ENVIRONMENTAL IMPACT ASSESSMENT REPORT (ALCHEMIE ORGANICS DIVISION) MANUFACTURING OF DYE/DYE INTERMEDIATES & PESTICIDES PRODUCTS

Transcription

1 ENVIRONMENTAL IMPACT ASSESSMENT REPORT OF (ALCHEMIE ORGANICS DIVISION) FOR MANUFACTURING OF DYE/DYE INTERMEDIATES & PESTICIDES PRODUCTS EXISTING SITE PLOT NO. 902 & 923, PHASE -III, GIDC, VAPI, DIST. VALSAD, GUJARAT. PREPARED BY M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT.LTD. Shed No. K -1, 7705/2,3,4 GIDC ESTATE, Ankleshwar Phone: (02646)220293; Fax: (02646) Website: info@jyotiom.com

2 TABLE OF CONTENTS SR. NO. CONTENTS PAGE NO. CHAPTER -1 INTRODUCTION 1.1 PURPOSE OF THE REPORT AND REGULATORY FRAMEWORK IDENTIFICATION OF THE PROJECT AND PROJECT PROPONENT KEY INFORMATION OF PROJECT IMPORTANCE AND JUSTIFICATION OF PROJECT NATURE OF THE PROJECT COST OF THE PROJECTAND TIME OF COMPLETION SITE SELECTION LOCATION OF THE PROJECT SALIENT FEATURES REGULATORY FRAMEWORK SCOPE AND OBJECTIVE OF EIA STUDY STRUCTURE OF EIA REPORT TERMS OF REFERENCE AND ITS COMPLIANCE 1.13 CHAPTER - 2 PROJECT DESCRIPTION 2.1 TYPE OF PROJECT NEED FOR THE PROJECT DETAILS OF PRODUCTS AND RAW MATERIAL DETAILS OF PRODUCT DETAILS OF RAW MATERIAL TRANSPORTATION OF RAW MATERIAL AND FINISHED PROCESS DESCRIPTION MANUFACTURING PROCESS DETAILS OF SOLVENT RECOVERY SYSTEM & ITS 2.64 MANAGEMENT 2.6 RESOURCE REQUIREMENT INFRASTRUCTURE FACILITIES (LAND) WATER REQUIREMENT ENERGY REQUIREMENT UTILITIES 2.72

3 SR. NO. CONTENTS PAGE NO MAN POWER EQUIPMENTS/MACHINERIES POLLUTION POTENTIAL SCENARIO EFFLUENT AND SEWAGE GENERATION GASEOUS EMISSION HAZARDOUS WASTE GENERATION 2.80 CHAPTER - 3 BASELINE ENVIRONMENT STATUS 3.1 INTRODUCTION WINDROSE AIR ENVIRONMENT WATER ENVIRONMENT NOISE ENVIRONMENT SOIL BASELINE DATA LAND USE PATTERNS BIOLOGICAL ENVIRONMENT & SOCIO ECONOMIC 3.26 ENVIRONMENT ECOLOGICAL INFORMATION FOREST FLORA FAUNA SOCIO-ECONOMIC ENVIRONMENT DEMOGRAPHIC DATA WITHIN THE REGION OF INTEREST LITERACY RATE OCCUPATIONAL STRUCTURE EARTHQUAKE VULNERABILITY WIND AND CYCLONE VULNERABILITY 3.51 CHAPTER - 4 IDENTIFICATION AND ASSESSMENT OF IMPACTS 4.1 IDENTIFICATION OF IMPACT PREDICTION AND ASSESSMENT OF IMPACT WATER ENVIRONMENT AIR ENVIRONMENT NOISE ENVIRONMENT LAND ENVIRONMENT 4.19

4 SR. NO. CONTENTS PAGE NO ECOLOGICAL ENVIRONMENT INFRASTRUCTURE AND SERVICES SOCIO-ECONOMIC IMPACT IMPACT MATRIX 4.21 CHAPTER - 5 ENVIRONMENT MONITORING PROGRAM 5.1 POLLUTION MONITORING AND SURVEILLANCE SYSTEM 5.1 CHAPTER -6 QUANTITATIVE RISK ASSESSMENT & DISASTER MANAGEMENT PLAN 6.1 SCOPE OF THE STUDY INTRODUCTION TO RISK ASSESSMENT OBJECTIVES OF RISK ASSESSMENT RISK ASSESSMENT QUALITATIVE RISK ASSESSMENT QUANTITATIVE RISK ASSESSMENT COMMENTS / RECOMMENDATIONS BASED ON CONSEQUENCE 6.59 ANALYSIS SAFETY SYSTEMS/SAFEGUARDS TO REDUCE THE RISK OF 6.59 FIRE, EXPLOSION AND TOXIC RELEASE: 6.5 AREA SPECIFIC RECOMMENDATIONS BASED ON QUALITATIVE RISK ASSESSMENT (SUMMARIZED): DISATER PREPAREDNESS & EMERGENCY MANAGEMENT 6.67 PLAN DEFINING THE NATURE/LEVEL OF EMERGENCY OBJECTIVES OF EMERGENCY MANAGEMENT SYSTEM STRUCTURE OF EMERGENCY MANAGEMENT SYSTEM OCCUPATIONAL HEALTH & SAFETY PROGRAMME OCCUPATIONAL HEALTH HOSPITAL FACILITIES & FACTORY MEDICAL OFFICER FACTORY MEDICAL OFFICER/OHC PERIODIC MEDICAL EXAMINATION DETAILS OF EXISTING OCCUPATIONAL AND SAFETY 6.81 HAZARDS ACTION PLAN FOR THE IMPLEMENTATION OF OHS STANDARDS AS PER OSHAS/USEPA 6.81

5 SR. NO. CONTENTS PAGE NO MEASURES ADOPTED BY COMPANY TO KEEP AIR BORNE 6.81 CONCENTRATION OF HAZARDOUS CHEMICALS BELOW PEL: WORKPLACE MONITORING ARRANGEMENTS FOR 6.82 HAZARDOUS CHEMICALS HEALTH EVALUATION OF WORKERS (EXPOSURE SPECIFIC) ACTION PLAN FOR SAFE HANDLING & SAFETY SYSTEM PLAN AND FUND ALLOCATION TO ENSURE THE 6.84 OCCUPATIONAL HEALTH & SAFETY OF ALL CONTRACT AND CASUAL WORKERS ARRANGEMENTS FOR ENSURING HEALTH AND SAFETY OF 6.86 WORKERS ENGAGED IN HANDLING OF TOXIC MATERIALS MOCK DRILLS TOXIC MANEGEMENT PLAN TREATMENT OF WORKERS AFFECTED BY ACCIDENTAL SPILLAGE CHEMICAL 6.87 CHAPTER- 7 PROJECT BENEFIT 7.1 SOCIO ECONOMIC ACTIVITIES OTHER TANGIBLE BENEFITS EMPLOYMENT POTENTIAL ACTION PLAN BUDGETARY ALLOCATION 7.3 CHAPTER- 8 ENVIRONMENT MANAGEMENT PLAN 8.1 INTRODUCTION AIM AND OBJECTIVE ENVIRONMENTAL MANAGEMENT CELL ENVIRONMENT MANAGEMENT PLAN OPERATIONAL PHASE (A) AIR ENVIRONMENT (B) WATER ENVIRONMENT (C) NOISE ENVIRONMENT (D) LAND ENVIRONMENT (E) GREEN BELT DEVELOPMENT (F) VEHICULAR POLLUTION CONTROL 8.21

6 SR. NO. CONTENTS 8.4.2(G) ENERGY CONSERVATION PROGRAMME (H) BUDGETORY PROVISION PROPOSED FOR ENVIRONMENT POLLUTION CONTROL MEASURES 8.4.2(I) HEALTH AND SAFETY 8.23 CHAPTER- 9 COMPLIANCE OF ENVIRONMENTAL CONDITIONS 9.1 INTRODUCTION SHOW CAUSE NOTICE REF. NO.1- GPCB/CCA-VSD-32/ID: / DATED 27/07/ SHOW CAUSE NOTICE REF. NO. 2-SCN DATED 11/12/ SHOW CAUSE NOTICE REF. NO. 3- SCN DATED 20/04/ SHOW CAUSE NOTICE REF. NO. 4- SCN DATED 10/08/ SHOW CAUSE NOTICE REF. NO. 5- SCN DATED 21/09/ SHOW CAUSE NOTICE REF. NO. 6- GPCB/VSD/ID-22980/ DATED 29/04/ SHOW CAUSE NOTICE REF. NO. 8- SCN DATED 05/08/2014. CHAPTER- 10 EXECUTIVE SUMMARY& CONCLUSION PAGE 10.1 INTRODUCTION LOCATION INVESTMENT INFRASTRUCTURE FACILITIES PROJECT DESCRIPTION NEED FOR THE PROJECT PRODUCTION AND RAW MATERIAL RESOURCE REQUIREMENT POLLUTION POTENTIAL SCENARIO BASELINE ENVIRONMENT STATUS STUDY AREA INCLUDED IN ENVIRONMENTAL SETTING CLIMATE OF THE STUDY AREA AMBIENT AIR QUALITY WATER QUALITY NOISE ENVIRONMENT SOIL LAND USE OF THE STUDY AREA BIOLOGICAL ENVIRONMENT IDENTIFICATION &ASSESSMENTOF IMPACT WATER ENVIRONMENT AIR ENVIRONMENT NOISE ENVIRONMENT 10.7 NO

7 SR. NO. CONTENTS PAGE LAND ENVIRONMENT ECOLOGICAL ENVIRONMENT INFRA STRUCTURE AND SERVICES SOCIO-ECONOMIC IMPACT ENVIRONMENT MONITORING PROGRAM RISK ASSESSMENT AND DISASTER MANAGEMENT PLAN RISK ASSESSMENT DISASTER MANAGEMENT PLAN OCCUPATIONAL HEALTH AND SAFETY MANAGEMENT 10.9 SYSTEM 10.7 PROJECT BENEFITS ENVIRONMENTAL MANAGEMENT PLAN CHAPTER- 11 DISCLOSURE OF CONSULTANT ENGAGED 11.1 SALIENT FEATURES SERVICES PROVIDED BY THE CENTRE OUTSTANDING ACHIVEMENTS STATUS OF NABET ACCREDITATION DECLARATION BY CONSULTANT 11.4 NO. LIST OF TABLES TABLE NO. TABLE NAME PAGE NO. CHAPTER -1 INTRODUCTION 1.1 DETAILS REGARDING DIRECTORS LIST OF PRODUCTS AS PER CCA LIST OF PRODUCTS AS PER PROPOSED SCENARIO CAPITAL COST PROJECTION SALIENT FEATURES OF THE PROJECT SITE STRUCTURE OF EIA REPORT TERMS OF REFERENCE PROPOSED BY UNIT ADDITIONAL TOR GIVEN BY INDUSTRIAL COMMITTEE OF MOEF 1.15 CHAPTER - 2 PROJECT DESCRIPTION 2.1 PROPETIES OF PRODUCTS DETAILS OF EXISTING RAW MATERIALS CONSUMPTION DETAILS OF PROPOSED RAW MATERIALS CONSUMPTION DETAILS OF RAW MATERIAL SOURCE AND METHOD OF 2.12

8 TABLE NO. TABLE NAME PAGE NO. TRANSPORTATION 2.5 DETAILS OF SOLVENT RECOVERY DETAILS OF INFRASTRUCTURE LAND USE BREAK UP OF TOTAL PLOT AREA DETAILS OF WATER CONSUMPTION FUEL CONSUMPTION REQUIREMENT ENERGY REQUIREMENT DETAILS OF EXISTING UTILITIES DETAILS OF PROPOSED UTILITIES MAN POWER REQUIREMENT DETAILS OF EQUIPMENT AND MACHINERIES DETAILS OF WASTE WATER GENERATION DETAILS OF FLUE GAS EMISSION DETAILS OF PROCESS EMISSION DETAILS OF PROCESS GASES SEND TO SRUBBER DETAILS OF HAZARDOUS WASTE GENERATION 2.80 CHAPTER - 3 BASELINE ENVIRONMENT STATUS 3.1 LIST OF MAJOR INDUSTRIES IN THE VAPI METEOROLOGICAL DATA DETAILS OF SAMPLING LOCATION OF AMBIENT AIR 3.7 QUALITY MONITORING 3.4 AMBIENT AIR QUALITY STATUS OF STUDY AREA DETAILS OF GROUND WATER MONITORING LOCATIONS DETAILS OF SURFACE WATER MONITORING LOCATIONS METHOD OF ANALYSIS WATER QUALITY PARAMETERS (GROUNDWATER 3.17 SOURCES) 3.9 WATER QUALITY PARAMETERS (SURFACE WATER 3.19 SOURCES) 3.10 CPCB RECOMMENDATIONS FOR COMMUNITY NOISE 3.20 EXPOSURE (1989) 3.11 NOISE LEVEL DATA LOCATIONS OF SOIL QUALITY MONITORING WITH RESPECT TO THE PROJECT SITE 3.22

