Safety Data Sheet (NOHSC:2011)

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier Commercial product name: WACKER CATALYST T Relevant identified uses of the substance or mixture and uses advised against Industrial. Use of substance / preparation: Intermediate chemical 1.3 Details of the supplier of the safety data sheet Manufacturer: Wacker Chemie AG Street/POB-No.: Hanns-Seidel-Platz 4 State/postal code/city: D München Telephone: Telefax: Distributor: Wacker Chemie AG Care of Wacker Chemicals Australia Pty Ltd Street/POB-No.: Unit 1 / 35 Dunlop Road State/postal code/city: Mulgrave, Victoria 3170 Telephone: Telefax: Information about the Safety Data Sheet: Telephone Telefax WLCP-MSDS@wacker.com 1.4 Emergency telephone number Emergency information: Regulatory Compliance Manager Emergency response service only (24h): Orica Australia SH&E Shared Services SECTION 2: Hazards identification Classification of the substance or mixture HAZARDOUS SUBSTANCE (according to the criteria of NOHSC). DANGEROUS GOOD (according to the ADG Code). Classification (67/548/EEC, 1999/45/EC): R-Phrase Description R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed. 2.2 Label elements Labelling (67/548/EEC, 1999/45/EC): Xn Harmful R-Phrase Description R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed. S-Phrase S46 Hazard ingredients (labelling EC): Bis(neodecanoyloxy)dioctylstannane 2.3 Other hazards No data are available. Description If swallowed, seek medical advice immediately and show this container or label. Page: 1/8

2 SECTION 3: Composition/information on ingredients Substances not applicable 3.2 Mixtures Chemical characterization (preparation) Organotin compound + Silicic acid ester Hazardous ingredients EC-No. CAS No. Material Content % Warning Label (EC) Symbol R-Phrases* Bis(neodecanoyloxy)dioctylstannane >20 <40 Xn R48/22-53 If the sum of ingredients is less than 100%, the material consists of further ingredients determined not to be hazardous or below their cut-off limits. *Classification codes are explained in section 16. SECTION 4: First aid measures Description of first aid measures General information: Take persons to a safe place. Observe self-protection for first aid. After inhalation: Keep the patient calm. If unconscious place in stable sideways position. Protect against loss of body heat. Seek medical advice and clearly identify substance. After contact with the skin: Wipe off excess material with cloth or paper. Remove contaminated or soaked clothing. Immediately rinse with plenty of soap and water. In serious cases, use emergency shower immediately. In the event of a visible skin change or other complaints, seek medical advice (show label or SDS where possible). After contact with the eyes: Rinse immediately with plenty of water for minutes. Keep eyelids well open to rinse the whole eye surface and eyelids with water. Seek medical advice in case of continuous irritation. After swallowing: If conscious, give several small portions of water to drink. Do not induce vomiting. Seek medical advice and clearly identify substance. 4.2 Most important symptoms and effects, both acute and delayed Any relevant information can be found in other parts of this section. 4.3 Advice for the doctor: No data are available. SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media: water spray, water mist, extinguishing powder, sand, foam, carbon dioxide. Extinguishing media which must not be used for safety reasons: water jet. 5.2 Special hazards arising from the substance or mixture - Page: 2/8

