Bromcresol Green-Methly Red Indicator

Transcription

1 Page 1 (8) SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name 1.2. Relevant identified uses of the substance or mixture and uses advised against Use Not suitable for use in Water analysis No dissuasions as long as the product is used to its purpose Details of the supplier of the safety data sheet Supplier Clemondo AB - Marisol Street address Box HELSINGBORG SVERIGE Telephone Fax Web site marisol@clemondo.se Emergency telephone number Emergency phone number Available outside office hours In case of emergency, call 112 for medical attendance,. Yes SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008, Annex VI Classification Carcinogenicity, hazard category 2 Hazard statements H351 Description The product has been classified by the Regulation (EC) No 1272/2008. For more information on the physical-chemical effects and the health and environmental effects, see section 9-12 of the SDS Label elements GHS labeling of the substance (in accordance with Regulation (EC) No 1272/2008, Annex VI) Pictogram

2 Page 2 (8) Signal word Hazard statements Precaution statements Warning H351 Suspected of causing cancer. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P281 Use personal protective equipment as required. P308 + P313 IF exposed or concerned: Get medical advice/attention Other hazards The product and its ingredients are not expected to be PBT and/or vpvb. SECTION 3: Composition/information on ingredients 3.2. Mixtures Chemical name CAS No. EC No. Concentration Classification R-phrase H-phrase Potassium chloride Methyl red sodium salt >30% - - <5% - Carc. 2, Aquatic Acute 1, Aquatic Chronic 1, Muta H341, H351, H400, H410 Substance additional information Section 16 for the full text of H-phrases mentioned in this section. SECTION 4: First aid measures 4.1. Description of first aid measures No special protective equipment is needed for those providing first aid. Inhalation Skin contact Take the victim into fresh air. Rinse immediately with plenty of water. Remove contaminated clothing. Eye contact Remove any contact lenses. Flush immediately with plenty of temperated water for at least 15 minutes. Seek medical attention if eyeirritation persists. Ingestion Rinse mouth and drink water Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Emergency shower and eye wash facilities must be available at the workplace. SECTION 5: Firefighting measures 5.1. Extinguishing media

3 Page 3 (8) Suitable extinguishing media Unsuitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. The product itself does not burn. None known Special hazards arising from the substance or mixture If involved in a fire, it may emit noxious and toxic fumes Advice for firefighters Special protective equipment for fire-fighters Use gas-tight protective clothing and respiratory protection that works independently of the ambient air. Use personal protective equipment. Other Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Information regarding appropriate equipment see section 8. Provide adequate ventilation. Do not inhale the vapors. Avoid skin / eye contact. Not drink, eat or smoke while handling and use Environmental precautions Prevent significant amounts of the product from entering streams, groundwater or wastewater. For larger spills in water notify waterworks alternative treatment plants. For larger spills that involve the risk of environmental damage contact the responsible within the municipality Methods and material for containment and cleaning up CONTAINMENT: Contain spill with soil, sand or other inert material. CLEANUP: Collected material is hazardous waste. Do not flush with water. Use mechanical handling equipment. Keep in suitable and closed containers for disposal Reference to other sections Reference to Section 8 for protective equipment and section 13 for waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Preventive handling precautions General hygiene Keep out of reach of children. Ensure good ventilation. Do not breathe vapours/dust. Observe normal care to avoid eye and skin contact Conditions for safe storage, including any incompatibilities

4 Page 4 (8) Store sealed in original packaging in a cool, dry and well-ventilated place Specific end use(s) laboratory chemicals SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Technical precaution measures Eye / face protection Safety gloves The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Wash hands before breaks and at the end of workday. safety glasses with side-shields Use chemical resistant gloves complying with EN374. Use protective gloves made of: Butyl rubber or nitrile rubber. IN FULL CONTACT: Glovematerial: Viton. Thickness: 0.70 mm. Breakthrough time: >480 min. IN SPLASH CONTACT: Glovematerial: Nitril. Thickness 0.40 mm. Breakthrough time: >30 min. Other skin protection Respiratory protection Environmental exposure controls Remove and wash contaminated clothing before re-use. Provide adequate ventilation. Avoid breathing dust or vapor. To limit the environmental exposure of the product, the product must be disposed of or incinerated in accordance with local regulations. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance, colour Appearance, physical state Auto-ignition temperature Bulk density Colour Decomposition temperature Evaporation rate Explosive properties Flammability (solid, gas) Flash point 1910 kg/m3 red brown

