Safety Data Sheet. Issue Date: 15-Aug-2018 Revision Date: 17-Aug-2018 Version 1 1. IDENTIFICATION. SPLASH Gas Line Antifreeze

Size: px
Start display at page:

Download "Safety Data Sheet. Issue Date: 15-Aug-2018 Revision Date: 17-Aug-2018 Version 1 1. IDENTIFICATION. SPLASH Gas Line Antifreeze"

Transcription

1 Safety Data Sheet Issue Date: 15-Aug-2018 Version 1 1. IDENTIFICATION Product identifier Product Name SPLASH Gas Line Antifreeze Other means of identification SDS/PART # , UN/ID No UN1230 Recommended use of the chemical and restrictions on use Recommended Use Gas line anti-freeze. Details of the supplier of the safety data sheet Manufacturer Address FMP 1380 Corporate Center Curve, Suite 200 Eagan, MN Phone: Emergency telephone number Emergency Telephone INFOTRAC (International) (North America) 2. HAZARDS IDENTIFICATION Appearance Clear colorless Physical state Liquid Odor Very, slight alcohol smell Classification Acute toxicity - Oral Category 3 Acute toxicity - Dermal Category 3 Acute toxicity - Inhalation (Vapors) Category 3 Acute toxicity - Inhalation (Dusts/Mists) Category 3 Specific target organ toxicity (single exposure) Category 1 Flammable Liquids Category 2 Signal Word Danger Hazard statements Toxic if swallowed Toxic in contact with skin Toxic if inhaled Causes damage to organs Highly flammable liquid and vapor Page 1 / 8

2 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapors/spray Keep away from heat/sparks/open flames/hot surfaces. No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF exposed: Call a POISON CENTER or doctor IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower Wash contaminated clothing before reuse Call a POISON CENTER or doctor if you feel unwell IF INHALED: Remove person to fresh air and keep comfortable for breathing Call a POISON CENTER or doctor IF SWALLOWED: Immediately call a POISON CENTER or doctor Rinse mouth IN CASE OF FIRE: Use CO2, dry chemical, or foam to extinguish Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS No. Weight-% **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret. ** Description of first aid measures 4. FIRST AID MEASURES General Advice Eye Contact IF exposed: Call a POISON CENTER or doctor/physician. Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin Contact Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Call a poison center or doctor/physician if you feel unwell. Page 2 / 8

3 Inhalation Ingestion Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician. Immediately call a poison center or doctor/physician. Rinse mouth. Most important symptoms and effects, both acute and delayed Symptoms Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes damage to organs. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media. Specific Hazards Arising from the Chemical Highly flammable liquid and vapor. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Methods for Clean-Up Prevent further leakage or spillage if safe to do so. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Do not breathe dust/fume/gas/mist/vapors/spray. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion proof equipment. Use only non-sparking tools. Take precautionary measures against static discharges. Keep cool. Wear protective gloves/protective clothing and eye/face protection. Conditions for safe storage, including any incompatibilities Page 3 / 8

4 Storage Conditions Incompatible Materials Store locked up. Store in a well-ventilated place. Keep cool. Keep container tightly closed. None known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Appropriate engineering controls STEL: 250 ppm TWA: 200 ppm S* TWA: 200 ppm TWA: 260 mg/m 3 (vacated) TWA: 200 ppm (vacated) TWA: 260 mg/m 3 (vacated) STEL: 250 ppm (vacated) STEL: 325 mg/m 3 (vacated) S* IDLH: 6000 ppm TWA: 200 ppm TWA: 260 mg/m 3 STEL: 250 ppm STEL: 325 mg/m 3 Engineering Controls Showers. Eyewash stations. Ventilation systems. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Refer to 29 CFR for eye and face protection regulations. Refer to 29 CFR for appropriate skin and body protection. Refer to 29 CFR for respiratory protection requirements. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state Liquid Appearance Clear colorless Odor Very, slight alcohol smell Color Odor Threshold Property Values Remarks Method ph Melting point / freezing point C / -144 F Boiling point / boiling range 64.4 C / 148 F Flash point 12.2 C / 54 F Evaporation Rate Flammability (Solid, Gas) Liquid-Not applicable Flammability Limit in Air Upper flammability or explosive limits Lower flammability or explosive limits Vapor Pressure Vapor Density Relative Density Water Solubility Solubility in other solvents Partition Coefficient Page 4 / 8

5 Autoignition temperature Decomposition temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties Reactivity Not reactive under normal conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to Avoid Keep out of reach of children. Incompatible materials None known based on information supplied. Hazardous decomposition products None known based on information supplied. Information on likely routes of exposure Product Information 10. STABILITY AND REACTIVITY 11. TOXICOLOGICAL INFORMATION Eye Contact Skin Contact Inhalation Ingestion Avoid contact with eyes. Toxic in contact with skin. Toxic if inhaled. Toxic if swallowed. Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50 = 6200 mg/kg (Rat) = mg/kg (Rabbit) = = ppm (Rat) 8 h = ppm mg/kg (Rabbit) (Rat) 4 h Symptoms related to the physical, chemical and toxicological characteristics Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity STOT - single exposure Based on the information provided, this product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Causes damage to organs. Numerical measures of toxicity Page 5 / 8

6 The following values are calculated based on chapter 3.1 of the GHS document. ATEmix (oral) mg/kg ATEmix (dermal) mg/kg ATEmix (inhalation-dust/mist) 0.50 mg/l ATEmix (inhalation-vapor) 3.00 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical name Algae/aquatic plants Fish Crustacea 18-20: 96 h Oncorhynchus mykiss ml/l LC50 static 28200: 96 h Pimephales promelas mg/l LC50 flow-through 100: 96 h Pimephales promelas mg/l LC50 static : 96 h Oncorhynchus mykiss mg/l LC50 flow-through : 96 h Lepomis macrochirus mg/l LC50 flow-through Persistence/Degradability. Bioaccumulation There is no data for this product. Mobility Chemical name Partition coefficient Other Adverse Effects 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. US EPA Waste Number Chemical name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes Included in waste stream: U154 F039 California Hazardous Waste Status Chemical name Page 6 / 8 California Hazardous Waste Status Toxic

7 Ignitable 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT UN/ID No UN1230 Proper Shipping Name Hazard class 3 Packing Group II IATA UN number UN1230 Proper Shipping Name Transport hazard class(es) 3 Subsidiary hazard class 6.1 Packing Group II IMDG UN number UN1230 Proper Shipping Name Transport hazard class(es) 3 Subsidiary Hazard Class 6.1 Packing Group II International Inventories 15. REGULATORY INFORMATION Chemical name TSCA DSL/NDSL EINECS/E LINCS ENCS IECSC KECL PICCS AICS X X X X X X X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA SARA 313 Chemical name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ CWA (Clean Water Act) Chemical name CAS No. Weight-% SARA Threshold Values % Page 7 / 8

8 This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ) US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical name California Proposition 65 - Developmental Chemical name New Jersey Massachusetts Pennsylvania X X X 16. OTHER INFORMATION NFPA HMIS Health Hazards Health Hazards Flammability Flammability Instability Physical hazards Special Hazards Personal Protection Issue Date: Revision Date: Revision Note: 15-Aug Aug-2018 New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 8 / 8