Glass Cleaner (Canada Market) Relevant identified uses of the substance or mixture and uses advised against

Transcription

1 Glass Cleaner (Canada Market) Safety Data Sheet Section 1: Identification Product identifier Product Name Synonyms Product Description Glass Cleaner (Canada Market) 0MS00120 Mixture. Relevant identified uses of the substance or mixture and uses advised against Recommended use Automotive Glass Cleaner Restrictions on use Details of the supplier of the safety data sheet Manufacturer Mopar (FCA US LLC Service & Customer Care Division) Lawrence Ave. Center Line, MI United States Telephone (General) Mopar Emergency telephone number Manufacturer Section 2: Hazard Identification UN GHS According to: UN Globally Harmonized System of Classification and Labelling of Chemicals (GHS) Classification of the substance or mixture UN GHS Label elements UN GHS Other hazards UN GHS United States (US) According to: OSHA 29 CFR HCS Page 1 of 10

2 Classification of the substance or mixture OSHA HCS 2012 H302 Acute Toxicity Oral Category 4 H320 Eye damage/irritation Category 2B Label elements OSHA HCS 2012 WARNING Hazard statements H302 Harmful if swallowed H320 Causes eye irritation Precautionary statements Prevention P264 Wash affected areas thoroughly after handling. P270 Do not eat, drink, or smoke when using this product Response P305 + P351 + P338: IF IN EYES: Rinse Caustiously with Water for Several Minutes. Remove Contact Lenses if Present and Easy to do so. Continue Rinsing. P301 + P312: If SWALLOWED : Call a POISON CENTER or Doctor/Physician P330 Rinse mouth P337 + P313: If eye irritation persists: Get medical attention Other hazards OSHA HCS 2012 Canada According to: WHMIS Storage/Disposal P501 Dispose of contents and container in accordance with local, regional, national, and/or international regulations. P102 Keep out of reach of children. OSHA Hazards: Irritant. Classification of the substance or mixture WHMIS Label elements WHMIS Other hazards WHMIS ANSI According to: American National Standards Institute Classification of the substance or mixture ANSI Label elements ANSI Page 2 of 10

3 Other hazards ANSI Other information NFPA Section 3 Composition/Information on Ingredients Substances Mixtures Composition Chemical Name Identifiers % Classifications According to LD50/LC50 Regulation/Directive CAS: Water EC Number:231 90% TO % EINECS: Isopropanol Dipropylene Glycol Methyl Ether Sodium Laureth Sulfate Acid Blue Green #3 CAS: EINECS: CAS: EINECS: % TO 6% 0.5% TO 1.5% CAS: % CAS: EINECS: CAS: EINECS: % 0.05% Comments NDA Hazardous Component: (OSHA 29 CFR ) NDA NDA NDA NDA The specific chemical identities and/or exact percentage concentration of composition may have been withheld as a trade secret. VOC Compliant 11/29/04. Section 4: First Aid Measures Page 3 of 10

4 Description of first aid measures Inhalation None known. Skin Wash with soap and water. Rinse thoroughly. Eye Rinse with water for 15 minutes. Get medical attention if irritation persists. Ingestion Do not induce vomiting. Get medical attention. Most important symptoms and effects, both acute and delayed None known. Indication of any immediate medical attention and special treatment needed Other information. Section 5: Fire Fighting Measures Extinguishing media Suitable Extinguishing Media Unsuitable Extinguishing Media Special hazards arising from the substance or mixture Unusual Fire and Explosion Hazards Hazardous Combustion Products Advice for firefighters Possible oxides of carbon. Firefighting Instructions : None known ; Firefighting Equipment : Bunker gear and SCBA.. Section 6 Accidental Release Measures Personal precautions, protective equipment and emergency procedures Personal Precautions Emergency Procedures Environmental precautions Avoid run off into storm sewers or ditches. Methods and material for containment and cleaning up Containment/Clean up Measures Section 7 Handling and Storage Land Spill : Avoid run off into storm sewers or ditches by containment with sand or absorbent material ; Water Spill : Remove from water with suitable absorbent material. Precautions for safe handling Handling Take normal care to prevent prolonged skin contact. Conditions for safe storage, including any incompatibilities Storage Keep from freezing or from heating above 110 F. Store in original container. Page 4 of 10

5 Section 8 Exposure Controls/Personal Protection Control parameters Exposure Limits/Guidelines Dipropylene Glycol Methyl Ether ( ) Isopropanol ( ) Isopropanol : 400 ppm (OSHA PEL & ACGIH TLV) Exposure Limits/Guidelines Result ACGIH NIOSH OSHA OSHA Vacated s STELs s STELs 100 ppm 150 ppm STEL 200 ppm 400 ppm STEL 100 ppm ; 600 mg/m3 150 ppm STEL; 900 mg/m3 STEL 400 ppm ; 980 mg/m3 500 ppm STEL; 1225 mg/m3 STEL 100 ppm ; 600 mg/m3 Not established 400 ppm ; 980 mg/m3 Not established 100 ppm ; 600 mg/m3 150 ppm STEL; 900 mg/m3 STEL 400 ppm ; 980 mg/m3 500 ppm STEL; 1225 mg/m3 STEL Exposure Control Notations OSHA Dipropylene Glycol Methyl Ether ( ): Skin: (prevent or reduce skin absorption) ACGIH Isopropanol ( ): Carcinogens: (A4 Not Classifiable as a Human Carcinogen) Dipropylene Glycol Methyl Ether ( ): Skin: (Skin potential significant contribution to overall exposure by the cutaneous route) OSHA Vacated Dipropylene Glycol Methyl Ether ( ): Skin: (Prevent or reduce skin absorption) Exposure controls Engineering The use of mechanical ventilation is not needed under normal conditions. Measures/Controls Personal Protective Equipment Respiratory Personal Protective Equipment is not needed under normal conditions. Eye/Face Not needed under normal conditions. Hands The use of rubber gloves is recommended for prolonged contact. Skin/Body Not needed under normal conditions. Environmental Exposure Controls Section 9 Physical and Chemical Properties Information on Physical and Chemical Properties Material Description Physical Form Liquid Appearance/Description Non viscous, clear. Color Blue Odor Mild alcohol. Taste No data available Particulate Type No data available Particulate Size No data available Aerosol Type No data available Odor Threshold No data available Physical and Chemical Properties No data available General Properties Boiling Point No data available Melting Point/Freezing Point No data available Decomposition Temperature No data available Heat of Decomposition No data available ph 6.7 to 7 Specific Gravity/Relative Density = 70 F( C) Water=1 Density No data available Bulk Density No data available Page 5 of 10

