Fiorio Colori SRL 8932 PIGMENT YELLOW 1

Transcription

1 SECTION Composition/information Accidental Physical Toxicological Ecological Regulatory Or information release information chemical measures... / properties >> on...//... ingredients >> /... >> / >>... / >>... / >> Sheet Page n / Pigmet re Lower LC50 Substances - N.I. Or Sax are (Inhalation inflammability Yellow adverse no - Dangerous subject contraindications, 1 - acquisto vapours) effects limit properties Stockholm use mixture: jets Industrial Convention: water Materials-7, to eliminate 1989 product Not Edition ified residues. (no significant component) CAS Make Upper LC50 - IFA GESTIS (Inhalation sure inflammability website leakage - mists limit site / powders) 100 is well aired. Evaluate mixture: Not compatibility available Not ified container (no significant to be used, component) by checking section 10. Contaminated material EC should Lower LD50 - ECHA (Oral) explosive be website disposed available limit mixture: in compliance with provisions Not set available forth Not in ified point 13. (no significant component) SECTION INDEX Upper LD50 Healthcare - Database (Dermal) explosive controls 1. SDS Identification limit models mixture: for chemicals - Ministry substance/mixture Not Health available Not ISS ified (Istituto (no Superiore significant di company/undertaking component) Sanità) - Italy 6.4. Vapour Reference pressure to available or sections SECTION 13. Disposal considerations 1.1. The Vapour Product full density wording identifier hazard (H) phrases is given in section 16 sheet Any Relative SKIN German Note Waste information CORROSION users: density regulation treatment personal / methods IRRITATION ification protection substances disposal is Not given hazardous available in sections to water 8 (VwVwS ) Solubility Self The Product information assessment name contained based in Annex present 3 sheet are based water-miscible 8932 on PIGMT our own YELLOW knowledge 1on date last version. Users must verify 3.2. Partition Does Mixtures SECTION Reuse, suitability Chemical when coefficient: meet name 7. possible. thoroughness ification n-octanol/water synonym Hling Neat product provided criteria storage residues information this should hazard according Not 8932 available PIGMT be considered to each YELLOW special specific non-hazardous use 1 product. waste. Auto-ignition Disposal -. This document must temperature be must performed be regarded through an as a authorised guarantee waste Not on any available management specific product firm, property. in compliance with national local regulations Decomposition SERIOUS Solid The Relevant Precautions use residues EYE this identified may for product DAMAGE temperature uses safe be suitable is hling / IRRITATION subject substance for disposal to our in direct or mixture an authorised control; refore, uses lfill site. users advised must, against under ir own responsibility, comply with current health Viscosity CONTAMINATED Chemical safety laws safety relevant PACKAGING regulations. assessment The producer is relieved from any liability arising from improper uses. Before Explosive Does Contaminated Provide Intended hling appointed use meet properties packaging staff ification product, with must adequate consult be criteria recovered all training for this or or on hazard disposed how sections Not Industrial to use available in chemical dye, subject this compliance material products. to regulations being in force in each country use. safety with national data sheet. waste Avoid management leakage regulations. product into SECTION environment. Oxidising No chemical properties safety 4. Do First assessment eat, aid drink measures or has smoke been during processed use. Not for available mixture substances it contains RESPIRATORY Changes Details to previous supplier OR SKIN review: SSITISATION safety data sheet SECTION The Description Conditions Or following information 14. sections for Transport first safe aid were storage, measures modified: including information SECTION any incompatibilities Does 01 Name / 02 / 03 meet / / Or 06 ification / 08 / 09 information / 10 criteria / 11 / 12 for / this 14 / hazard 15 / 16. Fiorio Colori SRL Not Keep VOC The Full address product specifically (Directive is product necessary. 