CONFIDOR SUPRA SAFETY DATA SHEET. Date of Issue: 23 May 2006 Date of Previsous Issue: 24 August Page 1 of 6

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1 1. Identification of the Substance/Mixture and Supplier. Product name: Other product names: Application: ERMA approval: Company: Telephone: Facsimile: Emergency telephone: Confidor Supra Confidor Supra EC 100 A systemic insecticide. Transferred under scheduled toxic substances Bayer New Zealand Limited, 3 Argus Place, Glenfield, Auckland, New Zealand Orica SH&E Shared services (24hr) 2. Hazards Identification. Hazard classification: Classification and type: Risk & Safety Phrases: Classified as not hazardous according to the criteria in the Hazardous Substances (Minimum Degrees of Hazard) Regulations HSNO Class 3.1D, 6.1E, 6.4A, 6.8A, 6.8C, 6.9B, 9.1A, 9.2B, 9.3B, 9.4A Combustible liquid - keep away from naked flame. May be harmful if swallowed, inhaled or absorbed through the skin. Harmful may cause eye irritation. Toxic may cause reproductive/development damage from repeated oral exposure. May cause harm to breast-fed children from repeated oral exposure. Harmful presumed to/may cause organ damage from repeated oral exposure at high doses. Toxic to aquatic organisms. Toxic to the soil environment. Toxic to terrestrial vertebrates. Very toxic to terrestrial invertebrates. R36, R48, R50 R57, R61, R64 3. Composition/Information on Ingredients. Chemical identity of ingredients Mixture: Ingredient CAS No. Content (%w/v) Imidacloprid Cyfluthrin N-Methyl % 2.40% 86.80% Page 1 of 6

2 4. First Aid Measures. pyrrolidone General information: Skin contact: Eye contact: Ingestion: Further information: Contaminated clothing and shoes must be removed immediately. Wash off thoroughly with plenty of water and soap, if available with polyethyleneglycol 400, subsequently rinse with water. After skin contact: Apply Vitamin E cream or simple toilet milks. In case of contact with eyes rinse thoroughly with plenty of lukewarm water for at least 15 minutes, Do not induce vomiting. Wash out mouth with water. Call a doctor immediately. Contact the National Poisons and Hazardous Chemicals Information centre in Dunedin, PO Box 913, Dunedin. Phone , 0800 POISON. 5. Fire-Fighting Measures. Suitable extinguishing media: Specific hazards during fire fighting: Water spray, carbon dioxide (CO2), foam, sand. In the event of fire the following can be released: Carbon monoxide (CO) Hydrogen chloride (HCI) Hydrogen cyanide (hydrocyanic acid) Nitrogen oxides (NOx) Recommended protective clothing: Further Information: Fire fighters must wear self contained breathing apparatus, do not breathe fumes. Contain the spread of the fire-fighting media. 6. Accidental Release Measures. Personal Precautions: Environmental Precautions: Procedure for spill: Emergency Procedures: Ensure suitable personal protection during removal of spillages. This means wearing eye protection, chemically resistant gloves, boots and overalls. Washings must be prevented from entering surface water drains or waterways. Keep all bystanders away. Wear goggles, half face-piece respirator with combined dust and vapour cartridge, full length clothing and PVC gloves. Page 2 of 6

3 Contaminated material must be disposed of in accordance with all local authority requirements. a. For quantities up to 50L of product bury in a secure approved landfill site. b. For quantities greater than 50L seek advice from the manufacturer (use emergency contact number) before attempting disposal. Contain in a secure location until disposal method is established. c. Decontaminate the spill area with detergent and water and rinse with the smallest volume of water practicable. Procedure for Disposal: a)triple rinsing or preferably pressure rinsing containers with water. Add the rinsings to the spray tank. DO NOT dispose of undiluted chemicals on site. b) Burning of empty containers if circumstances, especially wind direction, permit is an alternative method. Do not burn unless in a suitable incinerator. c) Product or unused spray mix should be disposed of according to label instructions. 7. Handling and Storage. Handling: Storage: Transfer and handle product only in a closed system. Keep container tightly closed in a cool, well ventilated place. Storage temperature 0-40 C. 8. Exposure Control/Personal Protection Exposure Standards: Engineering measures: N-methyl-2-pyrrolidone 80mg/m³ (MAK) Risk of cutaneous absorption. Use in well ventilated areas. Respiratory protection: Hand protection: Where insufficient ventilation, use suitable respiratory protection. Solvent-resistant gloves. Eye protection: Other protective equipment: Hygiene measures: Safety glasses with side-shields. Wear suitable protective clothing. Avoid inhaling aerosols and vapours. Avoid contact with eyes and skin. Store work clothes and street clothes separately. Wash Page 3 of 6

