SAFETY DATA SHEET. 1. Product and Company Identification

Transcription

1 SAFETY DATA SHEET 1. Product and Company Identification Product identifier Other means of identification Recommended use Recommended restrictions Manufacturer information Supplier Cover Free Not available Suppression of water evaporation and heat loss None known. NC Brands 4 Richards Ave. Norwalk, CT 6854 US Phone: (8) Emergency Phone: CHEMTREC (8) See above. 2. Hazards Identification Physical hazards Health hazards Environmental hazards WHMIS 215 defined hazards Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal WHMIS 215: Health Hazard(s) not otherwise classified (HHNOC) WHMIS 215: Physical Hazard(s) not otherwise classified (PHNOC) Hazard(s) not otherwise classified (HNOC) Supplemental information Not classified None. None. The mixture does not meet the criteria for classification. Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. None known None known None known. Not applicable. 3. Composition/Information on Ingredients Mixture Chemical name Cetyl Alcohol 1,2-Propanediol Common name and synonyms CAS number % All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First Aid Measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms develop or persist. Rinse skin with water/shower. Get medical attention if irritation develops and persists. Rinse with water. Get medical attention if irritation develops and persists. Rinse mouth. If ingestion of a large amount does occur, call a poison control center immediately. Direct contact with eyes may cause temporary irritation. #2157 Page: 1 of 7

2 Indication of immediate medical attention and special treatment needed General information Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods General fire hazards Hazardous combustion products Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Avoid contact with eyes and skin. Wear rubber gloves and safety glasses with side shields. 5. Fire Fighting Measures Foam. Dry chemical. Carbon dioxide. None known. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. No unusual fire or explosion hazards noted. May include and are not limited to: Oxides of carbon. 6. Accidental Release Measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. For personal protection, see section 8 of the SDS. Stop the flow of material, if this is without risk. Large Spills: Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions Precautions for safe handling Conditions for safe storage, including any incompatibilities Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. 7. Handling and Storage Avoid contact with eyes and skin. Avoid prolonged exposure. Use care in handling/storage. Store in original tightly closed container. Store away from incompatible materials (see Section 1 of the SDS). 8. Exposure Controls/Personal Protection Occupational exposure limits Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) Type Value 1,2-Propanediol (CAS ) US. AIHA Workplace Environmental Exposure Level (WEEL) Guides Type 1,2-Propanediol (CAS ) Biological limit values Appropriate engineering controls Form TWA 155 mg/m3 Vapor and aerosol. 1 mg/m3 Aerosol. 5 ppm Vapor and aerosol. Value Form TWA 1 mg/m3 Aerosol. No biological exposure limits noted for the ingredient(s). Good general ventilation (typically 1 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields. #2157 Page: 2 of 7

3 Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Rubber gloves. Confirm with a reputable supplier first. Wear suitable protective clothing. Not normally required if good ventilation is maintained. Not applicable. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Appearance Physical state Form Color Odor Odor threshold Liquid Liquid. Liquid. Orange ph 5-8 Melting point/freezing point Initial boiling point and boiling range Pour point Specific gravity Partition coefficient (n-octanol/water) Flash point Evaporation rate Flammability (solid, gas) 9. Physical and Chemical Properties Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Auto-ignition temperature Decomposition temperature Viscosity 8-9 lb/gal Complete 1. Stability and Reactivity Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. No dangerous reaction known under conditions of normal use. Material is stable under normal conditions. Do not mix with other chemicals. Strong oxidizing agents. May include and are not limited to: Oxides of carbon. 11. Toxicological Information Routes of exposure Eye, Skin contact, Inhalation, Ingestion. Information on likely routes of exposure Ingestion May cause stomach distress, nausea or vomiting. #2157 Page: 3 of 7