9 TABLE NO. TABLE NAME PAGE NO PARTICLE SIZE DISTRIBUTION OF SOIL SAMPLES LAND USE STATISTICS OF THE STUDY AREA LIST OF FLORA LIST OF FAUNA DEMOGRAPHIC DATA LITERACY RATE WITHIN 10 KM RADIAL DISTANCE 3.36 OF STUDY AREA 3.19 OCCUPATIONAL STRUCTURE DISTRIBUTION OF WORKERS 3.46 CHAPTER - 4 IDENTIFICATION AND ASSESSMENT OF IMPACTS 4.1 DETAILS OF PROCESS EMISSION CONCENTRATION OF PM CONCENTRATION OF NO X CONCENTRATION OF HCL AND CL CONCENTRATION OF HBr AND Br ENVIRONMENT IMPACT MATRIX (WITH MITIGATION 4.23 MEASURES) 4.7 CUMULATIVE IMPACT CHART 4.25 CHAPTER - 5 ENVIRONMENT MONITORING PROGRAM 5.1 EMISSION MONITORING PLAN 5.1 CHAPTER -6 RISK ASSESSMENT 6.1 DETAILS OF HAZARDOUS RAW MATERIALS HAZARDOUS PROPERTIES OF CHEMICALS RISK MATRIX FOR QUALITATIVE RISK ASSESSMENT RISK MATRIX FOR QUALITATIVE RISK ASSESSMENT STORAGE AND HANDLING OF TOXIC LIQUID CHEMICAL STORAGE AND HANDLING OF FLAMMABLE 6.14 CHEMICALS(LIKE TOLUNE, XYLENE, MCB, etc.) 6.7 STORAGE AND HANDLING OF SOLID CHEMICALS STORAGE AND HANDLING OF HYDROCHLORIC ACID 6.18 (30%) 6.9 STORAGE AND HANDLING OF CAUSTIC SODA LYE (48%) DAMAGES TO HUMAN LIFE DUE TO HEAT RADIATION 6.22

10 TABLE NO. TABLE NAME PAGE NO EFFECTS DUE TO INCIDENT RADIATION INTENSITY WEATHER DATA USED FOR THE STUDY SCENARIOS IDENTIFIED FOR CONSEQUENCE ANALYSIS SCENARIO#1 RELEASE OF TOLUENE (FULL BORE 6.27 RUPTURE OF UNLOADING HOSE 2 ) 6.15 SCENARIO#2 RELEASE OF MONO CHLOROBENZENE SCENARIO#3 RELEASE OF XYLENE (FULL BORE 6.34 RUPTURE OF UNLOADING HOSE 2 ) 6.17 SCENARIO#4 RELEASE OF HYDROGEN GAS SCENARIO#5 RELEASE OF TRIETHYL AMINE SCENARIO#6 RELEASE OF CHLORINE RESULTS SCENARIO#7 RELEASE OF BROMINE RESULTS SCENARIO#8 RELEASE OF AMMONIA FROM AMMONIA 6.52 CYLINDER STORAGE AREA 6.24 RESULTS SCENARIO#9 RELEASE OF DIMETHYL SULPHATE FROM 6.54 PUMP DISCHARGE LINE 6.26 RESULTS FLASH FIRE SCENARIOS LATE POOL FIRE SCENARIOS JET FIRE SCENARIOS EXPLOSION OVERPRESSURE SCENARIOS TOXIC RELEASE SCENARIOS: (FOR Cl2 & NH3) TOXIC RELEASE SCENARIOS :( FOR Br & DIMETHYL 6.58 SULPHATE) 6.33 SAFETY PRECAUTIONS RIGHT RESPIRATOR IS USED AS PER THE CHLORINE 6.64 CONCENTRATION 6.35 FIRE PROTECTION EQUIPMENTS DETAILS OF FIRE EXTINGUISHERS LIKELY ONSITE EMERGENCIES LIKELY OFF SITE EMERGENCIES 6.69

11 TABLE NO. TABLE NAME PAGE NO. CHAPTER- 7 PROJECT BENEFIT 7.1 ACTION PLAN 7.2 CHAPTER- 8 ENVIRONMENT MANAGEMENT PLAN 8.1 DETAILS OF CONTROL MEASURES FOR FLUE GAS 8.4 EMISSION AND PROCESS EMISSION 8.2 DETAILS OF CONTROL MEASURES FOR FUGITIVE 8.5 EMISSION 8.3 DETAILS OF EXISTING ETP UNITS DETAILS OF PROPOSED ETP UNITS DETAILS OF POWER COSUMPTION DETAILS OF ETP TANKS DETAILS OF ETP PUMPS EXISTING CHARACTERISTICS OF WASTEWATER BEFORE 8.14 TREATMENT & AFTER TREATMENT 8.9 EXPECTED CHARACTERISTICS OF WASTEWATER BEFORE 8.14 TREATMENT & AFTER TREATMENT 8.10 DETAILS OF DIFFERENT STP UNITS DETAILS OF CONTROL MEASURES FOR EFFLUENT AND 8.16 SEWAGE GENERATION 8.12 DETAILS OF CONTROL MEASURES FOR NOISE POLLUTION DETAILS OF HAZARDOUS WASTE GENERATION & 8.19 DISPOSAL MODE 8.14 DETAILS OF HAZARDOUS WASTE STORAGE CAPITAL COST AND RECURRING COST FOR ENVIRONMENT CONTROL MEASURES 8.22

12 LIST OF FIGURES FIGURE NO. FIGURE NAME PAGE NO. CHAPTER -1 INTRODUCTION 1.1 LOCATION OF PROJECT SITE GOOGLE EARTH OR SATELLITE IMAGE OF PROJECT 7 LOCATION WITH IN 5 KM 1.3 GOOGLE EARTH OR SATELLITE IMAGE OF PROJECT 8 LOCATION WITH IN 0.5 KM 1.4 IMAGE OF ALL FOUR CORNERS OF THE SITE SITE PLAN OF MEGHNAGAR 10 CHAPTER - 2 PROJECT DESCRIPTION 2.1 WATER BALANCE DIAGRAM (EXISTING) WATER BALANCE DIAGRAM (PROPOSED EXPANSION) 2.70 CHAPTER - 3 BASELINE ENVIRONMENT STATUS 3.1 WIND ROSE DIAGARM FOR PEROID OF MARCH TO MAY WIND CLASS FREQUENCY DISRTIBUTION LOCATION OF AMBIENT AIR QUALITY MONITORING 3.7 STATIONS 3.4 LOCATION OF GROUND WATER QUALITY MONITORING 3.13 STATIONS 3.5 LOCATION OF SURFACE WATER QUALITY MONITORING 3.14 STATIONS 3.6 LOCATION OF NOISE MONITORING STATIONS LOCATION OF SOIL MONITORING STATIONS LAND COVER MAP WITH VILLAGE LOCATION MAP OF RESERVED FOREST EARTHQUAKE VULNERABILITY MAP WIND AND CYCLONE VULNERABILITY MAP 3.51 CHAPTER - 4 IDENTIFICATION AND ASSESSMENT OF IMPACTS 4.1 IMPACT NETWORK ON AIR ENVIROENMENT IMPACT NETWORK ON NOISE ENVIRONMENT IMPACT NETWORK ON WATER ENVIRONMENT IMPACT NETWORK ON GROUND WATER ENVIRONMENT 4.5

13 FIGURE FIGURE NAME PAGE NO. NO. 4.5 IMPACT NETWORK ON SOCIO-ECONOMIC AND CULTURAL 4.6 ENVIRONMENT 4.6 IMPACT NETWORK ON LAND ENVIRONMENT ISOPLETHS OF NO X (SITE COORDINATES 0, 0) ISOPLETHS OF PM (SITE COORDINATES 0, 0) ISOPLETHS OF HCl (SITE COORDINATES 0, 0) ISOPLETHS OF Cl 2 (SITE COORDINATES 0, 0) ISOPLETHS OF HBr (SITE COORDINATES 0, 0) ISOPLETHS OF Br (SITE COORDINATES 0, 0) 4.18 CHAPTER -6 RISK ASSESSMENT 6.1 DETAILS OF STORAGE FACILITIES RISK CONTOURS FOR FLASH FIRE RISK CONTOURS FOR VAPOUR CLOUD EXPLOSION 6.28 (OVERPRESSURE RESULTS) 6.4 RISK CONTOURS FOR LATE POOL FIRE RISK CONTOURS FOR FLASH FIRE RISK CONTOURS FOR VAPOUR CLOUD EXPLOSION 6.32 (OVERPRESSURE RESULTS) 6.7 RISK CONTOURS FOR LATE POOL FIRE RISK CONTOURS FOR FLASH FIRE RISK CONTOURS FOR VAPOUR CLOUD EXPLOSION 6.36 (OVERPRESSURE RESULTS) 6.10 RISK CONTOURS FOR LATE POOL FIRE RISK CONTOURS FOR FLASH FIRE; RISK CONTOURS FOR VAPOUR CLOUD EXPLOSION 6.40 (OVERPRESSURE RESULTS) 6.13 RISK CONTOURS FOR JET FIRE RISK CONTOURS FOR TOXIC DISPERSION OF TEA FOR LEL 6.43 CONCENTRATON 6.15 RISK CONTOURS FOR FLASH FIRE RISK CONTOURS FOR VAPOUR CLOUD EXPLOSION 6.44 (OVERPRESSURE RESULTS) 6.17 RISK CONTOURS FOR LATE POOL FIRE RISK CONTOURS FOR CHLORINE (FOR IDLH 6.46

14 FIGURE FIGURE NAME PAGE NO. NO. CONCENTRATIONS: 10 PPM) 6.19 RISK CONTOURS FOR CHLORINE (FOR LC CONCENTRATIONS: 293 PPM) 6.20 RISK CONTOURS FOR DISPERSION OF BROMINE FOR IDLH & 6.49 LC50 CONCENTRATIONS: 6.21 RISK CONTOURS FOR DISPERSION OF AMMONIA FOR IDLH: PPM 6.22 RISK CONTOURS FOR DISPERSION OF AMMONIA FOR LC50: PPM 6.23 RISK CONTOURS FOR DISPERSION OF DMS FOR IDLH & LC CONCENTRATIONS 6.24 ON SITE/OFF SITE DISASTER CONTROL PLAN 6.70 CHAPTER- 8 ENVIRONMENT MANAGEMENT PLAN 8.1 FLOW DIAGRAM OF ENVIRONMERNTAL MANAGEMENT 8.2 CELL 8.1 EXISTING EFFLUENT TREATMENT PLANT FLOW DIAGRAM EFFLUENT TREATMENT PLANT FLOW DIAGRAM (PROPOSED 8.10 EXPANSION) 8.3 FLOW DIAGRAM OF STP 8.15 LIST OF ANNEXURE ANNEXURE ANNEXURE NAME NO. I COPY OF EC-JULY 2003 II COPY OF EC-JULY 2008 III COMPLIANCE REPORT OF EC (FROM BHOPAL) DOCUMENT IV COPY OF CCA V CCA COMPLIANCE VI GPCB REPORTS OF WATER AND WASTE WATER VII THIRD PARTY MONITORING REPORT

