Conforms to ANSI Z Standard (United States, Canada, Mexico, Brazil). Material Safety Data Sheet Anderol 757

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1 Conforms to ANSI Z Standard (United States, Canada, Mexico, Brazil). Material Safety Data Sheet Anderol 757. Product and company identification Common name Anderol 757 MSDS# AC040 Material use Lubricant. In case of emergency CANUTEC (63) (Canada) CHEMTREC (United States) MSDS authored by Kemika XXI Inc Date of issue 03/3/ Hazards identification Supplier/Manufacturer Anderol Canada Corp. 700 Third Line Oakville, ONT Canada L6J 5A3 Tel (905) Fax (905) Physical state Semi-solid (grease). Odor Mild. Color Amber (Light.) Hazard status This material is classified hazardous under OSHA regulations in the United States, the WHMIS Controlled Product Regulation in Canada, the NOM-08-STPS-2000 in Mexico and Brazil NBR Emergency overview CAUTION! MAY BE HARMFUL IF SWALLOWED. CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS BLOOD, PERIPHERAL NERVOUS SYSTEM. Do not ingest. Wash thoroughly after handling. Routes of entry Dermal contact. Eye contact. Inhalation. Ingestion. Potential acute health effects Eyes Skin Inhalation Ingestion Potential chronic health effects Medical conditions aggravated by overexposure See toxicological information (section ) 3. Name No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. May be harmful if swallowed. Carcinogenic effects Not applicable. Mutagenic effects Not applicable. Teratogenic effects Not applicable. Repeated or prolonged exposure to the substance can produce target organs damage. Composition/information on ingredients United States CAS number Lubricating oils (petroleum), C5-30, Triphenyl phosphate Canada Name CAS number % Lubricating oils (petroleum), C5-30, Triphenyl phosphate % Date of issue 03/3/2006 Page /7

2 Mexico Classification Name UN number IDLH H F R Special CAS number % Lubricating oils (petroleum), C5-30, hydrotreated neutral oil-based Not regulated Triphenyl phosphate UN mg/m Brazil Name CAS number % Lubricating oils (petroleum), C5-30, Triphenyl phosphate See Sections 8, and 4 for details. 4. Eye contact Skin contact Inhalation Ingestion First aid measures Notes to physician Protection of first-aiders 5. Fire-fighting measures Flammability of the product Products of combustion Check for and remove any contact lenses. In case of contact, immediately flush skin with plenty of water for at least 20 minutes while removing contaminated clothing and shoes. Get medical attention if irritation occurs. Wash with soap and water. Get medical attention if irritation occurs. If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms appear. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if symptoms appear. Not available. No action shall be taken involving any personal risk or without suitable training. May be combustible at high temperature. The final products of combustion are carbon oxides and water. Nitrogen, sulfur and metal oxides may also be produced in some cases. Extinguishing media Suitable Use an extinguishing agent suitable for the surrounding fire. Not suitable None known. Special exposure hazards No specific hazard. Special protective Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. 6. Accidental release measures Personal precautions Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment. Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Methods for cleaning up If emergency personnel are unavailable, vacuum or carefully scoop up spilled material and place in an appropriate container for disposal by incineration. Avoid creating dusty conditions and prevent wind dispersal. Date of issue 03/3/2006 Page 2/7

3 7. Handling Storage 8. Handling and storage Do not ingest. Wash thoroughly after handling. Keep container tightly closed. Keep container in a cool, well-ventilated area. Exposure controls/personal protection United States Lubricating oils (petroleum), C5-30, STEL 0 mg/m 3 5 minute(s). Form Mist TWA 5 mg/m 3 8 hour(s). Form Mist OSHA PEL Z2 (United States). STEL 0 mg/m 3 5 minute(s). Form Mist TWA 5 mg/m 3 8 hour(s). Form Mist Triphenyl phosphate ACGIH TLV (United States, /2005). TWA 3 mg/m 3 8 hour(s). Form All forms. NIOSH REL (United States, 2/200). TWA 3 mg/m 3 0 hour(s). Form All forms. OSHA PEL (United States, 8/997). TWA 3 mg/m 3 8 hour(s). Form All forms. Canada Lubricating oils (petroleum), C5-30, STEL 0 mg/m 3 5 minute(s). Form Mist TWA 5 mg/m 3 8 hour(s). Form Mist Triphenyl phosphate ACGIH TLV (United States, /2005). TWA 3 mg/m 3 8 hour(s). Form All forms. Diphenylamine ACGIH TLV (United States, /2005). TWA 0 mg/m 3 8 hour(s). Form All forms. Mexico Lubricating oils (petroleum), C5-30, STEL 0 mg/m 3 5 minute(s). Form Mist TWA 5 mg/m 3 8 hour(s). Form Mist Triphenyl phosphate NOM-00-STPS (Mexico, 9/2000). CCT 6 mg/m 3 5 minute(s). Form All forms. CPT 3 mg/m 3 8 hour(s). Form All forms. Brazil Lubricating oils (petroleum), C5-30, STEL 0 mg/m 3 5 minute(s). Form Mist TWA 5 mg/m 3 8 hour(s). Form Mist Triphenyl phosphate ACGIH TLV (United States, /2005). TWA 3 mg/m 3 8 hour(s). Form All forms. Diphenylamine ACGIH TLV (United States, /2005). TWA 0 mg/m 3 8 hour(s). Form All forms. Engineering measures Personal protection Eye protection No special ventilation requirements. Good general ventilation should be sufficient to control airborne levels. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Safety glasses with side shields. Date of issue 03/3/2006 Page 3/7