2010/75/EC) dangerous in clearly Observance labelled : under current provisions containers. good Keep industrial 0Via Italia, Code 28 International Carriage Dangerous Goods by Road (ADR) by Rail containers hygiene away is recommended. from any incompatible materials, see section 10 for details. VOC GERM (RID), Toxic Substance (volatile CELL International Control Act MUTAGICITY carbon) : Maritime (TSCA). District Country Dangerous Goods Code (IMDG), Gessate International Air Transport (MI) Association (IATA) regulations. Italy Most Specific important end use(s) symptoms effects, both acute delayed Does UN number meet ification criteria for this hazard Tel SECTION LEGD: 10. Stability reactivity Fax No episodes available damage to health ascribable to product have been reported CARCINOGICITY Not - ADR: European Agreement concerning carriage Dangerous goods by Road address competent person - CAS Reactivity NUMBER: Chemical Abstract Service Number responsible for Safety Data Sheet sds@fioriocolori.com CE50: Indication any immediate medical attention special treatment needed SECTION There Does UN proper Effective are meet 8. shipping concentration no particular Exposure ification name (required to induce a 50% effect) - CE NUMBER: Identifier risks in ESIS controls/personal reaction criteria (European for with this or archive hazard substances existing protection in substances) normal conditions use Emergency telephone number REPRODUCTIVE Not - CLP: EC Regulation 1272/ DNEL: Control Chemical Derived parameters stability No TOXICITY Effect Level For urgent inquiries refer to NUE EmS: SECTION 5. Firefighting measures During The Does Transport Emergency product meet hazard Schedule risk is stable ification (es) - GHS: Globally assessment Harmonized in normal process, System conditions criteria it is ification for essential this use hazard to storage. take labeling into consideration chemicals ACGIH occupational exposure levels for inert particulate 5.1. SECTION orwise Extinguishing ified media (PNOC respirable fraction: 3 mg/m3; PNOC inhalable fraction: 10 mg/m3). For values above se limits, use a P type STOT Not - IATA DGR: 2. International Hazards Air identification Transport Association Dangerous Goods Regulation filter, - IC50: Possibility - whose Immobilization SINGLE EXPOSURE hazardous (1, 2 Concentration or 3) must reactions be 50% chosen according to outcome risk assessment SUITABLE - IMDG: Classification EXTINGUISHING EQUIPMT The The Does Packing International powders meet group Maritime substance Code or for mixture dangerous goods - IMO: extinguishing International are potentially ification equipment Maritime explosive Organization criteria should be when for this mixed hazard conventional with air. kind: carbon dioxide, foam, powder water spray. UNSUITABLE EXTINGUISHING EQUIPMT STOT Not - The INDEX product NUMBER: is ified Identifier in as Annex hazardous VI CLP pursuant to provisions set forth in EC Regulation 1272/2008 (CLP) ( subsequent - amendments LC50: Exposure Conditions - REPEATED in Lethal particular. controls Concentration to avoid supplements). EXPOSURE 50% LD50: 5.2. Comply Avoid Does Environmental Lethal dose Special environmental meet ification hazards 50% - Hazard OEL: Occupational ification with hazards safety arising Exposure dust measures build-up. indication: from Level criteria for this hazard -- usually substance applied or when mixture hling chemical substances. HAND PROTECTION ASPIRATION Not - PBT: Persistent bioaccumulative toxic as REACH Regulation HAZARDS - PEC: Incompatible HAZARD required. Predicted CAUSED environmental materials BY EXPOSURE Concentration IN THE EVT OF FIRE SKIN - PEL: Label PROTECTION brea combustion products. The product is combustible, when powder is released