15 ANNEXURE NO. VIII IX X(A) X(B) X(C) X(D) X(E) XI XII XIII XIV XV XVI XVII XVIII XIX XX XXI XXII XXIII XXIV XXV XXVI XXVII XXVIII XXIX XXX ANNEXURE NAME QUESTIONNAIRE PLANT LAYOUT AND SITE PLAN SITE LOCATION MAPS TOPOSHEET OF PROJECT SITE 10km RADIAS DISTANCE FROM THE PROJECT SITE CO-originate SHOW LATTITUDE LONGITUDE OF FOUR CORNER GOOGLE MAP -EARTH COPY OF TOR LAND POSSESSION DOCUMENT WATER CONSUMPTION LETTER (ADDITIONAL) PHOTOGRAPHS OF PLANT AREAS METEOROLOGICAL DATA MONITORING DATES FOR AMBIENT AIR MONITORING SOP FOR HANDLING HAZARDOUS WASTE ENVIRONMENT HEALTH SAFETY POLICY DRAWINGS OF SCRUBBERS MEMBERSHIP CERTIFICATE OF TSDF SITE MSDS OF PRODUCTS AND RAW MATERIALS COMPLIANCE REPORT OF EXISTING UNIT BY MOEF, BHOPAL. SHOW CAUSE NOTICE AND REPLY. GUJARAT HIGH COURT STAY ORDER. UNDERTAKING OF JYOTI OM / CONSULTANT WORKER REPORTS UNDERTAKING NO BOND PESTISIDES PROVISIONAL MEMBER CERTIFICATE FROM RSPL FOR WASTE MIX PROCESSING FACILITY RECOMMENDATION LETTER SUBMITED TI SPCB FOR PROPOSED ACTIVITY EXECUTIVE SUMMARY

16 Chapter -1 INTRODUCTION 1.1 PURPOSE OF THE REPORT AND REGULATORY FRAMEWORK M/s. Aarti Industries Ltd. (Alchemie Organics Division) is located at plot no.902, 923, GIDC Estate, Phase-III, Vapi, and District: Valsad, Gujarat. The unit has valid CCA order AWH-53342, issue on dated 15/04/2013 for manufacturing of Dye/Dye intermediates & Pesticides products. Existing manufacturing involves unit operations like hydrogenation, diazotization, bromination, condensation and chlorination products. Total existing production capacity is 5595 MT/Year. The unit has proposed expansion for manufacturing of products by hydrogenation, diazotization, bromination, condensation and chlorination. Also, the unit has proposed new products based on hydrolysis. After expansion, total production capacity will be MT/Year. The unit has proposed expansion of existing unit. The products proposed by the unit fall in the schedule attached to the EIA Notification, i.e. Project No. 5(b) &5(f), Dye/Dye intermediates & Pesticides products. Since the project is established in industrial Estate, Vapi, and it is located within 10 Km distance from interstate boundary of Gujarat & Union Territories (Daman and Dadar& Nagar haveli) so it is classified as Category A project. Public hearing is not applicable to this expansion project as the unit is located in GIDC notified area. Environment Clearance will be evaluated by the Industrial committee of MoEF, New Delhi. The purpose of this report is to: Establish a pre-project baseline with respect to environmental indicators. Identify environment related impacts Evaluate safety related risk factors associated with project Propose appropriate mitigation measures for minimizing the adverse impacts to the extent possible Suggest Environment Management Plan Recommend Risk Management Plan M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 1. 1

17 This report is also made in the overall frame work of the Environmental Impact Assessment (EIA) Notification dated 14 th September 2006 (and subsequent amendments to the same) issued by the Ministry of Environment and Forests (MoEF), by providing required information with regards to the project as mentioned in the Terms of Reference issued by the Industrial committee of MoEF, New Delhi. 1.2 IDENTIFICATION OF THE PROJECT AND PROJECT PROPONENT PROJECT PROPONENT M/s. Aarti Industries Ltd. (Alchemie Organics Division) is one of company of Aarti Group. This group has more than 16 chemical industries spread over Gujarat, Madhya Pradesh and Maharashtra. The company has well established Research and Development division situated at GIDC, Vapi. The group has developed strong environment management cell and possess in house capabilities to undertake implementation of cleaner production technologies, green chemistry, zero liquid discharge systems, etc. besides carrying out environment impact assessments. Details regarding Directors are given in Table 1.1. TABLE: 1.1 DETAILS REGARDING DIRECTORS Sr. Name of Designation Address Telephone No. No. Directors 1. Shri. Rajendra Chairman& 1401, Antriksh V. Gogri Managing Director Murar road, Mulund (w), Mumbai Shri. Rashesh Vice chairman& 601,Antriksh C. Gogri Managing Director Morar Road, Mulund (W) Mumbai Shri. Parimal H. Desai Whole-Time Director A/ th Floor, Runwal Heights, L.S.B. Marg, Mulund (W) M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 1. 2

18 Sr. No. Name of Directors 4. Shri. Manoj M. Chheda 5. Shri. Kirit R. Mehta 6. Smt. Hetal GOGRI GALA 7. Shri. Renil R. Gogri Designation Address Telephone No. Mumbai Whole-Time Dunhill Villa CO Director OP. HSG. SOC. Ltd., Besant Road, Santa Cruz (W), Mumbai Whole-Time 10, Pushpendra Director Mension, Phiroj shah Mehta Road, Santa Cruz (W), Mumbai Whole - Time 558-B, Gopal Sadan, Director Block no. 801, 8 TH Floor, Jamshed Road, Matunga(E), Mumbai Whole - Time 1401, Antriksh Director Murar Road Mulund (W) Mumbai DETAILS OF EC The unit obtained first Environment Clearance [file no.j-11011/79/2002-ia II (I)] in July, 2003 from Ministry of Environment & Forests. Copy of Environment Clearance file no.j-11011//79/2002-ia II (I) is attached as annexure-i. After that the unit obtained second Environment Clearance [file no.j-11011/497/2008- IA II (I)] in 2008 from MOEF but Environment Clearance was not converted to any project and is now lapsed. Copy of Environment Clearance (file no.j11011/497/2008- IA II (I)) is attached as annexure-ii. Report on status of compliance of the conditions stipulated in the Environment Clearance file no. J-11011/79/2002-IA II (I)) from Regional Office of Ministry of Environment and Forest, Bhopal is attached as annexure-iii. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 1. 3

19 DETAILS OF CONSENT The unit has valid CCA order no. AWH-53342, issued on date 15/04/2013 for manufacturing of Dye/Dye intermediates & Pesticides products. The copy of CCA is attached as annexure-iv. Report on status of compliance of the conditions stipulated in the CCA order no. AWH is attached as annexure V. Also recent monitoring report of water quality; process emission from Regional Office of Gujarat Pollution Control Board is attached as annexure-vi. Third party monitoring report is attached as annexure-vii. Earlier questionnaire for industry sector is attached as annexure-viii. Existing manufacturing involves hydrogenation, diazotization, bromination, condensation and chlorination products. The list is given in Table 1.2. TABLE: 1.2 LIST OF PRODUCTS AS PER CCA Sr. Name of Products Quantity As Per Consent No. (MT / Year) 1. DCBH (Di Chloro Benzene Hydro chloride) ,3/2,5 DCP (Di Chloro Phenol) ,4,5 Tri Flouro Bromo Benzene Para Flouro Phenol (PFP) ,5 Di Chloro Nitro Benzene Quinal phose (TECH) (Diethyl 2-Hydroxy Thio phosphoryl Chloride) ,3 DFB( Di Flouro Benzene) Bromo 4 Flouro Acetanilide Di Chloro Bromo Benzene ,5/2,6 DFA (Di Flouro Aniline) ,6 Di Chloro Para Nitro Aniline Ortho Chloro Aniline Acetic Acid 26 Total 5595 By Products: 14. Sulphuric Acid (70%) Dilute Sulphuric Acid HBr Solution 87.5 Total M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 1. 4

20 The unit has proposed expansion for manufacturing of products by hydrogenation, diazotization, bromination, condensation and chlorination. Also, the unit has proposed new products based on hydrolysis. List of proposed new products is mentioned in Table no.1.3 TABLE: 1.3 LIST OF PRODUCTS AS PER PROPOSED SCENARIO Sr. No. Products 1. Hydrogenation 1.1 DCBH (Di Chloro Benzene Hydro chloride) 1.2 1,3 D.F.B.(Di Flouro Benzene) 1.3 3,5/2,6 DFA (Di Flouro Aniline) Quantity As Per Consent no. AWH in MT / Year Quantity As Per Proposed Expansion in MT / Year OT Base Di Anisidine Co-Products From Hydrogenation 1.6 Ortho Toluendine Ortho Anisidine Ortho Chloro Aniline Diazotization Sand Mayer Reaction 2.1 2,3/2,5 DCP (Di Chloro Phenol) 2.2 3,5 Di Chloro Nitro Benzene ,3,5 TCB Para Flouro Phenol (PFP) 3. Bromination 3.1 3,4,5 Tri Flouro Bromo Benzene Bromo 4 Flouro Acetanilide Di Chloro Bromo M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 1. 5

21 Sr. No. Products Benzene 3.4 Co-Product From Bromination Quantity As Per Consent no. AWH in MT / Year Quantity As Per Proposed Expansion in MT / Year Acetic Acid Condensation 4.1 Quinal phose (TECH) (Diethyl 2-Hydroxy Thio phosphoryl Chloride) Para Flouro Anisol Hydrolysis Chloro Amino Phenol Chloro Amino Phenol 6.3 2,3,4 Tri FlouroAniline 0 7. Chlorination 7.1 2,6 Di Chloro Para Nitro Aniline 7.1 2,4,6 Tri Chloro Aniline 0 By Products Total Sulphuric Acid (70%) Dilute Sulphuric Acid HBr Solution HCl (30%) Sodium sulphate Total KEY INFORMATION OF PROJECT IMPORTANCE AND JUSTIFICATION OF PROJECT: This is an existing unit. The customers are established. The unit has already achieved maximum production capacity. There are pending orders with the unit. The products are exported also. The products proposed for expansion are dye intermediates. The dyes manufacturing sector is making progress with average 15% growth rate. The domestic demand is also increasing. In the international market also, the demand for M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 1. 6

22 dyes and pigments is increasing. In this background the early implementation of the project is important. The expansion is proposed in the existing plot itself. There is enough area available for this project NATURE OF THE PROJECT The project is developed on principle of unit operations. The proponent has proposed to expand the unit in a way that it can carry out various unit operations. The design is made based on requirement of unit operations rather than based on individual products. The ever changing field of dyes and bulk drugs and discovery of new molecules has forced the chemical manufacturer to establish the unit which can undertake series reactions. The project also serves as pilot facility for group s other industries. Once products are standardizing, market is developed, expected specifications are meet, and the knowhow will be transferred to other units. The present unit will always look for new products COST OF THE PROJECTAND TIME OF COMPLETION Existing investment in plant and machinery, land, building etc. is Rs Lacs. The additional investment for proposed expansion will be Rs Lacs. It has been classified as Large Scale Industry. TABLE: 1.4 CAPITAL COST PROJECTION Sr. Purpose No. Existing (Rs. In Lacs) Proposed (Rs. In Lacs) Total (Rs. In Lacs) 1. Land Building Plant and Machinery Env. Protection & Safety a) Effluent treatment Plant b) Safety Equipment (PPE, fire extinguishers, Ventilation, etc.) C) Green belt development d) Fire Total M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 1. 7

23 The construction work will be started immediately after getting Environment Clearance. The project will be commissioned within 9 months time. Equipment suppliers are already sourced and detailed engineering is also completed SITE SELECTION The project proponent did not consider any other alternative site for proposed expansion as the unit has adequate space in existing plot for expansion LOCATION OF THE PROJECT The project site is located at plot no 902, 923, GIDC Estate, Phase-III, Vapi, Dist. Valsad, Gujarat. It is approximately 26 km distance from District: Valsad. The approximate geographical positioning of the project site is at Latitude: N and Longitude: 72 54' E. The unit is spread over in 11,970sq. m. area in GIDC Vapi. The site plant and plant layout are attached as annexure IX. The site location map on Indian map of 1:10, 00,000scales followed by 1:50,000/1:25,000 scales on A3/A2 sheet are attached as annexure-x-a. Topo sheet covered project site is attached as annexure- X-B. Location map showing 10 km radial distance from project site, longitude & latitude is also covered in annexure-x-c. Co-Ordinate showing latitude and longitude of four corner of project site is attached as annexure- X-D. And Google map image from Google earth is attached as annexure- X-E. 1.4 SALIENT FEATURES The plant is located in a well-developed industrial zone, which have all essential facilities such as internal roads, arrangement for supply of water and power to industries, effluent disposal facilities etc. The Vapi GIDC falls at Pardi Taluka of Gujarat. It is positioned on the bank of River Daman Ganga. It is situated to east of Daman (Central Territory) and to the West of Dadra and Nagar Haveli. Vapi is largely an industrial area dominated by small scale industries, especially chemical plants. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 1. 8

