PRODUCT SAFETY DATA SHEET

Transcription

1 PRODUCT SAFETY DATA SHEET 1. IDENTIFICATION OF THE PREPARATION AND THE COMPANY IDENTIFICATION. Trade Name: DETTOL Complete Clean Antibacterial Multi-Action Floor Wipes - Green Apple Product Format: White wet wipes packed in flow wrap/canister Product Use: Floor, Hard Surface Cleaner Supplier in UK: Reckitt Benckiser Wellcroft House Wellcroft Road Slough, Berkshire SL1 4AQ Contact Telephone: Supplier in The Republic Of Ireland: Reckitt Benckiser Ireland Ltd 7 Riverwalk Citywest Business Campus Dublin 24 Ireland Contact Telephone: Contact consumer.relations-ukroi@reckittbenckiser.com Date Issued: RB Ref No: Issue: RB parent code: Revisions: 07 Jan D v v1 Modification of Name/Revised Formula 2. HAZARDS IDENTIFICATION. In accordance with local and national regulations: Dangerous Preparations Directive 1999/45/EC, Detergent Regulation (EC) No 648/2004, Directive 98/8/EC (BPD). Symbol(s) Not dangerous. Most important hazards R-phrase(s) none DETTOL Complete Clean Antibacterial Multi-Action Floor Wipes - Green Apple.doc 1 of 10

2 3. COMPOSITION / INFORMATION ON INGREDIENTS. This product contains: Chemical Name CAS-No EINECS / ELINCS Ethanol EINECS: Benzyl-dimethyl-tetradecylazanium EINECS: 270- chloride REACH-No No information available No information available Proportion (% w/w) Classification CLP Classification 5 % - 10 % F; R11 Flam. Liq. 2 < 0.25 % C;R22-34 Skin Corr. 1B N;R50 (H314) Acute Tox. 4 (H302) Aquatic Acute 1 (H400) Other ingredients may be present as being disclosed by the ingredient declaration on package. 4. FIRST-AID MEASURES. For the full text of the R phrases mentioned in this Section, see Section 16. General advice Skin Contact Eye Contact Inhalation Ingestion Notes to Physician Protection of First-aiders Immediate medical attention is not required. If any symptoms persist, call a physician Show the container and / or this safety data sheet to the doctor in attendance Wash off with soap and water. If skin irritation persists, call a physician. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice if symptoms persist. Move to fresh air. If swallowed, seek medical advice immediately and show this container or label. Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Contains Denatured Ethyl Alcohol. Ingestion may result in ethanol poisoning. Treat symptomatically. Use personal protective equipment. Aggravated Medical Conditions:.. DETTOL Complete Clean Antibacterial Multi-Action Floor Wipes - Green Apple.doc 2 of 10

3 5. FIRE-FIGHTING MEASURES. Flash point: Suitable Extinguishing Media: Not applicable. woven fabric Expressed Liquid: 53 C - 55 C / F F As suitable for the surrounding fire. Unsuitable Extinguishing media (which must not be used for safety reasons): Specific Hazards Arising from the Chemical: Special protective equipment for fire-fighters Precautions for fire-fighting Keep product and empty container away from heat and sources of ignition. Wear self-contained breathing apparatus and protective clothing appropriate for fighting a chemical fire. Standard procedure for chemical fires. 6. ACCIDENTAL RELEASE MEASURES. Personal Precautions: Environmental Precautions: Methods for Cleaning up: Ensure adequate ventilation. Avoid contact with eyes Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. Wear personal protective equipment. Pick up and transfer to properly labelled containers for disposal. Large spills: Contain and collect for later disposal according to local, provincial, state or federal regulations. Methods for Containment: Prevent further leakage or spillage if safe to do so DETTOL Complete Clean Antibacterial Multi-Action Floor Wipes - Green Apple.doc 3 of 10

