Material Safety Data Sheet ROHM AND HAAS KOREA CO., LTD.

Transcription

1 Material Safety Data Sheet ROHM AND HAAS KOREA CO., LTD. Product name: AMBERLITE PWA10 Ion Exchange Resin Issue Date: Print Date: ROHM AND HAAS KOREA CO., LTD. encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions. 1. PRODUCT AND COMPANY IDENTIFICATION Product name: AMBERLITE PWA10 Ion Exchange Resin Recommended use of the chemical and restrictions on use Identified uses: Ion exchange and/or Adsorption process COMPANY IDENTIFICATION ROHM AND HAAS KOREA CO., LTD. A Dow Chemical Group Company 412 TEHERAN-RO (DAECHI-DONG) GANGNAM-GU SEOUL TEUGBYEOLSI SOUTH KOREA Customer Information Number: 82-(0) SDSQuestion@dow.com EMERGENCY TELEPHONE NUMBER 24-Hour Emergency Contact: Local Emergency Contact: HAZARDS IDENTIFICATION Classification of the substance or mixture This product is not hazardous per the Globally Harmonized System of Classification and Labelling (GHS). Other hazards 3. COMPOSITION/INFORMATION ON INGREDIENTS This product is a mixture. Component Common Name CASRN Concentration KECI Number Trademark of The Dow Chemical Company ("Dow") or an affiliated company of Dow Page 1 of 8

2 Weak base anion exchange polymer Not Required >= <= 51.0 % - Water DIHYDROGEN OXIDE >= <= 56.0 % KE FIRST AID MEASURES Description of first aid measures Skin contact: Wash off with soap and water. If skin irritation persists, call a physician. Eye contact: Rinse with plenty of water. If eye irritation persists, consult a specialist. Most important symptoms and effects, both acute and delayed: Aside from the information found under Description of first aid measures (above) and Indication of immediate medical attention and special treatment needed (below), any additional important symptoms and effects are described in Section 11: Toxicology Information. Indication of any immediate medical attention and special treatment needed Notes to physician: Treatment of exposure should be directed at the control of symptoms and the clinical condition of the patient. 5. FIREFIGHTING MEASURES Suitable extinguishing media: Water spray Carbon dioxide (CO2) Foam Dry chemical Unsuitable extinguishing media: Special hazards arising from the substance or mixture Hazardous combustion products: Unusual Fire and Explosion Hazards: Toxic fumes are generated when material is exposed to fire or fire conditions. Cool closed containers exposed to fire with water spray. Advice for firefighters Fire Fighting Procedures: Remain upwind. Avoid breathing smoke. Special protective equipment for firefighters: In the event of fire, wear self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Appropriate protective equipment must be worn when handling a spill of this material. See SECTION 8, Exposure Controls/Personal Protection, for recommendations. If exposed to material during clean-up operations, see SECTION 4, First Aid Measures, for actions to follow. Environmental precautions: No special environmental precautions required. Page 2 of 8

3 Methods and materials for containment and cleaning up: Keep spectators away. Floor may be slippery; use care to avoid falling. Transfer spilled material to suitable containers for recovery or disposal. 7. HANDLING AND STORAGE Precautions for safe handling: NOTE: This product as supplied is a whole bead resin and may produce slight eye irritation. However, the ground form of this resin should be treated as a severe eye irritant. Worker exposure to ground resins can be controlled with local exhaust ventilation at the point of dust generation, or use of suitable personal protective equipment (dust/mist air-purifying respirator and safety goggles). Avoid repeated freeze-thaw cycles; beads may fracture. If frozen, thaw at room temperature. Properly designed equipment is vital if these resins are to be used in conjunction with strong oxidizing agents such as nitric acid to prevent a rapid build-up of pressure and possible explosion. Consult a source knowledgeable in the handling of these materials before proceeding. Conditions for safe storage: Keep from freezing. Other data: CAUTION: Do not pack column with dry ion exchange resins. Dry beads expand when wetted; this expansion can cause glass column to shatter. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure limits are listed below, if they exist. Exposure limits have not been established for those substances listed in the composition, if any have been disclosed. Exposure controls Engineering controls: none Protective measures: Facilities storing or utilizing this material should be equipped with an eyewash facility. Individual protection measures Eye/face protection: Use safety glasses with side shields (ANSI Z87.1or approved equivalent). Skin protection Hand protection: Cotton or canvas gloves. Respiratory protection: No personal respiratory protective equipment normally required. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical state solid Beads Color off-white Odor Amine odor Odor Threshold ph Melting point/range 0 C Water Page 3 of 8