24 Water is available from G.I.D.C. water supply. G.I.D.C. Vapi is large industrial estate with a number of chemical plants, paper mill, textile processing plants and other allied industries total to about more than 705 units. Vapi Industrial Association (VIA) has set up a Disaster Management Cell to take care of any disaster in the vicinity. A Common Effluent Treatment Plant (CETP) and Common Hazardous Waste Storage Site are established and operated by M/s. Vapi Waste & Effluent Management Co. Ltd., Vapi. The treated effluent from CETP is discharged in to sea. The present unit will utilize TSDF facility. The unit is recycling back all effluent and will become zero discharge. The salient features of project site is covered under Table 1.5 TABLE: 1.5 SALIENT FEATURES OF THE PROJECT SITE Particulars Details Distance from project Site Taluka/ Tehsil Pardi Approx.15 Km District Valsad Approx. 26 Km Approx. Geographical Latitude: N -- positioning Longitude: E Nearest City Valsad Approx. 26 Km Nearest Town Vapi Approx. 4.4 Km Nearest Highway NH8 Approx. 3 Km Nearest Railway line/ Vapi 3.0 Km Railway station Nearest Domestic Airport/ Airbase Surat 90 Km 1.5 REGULATORY FRAMEWORK The proposed project fall under category 5(b) & 5(f) of the schedule, as per the EIA Notification, September 2006.As project located within 10 km radial distance from interstate boundary of Gujarat & Daman and Gujarat & Dadar Nagar Haveli. The unit requires obtaining Environmental clearance from Industrial Committee of MoEF, Delhi. The EIA report is based on the finalized TOR as received vide ref no. J /47/2015-IA II (I) dated: - 19 th January, Letter containing Terms of Reference (TOR) given by industrial committee of MoEF is attached as annexure-xi. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 1. 9

25 1.6 SCOPE & OBJECTIVES OF THE EIA STUDY This EIA Report is prepared to comply with the requirements of the Industrial committee, MoEF as per the guideline for the Clearance. The objectives of this EIA are: To describe the Project and associated works together with the requirements for carrying out the Project. To identify and describe the elements of the community and environment likely to be affected by the project, and / or likely to cause impacts upon the project, including both the natural and man-made environment; To identify and quantify emission sources and determine the severity of impacts on sensitive receivers and potential affected uses; To recognize and quantify any environmental impacts associated with the project and recommend appropriate mitigation measures; To study existing landscape and visual quality in the study area so as to evaluate the landscape and visual impacts of the project; To propose mitigation measures to minimise pollution, environmental disturbance and nuisance during construction and operation of the project; To identify, predict and evaluate the residual (that is, after practicable mitigation) environmental impacts and cumulative effects expected to arise during the construction and operation phases of the Project in relation to the sensitive receivers and potential affected uses; To identify, assess and specify methods, measures and standards, to be included in the detailed design, construction and operation of the project which are necessary to mitigate these impacts and reduce them to allowable levels within established standards / guidelines; To investigate the extent of side-effects of proposed mitigation measures that may lead to other forms of impacts; To identify constraints associated with the mitigation measures recommended in this EIA; To identify any additional studies necessary to fulfil the objectives to the requirements of this EIA Study. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

26 1.7 STRUCTURE OF EIA REPORT The generic structure of the EIA report, as per the guideline provided by MoEF is illustrated in the following tabulated format. TABLE: 1.6 STRUCTURE OF EIA REPORT Sr. EIA Structure Contents No. 1. Introduction Purpose of the report and regulatory frame work Identification of the project and project proponent Key Information of project Regulatory Frame work Scope & Objective of EIA study Structure of EIA report Terms of reference & Its Compliance 2. Project Description Condensed description of those aspects of the project (based on project feasibility study), likely to cause environmental effects. Description contains the details of the following: Type of project Need for the project Location details showing general location, specific location, project boundary & project site layout) Technology and process description Project description. Including drawings showing project layout, components of project etc. Schematic representations of the feasibility drawings which give information important for EIA purpose Description of mitigation measures incorporated into the project to meet environmental standards, M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

27 Sr. EIA Structure No. 3. Anticipated Environmental Impacts & Mitigation Measures Contents Details of Investigated Environmental impacts due to project location, possible accidents, project design, project construction, regular operations, final decommissioning or rehabilitation of a completed project Measures for minimizing and / or offsetting adverse impacts identified Irreversible and Irretrievable commitments of environmental components Assessment of significance of impacts (Criteria for determining significance, Assigning significance) Mitigation measures 4. Environmental Monitoring Program Technical aspects of environmental monitoring for the effectiveness of mitigation measures (incl. Measurement methodologies, frequency, location, data analysis, reporting schedules, emergency procedures, budget & procurement schedules) 5. Additional Study: Risk Hazard Identification Assessment & Disaster Risk Assessment & control/prevention Management Plan Measures Disaster Management 6. Project Benefits Detail of the Socioeconomic & other tangible benefits of the project M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

28 Sr. EIA Structure No. 7. Environment Management Plan Contents Description of the administrative aspects of ensuring that mitigation measures are implemented and their effectiveness monitored, after approval of the EIA. The Chapter consist of: Mitigation measures for impacts Pollution Prevention Plan Greenbelt Development Plan Mangrove Management Plan Dredging management Plan Waste management plan Environment Management Cell Budgetary Provisions for EMS 8. Summary & Conclusion Description of brief of EIA report 9. Disclosure of Consultant Engaged Detail of the EIA Consultant 1.8 TERMS OF REFERENCE AND ITS COMPLIANCE TABLE: 1.7 TERMS OF REFERENCE PROPOSED BY UNIT Sr. Terms of Reference No. 1. Site Description and plant layout 2. List of raw materials, solvents and their quantity and properties. 3. List of finished products, their properties and Topic Covered Under Locational Features covered under topic of Chapter -1 on page no. 1.8 Location map of showing project site in Valsad District is shown in annexure-x. Site plan & Plant Layout are attached as annexure-ix. Raw material consumption details are covered in table no.2.2 of chapter-2on page no.2.4. Physical &chemical properties of raw material are covered in annexure-xxi. List of product is covered in table no 1.3 of chapter - 1, on page no.1.5. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

29 Sr. Terms of Reference No. quantities 4. Process details with mass balance. 5. Solvent balance and recovery system 6. Details of process emissions, water discharge and hazardous waste generation and disposal. Topic Covered Under Manufacturing process & material balance are covered in topic 2.4 of chapter-2 from page no2.16 to page no Details covered under topic 2.5 of chapter-2 on page no Details of solvent recovery system are covered in Table no.8.3 of chapter -8 on page no.8.5. Details of flue gas emission and process emission covered under topic in Table no.2.16 & 2.17 of chapter - 2 on page no2.78. Details of waste water generation are covered under topic 2.7.1in table no.2.15 under chapter - 2 on page no Details of hazardous waste generation and disposal mode covered under topic 8.4.2(D) in Table no & 8.17 of chapter-8 on page no Complete Water balance Details of water balance covered under topic 8. Treatment plant details to achieve zero liquid discharge. 9. Details of Air pollution control system 10. Steps to control fugitive emissions in figure 2.1 & 2.2 of chapter -2, from page no.2.67 to Details of ETP and zero liquid discharge schemes covered under topic in Table no.8.5 to 8.13 & figure 8.5 of chapter-8 from page no.8.7 to Details of air pollution control plan are covered under topic 8.4.2(A) in table no.8.2 & 8.3 of capter-8 from page no.8.3 to 8.6. Details of air pollution control plan are covered under topic 8.4.2(A) in table no.8.2 & 8.3 of capter-8 from page no.8.3 to 8.6. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

30 Sr. Terms of Reference No. 11. Details of closed handling system for chemicals and reflux condenser over reactor. 12. Base line data for soil, water, air and noise for one season. 13. Environment impact assessment due to excavation and construction activities, manufacturing process and its operations, generation of wastes and methods adopted for minimizing impacts etc. 14. Details of Environmental Management Plan (EMP) and mitigation measures. 15. Occupational health and safety programme. Topic Covered Under The details of solvent recovery system are covered under topic 2.5 of chapter-2 on page no.2.64 and Table no.8.3 of chapter-8 on page no.8.5 & 8.6. Baseline details of Air, Water, Noise and Soil are covered in chapter-3 under topic 3.3, 3.4, 3.5 and 3.6 from page no.3.6 to No construction activity will be carried out. Other details are covered in chapter-4. Details are covered in chapter-8. Details are covered under topic 6.7of chapter- 6 from page no TABLE: 1.8 ADDITIONAL TOR GIVEN BY INDUSTRIAL COMMITTEE OF MOEF Sr. No. TOR condition Remarks Specific TOR 1. Commitment that no banned pesticides will be manufactured. Commitment that no banned pesticides will be manufactured is attached as 2. Details on solvents to be used, measures for solvent recovery and for emissions Control. an annexure XXVII. Details covered under topic 2.5 of chapter-2 on page M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

31 Sr. No. TOR condition 3. Details of process emissions from the proposed unit and its arrangement to control. 4. Ambient air quality data should include VOC, other process-specific pollutants* like NH 3 *, chlorine*, HCl*, HBr*, H 2 S*, HF*, CS 2 etc., (* - as applicable) 5. Work zone monitoring arrangements for hazardous chemicals. 6. Detailed effluent treatment scheme including segregation for units adopting Zero liquid discharge. 7. Action plan for odour control to be submitted. 8. A copy of the Memorandum of Understanding signed with cement manufacturers indicating clearly that they co-process organic solid/hazardous Waste generated. Remarks no Details of solvent recovery system are covered in Table no.8.3 of chapter-8 on page no.8.5. Process emission from the proposed unit is covered in table no.2.16 & 2.17 of chapter-2 on page no.2.78 and table no.8.2 & 8.3 of chapter-8 on page no.8.4 to 8.6. Details are covered in table no. 3.4 of chapter-3 from page no. 3.8 to Details are covered in (D) Of chapter-6 on page no Details are covered in of chapter-8 from page no.8.7 to There are no odour emissions chemicals. However, it is covered with fugitive emissions. Provisional membership certificate from RSPL for accepting co-process organic solid/hazardous waste generated is attached as M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

32 Sr. No. TOR condition 9. Authorization/Membership for the disposal of liquid effluent in CETP and solid/hazardous waste in TSDF, if any. 10. Material Safety Data Sheet for all the Chemicals are being used/will be used. 11. Authorization/Membership for the disposal of solid/hazardous waste in TSDF. Remarks annexure- XXVIII. The disposal of liquid effluent in CETP is not applicable because now, our unit is become zero liquid discharge unit. The details of waste in TSDF are attached as annexure-xx. MSDS is as annexure-xxi in soft copy CD Foam. Membership for the disposal of solid/hazardous waste in TSDF.as annexure-xx. 12. Details of incinerator if to be installed. Not Applicable. 13. Risk assessment for storage and handling of hazardous chemicals/solvents. Action plan for handling & safety system to be incorporated. 14. Arrangements for ensuring health and safety of workers engaged in handling of Toxic materials. Additional TOR 1. A separate chapter on status of compliance of Environmental Conditions granted by State/Centre to be provided. As per circular dated 30th May, 2012 issued by MoEF, a certified report by RO, MoEF on status of compliance of conditions on existing unit to be provided in EIA-EMP report. Details are covered in table no.6.5, 6.6, 6.7, 6.8 and 6.9 of chapter-6 from page no.6.13 to 6.20 and action plan is covered in of chapter- 6 from page no.6.83 & Details are covered in of chapter-6 on page no Details are covered in chapter-9. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

33 Sr. TOR condition No. 2. Public hearing is exempted as per Para 7(i) III Stage (3)(i)(b) of EIA Notification, 2006 For preparation of EIA/EMP Report, being site is located in the Notified industrial area. 3. Recommendation of SPCB to be submitted for proposed activity. 3 These TORs should be considered for the preparation of EIA /EMP for expansion of pesticide (from 5595 MTPA) at plot no.903,923,gidc Estate, Vapi, Gujarat by M/s. Aarti Industries Ltd. In addition to all the relevant information as per the General structure of EIA Given appendix III in the EIA Notification, Introduction 4. Public hearing is exempted as per para 7(i) III stage (3) (i) (b) of EIA Notification, 2006 for preparation of EIA/EMP report, being site is located in the Notified industrial area. You are requested to kindly submit the final EIA/EMP Prepared as per TORs to the Ministry for considering the proposal for environmental clearance within 3 years as per the MoEF O.M No. j-11013/41/2006- IA.II(I) dated 8 th October The consultants involved in the preparation of EIA/EMP report after accreditation with quality council of India/National accreditation board of Education and training (QCI/NABET) would need to Remarks Noted. Request letter submitted to SPCB is attached as annexure XXIX. Noted. Noted. Name and address of Consultant: Jyoti Om Chemical Research Centre Pvt. Ltd. F-11, Surajmoti Complex, M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