6 Water Solubility Completely Solvent Solubility No data available Viscosity No data available Explosive Properties No data available Oxidizing Properties: No data available Volatility Vapor Pressure No data available Vapor Density No data available Evaporation Rate 0.1 n Butyl Acetate = 1 VOC (Wt.) 32.9 g/liter (calculated) VOC (Vol.) No data available Volatiles (Wt.) No data available Volatiles (Vol.) No data available Flammability Flash Point Will not flash UEL No data available LEL No data available Autoignition No data available Self Accelerating Decomposition Temperature (SADT) No data available Heat of Combustion (ΔHc) No data available Burning Time No data available Flame Height No data available Flame Extension No data available Ignition Distance No data available Flame Duration No data available Flammability (solid, gas) No data available Environmental Half Life No data available Octanol/Water Partition coefficient No data available Coefficient of water/oil distribution No data available Bioaccumulation Factor No data available Bioconcentration Factor No data available Biochemical Oxygen Demand BOD/BOD5 No data available Chemical Oxygen Demand No data available Persistence No data available Degradation No data available Other Information Weight/Gallon : 8.18 lb/gal. Section 10: Stability and Reactivity Reactivity Chemical stability The product is stable. Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous polymerization will not occur. None None Hazardous decomposition products Oxides of carbon. Section 11 Toxicological Information Page 6 of 10

7 Information on toxicological effects GHS Properties Respiratory sensitization Serious eye damage/irritation Acute toxicity Aspiration Hazard Carcinogenicity Skin corrosion/irritation Skin sensitization STOT RE STOT SE Toxicity for Reproduction Germ Cell Mutagenicity Potential Health Effects Inhalation Acute (Immediate) Chronic (Delayed) Skin Acute (Immediate) Chronic (Delayed) Eye Acute (Immediate) Chronic (Delayed) Ingestion Acute (Immediate) Chronic (Delayed) Other information Classification The complete toxicological data for each ingredient is unknown and otherwise beyond the scope of this document. Section 12 Ecological Information Page 7 of 10

8 Toxicity This product may be harmful to fish and algae upon immediate exposure. Persistence and degradability Bioaccumulative potential Mobility in Soil Other adverse effects No information available. Section 13 Disposal Considerations Waste treatment methods Product waste Packaging waste Other Information Refer to Sections 5, 6, and 15 for disposal and regulatory information. Section 14 Transport Information UN number UN proper shipping name Transport hazard class (es) Packing group Environmental hazards DOT NDA NDA NDA NDA NDA TDG NDA NDA NDA NDA NDA IMO/IMDG NDA NDA NDA NDA NDA ADN NDA NDA NDA NDA NDA ADR/RID NDA NDA NDA NDA NDA IATA/ICAO NDA NDA NDA NDA NDA Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Other information DOT Unrestricted/Non regulated Section 15 Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications SARA Title III : No known reportable ingredients. Page 8 of 10

9 State Right To Know Component CAS NJ PA Acid Blue No No Dipropylene Glycol Methyl Ether Yes Yes Green # No No Isopropanol Yes Yes Sodium Laureth Sulfate No No Water No No Inventory Component CAS Canada DSL EU EINECS TSCA Acid Blue Yes Yes Yes Dipropylene Glycol Methyl Ether Yes Yes Yes Green # Yes Yes Yes Isopropanol Yes Yes Yes Sodium Laureth Sulfate Yes No Yes Water Yes Yes Yes Canada Labor Canada WHMIS Classifications of Substances Uncontrolled product Water according to WHMIS classification criteria Isopropanol B2, D2B (including 70%) Sodium Laureth Sulfate Not Listed Dipropylene Glycol Methyl Ether B3 Green # Not Listed Acid Blue Not Listed Canada WHMIS Ingredient Disclosure List Water Not Listed Isopropanol % Sodium Laureth Sulfate Not Listed Dipropylene Glycol Methyl Ether % Green # Not Listed Acid Blue Not Listed United States Environment U.S. CERCLA/SARA Section 313 Emission Reporting Water Not Listed 1.0 % de minimis concentration (only if Isopropanol manufactured by the strong acid process, no supplier Page 9 of 10

10 notification) Sodium Laureth Sulfate Not Listed Dipropylene Glycol Methyl Ether Not Listed Green # Not Listed Acid Blue Not Listed Other Information TSCA : All components are listed on the TSCA ; CERCLA : Not reportable ; Section 16 Other Information Revision Date Last Revision Date Preparation Date Disclaimer/Statement of Liability Page 10 of 10