Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Transcription

1 SECTION 1: Identification 1.1. Identification Product form Trade name Other means of identification : Mixtures : : To produce polyurethanes for coatings, elastomers, sealants, resins, castings, adhesives and plastics 1.2. Recommended use and restrictions on use Use of the substance/mixture 1.3. Supplier ALBERDINGK BOLEY INC 6008 West Gate City Boulevard Greensboro, NC USA T F Info@Alberdingkusa.com Emergency telephone number : Polyol component based on castor oil Emergency number : Emergency Contact (24-Hour-Number): Chemtrec or SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. GHS Label elements, including precautionary statements GHS-US labeling No labeling applicable 2.3. Other hazards which do not result in classification 2.4. Unknown acute toxicity (GHS US) SECTION 3: Composition/Information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % GHS-US classification 1,4-butanediol (CAS No) < 10 Acute Tox. 4 (Oral), H302 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. : Rinse eyes with water as a precaution. : Call a poison center/doctor/physician if you feel unwell Most important symptoms and effects (acute and delayed) 4.3. Immediate medical attention and special treatment, if necessary Treat symptomatically. 01/23/2017 EN (English US) Page 1

2 SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media 5.2. Specific hazards arising from the chemical Reactivity : Water spray. Dry powder. Foam. Carbon dioxide. : No reliable data available Special protective equipment and precautions for fire-fighters Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up Other information 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling Safe handling of the gas receptacle Safe use of the product Handling temperature : C Hygiene measures : Take up liquid spill into absorbent material. : Dispose of materials or solid residues at an authorized site. : Good ventilation of the workplace required. : Ensure good ventilation of the work station. Wear personal protective equipment. : (No data available specific to the product). : (No data available specific to the product) Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Maximum storage period : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. :. : Protect against frost. Store in a well-ventilated place. Keep cool. : 6 months Storage temperature : C SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Appropriate engineering controls Appropriate engineering controls Environmental exposure controls : Ensure good ventilation of the work station. : Avoid release to the environment Individual protection measures/personal protective equipment Hand protection: Protective gloves 01/23/2017 EN (English US) 2/5

3 Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Color Odor Odor threshold ph Melting point Freezing point : Liquid : light yellow Boiling point : > C Flash point : > C Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Solubility Log Pow Auto-ignition temperature : characteristic : :. : < 0.1 kpa : Soluble in ethanol. Water: Solubility in water of component(s) of the mixture : 1,4-butanediol: Complete Decomposition temperature : > 250 C Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties Oxidizing properties 9.2. Other information SECTION 10: Stability and reactivity Reactivity No reliable data available Chemical stability Stable under normal conditions Possibility of hazardous reactions : 2600 mpa.s No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials 01/23/2017 EN (English US) 3/5

4 10.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rat LD50 dermal rabbit LC50 inhalation rat (mg/l) ATE US (oral) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard 1525 mg/kg (Rat) > 2000 mg/kg (Rat) > 2000 mg/kg (Rabbit) > 5.1 mg/l/4h (Rat) mg/kg body weight SECTION 12: Ecological information Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. LC50 fish 1 > 1240 mg/l (LC50; 96 h) EC50 Daphnia mg/l (EC50; 48 h) Threshold limit algae mg/l (EC50; 72 h) Persistence and degradability Persistence and degradability ThOD Readily biodegradable in water g O₂/g substance Bioaccumulative potential Log Pow Bioaccumulative potential (OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method) Bioaccumulation: not applicable Mobility in soil Surface tension N/m (20 C) Other adverse effects Effect on the global warming GWPmix comment : No known effects from this product. : No known effects from this product. 01/23/2017 EN (English US) 4/5

5 SECTION 13: Disposal considerations Disposal methods Waste treatment methods SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transportation of Dangerous Goods Transport by sea : Dispose of contents/container in accordance with licensed collector s sorting instructions. Air transport SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR (a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part International regulations CANADA Listed on the Canadian DSL (Domestic Substances List) EU-Regulations Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) National regulations Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the AICS (Australian Inventory of Chemical Substances) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on KECI (Korean Existing Chemicals Inventory) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm SECTION 16: Other information Full text of H-phrases: H302 Harmful if swallowed SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 01/23/2017 EN (English US) 5/5