4 Skin protection/body Respiratory protection Hand protection. Not applicable. Not applicable. Natural rubber (latex). HMIS Code/Personal B protective equipment Personal protection in case Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSHapproved self-contained breathing apparatus or equivalent and full protective gear. of a large spill Wash hands, forearms and face thoroughly after handling compounds and before eating, smoking and using the lavatory and at the end of the day. Follow good industrial hygiene practice. 9. Physical and chemical properties Physical state Semi-solid (grease). Color Amber (Light.) Odor Mild. Specific gravity 0.87 to 0.92 (Water = ) Flash point Open cup >90 C (374 F)(Cleveland.). 0. Stability and reactivity Stability and reactivity Conditions of instability Incompatibility with various substances Hazardous polymerization Conditions of reactivity. The product is stable. None known. Reactive with oxidizing materials and acids. Will not occur. None known. Toxicological information Toxicity data Product/ingredient name Test Result Route Species Triphenyl phosphate LD50 LD50 LD mg/kg 320 mg/kg >7900 mg/kg Oral Oral Dermal Rat Mouse Rabbit Acute Effects Eyes Skin Inhalation Ingestion Potential chronic health effects Target organs No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. May be harmful if swallowed. Carcinogenic effects Not applicable. Mutagenic effects Not applicable. Teratogenic effects Not applicable. Contains material which may cause damage to the following organs blood, peripheral nervous system. Date of issue 03/3/2006 Page 4/7

5 2. Ecological information Product/ingredient name Triphenyl phosphate Environmental precautions Products of degradation Toxicity of the products of biodegradation Ecotoxicity data Species Period Result Daphnia magna (EC50) Pimephales promelas (LC50) 48 hour(s) mg/l 0.3 mg/l 0.36 mg/l 0.37 mg/l 0.4 mg/l 0.66 mg/l Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. The final products of biodegradation are carbon oxides and water. Nitrogen and sulfur oxides and metal salts may also be produced in some cases. The product itself and its products of degradation are not toxic. 3. Disposal considerations Waste disposal The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. 4. Transport information NAERG Not applicable. Regulatory information UN/ IMDG/ IATA DOT/ TDG Not regulated by any transport mode. 5. Regulatory information United States HCS Classification U.S. Federal regulations Target organ effects TSCA 8(b) inventory All components listed. SARA 302/304/3/32 extremely hazardous substances No products were found. SARA 302/304 emergency planning and notification No products were found. SARA 302/304/3/32 hazardous chemicals Triphenyl phosphate SARA 3/32 MSDS distribution - chemical inventory - hazard identification Triphenyl phosphate Immediate (acute) health hazard Clean Water Act (CWA) 307 No products were found. Clean Water Act (CWA) 3 No products were found. Clean Air Act (CAA) 2 accidental release prevention No products were found. Clean Air Act (CAA) 2 regulated flammable substances No products were found. Clean Air Act (CAA) 2 regulated toxic substances No products were found. Date of issue 03/3/2006 Page 5/7

6 State regulations Pennsylvania RTK Triphenyl phosphate (generic environmental hazard); Diphenylamine (environmental hazard, generic environmental hazard); 2,6-Ditert-butyl-p-cresol (generic environmental hazard) Massachusetts RTK Triphenyl phosphate; Diphenylamine; 2,6-Ditert-butyl-p-cresol; Benzotriazole New Jersey Lithium 2-hydroxystearate; Octadecanoic Acid, 2-Hydroxy-; Triphenyl phosphate; Diphenylamine; 2,6-Ditert-butyl-p-cresol WARNING This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Ingredient name Mexico Classification Health Cancer 0 Reproductive Diphenylamine No. Yes. No. No. Flammability Reactivity Special No significant risk level HAZARD RATINGS 4- Extreme 3- Serious 2- Moderate - Slight 0- Minimal Maximum acceptable dosage level Canada WHMIS (Canada) Not controlled under WHMIS (Canada). CEPA DSL All components listed. This product has been classified in accordance with the hazard criteria of the Canadian CPR, the United States OSHA, the Mexican NOM -08-STPS-2000 and the Brazilian NBR This MSDS contains all the information required by the CPR, OSHA, the American National Standard Institute (ANSI) Z400., NOM -08-STPS-2000 and NBR International lists 6. Other information Label requirements (U.S.A.) This product, (and its ingredients) is (are) listed on national inventories, or is (are) exempted from being listed, Australia (AICS), in Europe (EINECS/ELINCS), in Korea (TCCL), in Japan (METI), in the Philippines (RA6969). MAY BE HARMFUL IF SWALLOWED. CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS BLOOD, PERIPHERAL NERVOUS SYSTEM. Hazardous Material Information System (U.S.A.) HMIS RATING Health * Fire hazard Physical Hazard 0 Personal protection C HAZARD RATINGS 4- Extreme 3- Serious 2- Moderate - Slight 0- Minimal See section 8 for more detailed information on personal protection. National Fire Protection Association (U.S.A.) Health 0 Flammability Reactivity Special Date of issue 03/3/2006 Page 6/7

7 References Responsible name Date of issue Date of previous issue Version ANSI Z400., MSDS Standard, Manufacturer's Material Safety Data Sheet. - 29CFR Part OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 22, No. 2. Registration SOR/88-64, 3 December 987. Hazardous Products Act "Ingredient Disclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules, Clear Language version Official Mexican Standards NOM-08-STPS-2000 and NOM-004-SCT Brazil NBR Mr. Max Naggar 03/3/ /30/ Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue 03/3/2006 Page 7/7