Information Sheet

Transcription

1 Stability Transport Other formation. and reactivity.... / >>... / >> Information Sheet TLV: Environmental Incompatible Threshold materials. Limit hazards. Value - Information TLV CEILING: not Concentration that should not be exceeded durg any time of occupational exposure. Page n / 06 - TWA STEL: Short-term First Exposure aid exposure measures. controls/personal limit protection TWA: Hazardous Time-weighted 1. Identification decomposition average products. exposure of the limit substance/mixture and of the company/undertakg 4.1. Description of first aid measures Information VOC: Control Special specifically Volatile parameters. precautions not organic necessary. Compounds for Observance user. of good dustrial hygiene is recommended vpvb: Product Very identifier Persistent and very Bioaccumulative as for REACH Regulation 4.2. Information - WGK: Most important Water not hazard symptoms classes and (German). effects, both acute and delayed. Code: 11. Toxicological formation. BB21 No episodes of damage to health ascribable to the product have been reported Product Accordg Exposure Transport name to controls. currently bulk accordg available to data, Annex this II of product MARPOL73/78 has not and yet produced the IBC Code. health damages. Anyway, it must be handled accordg to good 4.3. dustrial GENERAL Indication practices. BIBLIOGRAPHY of any immediate medical attention and special treatment needed Information Comply Information 1. Relevant Directive identified with 1999/45/EC not not the relevant. uses safety measures and of followg the substance usually amendments or mixture and uses advised agast applied when handlg chemical substances HAND 2. Directive Information PROTECTION 67/548/EEC on toxicological and followg effects. amendments and adjustments None 3. Intended Regulation use required. (EU) 1907/2006 (REACH) of the European Sgle Parliament component silane-based adhesive. SKIN Information 4. Regulation 15. PROTECTION not (EU) Firefightg Regulatory 1272/2008 (CLP) measures. formation. of the European Parliament 1.3. None 5. Details Regulation of the required. (EU) supplier 790/2009 of the (I Atp. safety CLP) data of the sheet European Parliament EYE 6. Regulation Extguishg Safety, PROTECTION health (EU) media. and 453/2010 environmental of the European regulations/legislation Parliament specific for the substance or mixture. SUITABLE None 7. Name Regulation required. 12. (EU) Ecological 286/2011 (II Atp. formation. CLP) of the European Tover Srl Parliament EXTINGUISHING EQUIPMENT Seveso Extguishg RESPIRATORY 8. Full Regulation address category. (EU) substances PROTECTION 618/2012 (III Atp. CLP) of the European Via Rosa Parliament Luxemburg 2/A Use are: carbon dioxide and chemical powder. For product loss or leakage that has not caught fire, water spray can be None 9. District Regulation this and product Country used to required, (EU) disperse unless 487/2013 accordg flammable dicated (IV to vapours otherwise Atp. good CLP) workg and protect of the the practices. chemical European those tryg risk Parliament Avoid Collegno litterg. Inform the competent authorities, (TO) should the product reach waterways or sewers or contamate soil or vegetation. to assessment. stem the leak. Restrictions ENVIRONMENTAL 10. Regulation relatg (EU) to UNSUITABLE EXTINGUISHING EXPOSURE 944/2013 the product (V or CONTROLS. Atp. contaed CLP) of substances the European pursuant Parliament Italia to Annex XVII to EC Regulation 1907/2006. EQUIPMENT The 11. Contaed Regulation Do not emissions substance. (EU) use jets of generated 605/2014 water. by (VI manufacturg Atp. CLP) of the processes, European Tel. cludg Parliament those generated by ventilation equipment, should be checked to ensure Water compliance Pot. is not with effective environmental 52 for puttg standards. Diisononyl Fax Phtalate The Merck address Index. of the - 10th competent Editionout person fires but can be used to cool contaers exposed to flames to prevent explosions Substances - responsible Handlg Toxicity. Chemical for Candidate the Safety Safety List Data (Art. Sheet 59 REACH). fo@tover.com 5.2. Information - Niosh Special - Registry hazards 9. not Physical of arisg Toxic Effects from and the of chemical Chemical substance Substances properties. or mixture Substances - HAZARDS INRS Emergency - Fiche CAUSED subject telephone Toxicologique to BY authorisarion EXPOSURE number (toxicological (Annex IN THE XIV sheet) REACH). EVENT OF FIRE If Patty Information large Persistence - quantities Industrial on and of basic Hygiene the degradability. product physical and Toxicology are and volved chemical a properties. fire, they can make it considerably worse. Do not breathe combustion products. Substances Information Appearance - For N.I. urgent Sax - quiries Dangerous subject not to refer exportation properties to reportg of Industrial pursuant Materials-7, to paste Tover (EC) Reg Srl - 649/2012: tel. Edition Colour - ECHA Advice website for firefighters. Light wood or dark wood Odour GENERAL Bioaccumulative INFORMATION potential. Fat Substances Information Odour the threshold. case 2. subject not of Hazards fire, to the use Rotterdam jets identification. of water Convention: to cool the contaers to prevent the risk of explosions (product decomposition and excess pressure) and the ph. development of substances potentially hazardous for health. Always wear full fire prevention gear. Remove all contaers contag the 2.1. e Classification for users: of the substance or mixture product Meltg The Mobility formation pot from the / soil. freezg fire, contaed if pot. it is safe the to do present so. sheet are based on our own knowledge on the date of the last version. Users must verify the Substances Information SPECIAL Initial boilg PROTECTIVE subject not pot. to the Stockholm EQUIPMENT Convention: FOR FIRE-FIGHTERS > 100 C. The suitability product and is thoroughness not classified of as provided hazardous formation pursuant accordg to the provisions to each set specific forth use EC of Regulation the product. 