34 Sr. No. TOR condition include a certificate in this regard in the EIA/EMP reports prepared by them and data provided by other Organization(s)/Laboratories including their status of approvals etc. Remarks Nr. Hariom Nagar, Vadodara The consultants has got the stay order from HON. Generic terms of Reference(TOR) In respect of industry sector 1. Executive summary (maximum 2-3 sheets in A4 Size paper) of the project covering project description, description of the environment, anticipated environmental impacts & its mitigation measures, environmental management plan, environmental monitoring programme, public consultation, project benefits, Soc, impacts including R&R. 2. SITE DETAILS i ii iii Location of the project site covering village, Taluka/Tehsil, district and state on Indian map of 1:1000, 000 scale. A topo sheet of the study area of radius of 10km and site location on 1:50000/1:25000 scale on an A3/A2 sheet. Co-ordinates (lat-long) of all four corners of the site. Gujarat high court and it is attached as annexure-xxiv Executive summary is attaches as annexure - XXX. Location of project site covering village, Taluka/Tehsil, district and state on Indian map of 1:1000, 000 scales is attached as annexure-x- A. A topo sheet of the study area of radius of 10km and site location on 1:50000/1:25000 scales on an A3/A2 sheet is attached as annexure-x-b. A co-ordinates show (lattlong) of all four corners of the site is attached as M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

35 Sr. No. iv v vi vii TOR condition Google map-earth downloaded of the project site. A map showing environmental sensitivity [land use/land cover,water bodies,reserved forests wildlife sanctuaries, National parks, tiger reserve etc. ] and from critically/severely polluted area(s) and Ecosensitive Area within 10km radius of the project site vis-a-vis shortest (aerial) distance from the project. If the project is located within 10km of CPA/severely polluted area, confirm whether moratorium has been imposed on the area. Layout maps indicating existing unit as well proposed unit indicating storage area, plant area, green belt area, utilities etc. In addition, if located within the industrial area/estate/complex, layout of industrial area and location of unit within the industrial area/estate/complex, layout of industrial. Photographs of the proposed and existing (if applicable) plant site. If existing, In addition to Side map, provide photographs of plantation /greenbelt in Existing project. If fresh EC application,photographs 3. Land use break-up of total land of the project site (identified and acquired), government/private - agricultural, forest, Remarks annexure-x-d. Google map on Google earth show the project site is attached as annexure- X-E. Map is attached as annexure- X-B. Layout map indicating all the things is attached as annexure-ix. Photographs are attached as annexure-xiv. Details are covered under topic 3.14 of chapter-3 on page no M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

36 Sr. No. TOR condition wasteland, water bodies, settlements, etc shall be included. 4. A copy of the mutual agreement for land of the acquisition singed with land included. 5. Proposed shall be submitted to the ministry for environmental clearance only after acquisition of land shall be included. 6. Forest and wildlife related issues (if I ii applicable): Permission and approval for the use of forest land (forestry clearance), if any, and recommendations of the State Forest Department. Land use map based on High resolution satellite imagery (GPS) of the proposed site delineating the forestland (in case of projects involving forest land more than 40 ha) iii Status of Application submitted for iv obtaining the stage I forestry clearance along with latest status shall be submitted. The projects to be located within 10 km of the National Parks, Sanctuaries, Biosphere Reserves, Migratory Corridors of Wild Animals, the project proponent shall submit the map duly authenticated by Chief Wildlife Warden showing these features vis-à-vis the project location and the recommendations or comments of the Chief Wildlife Wardenthereon Remarks Land possession document is attached as annexure-xii. Existing unit. Full land acquired. Not Applicable M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

37 Sr. TOR condition No. V Wildlife Conservation Plan duly authenticated by the Chief Wildlife Warden of the State Government for conservation of Schedule I fauna, if any exists in the study area vi Copy of application submitted for clearance under the Wildlife (Protection) Act, 1972, to the Standing Committee of the National Board for Wildlife 7. Expansion/modernization proposal i Copy of all the Environmental clearance (s) including Amendments thereto obtained for the project from MOEF/SEIAA shall be attached as an annexure.a certified copy of the latest Monitoring report of the regional office of the Ministry of environmental and forests as per circular dated 30 th may, 2012 on the status of compliance of condition stipulated in all the existing environmental clearance including amendments should be provided. In addition, status of compliance of consent to operate for the on-going /existing operation of the project from SPCB shall be attached with the EIA-EMP reports. ii In case the existing project has not obtained environmental clearance, reasons for not talking EC under the provisions of the EIA notification 2006 shall be provided copies of consent to establish /No objection certificate and consent to operate (in case of units Remarks Copies of old EC are attached as Annexure I and II. and Compliance report of last EC is attached as Annexure III. Not Applicable. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

38 Sr. No. TOR condition operating prior to EIA Notification 2006, CTE and CTO of FY ) obtained from the SPCB Shall be submitted. Details of industrial operations 8. A list of major industries with name and type within study area (10km radius) shall be incorporated. 9. Details of proposed raw material and products along with production capacity. If expansion project, details for existing unit, separately for existing and new (proposed) unit. 10. Details of manufacturing process, major equipment and machinery. If expansion project details of existing unit, separately for existing and new (proposed) unit. 11. List of raw material required and its sources long with mode of transportation shall be included. All the trucks for raw material and finished product transportation must be environmentally compliant 12. Quantity of fuel required,its sources and characteristic and documentary evidence to substantiate confirmed fuel linkage shall be furnished 13. Project site layout plan to sale using Auto CAD showing raw material,fly ash and other storage plans bore well or water Remarks Details are covered in Table no.3.1 of chapter-3 from page no.3.2 to 3.4. Details are covered under topic 2.3 in Table no.2.2 & 2.3 of chapter-2 from page no.2.4 to Details are covered under topic 2.4 of chapter-2 from page no.2.16 to Details of Equipment and machinery are covered in Table no.2.14 of chapter-2 on page no.2.73 to Details are covered in Table no.2.4 of chapter-2 from page no.2.12 to Details are covered in Table no. 2.9 of chapter-2 on page no Steam is coming from neighbour industry. Plant layout is attached as annexure-ix. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

39 Sr. No. TOR condition storage,acquires dumping,waste disposal,green areas water bodies,rivers/drainage passing through the project site shall be include. 14. Manufacturing process details of all the plants including captive power plant if any along process flow chart shall be include. Remarks Details are covered under topic 2.4 of chapter-2 from page no.2.16 to Mass balance for the material and products shall be included. 16. Energy balance data for all the compensates of the plant shall be incorporated. 6. Environmental Status 17. Geological features and geo-hydrological status of the study shall be included. 18. Details of drainage of the project up to 5 km radius of study area. If the site within 1 km radius of any major river,peak and lean river discharge as well as flood occurrence frequency based on peak rainfall data of the past 30 years. Details of RL of the project site and mrl of the river should also be provided. 19. One season site-specific micro-metrological data using temperature relatively humanity,hour, wind speed and direction and rainfall Details are covered under topic 2.4 of chapter-2 from page no.2.16 to Electricity connected load given in Table no.2.10 of chapter -2, on page no Geological features given under topic 1.4 in chapter-1 on page no.1.4 & 1.5. Geo Hydrological is not applicable. Not Applicable. Details are covered in table no. 3.2, 3.3 & 3.4 of chapter- 3 from page no 3.4 to M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

40 Sr. No. TOR condition and AAQ data (except monsoon)at 8 location for PM 10,PM 2.5, SO 2,NO X, CO and HC (methane & non-methane) should be collected. The monitoring stations should take into account the pre-dominant wind direction, population zone and sensitive receptors including reserved forests Surface water supply quality of nearly river (60m upstream and downstream) and other surface drains at eight locations to be provided. 21. Ground water monitoring minimum at 8 locations shall be included. 22. Noise level monitoring at 8 locations shall be included. 23. Traffic study of the area for the proposed project the respect of the exist traffic,type of vehicles, frequency of vehicles for transportation of material additional traffic due to proposed project,parking arrangement etc. 24. Detailed description of flora and fauna (terrestrial and aquatic) existing in the study area shall be given with special reference to rare, endemic and endangered species. If Schedule-I fauna are found within the study area, a Wildlife Conservation Plan shall be prepared and furnished. Remarks Details are covered under topic 3.4 and Table no.3.6 of chapter-3 on page no & Details are covered under topic 3.4 and Table no.3.5 of chapter-3 on page no.3.13 & Details are covered in Table no.3.11 of chapter-3 on page no Details are covered under topic in chapter-4 on page no Details are covered in Table no.3.14 & 3.15 of chapter-3 from page no.3.26 to M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

41 Sr. TOR condition No. 25. Emission (g/sec) with and without the air pollution control measures. 26. Cumulative impact of all sources of emission (including transportation) on the AAQ of the area shall be well assessed. Details of the model used and input model used and input data used for modelling shall also be provided. The air quality contours should be plotted on allocation map showing the location of project site, habitation nearby, sensitive receptors, if any. 27. Impact of the transport of the raw materials and end products on the surrounding environment shall be assessed and provided. On this regard, options for transport of raw materials and finished products and wastes (large quantities) by rail or rail cum road transport or conveyor cum rail transport shall be examined. 28. Details of water requirement, water balance chart for new unit or for existing unit as well as proposed expansion (in case of expansion) 29. Source of water supply and quantity and permission of withdrawal of water (surface/ground) from Competent Authority. Remarks Details are covered in table no.2.18 of chapter 2 on page no Details are covered in Table no.4.1 of chapter-4 on page no Location map is shown in Figure no. 4.7 to 4.12 of chapter-4 on page no to Details are covered under topic of chapter-4 on page no Details are covered under topic of chapter-2 from page no.2.67 to Source of water supply and quantity and permission of withdrawal of water (surface/ground) from Competent Authority is attached as annexure-xiii. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

42 Sr. TOR condition No. 30. Details regarding quantity of effluents generated, recycled and reused and discharged to be provided. Methods adopted/to be adopted for the water conservation shall be included. Zero discharge effluent concepts to be adopted. 31. A note on treatment of wastewater from different plant operations, extent recycled and reused for different purposes shall be included. Complete scheme of effluent treatment. Characteristics of untreated and treated effluent to meet the prescribed standards of discharge under E(P) Rules. 32. Action plan for control of ambient air quality parameters as per NAAQES Standards for PM10, PM2.5, SO2 and NOx, etc as per GSR 826(E) dated 16 th November, An action plane to control and monitor secondary fugitive emissions from all the sources as per the latest permissible limits issued by the ministry vide G.S.R. 414 (E) dated 30 th May, Action plan for solid/hazardous waste generation, storage, utilization and disposal. Copies of MOU regarding utilization of solid waste shall also be included. EMP shall include the concept of wasteminimization, recycle/reuse/recover techniques, Energy conservation and natural resource conservation. Remarks Details are covered under topic of chapter-2 on page no.2.77 & Details are covered under topic of chapter-8 on page no.8.7 to Details are covered under topic (A) of chapter-8 from page no.8.5 to 8.8. Details are covered under topic (A) of chapter-8 from page no.8.3 to 8.6. Details are covered under topic (D) of capter-8 on page no.8.18 to M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

43 Sr. TOR condition No. 35. Proper utilization of fly ash shall be ensured as per Fly Ash Notification, 1999 and subsequent amendment in 2003 and A detailed plan of action should be provided. 36. Action plan for the green belt development plan in 33% area i.e. land with not less than trees per ha. Giving details of species, with of plantation, planning schedule etc. Shall be included. The green belt shall be around the project boundary and a scheme for greening of the roads used for the project shall also be incorporated. All rooftops/terraces shall have some green cover. 37. Action plan for rainwater harvesting measures at plant site shall be submitted to harvest rainwater from the roof tops and storm water drains to recharge the groundwater recharge structures may also be constructed outside the plant premises in consultation with local gram Panchayat and village hand to augment the ground water level, incorporation of water harvesting plan for the project is necessary, if source of water is bore well. 38. Environment Management Plan (EMP) to mitigate the adverse impacts due to the project along with item wise cost of its implementation. Total capital cost and recurring cost/annum for environmental pollution control measures shall be Remarks Not Applicable. Details are covered under topic (E) of chapter-8 on page no Not Applicable. In GIDC estate, rain water recharging is not recommended. Details are covered under topic 8.4.2(H) in Table no.8.18 of chapter-8 on page no M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