into air in sufficient concentrations Does Special Predicted elements meet precautions exposure in required. presence available ification for level user - PNEC: Predicted no criteria for this hazard effect a source concentration ignition, it can create explosive mixtures with air. Fires may start or get worse by leakage solid product EYE Not - Hazard REACH: pictograms: PROTECTION from EC Regulation container, 1907/ when it reaches high temperatures or through contact with sources ignition SECTION - RID: Hazardous required. Regulation 12. decomposition Ecological concerning products international information transport dangerous goods by train RESPIRATORY - Signal TLV: Advice Transport Threshold words: for firefighters in PROTECTION bulk Limit according Value -- to Annex II Marpol IBC Code Use Use - TLV a this CEILING: type product P filtering available Concentration according facemask, to good that whose should working practices. (1, be 2 exceeded or 3) Avoid during effective littering. any need, Inform time must occupational competent be defined authorities, exposure. according to should outcome product risk reach assessment waterways or GERAL (see contaminate - Hazard TWA stard STEL: statements: INFORMATION soil Short-term relevant 149). vegetation. exposure limit -- SECTION Use VIRONMTAL - TWA: jets Time-weighted water to EXPOSURE cool average containers exposure CONTROLS to limit prevent product decomposition development substances potentially hazardous for Toxicological information health. The - Precautionary VOC: Toxicity emissions Always Volatile statements: wear generated organic full Compounds-- fire by prevention manufacturing gear. processes, Collect extinguishing including those water generated to prevent by it from ventilation draining equipment, into sewer should system. be checked Dispose to ensure SECTION contaminated compliance LD50(Oral/rat) - vpvb: Very 15. with Persistent water > environmental Regulatory used mg/kg. for very extinction stards. Bioaccumulative information remains as for REACH fire Regulation according to regulations. SPECIAL - WGK: Water PROTECTIVE hazard available es EQUIPMT (German). FOR FIRE-FIGHTERS This product is subject to hazard labeling pursuant to EC Regulation 1272/2008 (CLP) subsequent amendments supplements Normal VME Safety, inalazione fire health fighting on : 10 toxicological clothing mg environmental / m3. i.e. fire effects kit (BS regulations/legislation 469), gloves (BS specific 659) for boots substance (HO specification or mixture A29 A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS 137) Metabolism, GERAL Or Persistence hazards BIBLIOGRAPHY toxicokinetics, degradability Seveso Category - Directive mechanism 2012/18/EC: action or information 1. Regulation (EU) 1907/2006 (REACH) European Parliament SECTION Accidental Physical release chemical measures properties 2. On Regulation basis (EC) available available 1272/2008 data, (CLP) product does European contain Parliament any PBT or vpvb in percentage greater than 0,1%. Restrictions 3. Regulation relating (EU) 790/2009 to product (I Atp. or CLP) contained European substances Parliament pursuant to Annex XVII to EC Regulation 1907/ SECTION Personal precautions, 3. Composition/information protective equipment on emergency ingredients procedures Regulation on (EU) on likely 2015/830 basic routes physical exposure European Parliament Regulation Bioaccumulative (EU) 286/2011 potential (II Atp. CLP) chemical European properties Parliament If Substances re are no in contraindications, Cidate List (Art. spray 59 REACH) powder with water to prevent formation dust Wear Appearance 6. Substances Regulation suitable (EU) protective available 618/2012 (III Atp. CLP) European Parliament On 7. Regulation basis (EU) available 487/2013 equipment data, (IV Atp. product (including CLP) does personal European contain powder protective Parliament any SVHC equipment in percentage referred to greater under than Section 0,1%. 