3 5.3 Advice for firefighters Special protective equipment for fire fighting: Use respiratory protection independent of recirculated air. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Wear personal protection equipment (see section 8). Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. Ensure adequate ventilation. 6.2 Environmental precautions Prevent material from entering sewers or surface waters. Inform authorities if substance leaks into surface waters, sewerage or ground. Contain any fluid that runs out using suitable material (e.g. earth). Retain contaminated water/extinguishing water. Dispose of in prescribed marked containers. 6.3 Methods and material for containment and cleaning up Take up mechanically and dispose of according to local/state/federal regulations. Do not flush away with water. For small amounts: Absorb with a liquid binding material such as diatomaceous earth and dispose of according to local/state/federal regulations. Contain larger amounts and pump up into suitable containers. Clean any slippery coating that remains using a detergent / soap solution or another biodegradable cleaner. Further information: Eliminate all sources of ignition. 6.4 Reference to other sections Relevant information in other sections have to be considered. This applies in particular for information given on personal protective equipment (section 8) and on disposal (section 13). SECTION 7: Handling and storage Precautions for safe handling Precautions for safe handling: Ensure adequate ventilation. Reseal opened containers carefully. Precautions against fire and explosion: Take precautionary measures against electrostatic charging. Keep away from open flames, heat and sparks. Cool endangered containers with water. In partly emptied containers formation of explosive mixtures is possible. 7.2 Conditions for safe storage, including any incompatibilities Conditions for storage rooms and vessels: Protect against frost. Make sure there is no possibility of entering the ground. Advice for storage of incompatible materials: not applicable Further information for storage: Keep container tightly closed and store in a cool, well ventilated place. Store in a dry and cool place. Protect against moisture. Minimum temperature allowed during storage and transportation: 0 C Maximum temperature allowed during storage and transportation: 30 C 7.3 Specific end use(s) No data are available. 7.4 Regulations and standards (Australia): Store in accordance with Dangerous Goods (Storage & Handling) Regulations and AS/NZS 4681 The Storage and Handling of Class 9 (miscellaneous) Dangerous Goods and Articles.Also classified as a C1 Combustible Liquid which should be stored in accordance with AS 1940 Storage & Handling of Flammable & Combustible Liquids. SECTION 8: Exposure controls/personal protection 8. Page: 3/8

4 8.1 Control parameters Maximum airborne concentrations at the workplace: CAS No. Material Type mg/m 3 ppm Dust fract. Fibre/m 3 Tin compounds (organic) ES_AU Propanol OEL Propanol ES_AU Aerosol - respirable fraction AGW The aerosol limit specified is a recommendation should aerosol be formed during processing. 8.2 Exposure controls Exposure in the work place limited and controlled General protection and hygiene measures: Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. Do not eat, drink or smoke when handling. Wash hands at the end of work and before eating. Personal protection equipment: Respiratory protection In case of long or strong exposure: gas mask filter A. Hand protection Protective gloves made of butyl rubber, nitrile rubber protective gloves. At any sign of decay or chemical permeability remove gloves immediately and replace. Gloves suitable for up to 60 minutes' use. The selection of appropriate gloves not only depends on the material, but also on other quality characteristics, and may vary depending on the manufacturer. Please observe information from your glove supplier in terms of permeability and breakthrough time. Eye protection tight fitting protective goggles. Skin protection protective clothing Exposure to the environment limited and controlled Prevent material from entering surface waters and soil. Observe local waste water bye-laws for organo tin and tin compounds. Do not introduce large amounts into purification plants Specific notes (Australia): Select and use respirators in accordance with AS1715/1716. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties General information: Physical state / form...: liquid Colour...: colourless Odour...: slight Important information about the protection of health, safety and the environment: Property: Value: Method: Melting point / melting range...: not determined Boiling point / boiling range...: C at 1013 hpa Flash point...: 70 C (ISO 2719) Ignition temperature...: > 240 C (DIN 51794) Lower explosion limit (LEL)...: not applicable Upper explosion limit (UEL)...: not applicable Vapour pressure...: approx. 1 hpa at 20 C Density...: approx g/cm³ at 25 C (DIN 51757) Water solubility / miscibility...: virtually insoluble ph-value...: not applicable Viscosity (dynamic)...: approx. 2 mpa.s at 23 C Page: 4/8

5 9.2 Other information Re 9.2 solubility in water: Hydrolytic decomposition occurs. Hydrolysis products reduce the flash point. Thermal decomposition...: not applicable SECTION 10: Stability and reactivity Reactivity; Chemical stability; Possibility of hazardous reactions If stored and handled in accordance with standard industrial practices no hazardous reactions are known. Relevant information can possibly be found in other parts of this section Conditions to avoid moisture 10.5 Incompatible materials Reacts with: water, basic substances and acids. Reaction causes the formation of: alcohols Hazardous decomposition products If stored and handled properly: none known. Under the effect of humidity, water and protic agents: alcohols. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage / eye irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Page: 5/8