44 Sr. No. TOR condition included. 39. Details of Rehabilitation & Resettlement (R & R) involving the project. R & R shall be as per policy of the state govt. And a detailed action plan shall be included. 40. Action plan for post project environmental monitoring shall be submitted. 41. Disaster Preparedness and Emergency Management Plan including Risk Assessment and damage control needs to be addressed and included. 42. Occupational Health: i ii iii Details of existing occupational & safety hazardous. What are the levels of above mentioned they are within permissible Exposure level (PEL).If these are not with in PEL so that health of the workers can be preserved. Details of exposure specific health status evaluation of worker. If the workers health is being evaluated by pre designed format, chest x rays, Audiometry, Spirometry, Vision testing (Far & Near vision, colour vision and any other ocular defect) ECG, during pre-placement and periodical examinations give the details of the same. Details regarding last month analysed data of above mentioned parameters as per age, sex, duration of exposure and department wise. Remarks Not Applicable. Environment monitoring plan covered in chapter-5. Details are covered under topic 6.3 in Table no.6.3 & 6.4 of chapter-6 from page no to Details are covered under topic of chapter-6 on page no Details are covered under topic of chapter-6 on page no Reports of premedical, post medical, and last medical are attached as annexure-xxvi. Annual report of health status of works with Details are covered under M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

45 Sr. No. iv v TOR condition special reference to occupational health and safety. Action plan for the implementation of OHS standard as per OSHAS/USEPA. Plan and fund allocation to ensure the occupational health & safety of all contract and causal workers. 43. Corporate Environmental Policy i ii Does the company have a well laid down Environment Policy approved by its Board of Directors? If so, it may be detailed in the EIA report. Does the Environment Policy prescribe for standard operating process / procedures to bring into focus any infringement / deviation / violation of the environmental or forest norms / conditions? If so, it may be detailed in the EIA. iii What is the hierarchical system or iv Administrative order of the company to deal with the environmental issues and for ensuring compliance with the environmental clearance conditions? Details of this system may be given. Does the company have system of reporting of non-compliances / violations of environmental norms to the Board of Directors of the company and / or Shareholders or stakeholders at large? This reporting mechanism shall be detailed in Remarks topic of chapter-6 on page no Details are covered under topic of chapter-6 on page no Details are covered under topic of chapter-6 on page no.6.84 & Environment policy approved by its Board of Directors is attached as annexure-xviii. Details are covered under topic 8.3 of chapter-8 on page no Details are covered under topic 8.3 of chapter-8 on page no Details are covered under topic 8.3 of chapter-8 on page no M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

46 Sr. No. TOR condition the EIA report 44. Details regarding infrastructure facilities such as sanitation, fuel, restroom etc. to be provided to the labour force during construction as well as to the casual workers including truck drivers during operation phase. 45. At least 5% of the total cost of the project shall be earmarked towards the enterprise social commitment based on public hearing issue and item wise details along with time bound action plan shall be included. Socialeconomic development activities need to be elaborated upon. 46. Any litigation pending against the project and/or any direction/order passed by any Court of Law against the project, if so, details thereof shall also be included. Has the unit received any notice under the Section 5 of Environment (Protection) Act, 1986 or relevant Sections of Air and Water Acts? If so, details thereof and compliance/atr to the notice(s) and present status of the case. 47. The questionnaire for industry sector (available on MoEF Website) shall be submitted as an annexure to the EIA-EMP reports. 48. TORs prescribed by the expert appraisal Committee (industry) shall be considered for preparation of EIA-EMP reports for the Remarks This is existing unit and no construction will be carried out. Details are covered under topic in Table no.2.6 of chapter-2 on page no Details are covered under topic 7.4 of chapter-7 on page no All details are covered under chapter 9. The questionnaire for industry sector is attached as annexure-viii. Instruction followed. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

47 Sr. No. TOR condition project in addition to all the relevant information as per the genetic structure of EIA is given is appendix IIIA in the EIA notification,2006.where the documents provided are in language other than English,an English translation shall be provided. The draft EIA EMP, report shall be submitted to the state pollution control board of the concerned state for the conduct public hearing. The SPCB shall conduct public hearing/public consultation, district wise, as per the provisions of EIA Notification, 2006.the issues raised in the public hearing and during the consultation process and the committee made by the project proponent the same shall include separately in EIA-EMP reports in the from tabular chart with financial budget (capital and revenue) along with time-schedule of implementation for complying with the commitments made. The final EIA reports shall submitted to the ministry for obtaining environmental clearance. 49. A tabular chart with index for point wise compliance of above TORs. 50. The TORs prescribed shall be valid for a period of three years for submission of the EIA-EMP Reports. Along with public hearing proceedings(whatever stipulated ) Remarks Details are covered in Table no.1.7 & 1.8 of chapter-1 from page no.1.13 to Noted. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

48 Sr. No. TOR condition Remarks ADDITIONAL TORs FOR SYNTHETIC ORGANIC CHEMICAL INDUSTRY 1. Manufacturing process details along with the chemical reaction and process flow chart. Details are covered under topic 2.4 of chapter-2 from page no.2.16 to Name of all solvent to be used in the process and details of the solvent recovery system. Details are covered under topic 2.5 of chapter-2 on page no Design details of ETP, incinerator, if any along with boiler, scrubber/bag filters etc. Design details of ETP are covered in Table no.8.4 to 8.13 of chapter-8 on page no.8.11 to Drawing of scrubber is attached as annexure-xix. 4. The details of solid and hazardous waste generation, storage, utilisation and disposal Details of solid and hazardous waste generation, particularly related to the hazardous storage are covered under calorific value of hazardous waste and detailed characteristic of the hazardous waste.action plan of the disposal of fly ash generated from boiler shall include. topic and in Table no.2.19 of chapter-2 on page no.2.12 & The details of solid and hazardous waste utilisation and disposal are covered under topic (D) in Table no & 8.17 of chapter-8 from page no to Precaution to be taken during the storage and transportation of hazardous chemical shall be clearly mentioned and incorporated. Details are covered in Table no of chapter-6 on page no & Material safety data sheet for all the chemicals are being used/will be used. AS Material safety data sheets for all raw material and M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

49 Sr. No. TOR condition No./RTECS No./DOT/UN ETC to be mentioned against each chemicals. 7. Details of VOC monitoring in the working zone environment, and other hazardous emission such as chlorine, HCl, etc if any. 8. Authorization/membership for disposal of the solid/hazardous waste in TSDF. 9. Risk assessment for the storage for chemicals /solvents. Action plan for the handing & safety system. Remarks products are attached as annexure-xxi. Details are covered under chapter-6. Authorization/membership for disposal of the solid/hazardous waste in TSDF is attached as annexure-xx. Details are covered under topic 6.5 of chapter-6 on page no Details of occupation health programme. Details are covered under i ii iii iv v To which chemical, workers are exposed directly or indirectly. Whether these chemical, are chemical within threshold limit values (TLV)/permissible exposure levels as per ACGIH recommendation. What measure company has taken to keep these chemicals within PEL/TLV? How the workers evaluated concerning their exposure to chemical during pre-placement and periodical medical monitoring. Liver function test (LFT) during preplacement and periodical examination. topic 6.7 of chapter-6 on page no Details are covered under topic of chapter-6 on page no Details are covered under topic of chapter-6 on page no Details are covered under topic of chapter-6 on page no Details are covered under topic of chapter-6 on page no Details are covered under topic of chapter-6 on M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

50 Sr. No. TOR condition Remarks page no A toxic management plan shall be prepared. Details are covered under 11. A write up on safe practice followed for handing, storage, transportation and unloading of chemical to be submitted. 12. What are onsite and offsite emergency plan during chemical disaster. 13. A write up on treatment of workers affected by accidental spillage chemical. topic 6.8 of chapter-6 in page no Details are covered under topic of chapter-6 on page no.6.60 & Details are covered in table no & 6.38 on page no Details are covered under topic 6.9 of chapter-6 on page no M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

51 Chapter 2 PROJECT DESCRIPTION 2.1 TYPE OF PROJECT M/s. Aarti Industries Ltd. (Alchemie Organics Division) located at plot no 902, 923, GIDC Estate, Phase-III, Vapi, Dist.:-Valsad, Gujarat is manufacturing Dye/Dye intermediates & Pesticides products. The project falls under category 5(f) and 5(b) of the schedule, as per the EIA Notification, September 2006 and its amendment. The unit has valid CCA order no. AWH-53342, issued on date 15/04/2013 for manufacturing of Dye/Dye intermediates & Pesticides products. Total existing production capacity is 5595 MT/Year. After proposed expansion proposed production capacity will be MT/Year. The unit has proposed expansion in existing products and also proposed some new products. The production capacity of existing and proposed products is given in Table 1.2and NEED FOR THE PROJECT Any investment decision is done based on techno economic viability of the project. The project has to be technically feasible and financially viable in nature. The existing unit is in export market for several years. They have range of products from various units and catering to the need of industries. The demand for newer molecules used to be regular feature from several countries as well as from India. This necessitude the project proponent to explore in the R& D department the manufacturing possibility. Once getting success in synthesizing these products at laboratory scale the financial viability was evaluated. The edge over other products resulted in the management decision to implement the project at the custom division. Once the production and manufacturing is optimized, the product may be scaled up at different location also. Moreover, the demand for existing product was constantly fluctuating. There arise competitions from other manufacturers for existing range of products. So as long term planning, the management decided to introduce new range of products. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

52 2.3DETAILS OF PRODUCTS AND RAW MATERIAL DETAILS OF PRODUCT Existing total production capacity of the unit is 5595 MT/Year. The By-product formation is MT/Year. After expansion the total production will be MT/Year and the byproduct formation will be MT/Year. The list of the existing and proposed products and their production capacity are given in Table 1.2 and 1.3. Properties of products are given in Table 2.1 TABLE: 2.1 PROPETIES OF PRODUCTS Sr. No. Name of Products 1. DCBH (Di Chloro Benzene Hydro chloride) 2. 2,3/2,5 DCP (Di Chloro Phenol) 3. 3,4,5 Tri FlouroBro mo Benzene 4. Para Flouro Phenol (PFP) 5. 3,5 Di Chloro Nitro Benzene Physical State Solid Solid Solid /Liquid FP O C N A N A BP O C Vapor Density (Air=1) LEL UEL % LD 50 Mg/Kgs LC 50 Mg/L TLV By OSHA (Ppm) NA NA NA NA NA Sp. Gravity (Water =1) 211 NA NA NA NA g/ ml NA NA NA NA Solid NA NA NA Solid N A NA NA NA NA NA NA M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

53 6. Quinal phose (TECH) (Diethyl 2- Hydroxy Thiophosp horyl Chloride) 7. 1,3 DFB( Di Flouro Benzene) 8. 2 Bromo 4 Flouro Acetanilide 9. Di Chloro Bromo Benzene 10. 3,5/2,6 DFA (Di Flouro Aniline) 11. 2,6 Di Chloro Para Nitro Aniline 12. Ortho Chloro Aniline 13. Acetic Acid 14. Sulphuric Acid (70%) 15. Dilute Sulphuric Acid 16. HBr Solution Liquid NA NA NA NA 1.32 Liquid g/cm 3 NA NA NA NA Solid Solid N A N A NA NA NA NA NA NA NA NA NA NA NA NA Solid NA NA NA NA 1 Solid N A Liquid 10 4 Liquid Liquid N A Liquid N A Liquid N A NA NA NA 1500 NA NA NA NA NA NA NA NA NA 2140 NA NA NA NA NA >90 NA M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

54 2.3.2 DETAILS OF RAW MATERIAL Product wise raw material consumption for existing and proposed products is covered in Table no The list of name of existing and proposed raw materials with consumption quantity in MT/Month for each product is provide in Table no.2.3 and 2.3. TABLE: 2.2 DETAILS OF EXISTING RAW MATERIALS CONSUMPTION Sr. No. Name of Products Proposed production Capacity (MT/ Month) Name of Raw Materials Consumption per ton of ton product Proposed consumption Quantity (MT/Month) 1 Hydrogenation 1.1 DCBH (Di 250 ONCB Chloro Caustic lye Benzene Fresh Hydro chloride) Toluene Rec toluene Catalyst H HCl 30% Soda ash H 2 SO 4 62% NaCl ,3 D.F.B.(Di Flouro Benzene) 1.3 3,5/2,6 DFA (Di Flouro Aniline) Di Flouro Chloro Benzene Tri ethyl amine Rec. Tri ethyl amine Caustic flakes 2.5 DI Chloro Di Flouro Benzene Catalyst Hydrogen HCl 30 % Ammonia Catalyst Caustic lye 48% M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

