SAFETY DATA SHEET. Emergency Assistance Chemtrec Serious eye damage/eye irritation

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Product code 379 Recommended use Recommended restrictions IN-SPEC WAVELENGTH VERIFICATION STANDARD, SAMARIUM OXIDE professional, scientific and technical activities: scientific research and development ne known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name GFS Chemicals, Inc. Address P.O. Box 245 Powell, OH United States Telephone Phone Toll Free Fax Website Emergency phone number Emergency Assistance Chemtrec Hazard(s) identification Physical hazards t classified. Health hazards Skin corrosion/irritation Serious eye damage/eye irritation Environmental hazards t classified. OSHA defined hazards t classified. Category 2 Category 1 Label elements Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Danger Causes skin irritation. Causes serious eye damage. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Store away from incompatible materials. Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. ne known. ne. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % WATER < 90* SAMARIUM PERCHLORATE < 20* 1 / 7

2 Chemical name Common name and synonyms CAS number % PERCHLORIC ACID < 5* *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information Move to fresh air. Call a physician if symptoms develop or persist. Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Rinse mouth. Get medical attention if symptoms occur. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Skin irritation. May cause redness and pain. Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions Specific methods General fire hazards 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. unusual fire or explosion hazards noted. Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section of the SDS. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Do not get this material in contact with eyes. Avoid contact with eyes, skin, and clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, including any incompatibilities. Exposure controls/personal protection Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). Occupational exposure limits exposure limits noted for ingredient(s). Biological limit values biological exposure limits noted for the ingredient(s). 2 / 7

3 Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield. Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Wear appropriate chemical resistant gloves. Wear appropriate chemical resistant clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold ph Clear. Liquid. Liquid. Pale yellow. Odorless. Melting point/freezing point 32 F (0 C) estimated Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) 212 F (100 C) estimated Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Miscible. Decomposition temperature Viscosity Other information Density Percent volatile Specific gravity 10. Stability and reactivity Reactivity Chemical stability 1.1 g/cm3 estimated 5 % estimated 1.1 estimated The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. 3 / 7

4 Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Hazardous polymerization does not occur. Contact with incompatible materials. Strong oxidizing agents. Toxic gas. 11. Toxicological information Information on likely routes of exposure Inhalation Skin contact Eye contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization adverse effects due to inhalation are expected. Causes skin irritation. Causes serious eye damage. Expected to be a low ingestion hazard. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Skin irritation. May cause redness and pain. Causes skin irritation. Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Causes serious eye damage. This product is not expected to cause skin sensitization. data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity US. National Toxicology Program (NTP) Report on Carcinogens Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard 12. Ecological information Ecotoxicity This product is not expected to cause reproductive or developmental effects. t classified. t classified. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence and degradability data is available on the degradability of this product. Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging data available. data available. other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 4 / 7

5 14. Transport information DOT UN number UN3264 UN proper shipping name Corrosive liquid, acidic, inorganic, n.o.s. (PERCHLORIC ACID) Transport hazard class(es) Class Subsidiary risk - Label(s) Packing group III Special precautions for Read safety instructions, SDS and emergency procedures before handling. user Special provisions IB3, T7, TP1, TP2 Packaging exceptions 154 Packaging non bulk 203 Packaging bulk 241 IATA UN number UN3264 UN proper shipping name Corrosive liquid, acidic, inorganic, n.o.s. (PERCHLORIC ACID) Transport hazard class(es) Class Subsidiary risk - Packing group III Environmental hazards. ERG Code L Special precautions for Read safety instructions, SDS and emergency procedures before handling. user Other information Passenger and cargo Allowed. aircraft Cargo aircraft only Allowed. IMDG UN number UN3264 UN proper shipping name CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (PERCHLORIC ACID) Transport hazard class(es) Class Subsidiary risk - Packing group III Environmental hazards Marine pollutant. EmS F-A, S-B Special precautions for Read safety instructions, SDS and emergency procedures before handling. user Transport in bulk according to t established. Annex II of MARPOL 73/7 and the IBC Code DOT 5 / 7

6 IATA; IMDG 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR One or more components are not listed on TSCA. TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) CERCLA Hazardous Substance List (40 CFR 302.4) t listed. SARA 304 Emergency release notification Superfund Amendments and Reauthorization Act of 196 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - SARA 302 Extremely hazardous substance t listed. SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 6.130) Safe Drinking Water Act (SDWA) US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) t listed. US. Massachusetts RTK - Substance List PERCHLORIC ACID (CAS ) US. New Jersey Worker and Community Right-to-Know Act PERCHLORIC ACID (CAS ) US. Pennsylvania Worker and Community Right-to-Know Law PERCHLORIC ACID (CAS ) US. Rhode Island RTK US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 196 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Canada Domestic Substances List (DSL) n-domestic Substances List (NDSL) 6 / 7

7 Country(s) or region Inventory name On inventory (yes/no)* China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Version # 01 August Yes Disclaimer Revision Information GFS Chemicals cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information in the sheet was written based on the best knowledge and experience currently available. Composition / Information on Ingredients: Ingredients Physical & Chemical Properties: Multiple Properties Transport Information: Proper Shipping Name/Packing Group 7 / 7