4 7. HANDLING AND STORAGE. Handling: Storage: Storage Classification Ensure adequate ventilation. Use only according to our recommendations. Avoid contact with eyes. Do not ingest. Wash hands after handling. Keep away from open flames, hot surfaces and sources of ignition Store in original container in areas inaccessable to small children and pets. Keep container tightly closed Keep out of the reach of children. 13 (=Non-combustible solids, following German VCI-concept) 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION. Exposure limits Chemical Name EU Germany TRGS900: Ethanol TWA: 500 ppm TWA: 960 mg/m 3 German mak: France - OEL Belgium - OEL Netherlands - OEL MAK: 500 ppm VLCT: 5000 ppm TWA: 1000 ppm MAK: 960 mg/m 3 Peak: 1000 ppm VLCT: 9500 mg/m 3 TWA: 1907 mg/m 3 STEL: 1900 mg/m 3 TWA: 260 mg/m 3 Peak: 1920 mg/m 3 = 1000 ppm VME Category Ethyl alcohol = 1900 mg/m 3 VME Ethyl alcohol Chemical Name Norway - OEL UK - OES Portugal - OEL Spain - OEL Sweden - OEL Austria - OEL Ethanol TWA: 500 ppm = 3000 ppm STEL TWA: 1000 ppm VLA-ED: 1000 STV: 1000 ppm STEL: 2000 ppm TWA: 950 mg/m Ethyl alcohol ppm VLA-ED: 1910 STV: 1900 mg/m 3 STEL: 3800 LLV: 1000 mg/m 3 mg/m 3 = 5760 mg/m 3 mg/m 3 LLV: 500 ppm MAK: 1000 ppm STEL MAK: 1900 mg/m 3 Ethyl alcohol = 1000 ppm TWA Ethyl alcohol = 1920 mg/m 3 TWA Ethyl alcohol Chemical Name Finland - OEL Italy - OEL Ethanol TWA: 1000 ppm TWA: 1900 mg/m 3 STEL: 1300 ppm STEL: 2500 mg/m 3 DETTOL Complete Clean Antibacterial Multi-Action Floor Wipes - Green Apple.doc 4 of 10

5 Occupational exposure controls Engineering Controls: Ensure adequate ventilation, especially in confined areas. Personal Protective Equipment Respiratory Protection: Eye Protection Hand Protection: No special protective equipment required. Not required under normal use Avoid contact with eyes. Emergency responders should wear full eye and face protection. Not required under normal use Skin and Body Protection: Usual safety precautions while handling the product will provide adequate protection. Hygiene measures When using, do not eat, drink or smoke. Wash hands after use to prevent possible eye irritation from accidental contact with any residue on the hands. Environmental exposure controls Local authorities should be advised if significant spillages cannot be contained 9. PHYSICAL AND CHEMICAL PROPERTIES. Physical State: Appearance: Colour: Odour: ph Solid. Clear liquid on wipes White Characteristic of variant (Bulk Liquid) Boiling Point/Range: Melting point/range Solubility: Specific Gravity / Density [g/ml]: Not applicable Not applicable, liquid impregnated non-woven fabric. Not applicable. Flash Point: Not applicable, solid. (Liquid Phase):53-55 C / F DETTOL Complete Clean Antibacterial Multi-Action Floor Wipes - Green Apple.doc 5 of 10

6 10. STABILITY AND REACTIVITY. Stability Conditions to Avoid: Incompatible Products Hazardous Decomposition Products: Polymerization: Stable under normal conditions. Store away from excessive heat and moisture. Do not mix with other household chemicals Oxides of carbon and unknown organic compounds. Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION. DETTOL Complete Clean Antibacterial Multi-Action Floor Wipes - Green Apple.doc 6 of 10