6 Specific target organ toxicity (repeated exposure) Aspiration hazard Further toxicological information Product(s) of hydrolysis: Risk of serious damage to eyes. SECTION 12: Ecological information Toxicity No data known Persistence and degradability Product(s) of hydrolysis: propanol and silicic acid Bioaccumulative potential Bioaccumulation is not excluded Mobility in soil No data known Other adverse effects none known SECTION 13: Disposal considerations Waste treatment methods Material Recommendation: Dispose of according to regulations by incineration in a special waste incinerator. Observe local/state/federal regulations Uncleaned packaging Recommendation: Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used. Observe local/state/federal regulations. Uncleaned packaging should be treated with the same precautions as the material. SECTION 14: Transport information UN number; UN proper shipping name; Transport hazard class(es); Packing group Land transport ADG Code (road and rail):: Valuation...: Hazardous product 14.1 UN no....: Proper Shipping Name...: Environmentally hazardous substance, liquid, n.o.s..(contains dioctyl tin compounds) 14.3 Class...: Packaging Group...: III HazChem Code...: 3Z Page: 6/8

7 Further information...: Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082 are not subject to the ADG Code when transported by road or rail in (a) packagings; (b) IBCs; or (c) any other receptacle not exceeding 500 kg(l). Transport by sea IMDG-Code: Valuation...: Hazardous product 14.1 UN no....: Proper Shipping Name...: Environmentally hazardous substance, liquid, n.o.s..(contains dioctyl tin compounds) 14.3 Class...: Packaging Group...: III Air transport ICAO-TI/IATA-DGR: Valuation...: Hazardous product 14.1 UN no....: Proper Shipping Name...: Environmentally hazardous substance, liquid, n.o.s..(contains dioctyl tin compounds) 14.3 Class...: Packaging Group...: III 14.5 Environmental hazards Hazardous to the environment: yes Marine Pollutant (IMDG): yes 14.6 Special precautions for user Relevant information in other sections have to be considered Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Bulk transport in tankers is not intended. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National and local regulations must be observed. For information on labelling please refer to section 2 of this document Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) Australia: Poisons Schedule number: No Poisons Schedule number allocated Other international regulations Details of international registration status: Listed on or in accordance with the following inventories: EINECS - Europe ECL - Korea ENCS - Japan AICS - Australia IECSC - China DSL - Canada PICCS - Philippines TSCA - USA Page: 7/8

8 SECTION 16: Other information Material The details in this document are based on the state of our knowledge at the time of revision. They do not constitute an assurance of the described product properties in terms of statutory warranty requirements. The providing of this document to a recipient does not relieve the recipient of his or her responsibility toward compliance with all laws and stipulations applicable to the product. This applies in particular to the further sale or distribution of the product or substances or items containing the product, in other jurisdictions and with regard to the protection of third-party intellectual property rights. If the described product is processed or mixed with other substances or materials, the details stated in this document cannot be conferred to the resultant new product unless this has been expressly mentioned. If the product is repackaged, the recipient is obligated to additionally provide the required safety-related information. All deliveries are subject to the WACKER SILICONES Health Care Policy, which is available at Further information: Vertical lines in the left-hand margin indicate changes compared with the previous version. This version supersedes all previous versions. R-Phrase Description R48/22 R53 Harmful: danger of serious damage to health by prolonged exposure if swallowed. May cause long-term adverse effects in the aquatic environment Glossary of Terms: CAS No. - Chemical Abstracts Service Registry Number UN No. - United Nations Dangerous Goods Number ADG Code - Australian Dangerous Goods Code for the Transport of Dangerous Goods by Road & Rail IMDG Code - International Maritime Dangerous Goods Code IATA Regs - International Air Transport Association (IATA) Dangerous Goods Regulations NOHSC - Australian National Occupational Health and Safety Commission (Note: NOHSC documents are now published by the ASCC) ASCC - Australian Safety & Compensation Council OEL - Occupational exposure limit in Great Britain AGW - Occupational exposure limit in Germany ES_AU - Occupational exposure limit in Australia - End of Safety Data Sheet - Page: 8/8