4 Inhalation Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Acute Dermal LD5 Inhalation LC5 Oral LD5 Cetyl Alcohol (CAS ) Acute Dermal LD5 Inhalation LC5 Oral LD5 Skin corrosion/irritation Exposure minutes Erythema value Oedema value Serious eye damage/eye irritation Corneal opacity value Iris lesion value Conjunctival reddening value No adverse effects due to inhalation are expected. No adverse effects due to skin contact are expected. May be irritating to eyes. Direct contact with skin may cause irritation. Direct contact with eyes may cause temporary irritation. Species Rabbit Not available Dog Guinea pig Mouse Rabbit Rat Guinea pig Rabbit Not available Mouse Rat May cause irritation. May be irritating to eyes. Conjunctival oedema value Recover days Respiratory or skin sensitization Respiratory sensitization Skin sensitization Mutagenicity This product is not expected to cause skin sensitization. Test Results 28 mg/kg 19 mg/kg 184 mg/kg 239 mg/kg 148 mg/kg 2 mg/kg < 1 g/kg, HSDB, Patty's Industrial Hygiene and Toxicology 8 mg/kg, 24 Hours, ECHA 26 mg/kg, LOLI 32 mg/kg, Sax's Dangerous Properties of Industrial Materials > 796 mg/kg, ECHA > 5 mg/kg, ECHA > 2 mg/kg, ECHA 5 mg/kg, LOLI No data available to indicate product or any components present at greater than.1% are mutagenic or genotoxic. #2157 Page: 4 of 7

5 Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. US. OSHA Specifically Regulated Substances (29 CFR ) Reproductive toxicity Teratogenicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects This product is not expected to cause reproductive or developmental effects. 12. Ecological Information Ecotoxicity See below Ecotoxicological data Species Test Results Crustacea EC5 Daphnia 1 mg/l, 48 Hours Aquatic Crustacea EC5 Water flea (Daphnia magna) > 1 mg/l, 48 hours Fish LC5 Fathead minnow (Pimephales promelas) 71 mg/l, 96 hours Persistence and degradability Bioaccumulative potential Mobility in soil Mobility in general Other adverse effects No data is available on the degradability of this product. No data available. No data available. No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal Considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Transport of Dangerous Goods (TDG) Proof of Classification U.S. Department of Transportation (DOT) Not regulated as dangerous goods. Transportation of Dangerous Goods (TDG - Canada) Not regulated as dangerous goods. Canadian federal regulations Export Control List (CEPA 1999, Schedule 3) Greenhouse Gases Precursor Control Regulations WHMIS 215 Exemptions 14. Transport Information In accordance with Part (SOR/ ) of the Transportation of Dangerous Goods Regulations, we certify that the classification of this product is correct as of the SDS date of issue. 15. Regulatory Information This product has been classified in accordance with the hazard criteria of the HPR and the SDS contains all the information required by the HPR. Not applicable #2157 Page: 5 of 7

6 US federal regulations TSCA Section 12(b) Export Notification (4 CFR 77, Subpt. D) CERCLA Hazardous Substance List (4 CFR 32.4) US. OSHA Specifically Regulated Substances (29 CFR ) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories SARA 32 Extremely hazardous substance SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Other federal regulations Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No No No Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (4 CFR 68.13) US state regulations US - Minnesota Haz Subs: Listed substance US - New Jersey RTK - Substances: Listed substance US - Texas Effects Screening Levels: Listed substance Cetyl Alcohol (CAS ) US. Massachusetts RTK - Substance List US. New Jersey Worker and Community Right-to-Know Act Listed. Listed. Listed. US. Pennsylvania Worker and Community Right-to-Know Law US. Rhode Island RTK US. California Proposition 65 Not Listed. Inventory status Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information No Yes Severe Serious Moderate Slight Minimal LEGEND HEALTH FLAMMABILITY PHYSICAL HAZARD PERSONAL PROTECTION / 1 X 1 #2157 Page: 6 of 7

7 Disclaimer Issue date Version # 1 Effective date Prepared by Other information The information in the sheet was written based on the best knowledge and experience currently available. Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. 28-April April-217 Dell Tech Laboratories, Ltd. Phone: (519) For an updated SDS, please contact the supplier/manufacturer listed on the first page of the document. #2157 Page: 7 of 7