1272/2008 (CLP) (and subsequent Normal Boilg range. fire fightg clothg i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) combation with This amendments document and must supplements). not be regarded as a guarantee on any specific product property self-contaed Flash The Results use pot. of of this PBT open product and circuit vpvb positive is not assessment. subject pressure to compressed our > direct 100 air control; breathg C. therefore, apparatus users (BS must, EN 137). under their own responsibility, comply with the current Healthcare Evaporation controls. Rate health Regulation and safety 1272/2008 laws and (CLP) regulations. and followg The producer amendments is relieved and from adjustments. any liability arisg from improper uses. On Flammability the basis of solids and data, gases the product does not not conta flammable any PBT or vpvb percentage greater than 0,1%. Provide Information appoted not Lower flammability 6. Accidental staff with adequate limit. release trag measures. on how to use chemical products. Hazard classification and dication: Changes Product Upper Other flammability not adverse to previous tended effects. limit. review: for uses provided for by Dir. 2004/42/CE Lower Personal explosive precautions, limit. protective equipment and emergency 2.2. The Label followg elements. sections were modified: procedures Information Use Upper Chemical / 03 breathg explosive / 04 not / 06 safety equipment / limit. 07 assessment. / 08 / 10 if / fumes 11 / 13 or / 15 powders / 16. are released to the air. These dications apply for both processg staff and those volved Vapour emergency pressure. procedures. Hazard labellg pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements. No Vapour chemical density safety assessment has been processed for the mixture and the substances it contas Relative Environmental density. 13. Disposal considerations. precautions. 1,676 Kg/l Hazard pictograms: -- The Solubility product must not penetrate to the sewer system soluble or come to water contact with surface water or ground water Partition coefficient: 16. Other n-octanol/water formation. Signal Waste words: treatment methods Reuse, Auto-ignition Methods when and temperature. possible. material Neat for product contament residues and should cleang be considered up. special non-hazardous waste. Disposal LEGEND: Decomposition Confe usg must be temperature. earth performed ert through material. an authorised Collect as waste much Hazard statements: -- management material as possible firm, compliance and elimate with the national rest usg and jets local of regulations. water. Contamated material - CONTAMINATED Viscosity should ADR: be European disposed Agreement PACKAGING of compliance concerng with the carriage provisions of Dangerous set forth pot goods 13. by Road - Explosive properties Contamated Precautionary CAS NUMBER: statements: packagg Chemical must Abstract be recovered -- Service Number or disposed of compliance with national waste management regulations Oxidisg CE50: Reference Effective properties to other concentration sections. (required to duce a 50% effect) Any CE Other formation NUMBER: formation Other hazards. Identifier on personal ESIS protection (European and disposal archive is of given existg sections substances) 8 and Information CLP: EC Regulation 14. not Transport 1272/2008formation On DNEL: UN the number. basis Derived of available No Effect data, Level the product does not conta any PBT or vpvb percentage greater than 0,1%. 7. Handlg and storage. - EmS: Emergency 10. Stability Scheduleand reactivity. - GHS: Globally Harmonized System of classification and labelg of chemicals IATA Precautions DGR: 3. International Composition/formation for safe handlg. Air Transport Association Dangerous on gredients. Goods Regulation Before - IC50: Reactivity. UN proper Immobilization handlg shippg the Concentration name. product, consult 50% 3.1. Substances. all the other sections of this material safety data sheet. Avoid leakage of the product to the There - environment. IMDG: are International no particular Do not eat, Maritime risks drk of Code or reaction smoke for with dangerous durg other use. substances goods normal conditions of use. - IMO: International Maritime Organization Information not relevant INDEX Conditions Chemical NUMBER: stability. for safe Identifier storage, Annex cludg VI of any CLP compatibilities Keep The LC50: product Transport the Lethal product is hazard Concentration stable clearly class(es). normal labelled 50% conditions contaers. of use Keep and storage Mixtures. contaers away from any compatible materials, see section 10 for details. - LD50: Lethal dose 50% OEL: Specific Possibility Occupational end of use(s). hazardous Exposure reactions. Level The product does not conta substances classified as beg hazardous to human health or the environment pursuant to the provisions set - Information No PBT: hazardous Persistent not reactions bioaccumulative are foreseeable and toxic normal as REACH conditions Regulation of use and storage. forth Directives 67/548/EEC and/or EC Regulation 1272/2008 (CLP) (and subsequent amendments and supplements) such quantities PEC: Packg Predicted group. environmental Concentration as to require the statement PEL: Conditions Predicted to exposure avoid. level - None PNEC: particular. Predicted However no effect the concentration usual precautions used for chemical products should be respected. - REACH: EC Regulation 1907/ RID: Regulation concerng the ternational transport of dangerous goods by tra