4 Freezing point Boiling point (760 mmhg) 100 C Water Flash point Evaporation Rate (Butyl Acetate = 1) Flammability (solid, gas) Lower explosion limit Upper explosion limit Vapor Pressure Relative Vapor Density (air = 1) Relative Density (water = 1) Water solubility insoluble Partition coefficient: n- octanol/water Auto-ignition temperature > C Decomposition temperature Kinematic Viscosity Explosive properties Oxidizing properties Molecular weight Percent volatility % Water Particle size mm NOTE: The physical data presented above are typical values and should not be construed as a specification. 10. STABILITY AND REACTIVITY Reactivity: Chemical stability: Possibility of hazardous reactions: Stable under normal conditions. Product will not undergo polymerization. Conditions to avoid: Incompatible materials: Avoid contact with the following: Strong Oxidizers Nitric acid Hazardous decomposition products: Thermal decomposition may yield the following: monomer vapors 11. TOXICOLOGICAL INFORMATION Toxicological information appears in this section when such data is available. Page 4 of 8

5 Information on the likely route of exposure Please refer to the information below. Acute toxicity Acute oral toxicity LD50, Rat, > 5,000 mg/kg Acute dermal toxicity LD50, Rabbit, > 5,000 mg/kg Acute inhalation toxicity Skin corrosion/irritation Serious eye damage/eye irritation Skin and Respiratory Sensitization Specific Target Organ Systemic Toxicity (Single Exposure) Specific Target Organ Systemic Toxicity (Repeated Exposure) Carcinogenicity Teratogenicity Reproductive toxicity Mutagenicity Aspiration Hazard Additional information No data are available for this material. The information shown is based on profiles of compositionally similar materials. 12. ECOLOGICAL INFORMATION Ecotoxicological information appears in this section when such data is available. Page 5 of 8

6 General Information Limited effects are expected from exposure of the environmental compartments by insoluble plastic beads of large diameter (300 to 1200 microns). Ecotoxicity. Persistence and degradability. Bioaccumulative potential. Mobility in Soil. Results of PBT and vpvb assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vpvb) at levels of 0.1% or higher. Other adverse effects. 13. DISPOSAL CONSIDERATIONS Disposal methods: Unused material may be incinerated or landfilled in facilities meeting local, state, and federal regulations. Disposal precautions: Customers are advised to check their local legislation governing the disposal of waste materials. Contaminated packaging: Empty containers should be taken to local recyclers for disposal. Refer to applicable federal, state, and local regulations. 14. TRANSPORT INFORMATION Classification for ROAD and Rail transport: UN number Proper shipping name Not regulated for transport Class Packing group Environmental hazards Special precautions for. user Classification for SEA transport (IMO-IMDG): Page 6 of 8

7 UN number Proper shipping name Class Packing group Marine pollutant Special precautions for user Transport in bulk according to Annex I or II of MARPOL 73/78 and the IBC or IGC Code Not regulated for transport. Consult IMO regulations before transporting ocean bulk Classification for AIR transport (IATA/ICAO): UN number Proper shipping name Not regulated for transport Class Packing group Special precautions for. user This information is not intended to convey all specific regulatory or operational requirements/information relating to this product. Transportation classifications may vary by container volume and may be influenced by regional or country variations in regulations. Additional transportation system information can be obtained through an authorized sales or customer service representative. It is the responsibility of the transporting organization to follow all applicable laws, regulations and rules relating to the transportation of the material. 15. REGULATORY INFORMATION Regulation under the Occupational Safety and Health Act The product is not classified as hazardous by ISHL in Korea. Regulation under the Chemical Control Act Not regulated by Chemical Control Act Dangerous Substances Safety Management Act Not regulated by Dangerous Substance Safety Management Act Waste Management Law For all countries the disposal methods must be in compliance with national and provincial laws and any municipal or local by laws. Other requirements in domestic and other countries Korea. Korean Existing Chemicals Inventory (KECI) (KECI): A new substance notification or exemption has been submitted and approved on an intentional component of this product in compliance with the local regulations. Page 7 of 8

8 16. OTHER INFORMATION Revision Identification Number: / 1836 / Issue Date: / Version: 3.0 Most recent revision(s) are noted by the bold, double bars in left-hand margin throughout this document. Date of first issue: 06/08/2011 Information Source and References This SDS is prepared by Product Regulatory Services and Hazard Communications Groups from information supplied by internal references within our company. ROHM AND HAAS KOREA CO., LTD. urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturerspecific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version. Page 8 of 8