8 safety data sheet) to prevent any Colour contamination skin, eyes personal clothing. yellow These indications apply for both processing staff those involved in emergency procedures. Odour Delayed 8. Contains: Regulation Substances subject immediate (EU) 944/2013 to authorisarion effects (V as Atp. well CLP) (Annex as chronic European XIV REACH) effects odourless from Parliament short long-term exposure 9. Regulation (EU) 605/2014 (VI Atp. CLP) European Parliament Odour threshold 6.2. ph 10. Identification Mobility Regulation Environmental in soil (EU) available 2015/1221 Conc. (VII % Atp. CLP) Classification European 1272/2008 Parliament (CLP) 11. Regulation (EU) precautions 2016/918 (VIII Atp. CLP) European 8-10 Parliament Melting point / freezing point The Initial Interactive Substances product boiling effects subject available to exportation reporting pursuant to (EC) Reg. 649/2012: - The Merck Index. must point - 10th penetrate Editioninto sewer system Not or come into contact with surface water or ground water. Boiling range 6.3. Flash - Hling Chemical Methods point available Safety Substances - INRS Results - Fiche subject PBT Toxicologique material to vpvb for Rotterdam (toxicological containment assessment Convention: sheet) cleaning up Evaporation Rate Collect Flammability ACUTE - Patty - TOXICITY Industrial Hygiene Toxicology On basis leaked available solids product data, gases place product it in containers does contain for Not recovery available any PBT or disposal. or vpvb If in percentage product is greater flammable, than 0,1%. use explosion-pro equipment. If

2 SECTION 3. Composition/information on ingredients... / >> Pigmet Yellow 1 acquisto CAS 100 EC INDEX The full wording hazard (H) phrases is given in section 16 sheet. Page n. 2 / Mixtures relevant SECTION 4. First aid measures 4.1. Description first aid measures Not specifically necessary. Observance good industrial hygiene is recommended Most important symptoms effects, both acute delayed No episodes damage to health ascribable to product have been reported Indication any immediate medical attention special treatment needed SECTION 5. Firefighting measures 5.1. Extinguishing media SUITABLE EXTINGUISHING EQUIPMT The extinguishing equipment should be conventional kind: carbon dioxide, foam, powder water spray. UNSUITABLE EXTINGUISHING EQUIPMT in particular Special hazards arising from substance or mixture HAZARDS CAUSED BY EXPOSURE IN THE EVT OF FIRE Do brea combustion products. The product is combustible, when powder is released into air in sufficient concentrations in presence a source ignition, it can create explosive mixtures with air. Fires may start or get worse by leakage solid product from container, when it reaches high temperatures or through contact with sources ignition Advice for firefighters GERAL INFORMATION Use jets water to cool containers to prevent product decomposition development substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into sewer system. Dispose contaminated water used for extinction remains fire according to regulations. SPECIAL PROTECTIVE EQUIPMT FOR FIRE-FIGHTERS Normal fire fighting clothing i.e. fire kit (BS 469), gloves (BS 659) boots (HO specification A29 A30) in combination with self-contained open circuit positive pressure compressed air breathing apparatus (BS 137). SECTION 6. Accidental release measures 6.1. Personal precautions, protective equipment emergency procedures If re are no contraindications, spray powder with water to prevent formation dust. Wear suitable protective equipment (including personal protective equipment referred to under Section 8 safety data sheet) to prevent any contamination skin, eyes personal clothing. These indications apply for both processing staff those involved in emergency procedures Environmental precautions The product must penetrate into sewer system or come into contact with surface water or ground water Methods material for containment cleaning up Collect leaked product place it in containers for recovery or disposal. If product is flammable, use explosion-pro equipment. If