2 Page n. 2 / 6 4. First aid measures Description of first aid measures. specifically necessary. Observance of good dustrial hygiene is recommended Most important symptoms and effects, both acute and delayed. No episodes of damage to health ascribable to the product have been reported Indication of any immediate medical attention and special treatment needed. 5. Firefightg measures Extguishg media. SUITABLE EXTINGUISHING EQUIPMENT Extguishg substances are: carbon dioxide and chemical powder. For product loss or leakage that has not caught fire, water spray can be used to disperse flammable vapours and protect those tryg to stem the leak. UNSUITABLE EXTINGUISHING EQUIPMENT Do not use jets of water. Water is not effective for puttg out fires but can be used to cool contaers exposed to flames to prevent explosions Special hazards arisg from the substance or mixture. HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE If large quantities of the product are volved a fire, they can make it considerably worse. Do not breathe combustion products Advice for firefighters. GENERAL INFORMATION In the case of fire, use jets of water to cool the contaers to prevent the risk of explosions (product decomposition and excess pressure) and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Remove all contaers contag the product from the fire, if it is safe to do so. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS Normal fire fightg clothg i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) combation with self-contaed open circuit positive pressure compressed air breathg apparatus (BS EN 137). 6. Accidental release measures Personal precautions, protective equipment and emergency procedures. Use breathg equipment if fumes or powders are released to the air. These dications apply for both processg staff and those volved emergency procedures Environmental precautions. The product must not penetrate to the sewer system or come to contact with surface water or ground water Methods and material for contament and cleang up. Confe usg earth or ert material. Collect as much material as possible and elimate the rest usg jets of water. Contamated material should be disposed of compliance with the provisions set forth pot Reference to other sections. Any formation on personal protection and disposal is given sections 8 and Handlg and storage Precautions for safe handlg. Before handlg the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product to the environment. Do not eat, drk or smoke durg use Conditions for safe storage, cludg any compatibilities. Keep the product clearly labelled contaers. Keep contaers away from any compatible materials, see section 10 for details Specific end use(s).

3 Page n. 3 / 6 8. Exposure controls/personal protection Control parameters Exposure controls. Comply with the safety measures usually applied when handlg chemical substances. HAND PROTECTION None required. SKIN PROTECTION None required. EYE PROTECTION None required. RESPIRATORY PROTECTION None required, unless dicated otherwise the chemical risk assessment. ENVIRONMENTAL EXPOSURE CONTROLS. The emissions generated by manufacturg processes, cludg those generated by ventilation equipment, should be checked to ensure compliance with environmental standards. 9. Physical and chemical properties Information on basic physical and chemical properties. Appearance paste Colour Light wood or dark wood Odour Fat Odour threshold. ph. Meltg pot / freezg pot. Initial boilg pot. > 100 C. Boilg range. Flash pot. > 100 C. Evaporation Rate Flammability of solids and gases not flammable Lower flammability limit. Upper flammability limit. Lower explosive limit. Upper explosive limit. Vapour pressure. Vapour density Relative density. 1,676 Kg/l Solubility soluble water Partition coefficient: n-octanol/water Auto-ignition temperature. Decomposition temperature. Viscosity Explosive properties Oxidisg properties 9.2. Other formation. 10. Stability and reactivity Reactivity. There are no particular risks of reaction with other substances normal conditions of use Chemical stability. The product is stable normal conditions of use and storage Possibility of hazardous reactions. No hazardous reactions are foreseeable normal conditions of use and storage Conditions to avoid. None particular. However the usual precautions used for chemical products should be respected.