4 9. Physical and Chemical Properties hand before breaks and at the end of work. Change contaminated protective clothing. Keep away from food, drinks and tobacco. Form: Colour: Odour: Melting point:/boiling point: Density: Vapour pressure: Specific gravity: Solubility in water: ph: Flash point: Partition Coefficient: Liquid, clear brown aromatic ca.a1.07 g/cm³ at 20 C approx. 1.07g/m³ at 20 C emulsifiable at 1% 88 C Log P Octanol/water = imidacloprid: 0.57 = cyfluthrin : approx Stability and Reactivity Conditions to avoid: Materials to avoid Hazardous reactions: Extremes of temperature and direct sunlight. None No hazardous reactions when stored and handled according to prescribed instructions. Stable under recommended storage conditions. 11. Toxicological Information Acute oral toxicity: LD 50 : (rat) >2500mg/kg (Bayer) Acute Dermal Toxicity Acute Inhalation Toxicity: LD 50 (rat) >4000mg/kg (Bayer) LC 50 (rat) 4.99mg/L (4h) as aerosol highest attainable conc. Skin irritation: Non-irritant(rabbit) Eye irritation: No eye irritation (rabbit) Sensitization: Non-sensitizing (guinea pig). OECD Test Guideline 406, Buehler test Page 4 of 6

5 12. Ecological Information Acute fish toxicity: Cyfluthrin: Imidacloprid: LC50: mg/L ; rainbow trout (Oncorhynchus mykiss) (96h) LC50: 211mg/L rainbow trout (Oncorhynchus mykiss) (96h) Toxicity to Daphnia: Cyfluthrin: Imidacloprid: EC50: mg/L water flea (Daphnia magna) (48h) EC50: 85mg/L water flea (Daphnia magna) (48h) Exposure time: 96 h Toxicity to algae: Cyfluthrin: Imidacloprid: IC50 : > 10mg/L (Desmodesmus subspicatus) Growth rate Exposure time: 72h IC50: > 10mg/L (Desmodesmus subspicatus) Growth rate Exposure time: 72h 13. Disposal Considerations: Product Disposal: Container Disposal: Dispose of this product only by using according to the label, or at an approved landfill or other approved facility. Triple rinse the empty container adding rinseate to the spray tank. Recycle if possible. If allowed under local authority, burn if Circumstances, especially wind direction permit, otherwise crush and bury in an approved local authority facility. Do not use container for any other purpose. 14. Transportation Information. Page 5 of 6

6 Rail/Road (RID/ADR) Sea (IMDG-Code) Air (ICAO/IATA) Not dangerous goods. Not dangerous goods. Not dangerous goods. 15. Regulatory Information. HSNO Approval Number: HSR HSNO Controls(inc. Tracking): See for controls. Approved Handlers required: ACVM Registration: ACVM Controls: Approved Handlers required at time of use. P6024 See for registration conditions. 16. Other Information: 3.1D Combustible liquid - keep away from naked flame. 6.1E May be harmful if swallowed, inhaled or absorbed through the skin. 6.4A Harmful may cause eye irritation. 6.8A Toxic may cause reproductive/development damage from repeated oral exposure. 6.8C May cause harm to breast-fed children from repeated oral exposure. 6.9B Harmful presumed to/may cause organ damage from repeated oral exposure at high doses. 9.1A Toxic to aquatic organisms. 9.2B Toxic to the soil environment. 9.3B Toxic to terrestrial vertebrates. 9.4A Very toxic to terrestrial invertebrates. R36 Irritating to eyes. R48 Danger of serious damage to health by prolonged exposure. R50 Very toxic to aquatic organisms. R57 Toxic to bees. R61 May cause harm to the unborn child. R64 May cause harm to breast -fed babies. Registered trademark of Bayer. The data given here is based on current knowledge and experience. The purpose of this Safety Data Sheet is to describe products in terms of their safety requirements. The above details do not imply any guarantee concerning composition, properties or performance of the product. Page 6 of 6