SAFETY DATA SHEET. Restrictions on use : Reserved for industrial and professional use.

Transcription

1 Section: 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable. Recommended use : Sanitizer Restrictions on use : Reserved for industrial and professional use. Product dilution information : No dilution information provided. Company : Ecolab Co Tomken Road Mississauga, Ontario Canada L4W 2X Emergency health information : (US/Canada), (outside US) Issuing date : 05/24/2017 Section: 2. HAZARDS IDENTIFICATION GHS Classification Eye irritation : Category 2B GHS Label element Hazard pictograms : Signal Word Hazard Statements Precautionary Statements Other hazards : Caution : Causes eye irritation. : Prevention: Wash skin thoroughly after handling. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. : None known. Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration: (%) Urea Benzalkonium chloride Octyl decyl dimethyl ammonium chloride Didecyl Dimethyl Ammonium Chloride Dioctyl dimethyl ammonium chloride / 8

2 Section: 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed If inhaled Protection of first-aiders Notes to physician Most important symptoms and effects, both acute and delayed : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. : Remove to fresh air. Treat symptomatically. Get medical attention immediately. : If potential for exposure exists refer to Section 8 for specific personal protective equipment. : Treat symptomatically. : See Section 11 for more detailed information on health effects and symptoms. Section: 5. FIREFIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during firefighting Hazardous combustion products Special protective equipment for firefighters Specific extinguishing methods Risk of explosion. : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : None known. : Not flammable or combustible. : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus : Use personal protective equipment. : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. : Not available. Section: 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for : Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Sweep up and shovel into suitable containers for disposal / 8

3 containment and cleaning up Section: 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage : Do not breathe dust/fume/gas/mist/vapours/spray. Use only with adequate ventilation. Wash hands thoroughly after handling. : Keep out of reach of children. Store in suitable labeled containers. Storage temperature : -20 C to 40 C Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures : No special protective equipment required. : No special protective equipment required. : No special protective equipment required. : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Section: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour Odour : powder : opaque, blue : ammoniacal ph : , (1 %) Flash point Odour Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure : Not applicable., Does not sustain combustion / 8

4 Relative vapour density Relative density Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Auto-ignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC : soluble Section: 10. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : No dangerous reaction known under conditions of normal use. : None known. : Bases Acids Metals : Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus Section: 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes Skin Ingestion Inhalation Chronic Exposure : Causes eye irritation. : Health injuries are not known or expected under normal use. : Health injuries are not known or expected under normal use. : Health injuries are not known or expected under normal use. : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact : Redness, Irritation / 8

5 Skin contact Ingestion Inhalation : No symptoms known or expected. : No symptoms known or expected. : No information available. Toxicity Product Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration toxicity Components Acute oral toxicity : Urea LD50 rat: 8,471 mg/kg Benzalkonium chloride LD50 rat: 344 mg/kg Octyl decyl dimethyl ammonium chloride LD50 rat: 238 mg/kg Didecyl Dimethyl Ammonium Chloride LD50 rat: 1,150 mg/kg Dioctyl dimethyl ammonium chloride LD50 rat: 238 mg/kg Components Acute inhalation toxicity : Urea 4 h LC50 rat: 2.71 mg/l Benzalkonium chloride 4 h LC50 rat: mg/l Octyl decyl dimethyl ammonium chloride 4 h LC50 rat: 0.07 mg/l / 8

6 Didecyl Dimethyl Ammonium Chloride 4 h LC50 rat: 0.07 mg/l Dioctyl dimethyl ammonium chloride 4 h LC50 rat: 0.07 mg/l Components Acute dermal toxicity : Urea LD50 rat: 8,200 mg/kg Benzalkonium chloride LD50 rabbit: 3,340 mg/kg Octyl decyl dimethyl ammonium chloride LD50 rabbit: 2,930 mg/kg Didecyl Dimethyl Ammonium Chloride LD50 rabbit: 2,930 mg/kg Dioctyl dimethyl ammonium chloride LD50 rabbit: 2,930 mg/kg Section: 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Components Toxicity to fish : This product has no known ecotoxicological effects. : 48 h EC50: 11.5 mg/l : Urea 96 h LC50 Fish: mg/l Octyl decyl dimethyl ammonium chloride 96 h LC50 Fish: 1 mg/l Didecyl Dimethyl Ammonium Chloride 96 h LC50 Fish: 1 mg/l Persistence and degradability Not applicable - Biocide Bioaccumulative potential no data available Mobility in soil no data available Other adverse effects no data available / 8

7 Section: 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations : Do not contaminate ponds, waterways or ditches with chemical or used container. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. Dispose of in accordance with local, state, and federal regulations. Section: 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (TDG) Not dangerous goods Sea transport (IMDG/IMO) Not dangerous goods Section: 15. REGULATORY INFORMATION This product has been classified according to the hazard criteria of the HPR and the SDS contains all of the information required by the HPR. The components of this product are reported in the following inventories: Switzerland. New notified substances and declared preparations : United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL. Australia. Industrial Chemical (Notification and Assessment) Act : New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand : Japan. ENCS - Existing and New Chemical Substances Inventory : not determined Korea. Korean Existing Chemicals Inventory (KECI) : Philippines Inventory of Chemicals and Chemical Substances (PICCS) : not determined / 8

8 Health Instability SAFETY DATA SHEET China Inventory of Existing Chemical Substances : Taiwan Chemical Substance Inventory : not determined Section: 16. OTHER INFORMATION NFPA: Flammability HMIS III: 0 HEALTH FLAMMABILITY 0 PHYSICAL HAZARD 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Issuing date : 05/24/2017 Version : 1.1 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text / 8