1 Marine water sediment mg kgwwt-1 Total daily intake man via the environment E-06 mg.kgdw-1.d-1 Compartment PEC Unit Remark Air (annual average) E-05 mgc.m-3 Table 16. Estimated exposure for workers / contributing scenario for PROC 8b and 9 Calculation tool used: workplace measurements Route of exposure dose / conc Unit Justification Long-term exposure, systemic, inhalative mg/m 3 Exposure including PPE. Work place measurements with Gravikon VC 25 17/59

28 Table 17. Estimated exposure for workers / contributing scenario for PROC 14 Calculation tool used: work place measurements Route of exposure dose / conc Unit Justification Long-term exposure, systemic, inhalative mg/m Exposure including PPE. Work place measurements with Gravikon VC Spraying of Pigment Containing Products Exposure Scenario (ES6) Environmental assessment in Scenario 4 based on ERCs 5 and 8c. Refinements used were: Measured release to air, sewage and soil: For estimating the industrial and professional use of the substance in coating applications, different scenarios were calculated. These were - considering the industrial use (ERC 5) - spercs 12, 14, 17a/b, 18 from CEPE ansd sperc 1 from ACEA. As a specific tonnage allocation is not possible, the tonnage estimated for use in paints has been divided equally by the number of spercs (5). For the professional use scenario (ERC 8c) no differentiation has been performed and thus and the full production tonnage has been used. For ERC 8c and ERC 8f, the default parameters have been used for the calculation. For all use scenarios all calculations will be reported Number of the ES 6 Title of exposure scenario Spraying of pigment containing products Name of contributing environmental scenario (1,2) and corresponding ERC Name(s) of contributing worker scenarios and corresponding PROCs Industrial use resulting in inclusion into or onto a matrix, ERC 5 Wide dispersive indoor use resulting in inclusion into or onto a matrix, ERC 8c Industrial and Professional Spraying of paint containing pigments (PROC 7, 11) Contributing exposure scenario (1) controlling environmental exposure (CEPE 12) Annual site tonnage Maximum amount used daily at a site Frequency and duration of use Continuous release. Environment factors and operational conditions Emission days Local freshwater dilution factor Local marine water dilution factor Indoor use. Release fraction to air from process 0 Release fraction to wastewater from process 0.01 Release fraction to soil from process 0 Technical conditions and measures 200 (tonnes/year) 548 (kg/day) 365 (days/year) 10 (default) 100 (default) 18/59

29 Type of STP Local Assumed sewage treatment plant flow 2000 (m3/d) Assumed flow of receiving water (m3/d) (m3/d) Contributing exposure scenario (1) controlling environmental exposure (CEPE 14) Annual site tonnage 200 (tonnes/year) Maximum amount used daily at a site 548 (kg/day) Frequency and duration of use Continuous release. Environment factors and operational conditions Emission days 365 (days/year) Local freshwater dilution factor 10 (default) Local marine water dilution factor 100 (default) Indoor use. Release fraction to air from process 0 Release fraction to wastewater from process 0.01 Release fraction to soil from process Technical conditions and measures Type of STP Local Assumed sewage treatment plant flow 2000 (m3/d) Assumed flow of receiving water (m3/d) (m3/d) Contributing exposure scenario (1) controlling environmental exposure (CEPE 17a) Annual site tonnage 200 (tonnes/year) Maximum amount used daily at a site 909 (kg/day) Frequency and duration of use Continuous release. Environment factors and operational conditions Emission days 220 (days/year) Local freshwater dilution factor 10 (default) Local marine water dilution factor 100 (default) Indoor use. Release fraction to air from process Release fraction to wastewater from process 0 Release fraction to soil from process 0 Technical conditions and measures Type of STP Local Assumed sewage treatment plant flow 2000 (m3/d) Assumed flow of receiving water (m3/d) (m3/d) Contributing exposure scenario (1) controlling environmental exposure (CEPE 18) 19/59

30 Annual site tonnage 200 (tonnes/year) Maximum amount used daily at a site 889 (kg/day) Frequency and duration of use Continuous release. Environment factors and operational conditions Emission days 225 (days/year) Local freshwater dilution factor 10 (default) Local marine water dilution factor 100 (default) Indoor use. Release fraction to air from process Release fraction to wastewater from process Release fraction to soil from process 0 Technical conditions and measures Type of STP Local Assumed sewage treatment plant flow 2000 (m3/d) Assumed flow of receiving water (m3/d) (m3/d) Contributing exposure scenario (1) controlling environmental exposure (ACEA 1) Annual site tonnage 200 (tonnes/year) Maximum amount used daily at a site 548 (kg/day) Frequency and duration of use Continuous release. Environment factors and operational conditions Emission days 365 (days/year) Local freshwater dilution factor 10 (default) Local marine water dilution factor 100 (default) Indoor use. Release fraction to air from process Release fraction to wastewater from process 0 Release fraction to soil from process Technical conditions and measures Type of STP Local Assumed sewage treatment plant flow 2000 (m3/d) Assumed flow of receiving water (m3/d) (m3/d) Contributing exposure scenario controlling environmental exposure (ERC 8c) Annual site tonnage 2000 (tonnes/year) Average daily use over a year for wide dispersive use 5480 (kg/day) Frequency and duration of use 20/59

31 Continuous release. Environment factors and operational conditions Emission days Local freshwater dilution factor Local marine water dilution factor 365 (days/year) 10 (default) 100 (default) Indoor use. Release fraction to air from process Release fraction to wastewater from process Release fraction to soil from process 0.15 (default) 0.01(default) 0 (default) Technical conditions and measures Type of STP Assumed sewage treatment plant flow municipal / onsite 2000 (m3/d) Assumed flow of receiving water (m3/d) (m3/d) Contributing exposure scenario (1) controlling worker exposure for PROC 7, 11 Name of contributing exposure High pressure spray painting with substantial generation of mist/haze scenario Product characteristic Physical state of the product Concentration of substance in product Dustiness Solvent suspension 5 % Non-dusty Frequency and duration of use/exposure Duration of exposure > 4 Hours/day Frequency of exposure < 240 Days /year Human factors not influenced by risk management Other given operational conditions affecting workers exposure Locality Inside Room volume > 1000 m 3 Ventilation Equipment Immission controls Separation Spray cabin Not applicable Worker is within one meter of source Technical conditions and measures at process level (source) to prevent release None. Technical conditions and measures to control dispersion from source towards the worker Local exhaust ventilation No Organisational measures to prevent /limit releases, dispersion and exposure Conditions and measures related to personal protection, hygiene and health evaluation 21/59