: COMPOUND SILICONE

Transcription

1 Date of issue: 05/04/2016 Revision date: 05/04/2016 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name : Mixtures Product code : : COMPOUND SILICONE 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category : Industrial use,professional use Uses advised against 1.3. Details of the supplier of the safety data sheet ITW Spraytec 5 bis, rue Retrou F Asnières sur Seine - France T +33(0) F +33(0) infofds@itwpc.com Emergency telephone number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Hazardous to the aquatic environment Acute Hazard, Category 1 H400 Hazardous to the aquatic environment Chronic Hazard, Category 1 H410 Full text of H statements : see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) GHS09 : Warning : H410 - Very toxic to aquatic life with long lasting effects : P273 - Avoid release to the environment P391 - Collect spillage P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures 07/02/2017 EN (English) 1/7

2 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] zinc oxide (CAS No) (EC No) (EC Index No) (REACH-no) Full text of H-statements: see section Aquatic Acute 1, H400 Aquatic Chronic 1, H410 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Move the affected person away from the contaminated area and into the fresh air. : Wash skin with mild soap and water. Take off contaminated clothing and wash it before reuse. : Immediately rinse with plenty of water (for at least 15 minutes). : Do NOT induce vomiting. IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact : At high concentrations, the vapours can be irritating to the respiratory system. : Prolonged or repeated contact with the skin may cause dermatitis Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Carbon dioxide. Foam Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : Do not use a heavy water stream. Do not use a solid water stream as it may scatter and spread fire. : Release of poisonous gas Advice for firefighters Firefighting instructions Protection during firefighting : Prevent fire fighting water from entering the environment. Exercise caution when fighting any chemical fire. : Do not enter fire area without proper protective equipment, including respiratory protection. Do not breathe fumes from fires or vapours from decomposition. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures For non-emergency personnel : May be dangerously slippery if spilled. Protective equipment : Concerning personal protective equipment to use, see section For emergency responders 6.2. Environmental precautions Dike and contain spill. Stop leak without risks if possible Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections : Collect all waste in suitable and labelled containers and dispose according to local legislation. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Concerning personal protective equipment to use, see section 8. Concerning disposal elimination after cleaning, see section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : May be dangerously slippery if spilled. : Handle in accordance with good industrial hygiene and safety procedures. Avoid prolonged and repeated contact with skin. 07/02/2017 EN (English) 2/7

3 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Heat and ignition sources Information on mixed storage 7.3. Specific end use(s) No additional information. : Keep away from food, drink and animal feeding stuffs. Store in a dry, well ventilated place away from sources of heat, ignition and direct sunlight. Keep container closed when not in use. Protect from moisture. Keep only in original container. : Keep away from. Heat sources. Open flame. Sparks. No smoking. : Strong oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Additional information : 8.2. Exposure controls Materials for protective clothing: Wear suitable protective clothing Hand protection: Chemical resistant gloves (according to European standard NF EN 374 or equivalent). Nitrile rubber gloves. Time of penetration is to be checked with the glove producer Eye protection: Avoid contact with eyes Respiratory protection: No special respiratory protection equipment is recommended under normal conditions of use with adequate ventilation. Where excessive vapour, mist, or dust may result, use approved respiratory protection equipment Other information: Handle in accordance with good industrial hygiene and safety practice. When using do not eat, drink or smoke. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point : Solid : Paste. : White. : characteristic. Flash point : > 60 C Auto-ignition temperature : > 227 C Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : 2000 kg/m³ : insoluble in water. soluble in most organic solvents. : > 20,5 mm²/s 07/02/2017 EN (English) 3/7