55 Sr. No. Name of Products 2 Diazotization 2.1 2,3/2,5 DCP (Di Chloro Phenol) 2.2 3,5 Di Chloro Nitro Benzene 2.3 Para Flouro Phenol (PFP) 3 Bromination 3.1 3,4,5 Tri Flouro Bromo Benzene Bromo 4 Flouro Acetanilide Proposed production Capacity (MT/ Month) Name of Raw Materials Consumption per ton of ton product Hydrogen Proposed consumption Quantity (MT/Month) 25 H 2 SO DCA Mixed acid , DCPNA NSA 36 % Formaldeh yde 37 % Soda ash H 2 SO % Sodium Nitrate Para flouro aniline HCl 30% MIBK Rec. MIBK Lime H 2 SO Sodium nitrate Tri flouro aniline HBr solution Cupurious bromide Para Flouro Aniline Acetic an hydried Bromine H 2 O (50%) NaHSO % solution Soda 25 % solution M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

56 Sr. No. Name of Products 3.3 Di Chloro Bromo Benzene Proposed production Capacity (MT/ Month) Name of Raw Materials Fresh Mono chloro benzene Rec. Mono chloro benzene Fresh ortho di chloro benzene Rec ortho dichloro benzene Consumption per ton of ton product Aluminum chloride Bromine NaHSO % Soda ash 10% Proposed consumption Quantity (MT/Month) 4 Condensation 4.1 Quinalphose 50 HQ (TECH) Acetone (Diethyl 2- Rec Hydroxy Thiophospho acetone KOH ryl Chloride) K 2 CO DETPC Xylene Rec Xylene Stabilizer Chlorination 5.1 2,6 DCPNA PNA W/c MCB Dry HCl Borex Chlorine %NaHC O M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

57 TABLE: 2.3 DETAILS OF PROPOSED RAW MATERIALS CONSUMPTION Sr. No. Name of Products Proposed production Capacity (MT/ Month) Name of Raw Materials Consumption per ton of ton product Proposed consumption Quantity (MT/Month) 1 Hydrogenation 1.1 DCBH (Di 650 ONCB Chloro Caustic lye Benzene Fresh Hydro chloride) Toluene Rec toluene Catalyst H HCl 30% Soda ash H 2 SO 4 62% NaCl Di Anisidine 650 ONA Rec Toluene Toluene Dichlone Emulsifier Caustic lye % Catalyst Hydrogen HCl 3% Soda Ash Spent Acid Thio urea HCl Salt Sol n OT Base 650 ONT Toluene Rec Toluene Dichlone Emulsifier Caustic lye % Catalyst Hydrogen HCl(3%) M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

58 Sr. No. Name of Products 1.4 1,3 D.F.B.(Di Flouro Benzene) 1.5 3,5/2,6 DFA (Di Flouro Aniline) 2 Diazotization 2.1 2,3/2,5 DCP (Di Chloro Phenol) 2.2 3,5 Di Chloro Nitro Benzene Proposed production Capacity (MT/ Month) Name of Raw Materials 650 Di Flouro Chloro Benzene Consumption per ton of ton product Proposed consumption Quantity (MT/Month) Soda Ash Spent Acid Thio urea HCl Salt Soln Tri ethyl amine Rec. Tri ethyl amine Caustic flakes 650 DI Chloro Di Flouro Benzene Catalyst Hydrogen HCl (30 %) Ammonia Catalyst Caustic lye % Hydrogen H 2 SO DCA Mixed acid , DCPNA NSA 36 % Formaldeh yde 37 % Soda ash ,3,5 TCB 200 2,4,6TCA NSA 39% H 2 SO Para Flouro Phenol (PFP) 200 H 2 SO 4 70% HCHO % Soda ash M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

59 Sr. No. Name of Products 3 Bromination 3.1 3,4,5 Tri Flouro Bromo Benzene Bromo 4 Flouro Acetanilide 3.3 Di Chloro Bromo Benzene Proposed production Capacity (MT/ Month) Name of Raw Materials Consumption per ton of ton product Proposed consumption Quantity (MT/Month) Sodium Nitrate Para Flouro aniline HCl 30% MIBK Rec. MIBK Lime H 2 SO Sodium Nitrate Tri Flouro aniline HBr solution Cupurious bromide Para Flouro Aniline Acetic an hydride Bromine H 2 O (50%) NaHSO % solution Soda 25 % solution Fresh Mono chloro benzene Rec Monochlor o benzene Fresh ortho di Chloro benzene Rec ortho dichloro M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

60 Sr. No. Name of Products 4 Condensation 4.1 Para Flouro Anisol Proposed production Capacity (MT/ Month) Name of Raw Materials Consumption per ton of ton product benzene Aluminum chloride Bromine NaHSO % Soda ash 10% Proposed consumption Quantity (MT/Month) PFA DMS NaOH % NaHCO % 5 Quinalphose 50 HQ (TECH) Acetone (Diethyl 2- Rec Hydroxy Thiophospho acetone KOH ryl Chloride) K 2 CO DETPC Xylene Rec Xylene Stabilizer Hydrolysis CAP ,5-DCNB Caustic Lye Ammonia Catalyst Hydrogen gas H 2 SO Charcoal Sodium Dithionate Hydrazine Hydrate CAP ,4-DCNB Caustic Lye Ammonia M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

61 Sr. No. Name of Products Proposed production Capacity (MT/ Month) Name of Raw Materials Consumption per ton of ton product Catalyst Hydrogen gas H 2 SO Charcoal Sodium Dithionate Hydrazine Hydrate 6.3 2,3,4 TFA ,3, TFNB Extract 2,3,4 TFNB Ammonia Catalyst Hydrogen gas Proposed consumption Quantity (MT/Month) 7 Chlorination 7.1 2,6 DCPNA PNA W/c MCB Dry HCl Borax Chlorine %NaHC O ,4,6 TCA Aniline MCB HCl gas Chlorine Soda Ash NaOH Flakes Thio urea M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

62 RAW MATERIAL STORAGE AND HANDLING Raw materials are stored in M.S. Tank, S.S. Tank, and HDPE Carboys, fiber drums, glass bottle and cylinders. Hazardous flammable substances are separately stored in solvent tank farm area within premises. Solvents like Xylene, Toluene, Acetone, MCB and MIBK etc. are stored in MS/SS tank with all precautionary process instrumentation and safety appliances. Tank storing hazardous liquid chemicals are provided with dyke wall. Flame arrester cum breather valve and flame proof fittings are provided at tank farm. Solvent transfer is done by pumps. Reactor and solvent handling pumps have mechanical seal with flame proof electrical fitting. The solvent storage area is restricted for unauthorized persons. Proper earthling is provided in all electrical equipment whenever solvent handling is done TRANSPORTATION OF RAW MATERIALS AND FINISHED PRODUCTS The raw materials and finished goods are transported through tankers and trucks. There is well developed road structure in GIDC, Vapi as well as within premises also. No additional road infrastructure will be required for transportation. The raw material source will be standard manufacturer or supplier. Indicative list along with mode of transportation is included in Table no TABLE: 2.4 DETAILS OF RAW MATERIAL SOURCE AND METHOD OF TRANSPORTATION Sr. No. Name of Raw Material Mode of Transport Type of Container Source 1. ONCB Truck Above Ground Tank Aarti Industries ltd, Vapi 2. Fresh Toluene Tanker Under Ground Tank Reliance Industries, Surat 3. Rec. toluene Tanker Under Ground In House Tank 4. Catalyst Truck HDPE drum Ravinda Heruse, Udaipur 5. Hydrogen Cylinder bank Cylinder Bank Aarti Industries ltd, Jhagadia 6. HCl 30% Tanker Above Ground Tank Aarti Industries ltd, Vapi M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

63 Sr. No. Name of Raw Material Mode of Transport Type of Container Source 7. Soda ash Truck Bag Nirma Industries 8. H 2 SO 4 62% Tanker Above Ground In House Tank 9. NaCl Truck Bag Chugule Salt, Vatva 10. ONA Tanker Above Ground Tank Aarti industries Ltd, Vapi 11. Dichlone Truck Bag Chem clone, Ahmedabad 12. Emulsifier Tanker Drum 13. Caustic lye 48% Tanker Above Ground Gujarat Alkali, Dahej Tank 14. HCl 3% Tanker Above Ground In House Tank 15. Spent Acid Tanker Above Ground In House Tank 16. Thiourea Truck Bag Zibo Linza Fine Chem, China 17. Salt Soln Tanker Bag In House 18. Di Flouro Chloro Tanker HDPE Drum Aarti Industries Ltd, Benzene Vapi Nescent Division 19. Triethyl amine Truck HDPE Drum Alkali Amine, 20. Rec.Tri ethyl Tanker Above Ground In House amine Tank 21. Caustic flakes Truck Bag Gujarat Alkali, Dahej 22. Di Chloro Di Tanker HDPE Drum Aarti Industries Ltd, Flouro Benzene Vapi Nescent Division 23. Ammonia Truck Cylinder Vadilal Gas, Vapi 24. H 2 SO 4 Tanker Above Ground Tank Aarti Industries Ltd, Vapi 25. DiChloro Aniline Tanker HDPE Drum Aarti industries ltd, Jhagadia 26. Mixed acid Tanker Above Ground Tank Aarti Industries Ltd, Vapi Nescent Division 27. 2,6 DCPNA Truck Bag Shanti Intermediate, Vapi 28. NSA 36 % Truck Above Ground Tank Aarti Industries Ltd, Vapi Nescent Division 29. Formaldehyde Tanker Above Ground Atul Ltd, 37 % Tank 30. 2,4,6TCA Tanker Bag Aarti Industries Ltd, Vapi 31. NSA 39% Truck Above Ground Tank Aarti Industries Ltd, Vapi Nescent Division M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

64 Sr. No. Name of Raw Material Mode of Transport Type of Container Source 32. H 2 SO 4 70% Tanker Above Ground Tank Aarti Industries Ltd, Vapi 33. Sodium nitrate Truck Bag R Nandalal& Sons, Mumbai 34. Para flouro aniline Tanker HDPE Drum Aarti Industries Ltd, Jagadia 35. Methyl Iso Butyl Tanker Underground Urmi Chemicals Ketone Tank 36. Rec. MIBK Tanker Underground In House Tank 37. Lime Truck Bag Devashi Petoleum 38. Tri flouro aniline Tanker HDPE Drum Aarti Industries Ltd, Tarapure 39. HBr solution Tanker Above Ground In House Tank 40. Cupurious bromide Truck Bag Yogi Dye Chem Industries Ltd,Mumbai 41. Acetic anhydride Tanker Above Ground Tank Ashok Organics Industries, Vadodara 42. Bromine Truck Glass Bottle Sejal Chemicals 43. H 2 O 2 (50%) Tanker HDPE Drum Suvidhi Enterprise, Vapi 44. NaHSO 3 20% Tanker Above Ground In House solution Tank 45. Soda 25 % Tanker Above Ground In House solution Tank 46. Mono chloro benzene Tanker Above Ground Tank Aarti Industries Ltd, Vapi 47. Rec. Mono chloro Tanker Above Ground In House benzene Tank 48. Ortho Di Chloro Benzene Tanker Above Ground Tank Aarti Industries Ltd, Vapi 49. Rec Ortho Di Tanker Above Ground In House chloro Benzene Tank 50. Aluminum Chloride Truck Bag Trevadi Chemical, Vadodara 51. Nahso 3 10 % Tanker Above Ground In House Tank 52. Soda Ash 10% Tanker Above Ground In House Tank 53. HQ Tanker Above Ground Tank Prolific Chemical, Tarapure 54. Acetone Tanker Underground Tank C,J, Shaha & Company,Mumbai 55. Rec. Acetone Tanker Underground Tank In House M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