3 SECTION 6. Accidental release measures... / >> Page n. 3 / 8 re are no contraindications, use jets water to eliminate product residues. Make sure leakage site is well aired. Evaluate compatibility container to be used, by checking section 10. Contaminated material should be disposed in compliance with provisions set forth in point Reference to or sections Any information on personal protection disposal is given in sections SECTION 7. Hling storage 7.1. Precautions for safe hling Before hling product, consult all or sections this material safety data sheet. Avoid leakage product into environment. Do eat, drink or smoke during use Conditions for safe storage, including any incompatibilities Keep product in clearly labelled containers. Keep containers away from any incompatible materials, see section 10 for details Specific end use(s) SECTION 8. Exposure controls/personal protection 8.1. Control parameters During risk assessment process, it is essential to take into consideration ACGIH occupational exposure levels for inert particulate orwise ified (PNOC respirable fraction: 3 mg/m3; PNOC inhalable fraction: 10 mg/m3). For values above se limits, use a P type filter, whose (1, 2 or 3) must be chosen according to outcome risk assessment Exposure controls Comply with safety measures usually applied when hling chemical substances. HAND PROTECTION required. SKIN PROTECTION required. EYE PROTECTION required. RESPIRATORY PROTECTION Use a type P filtering facemask, whose (1, 2 or 3) effective need, must be defined according to outcome risk assessment (see stard 149). VIRONMTAL EXPOSURE CONTROLS The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental stards. VME inalazione : 10 mg / m3. SECTION 9. Physical chemical properties 9.1. on basic physical chemical properties Appearance powder Colour yellow Odour odourless Odour threshold ph 8-10 Melting point / freezing point Initial boiling point Boiling range Flash point Evaporation Rate Flammability solids gases

4 SECTION 9. Physical chemical properties... / >> Lower inflammability limit Upper inflammability limit Lower explosive limit Upper explosive limit Vapour pressure Vapour density Relative density Solubility Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidising properties 9.2. Or information VOC (Directive 2010/75/EC) : 0 VOC (volatile carbon) : 0 water-miscible Page n. 4 / 8 SECTION 10. Stability reactivity Reactivity There are no particular risks reaction with or substances in normal conditions use Chemical stability The product is stable in normal conditions use storage Possibility hazardous reactions The powders are potentially explosive when mixed with air Conditions to avoid Avoid environmental dust build-up Incompatible materials Hazardous decomposition products SECTION 11. Toxicological information LD50(Oral/rat) > mg/kg on toxicological effects Metabolism, toxicokinetics, mechanism action or information on likely routes exposure Delayed immediate effects as well as chronic effects from short long-term exposure Interactive effects ACUTE TOXICITY

5 SECTION 11. Toxicological information... / >> LC50 (Inhalation - vapours) mixture: LC50 (Inhalation - mists / powders) mixture: LD50 (Oral) mixture: LD50 (Dermal) mixture: Not ified (no significant component) Not ified (no significant component) Not ified (no significant component) Not ified (no significant component) Page n. 5 / 8 SKIN CORROSION / IRRITATION SERIOUS EYE DAMAGE / IRRITATION RESPIRATORY OR SKIN SSITISATION GERM CELL MUTAGICITY CARCINOGICITY REPRODUCTIVE TOXICITY STOT - SINGLE EXPOSURE STOT - REPEATED EXPOSURE ASPIRATION HAZARD SECTION 12. Ecological information Use this product according to good working practices. Avoid littering. Inform competent authorities, should product reach waterways or contaminate soil or vegetation Toxicity Persistence degradability Bioaccumulative potential Mobility in soil Results PBT vpvb assessment On basis available data, product does contain any PBT or vpvb in percentage greater than 0,1%.