5 Page 5 (8) Initial boiling point and boiling range Melting point Melting point / freezing point Odour Odour treshold Oxidising properties Partition coefficient: n-octanol / water ph in solution ph value Physical state Relative density Solubility Upper / lower flammability or explosive limits Vapour density Vapour pressure Viscosity 181 C Odorless 9 (5% solution) dry powder Water-soluble 9.2. Other information SECTION 10: Stability and reactivity Reactivity Reactivity Stable under normal conditions Chemical stability Chemical stability Stable under normal conditions Possibility of hazardous reactions Possibility of hazardous reactions Hazardous polymerisation does not occur Conditions to avoid Conditions to avoid Extremes of temperature and direct sunlight.

6 Page 6 (8) Incompatible materials Incompatible materials None known Hazardous decomposition products Hazardous decomposition products No decomposition if stored and applied as directed. SECTION 11: Toxicological information Information on toxicological effects Information on toxicological effects acute toxicity skin corrosion/irritation serious eye damage/irritation Respiratory/skin sensitization germ cell mutagenicity Genotoxicity carcinogenicity reproductive toxicity STOT-single exposure STOT-repeated exposure Harmful if inhaled LD50 Oral For the product itself there are no toxicological data available. H351 Suspected of causing cancer. LD50(Potassium chloride): 2600 mg/kg (rat) SECTION 12: Ecological information Toxicity Acute fish toxicity Acute algae toxicity Acute crustacean toxicity LC50(96h)(Potassium chloride): 920 mg/l (Gambusia affinis) EC50(72h)(Potassium chloride): 2500 mg/l (Selenastrum capricornutum, green algae) EC50(48h)(Potassium chloride): 825 mg/l (Daphnia magna, water flea) Persistence and degradability Bioaccumulative potential

7 Page 7 (8) Mobility in soil Results of PBT and vpvb assessment Results of PBT and vpvb assessment The product and its agents are not expected to be PBT and/or vpvb Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Disposal considerations Packaging Leave for destruction according to local regulations. Emptying: Put the emptied container upside down to drain. Gather the remaining contents, and add to the process where the product is used, or send for special handling. Wait until the bottle is dry. Sort bottle and cap as plastic packaging. If spillage or waste cannot be recycled in-house, contact an approved, licensed contractor. Other Waste code (EWC) laboratory chemicals, consisting of or containing dangerous substances, including mixtures of laboratory chemicals SECTION 14: Transport information UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Environmental hazards The product is not classified as environmentally hazardous Special precautions for user

8 Page 8 (8) Transport in bulk according to Annex II of Marpol and the IBC Code Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code The load is not intended for bulk transport. SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU regulations European Parliament and Council Regulation (EC) No 1907/2006 of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH ), establishing a European Chemicals Agency, amending Directive 1999/45/EC. Repealing Council Regulation ( EEC) No 793 /93 and Commission Regulation (EC) No 1488/ 94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EEC and 2000/21/EC, as amended. Responsibility for managing the risks of substances should lie with the natural or legal persons that manufactures, imports or uses these substances, or who places the products on the market. Information about the application of this Regulation shall be examined by all of the above. Customer shall comply with the instructions followed by the SDS which the manufacturer and the user of these substances developed to assess risks. National regulations Chemical (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009 No 716) (CHIP4). When handling the product, the customer must follow the safety data sheet classification and labeling Chemical safety assessment Chemical safety assessment No chemical safety assessment. SECTION 16: Other information References to key literature and data sources Evaluation methods for classification The statements in this safety data sheet are based on information of our raw material suppliers. The product has been classified by the Regulation (EC) No 1272/2008. Phrase meaning Aquatic Acute 1 - Hazardous to the aquatic environment Acute hazard category 1 Aquatic Chronic 1 - Hazardous to the aquatic environment Chronic hazard category 1 Carc. 2 - Carcinogenicity, hazard category 2 Muta. 2 - Germ cell mutagenicity, hazard category 2 H341 - Suspected of causing genetic defects. H351 - Suspected of causing cancer. H400 - Very toxic to aquatic life. H410 - Very toxic to aquatic life with long lasting effects.