Copper-II-Sulfate-5-Hydrate

Transcription

1 Revised edition: Version: 101 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Copper-II-Sulfate-5-Hydrate Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Industrial application. Animal feed additive Water treatment. Algaecide Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 H302 Cat.: 4 H315 Cat.: 2 H319 Cat.: 2 H410 Cat.: 1 Acute aquatic toxicity, category 1 Hazardous to the aquatic environment, hazard category 1 Acute toxicity (oral), hazard category 4 Skin irritation, category 2 Eye irritation, category 2 Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Very toxic to aquatic life with long lasting effects. Classification according to EC Regulation No. 67/548 or No. 1999/45 Harmful (Xn) R22 Irritating (Xi) R36 Irritating (Xi) R38 Hazardous to the R50 Harmful if swallowed. Irritating to eyes. Irritating to skin. Very toxic to aquatic organisms. 2

2 environment (N) Safety Phrases: R53 Page 2 May cause long-term adverse effects in the aquatic environment Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: GHS07-1 GHS09 Signal word: Hazard designation: Safety designation: H302 H315 H319 H410 P273 P280 P301+P312 P302+P352 P305+P351+P338 P337+P313 P362 Warning Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Very toxic to aquatic life with long lasting effects. Avoid release to the environment. Wear protective gloves/ clothing/ eye/ face protection. If swallowed: Call a poison center or physician if you feel unwell. If on skin: Wash with soap and water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses and continue rinsing. If eye irritation persists: Get medical advice/ attention. Take off contaminated clothing and wash before reuse Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Copper(II)-sulfate-pentahydrate Hazardous Ingredients: Copper(II)-sulfate-Pentahydrate (Xn; R22-36/38-50/53; H ) CAS-Nr: EINECS-Nr: EC-Nr: Additional information: 3

3 Page First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Intoxication symptoms may occur after several hours, therefore a 48 hour medical observation is necessary. Supply fresh air. If required give artificial respiration. In case of complaints or unconsiousness consult a physician. In case of unconsciousness place patient stable in side position for transportation. Remove contaminated clothing immediately. Wash off immediately with plenty of water and soap. If irritation continues consult a physician. Rinse open eyes with plenty of water. In case of discomfort seek medical help After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with plenty of water. Induce vomiting as long as affected person is conscious. Immediately get medical help. Symptoms: No further information available Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: No further information available. Product itself does not burn. Use extinguishing media for surrounding fire Unsuitable extinguishing media: Water Special Hazards arising from the Substance or Mixture Special hazards: Advice for Firefighters Protective equipment: In case of fire: formation of sulfur dioxide and trioxide. Wear self-contained respiratory protective device and full protective gear. Further information: 4

4 Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Page 4 Contaminated extinguishing water and debris should be disposed of according to local regulations Personal precautions: Environmental Precautions Avoid formation of dust, wear protective clothing. Keep spectators away. Ensure adequate ventilation Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water. Contact local authorities if product pollutes soil or vegetation Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Remove remains with water. Take up mechanically and collect in suitable containers for disposal. For information for safe handling see Section 7. Protective clothing, see Section 8. See Section 13 for information on disposal. Provide adequate ventilation. When dissolving: always pour the product into the water. Never pour water into the product Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Avoid contact with skin, eyes and clothing. Do not inhale dust. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Further Information: Store containers in a well ventilated location. Store in tightly sealed containers in a dry and cool room. Observe official regulations on storage and handling of water hazardous substances. Precautionary measures in reference to the general rules concerning fire prevention. 13; Non combustible solids 5

5 7. 3. Specific End Use(s) Page Further information: No further information available. Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): none known Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation in case of dust formation. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Avoid contact with skin, eyes and clothing. Do not inhale dust. In case of formation of dust. Dust mask recommended when very dusty: with particle filter P2. Chemical protective gloves (EN 374 (Europe), F739 (US)). Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material and dexterity. Always seek advice from glove suppliers. Tightly fitting safety goggles (EN 166). Protective clothing, chemical resistant safety shoes Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Avoid contamination of sewage system, open water ways and ground water. Form: crystalline Color: blue 6

6 Odor: odorless Page 6 Odor threshold: ph-value: 4 (50 g/l; 20 C) Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: not determined not applicable not applicable not flammable not determined not determined 10 hpa (20 C) 2.28 g/cm3 (20 C) 288 g/l not determined not determined Splitting of the water of crystallization of the pentahydrate: 30 C (splitting of 2 waters) 110 C (splitting of further 2 waters of crystalliza tion) 250 C, splitting of the water of crystallization of the monohydrate not applicable Product does not present an explosion hazard. Oxidizing properties: Bulk density: Further Information Solubility in solvents: 7

7 Viscosity, kinematic Page Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Stable if used according to specifications. Loss of water of crystallization when heated. Stable if used according to specifications. Thermal decomposition beween C: successive loss of crystal water up to the water-free (anhydrous) product (colorless). Thermal decomposition above 500 C: release of sulfu r dioxide. None known. None known. Contact of aqueous solutions with various metals (iron, zinc, aluminium, ect.): heavy corrosion, formation of sulphur oxide gases. 300 mg/kg (rat) Slight irritant effect. Slight irritant effect Inhalation: 8

8 Page 8 Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Harmful if swallowed. No sensitizing effects known. No data available. No data available. No data available. No data available Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: LC50: < 1 mg/l (96h, fish) Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: Method is not applicable for inorganic substances. No data available. The contents of the preparation do not comply with the criteria for the classification as PBT or vpvb. Harmful for fish and bacteria. Very toxic for water organisms. AOX Value: 9

9 13. Disposal Considerations Waste Treatment Methods Page 9 Product: Dispose of according to official national and local regulations. European Waste Code (EWC): Uncleaned packaging: Dispose of according to official local regulations Waste Code No.: Transport Information UN Number ADR, IMDG, IATA 3077 UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes UMWELTGEFÄHRDENDER STOFF, FEST, N.A.G. (Kupfer(II)-sulfat) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Copper-sulphate) ADR Class: 9 Hazard no.: 9 Classification code: Tunnel no.: M7 E IMDG Class (sea): 9 Hazard no.: 9 EmS No.: F-A,S-F IATA Class: Hazard no.: 9 Packaging Group ADR/RID: IMDG: III III IATA: Environmental Hazards Special Precautions for User III Labelling according ADR/RID: fish and tree Labelling according IMDG: fish and tree Labelled with "P" according 2.10 IMDG: yes Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information 10

10 Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Page 10 Water hazard class: 2, hazardous for water Local regulations on chemical accidents: Employment restrictions: The employment restrictions for young workers in accordance with the Youth Employment Protection Law (94/33/EC) are to be observed Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has not been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.