4 9.2. Other information SECTION 10: Stability and reactivity Reactivity Stable under normal conditions Chemical stability Possibility of hazardous reactions Conditions to avoid Heat. Sparks. Open flame. Ignition sources Incompatible materials Strong oxidizers Hazardous decomposition products. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard COMPOUND SILICONE Viscosity, kinematic > 20,5 mm²/s SECTION 12: Ecological information Toxicity Persistence and degradability COMPOUND SILICONE Persistence and degradability Bioaccumulative potential COMPOUND SILICONE Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects Other adverse effects : Do not discharge the product into the environment. Do not flush into surface water or sewer system. SECTION 13: Disposal considerations Waste treatment methods Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. 07/02/2017 EN (English) 4/7

5 Ecology - waste materials : Collect all waste in suitable and labelled containers and dispose according to local legislation. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN ADR IMDG IATA ADN RID UN number UN proper shipping name Transport document description, 9, III, (E), 9, III, MARINE POLLUTANT Environmentally hazardous substance, solid, n.o.s. Environmentally hazardous substance, solid, n.o.s., 9, III, 9, III, 9, III Transport hazard class(es) Packing group III III III III III Environmental hazards Marine pollutant : Yes Special precautions for user - Overland transport Classification code (ADR) : M7 Special provisions (ADR) : 274, 335, 601, 375 Limited quantities (ADR) Excepted quantities (ADR) Packing instructions (ADR) Special packing provisions (ADR) Mixed packing provisions (ADR) Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage : 5kg No supplementary information available : P002, IBC08, LP02, R001 : PP12, B3 : MP10 : T1, BK1, BK2 : TP33 : SGAV, LGBV : AT Transport category (ADR) : 3 Special provisions for carriage - Packages (ADR) Special provisions for carriage - Bulk (ADR) Special provisions for carriage - Loading, unloading and handling (ADR) : V13 : VC1, VC2 : CV13 Hazard identification number (Kemler No.) : 90 Orange plates : Tunnel restriction code (ADR) : E EAC code : 2Z 07/02/2017 EN (English) 5/7

6 - Transport by sea Special provisions (IMDG) : 274, 335, 966, 967, 969 Limited quantities (IMDG) Excepted quantities (IMDG) Packing instructions (IMDG) Special packing provisions (IMDG) IBC packing instructions (IMDG) IBC special provisions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) Stowage and handling (IMDG) - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) : 5 kg : P002, LP02 : PP12 : IBC08 : B3 : T1, BK1, BK2, BK3 : TP33 : F-A : S-F : A : SW23 : Y956 : 30kgG PCA packing instructions (IATA) : 956 PCA max net quantity (IATA) : 400kg CAO packing instructions (IATA) : 956 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) - Inland waterway transport Classification code (ADN) : 400kg : A97, A158, A179, A197 : 9L : M7 Special provisions (ADN) : 274, 335, 375, 601 Limited quantities (ADN) Excepted quantities (ADN) Carriage permitted (ADN) Equipment required (ADN) : 5 kg Number of blue cones/lights (ADN) : 0 - Rail transport Classification code (RID) : T* B** : PP, A : M7 Special provisions (RID) : 274, 335, 375, 601 Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Special packing provisions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) : 5kg Transport category (RID) : 3 Special provisions for carriage Packages (RID) Special provisions for carriage Bulk (RID) Special provisions for carriage - Loading, unloading and handling (RID) Colis express (express parcels) (RID) : P002, IBC08, LP02, R001 : PP12, B3 : MP10 : T1, BK1, BK2 : TP33 : SGAV, LGBV : W13 : VC1, VC2 : CW13, CW31 : CE11 Hazard identification number (RID) : Transport in bulk according to Annex II of Marpol and the IBC Code Not applicable 07/02/2017 EN (English) 6/7

7 SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances National regulations Germany VwVwS Annex reference : Water hazard class (WGK) 2, hazard to waters (Classification according to VwVwS, Annex 4) 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Denmark Classification remarks : Emergency management guidelines for the storage of flammable liquids must be followed Chemical safety assessment SECTION 16: Other information Full text of H- and EUH-statements: Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 H400 H410 Very toxic to aquatic life Very toxic to aquatic life with long lasting effects SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 07/02/2017 EN (English) 7/7