6 SECTION 12. Ecological information... / >> Or adverse effects Page n. 6 / 8 SECTION 13. Disposal considerations Waste treatment methods Reuse, when possible. Neat product residues should be considered special non-hazardous waste. Disposal must be performed through an authorised waste management firm, in compliance with national local regulations. Solid residues may be suitable for disposal in an authorised lfill site. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed in compliance with national waste management regulations. SECTION 14. Transport information The product is dangerous under current provisions Code International Carriage Dangerous Goods by Road (ADR) by Rail (RID), International Maritime Dangerous Goods Code (IMDG), International Air Transport Association (IATA) regulations UN number UN proper shipping name Transport hazard (es) Packing group Environmental hazards Special precautions for user Transport in bulk according to Annex II Marpol IBC Code relevant SECTION 15. Regulatory information Safety, health environmental regulations/legislation specific for substance or mixture Seveso Category - Directive 2012/18/EC: Restrictions relating to product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006 Substances in Cidate List (Art. 59 REACH) On basis available data, product does contain any SVHC in percentage greater than 0,1%. Substances subject to authorisarion (Annex XIV REACH) Substances subject to exportation reporting pursuant to (EC) Reg. 649/2012: Substances subject to Rotterdam Convention:

7 SECTION 15. Regulatory information... / >> Substances subject to Stockholm Convention: Healthcare controls German regulation on ification substances hazardous to water (VwVwS 2005) Self assessment based on Annex Chemical safety assessment No chemical safety assessment has been processed for mixture substances it contains. Page n. 7 / 8 SECTION 16. Or information Toxic Substance Control Act (TSCA). LEGD: - ADR: European Agreement concerning carriage Dangerous goods by Road - CAS NUMBER: Chemical Abstract Service Number - CE50: Effective concentration (required to induce a 50% effect) - CE NUMBER: Identifier in ESIS (European archive existing substances) - CLP: EC Regulation 1272/ DNEL: Derived No Effect Level - EmS: Emergency Schedule - GHS: Globally Harmonized System ification labeling chemicals - IATA DGR: International Air Transport Association Dangerous Goods Regulation - IC50: Immobilization Concentration 50% - IMDG: International Maritime Code for dangerous goods - IMO: International Maritime Organization - INDEX NUMBER: Identifier in Annex VI CLP - LC50: Lethal Concentration 50% - LD50: Lethal dose 50% - OEL: Occupational Exposure Level - PBT: Persistent bioaccumulative toxic as REACH Regulation - PEC: Predicted environmental Concentration - PEL: Predicted exposure level - PNEC: Predicted no effect concentration - REACH: EC Regulation 1907/ RID: Regulation concerning international transport dangerous goods by train - TLV: Threshold Limit Value - TLV CEILING: Concentration that should be exceeded during any time occupational exposure. - TWA STEL: Short-term exposure limit - TWA: Time-weighted average exposure limit - VOC: Volatile organic Compounds - vpvb: Very Persistent very Bioaccumulative as for REACH Regulation - WGK: Water hazard es (German). GERAL BIBLIOGRAPHY 1. Regulation (EU) 1907/2006 (REACH) European Parliament 2. Regulation (EC) 1272/2008 (CLP) European Parliament 3. Regulation (EU) 790/2009 (I Atp. CLP) European Parliament 4. Regulation (EU) 2015/830 European Parliament 5. Regulation (EU) 286/2011 (II Atp. CLP) European Parliament 6. Regulation (EU) 618/2012 (III Atp. CLP) European Parliament 7. Regulation (EU) 487/2013 (IV Atp. CLP) European Parliament 8. Regulation (EU) 944/2013 (V Atp. CLP) European Parliament 9. Regulation (EU) 605/2014 (VI Atp. CLP) European Parliament 10. Regulation (EU) 2015/1221 (VII Atp. CLP) European Parliament 11. Regulation (EU) 2016/918 (VIII Atp. CLP) European Parliament - The Merck Index. - 10th Edition - Hling Chemical Safety - INRS - Fiche Toxicologique (toxicological sheet) - Patty - Industrial Hygiene Toxicology

8 SECTION 16. Or information... / >> - N.I. Sax - Dangerous properties Industrial Materials-7, 1989 Edition - IFA GESTIS website - ECHA website - Database SDS models for chemicals - Ministry Health ISS (Istituto Superiore di Sanità) - Italy Page n. 8 / 8 Note for users: The information contained in present sheet are based on our own knowledge on date last version. Users must verify suitability thoroughness provided information according to each specific use product. This document must be regarded as a guarantee on any specific product property. The use this product is subject to our direct control; refore, users must, under ir own responsibility, comply with current health safety laws regulations. The producer is relieved from any liability arising from improper uses. Provide appointed staff with adequate training on how to use chemical products. Changes to previous review: The following sections were modified: 01 / 02 / 03 / 05 / 06 / 08 / 09 / 10 / 11 / 12 / 14 / 15 / 16.