7 PRODUCT TOXICITY DATA LD 50 Oral: LD 50 Dermal: LC 50 Inhalation (Dust): LC 50 Inhalation (Vapor): ACUTE EFFECTS Eye Irritation Skin Irritation Inhalation Ingestion Sensitization Chronic Effects Specific Effects Carcinogenic Effects: Mutagenic Effects Reproductive Toxicity: Additional Toxicity Information: None expected during normal use. May cause eye irritation upon direct contact with eyes. None expected during normal conditions of use. None expected during normal conditions of use. Health injuries are not known or expected under normal use. Contains denatured ethyl alcohol. May be harmful if swallowed. See Section 4 for First Aid instructions. Not expected to be a skin sensitiser.. Not listed as carcinogenic by OSHA, NTP or IARC... Information given is based on data on the components and the toxicology of similar products. COMPONENT TOXICITY DATA Chemical Name CAS-No LD50 Oral - with units - Rat - mg/kg Ethanol mg/kg ( Rat ) Benzyl-dimethyl-tetradecylazanium chloride mg/kg ( Rat ) LD50 Dermal - With Units - Rat/Rabbit - mg/kg LC50 Inhalation - With units - Rat/Rabbit DETTOL Complete Clean Antibacterial Multi-Action Floor Wipes - Green Apple.doc 7 of 10

8 12. ECOLOGICAL INFORMATION. Ecotoxicity: PRODUCT TOXICITY DATA Aquatic toxicity: This product is not classified as an environmental hazard. COMPONENT TOXICITY DATA Ethanol Freshwater Fish Microtox Water Flea LC50 96 h Oncorhynchus mykiss ml/l LC50 96 h Pimephales promelas >100 mg/l LC50 96 h Pimephales promelas mg/l EC50 = mg/l 5 min LC50 48 h mg/l EC50 24 h mg/l EC50 48 h 2 mg/l Other Information Ozone depletion potential; ODP; (R-11 = 1). Global Warming Potential (GWP):. Additional Ecological Information: Any contained surfactants are ultimately biodegradable according to the EU Detergent Regulation, 648/2004. DETTOL Complete Clean Antibacterial Multi-Action Floor Wipes - Green Apple.doc 8 of 10

9 13. DISPOSAL CONSIDERATIONS. Disposal Methods and Containers: Special Precautions for Landfill or Incineration: Contaminated Packaging: Dispose of according to Local, State and Federal regulations. Dispose of empty container in household trash. For bulk quantities dispose of in accordance with local, regional or national requirements. For further information contact your local waste authority. Further information: According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the user based on the application for which the product was used. Packaging and container to be recycled only if emptied completely! EWC waste disposal No: 14. TRANSPORT INFORMATION. General remarks Not classified as dangerous in the meaning of transport regulations. For long distance transport of bulk material or shrunk pallet take into consideration sections 7 and 10. ICAO IATA IMDG/IMO RID ADR ADN Not regulated Not regulated not regulated Not regulated Not regulated Not regulated DETTOL Complete Clean Antibacterial Multi-Action Floor Wipes - Green Apple.doc 9 of 10

10 15. REGULATORY INFORMATION. Chemical Safety Assessment following regulation 1907/2006/EC: Not relevant. In accordance with local and national regulations: Dangerous Preparations Directive 1999/45/EC, Detergent Regulation (EC) No 648/2004, Directive 98/8/EC (BPD). Symbol(s) Not dangerous. R -phrase(s) None S -phrase(s) S 2 - Keep out of the reach of children S46 - If swallowed, seek medical advice immediately and show this container or label 16. OTHER INFORMATION. Text of R phrases mentioned in Section 3 R11 - Highly flammable. R34 - Causes burns. R50 - Very toxic to aquatic organisms. R21/22 - Harmful in contact with skin and if swallowed. This document complements the technical usage instructions but does not replace them. The information contained herein is based on our best current knowledge if the product concerned, and is given in good faith. The attention of recipients is drawn to (amongst other things) the element of risk consequent to use of the product other than that for which it was intended. In no way does this document remove the need of the recipient of the product to fully understand and apply statutory requirements. It is the recipient's sole responsibility to take due precautions relative to the use made of the product. All information contained herein is only to assist the recipient in fulfilling their statutory duty connected with the use of hazardous materials. This list of information must not be considered as exhaustive, and does not exonerate the recipient from taking other precautions described in documents other than those mentioned, concerning the storage and use of the product, for which they remain the sole person responsible. DETTOL Complete Clean Antibacterial Multi-Action Floor Wipes - Green Apple.doc 10 of 10