4 10. Stability and reactivity.... / >> Page n. 4 / Incompatible materials Hazardous decomposition products. 11. Toxicological formation. Accordg to currently available data, this product has not yet produced health damages. Anyway, it must be handled accordg to good dustrial practices Information on toxicological effects. 12. Ecological formation. Use this product accordg to good workg practices. Avoid litterg. Inform the competent authorities, should the product reach waterways or sewers or contamate soil or vegetation Toxicity Persistence and degradability Bioaccumulative potential Mobility soil Results of PBT and vpvb assessment. On the basis of available data, the product does not conta any PBT or vpvb percentage greater than 0,1% Other adverse effects. 13. Disposal considerations Waste treatment methods. Reuse, when possible. Neat product residues should be considered special non-hazardous waste. Disposal must be performed through an authorised waste management firm, compliance with national and local regulations. CONTAMINATED PACKAGING Contamated packagg must be recovered or disposed of compliance with national waste management regulations. 14. Transport formation UN number UN proper shippg name Transport hazard class(es) Packg group.

5 14. Transport formation.... / >> Tover Srl Page n. 5 / Environmental hazards Special precautions for user Transport bulk accordg to Annex II of MARPOL73/78 and the IBC Code. Information not relevant. 15. Regulatory formation Safety, health and environmental regulations/legislation specific for the substance or mixture. Seveso category. Restrictions relatg to the product or contaed substances pursuant to Annex XVII to EC Regulation 1907/2006. Contaed substance. Pot. 52 Diisononyl Phtalate Substances Candidate List (Art. 59 REACH). Substances subject to authorisarion (Annex XIV REACH). Substances subject to exportation reportg pursuant to (EC) Reg. 649/2012: Substances subject to the Rotterdam Convention: Substances subject to the Stockholm Convention: Healthcare controls. Product not tended for uses provided for by Dir. 2004/42/CE Chemical safety assessment. No chemical safety assessment has been processed for the mixture and the substances it contas. 16. Other formation. LEGEND: - ADR: European Agreement concerng the carriage of Dangerous goods by Road - CAS NUMBER: Chemical Abstract Service Number - CE50: Effective concentration (required to duce a 50% effect) - CE NUMBER: Identifier ESIS (European archive of existg substances) - CLP: EC Regulation 1272/ DNEL: Derived No Effect Level - EmS: Emergency Schedule - GHS: Globally Harmonized System of classification and labelg of chemicals - IATA DGR: International Air Transport Association Dangerous Goods Regulation - IC50: Immobilization Concentration 50% - IMDG: International Maritime Code for dangerous goods - IMO: International Maritime Organization - INDEX NUMBER: Identifier Annex VI of CLP - LC50: Lethal Concentration 50% - LD50: Lethal dose 50% - OEL: Occupational Exposure Level - PBT: Persistent bioaccumulative and toxic as REACH Regulation - PEC: Predicted environmental Concentration - PEL: Predicted exposure level - PNEC: Predicted no effect concentration - REACH: EC Regulation 1907/ RID: Regulation concerng the ternational transport of dangerous goods by tra

6 16. Other formation.... / >> Tover Srl Page n. 6 / 6 - TLV: Threshold Limit Value - TLV CEILING: Concentration that should not be exceeded durg any time of occupational exposure. - TWA STEL: Short-term exposure limit - TWA: Time-weighted average exposure limit - VOC: Volatile organic Compounds - vpvb: Very Persistent and very Bioaccumulative as for REACH Regulation - WGK: Water hazard classes (German). GENERAL BIBLIOGRAPHY 1. Directive 1999/45/EC and followg amendments 2. Directive 67/548/EEC and followg amendments and adjustments 3. Regulation (EU) 1907/2006 (REACH) of the European Parliament 4. Regulation (EU) 1272/2008 (CLP) of the European Parliament 5. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament 6. Regulation (EU) 453/2010 of the European Parliament 7. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament 8. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament 9. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament 10. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament 11. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament - The Merck Index. - 10th Edition - Handlg Chemical Safety - Niosh - Registry of Toxic Effects of Chemical Substances - INRS - Fiche Toxicologique (toxicological sheet) - Patty - Industrial Hygiene and Toxicology - N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition - ECHA website e for users: The formation contaed the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided formation accordg to each specific use of the product. This document must not be regarded as a guarantee on any specific product property. The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arisg from improper uses. Provide appoted staff with adequate trag on how to use chemical products. Changes to previous review: The followg sections were modified: 02 / 03 / 04 / 06 / 07 / 08 / 10 / 11 / 13 / 15 / 16.