65 Sr. No. Name of Raw Material Mode of Transport Type of Container Source 56. KOH Truck Bag Gujarat Alkali, Dahej 57. K 2 CO 3 Truck Bag Vital Organics 58. DETCL Tanker Above Ground Excel Industries, Roha Tank 59. Xylene Tanker Underground Tank Reliance Industries, Surat 60. Rec.Xylene Tanker Underground In House Tank 61. Stabilizer Tanker HDPE Drum Meckwell Industries, Vapi 62. DMS Truck HDPE Drum Aarti Industries Ltd, Vapi 63. Naoh 15% Tanker Above Ground In House Tank 64. Nahco 3 10% Tanker Above Ground In House Tanku 65. 2,5-DCNB Truck Bag Aarti Industries Ltd, Jhagadia 66. Charcoal Truck Bag Hershil Entriprise, Mumbai 67. Sodium Dithionate Truck Bag Remik Chemical Pvt. Ltd 68. Hydrazine Hydrate Tanker Glass Bottle Antares Chem Private Limited 69. 2,3,4 TFNB Truck HDPE Drum Aarti Industries Ltd, Tarapure 70. Extract 2,3,4 TFNB Truck HDPE Drum Aarti Industries Ltd, Tarapure 71. PAN W/C Truck Bag Aarti Industries Ltd, Vapi 72. DRY HCl Cylinder Bank Cylinder Gujarat Floro chem Ltd 73. Borex Truck Bag Sumukha Farm Products Pvt. Ltd. 74. Chlorine Truck Cylinder Gujarat Alkali, Dahej 75. Aniline Truck HDPE Drum Aarti Industries Ltd, Jhagadia M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

66 2.4 PROCESS DESCRIPTION MANUFACTURING PROCESS 1. HYDROGENATION 1.1 PRODUCT: DICHLORO BENZIDEN HYDROCHLORIDE (DCBH) BRIEF MANUFACTUIRNG PROCESS 1) ONCB reacts with hydrogen in presences of cat & caustic lye to form OCA & hydrazo.toluene is used as a solvent. 2) Reaction mass filter to remove catalyst. Catalyst is reused for next batch. 3) Remove water layer by separation. 4) OCA removed by making hydrochloride by hydrochloric acid 5) OCA hydrochloride neutral by soda ash & distilled out. 6) Hydro toluene reacts with Sulphuric acid to form Di Chloro benzidine sulphate. 7) Toluene layer neutralized & distilled, Recovered toluene used for next batch. 8) Di Chloro benzidine sulphate reacts with hydrochloric acid & salt to form Di Chloro benzidine hydrochloride, which on centrifuging get wet cake of product. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

67 CHEMICAL REACTION NO2 Cl + 5 H2 Ortho-Nitro Chloro Benzene Hydrogen 2 x x 2 Catlyst Toluene Cl H H N N Hydrazo 253 Cl + 4 H2O Water 4 x 18 Cl H H Cl Cl Cl N N + H 2SO4 + H2O H2N NH2.H2SO4+ H2O Hydrazo 253 Sulphuric Acid Water Di Chloro Benzidene Sulphate Water Cl Cl Cl Cl H2N NH2.H2SO4+ 2HCl HCl H2N NH2 HCl+ H2SO M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

68 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

69 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

70 1.2 PRODUCT: DI ANISIDINE BRIEF MANUFACTURING PROCESS ONA reacts with Hydrogen in the presence of catalyst to form OA and hydro toluene. The hydro toluene layer reacts with H 2 SO 4 and HCl in the presence of this urea to form Di anisidine CHEMICAL REACTION Step-1 Hydrogenation of Ortho nitro anisole 2 NO 2 OCH3 + 5H 2 Catalyst NaOH,Dichlone H 3 CO NH NH OCH 3 + 4H 2 O 2 X X X 18 1-methoxy-2-nitrobenzene 1,2-bis(2-methoxyphenyl)hydrazine Step-2 Rearrangement H 3 CO NH NH OCH 3 + HCl+ H 2 SO 4 HCl. H 2 N NH 2.HC 244 g/mole 1,2-bis(2-methoxyphenyl)hydrazine H 3 CO OCH g/mole Dianisidine M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

71 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

72 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

73 1.3 PRODUCT : OT BASE BRIEF MANUFACTURING PROCESS ONT reacts with Hydrogen in the presence of catalyst to form OT and hydro toluene. The hydro toluene layer reacts with H 2 SO 4 and HCl in the presence of thio urea to form OT Base. CHEMICAL REACTION Step-1 Hydrogenation of Ortho nitro anisole NO 2 H 3 C NH NH CH 3 2 CH3 + 5H 2 Catalyst NaOH,Dichlone + 4H 2O 2 X X X 18 1-methyl-2-nitrobenzene 1,2-bis(2-methylphenyl)hydrazine Step-2 Rearrangement H 3 C NH NH CH 3 + HCl+ H 2 SO 4 HCl. H 2 N NH 2.HC 212 g/mole 1,2-bis(2-methylphenyl)hydrazine H 3 C CH g/mole OT Base M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

74 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

75 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

76 1.4 PRODUCT : 1,3 D.F.B.(DI FLOURO BENZENE) BRIEF MANUFACTURING PROCESS 1) Di Flouro Chloro benzene reacts with hydrogen in presences of catalyst to get crude Di Flouro benzene. Tri ethyl amine use as a solvent. 2) Reaction mass filter to remove catalyst. Catalyst reuse for next batch. 3) Filter reaction mass acidify with hydrochloric acid to get crude DFA & TEA hydrochloride. 4) TEA hydrochloride the neutral with caustic flakes to get TEA which is recycled to next batch. 5) Crude DFB distilled to get pure DFB. CHEMICAL REACTION M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

77 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

78 1.5 PRODUCT : 3,5/2,6 DFA (DI FLOURO ANILINE) BRIEF MANUFACTURING PROCESS 1) Di chloro di flouro nitro benzene reacts with hydrogen gas in presences of catalyst, ammonia, caustic lye to get crude DFA. 2) Reaction mass then filters to remove catalyst. CATALYST reuse in next batch. 3) Remove water layer by separating. 4) After distillation gets pure product CHEMICAL REACTION M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

79 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

80 2 DIAZOTIZATION 2.1 PRODUCT :2,3/2,5 DCP (DI CHLORO PHENOL) BRIEF MANUFACTURING PROCESS 1) Di Chloro aniline reacts with sulphuric acid to for Di chloro aniline sulphate. 2) Di Chloro aniline sulphate reacts with mix acid to for dizo mass. 3) Dizo mass reacts with dilute sulphuric acid to form crude Di Chloro phenol. In 1) This reaction N 2 gas evold & spent acid generate. 4) Crude Di Chloro phenol separate out & distilled to get pure di chloro phenol. CHEMICAL REACTION M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

81 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

82 2.2 PRODUCT : 3,5 DI CHLORO NITRO BENZENE BRIEF MANUFACTURING PROCESS 1) DCPNA reacts with mix acid/nsa to get dizo mass. 2) Dizo mass reacts with formaldehyde & water to get crude 3.5 dichloride nitro 5) Benzene & dilute Sulphuric acid. 3) After separation & distilled get pure 3, 5 di chloro nitro benzene. CHEMICAL REACTION M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

83 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

84 2.3 PRODUCT : 1,3,5 TCB BRIEF MANUFACTURING PROCESS 2, 4, 6 TCA, NSA & H 2 SO 4 undergone for Diazotization. The Diazotized mass will decompose in presence of formaldehyde and water. The Organic layer getting after decomposition will wash and distilled we will get distilled 3, 5 TCB. CHEMICAL REACTION Cl NH 2 Cl + HO O S O NO2 Cl N=N HSO 4 Cl Cl Cl + + HCHO + H2O + H2SO4 + HCOOH + N2 Cl Cl Cl 2, 4, 6-TCA NSA Diaz Formaldehyde 1, 3, 5-TCB Formic Acid M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

85 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

86 2.4 PRODUCT : PARA FLOURO PHENOL (PFP) BRIEF MANUFACTURING PROCESS 1) Para Flouro aniline reacts with hydrochloric acid to form tri Flouro aniline 4) Hydrochloride. 2) Para Flouro aniline hydrochloride reacts with sodium nitrate to form dizo mass. 3) These dizo mass reacts with dilute Sulphuric acid to form crude Para Flouro 5) Phenol. This is extract with methyl isobutyl ketone. 4) After separation & distillation get pure Para Flouro phenol. 5) Distilled MIBK reuse for next batch. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

87 CHEMICAL REACTION M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

88 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

89 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

90 3 BROMINATION 3.1 PRODUCT: 3, 4, 5 TRI FLOURO BROMO BENZENE BRIEF MANUFACTURING PROCESS 1) Tri Flouro aniline reacts with Sulphuric acid to form Tri Flouro aniline sulphate. 2) Tri Flouro aniline sulphate reacts with sodium nitrate to form dizo mass. 3) These dizo mass reacts with hydrogen bromide solution & cuprous bromide to form crude triflouro bromo benzene & dilute sulphuric acid. 4) After separation & distillation get pure Tri Flouro Bromo benzene. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

91 CHEMICAL REACTION M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

92 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

93 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

94 3.2 PRODUCT:2 BROMO 4 FLOURO ACETANILIDE BRIEF MANUFACTURING PROCESS Para Flouro aniline reacts with acetic anhydride to gets acetic acid & PFA slurry. Acetic acid recover & remaining mass dumped in water to get PFA slurry. PFA slurry reacts with bromine & hydrogen peroxide to gate crude PFAC slurry. This is neutral by sodium bi sulphate solution & soda ash. Crude BFAC slurry extracted in mono chloro benzene for purification. Water separated removed mono chloro benzene to gate wet cake of BFAC. Recovered MCB reuse in next batch. Wet cake of BFAC on drying get pure product of Bromo Flouro Acetanalide. CHEMICAL REACTION M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

95 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

96 3.3 PRODUCT :DI CHLORO BROMO BENZENE BRIEF MANUFACTURING PROCESS Ortho di chloro benzene reacts with bromine in presences of aluminum chloride to get reaction mass of DCBrB & hydrogen bromide solution Reaction mass natural by sodium bi sulphate & soda ash. Crude reaction mass take for distillation & remove excess ODCB which is reuse in next batch. After distillation pure product DCBrB gets. CHEMICAL REACTION M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

97 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

98 4. CONDENSATION 4.1 PRODUCT :PARA FLOURO ANISOL BRIEF MANUFACTURING PROCESS PFP reacts with DMS & NaOH, then the organic layer will wash and distilled we will get pure PFA. CHEMICAL REACTION Step 1 OH O + O S O NaOH O CH 3 O CH 3 O H F 3 C H 3 C F Para Flouro Phenol DMS Para Flouro Anisole 40 + O CH 4 O S O Na + H2O 18 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

99 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

100 5. PRODUCT: QUINALPHOSE (TECH) (DIETHYL 2-HYDROXY THIOPHOSPHORYL CHLORIDE) BRIEF MANUFACTURING PROCESS 1) 2 hydroxyquazilinol react with di ethyl thiophosporil chloride in presences of Potassium carbonate & potassium hydroxide to form crude quinalphose. Acetone is as a solvent. 2) Acetone recover & use in next batch. 3) Crude quinalphose extract in xylene. 4) After separation of xylene extracted mass added stabilizer. Concentrated ML Sends for incineration. 5) Removed xylene gets pure quinalphose (tech grade) 6) Recovered xylene recycles in next batch. CHEMICAL REACTION M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

101 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

102 6 HYDROLYSIS 6.1 PRODUCT :4 CAP BRIEF MANUFACTURING PROCESS 2, 5 DCNB, Caustic lye Ammonia & water is undergone for hydrolysis. Then the reaction mass will hydrogenated in presences of catalysts. This reaction mass will react with H 2 SO 4 after filtration we will get crude 4CAP.It will undergone for charcoal treatment and filtration will get wet cake of 4CAP.The wet cake will drying and produce pure 4CAP. CHEMICAL REACTION M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

103 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

104 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

105 6.2 PRODUCT : 2 CAP BRIEF MANUFACTURING PROCESS 3, 4 DCNB, Caustic lye Ammonia & water is undergone for hydrolysis. Then the reaction mass will hydrogenated in presences of catalysts. This reaction mass will react with H 2 SO 4 after filtration we will get crude 2CAP.It will undergone for charcoal treatment and filtration will get wet cake of 2CAP.The wet cake will drying and produce pure 2CAP. CHEMICAL REACTION M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

106 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

107 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

108 6.3 PRODUCT :2,3,4 TFA BRIEF MANUFACTURING PROCESS 2, 3, 4-TFNB, Water& NH 3 are hydrogenated in presence of catalyst. Then the reaction mass will filtered. The aqueous layer will further treat and organic layer will distilled under Vacuum. By distillation we will get Pure 2, 3, 4 TFA. CHEMICAL REACTION M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

109 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

110 7 CHLORINATION 7.1 PRODUCT: 2, 6 DCPNA BRIEF MANUFACTURING PROCESS 1) Wet cake of 2, 6 DCPNA on drying gets dry 2, 6 DCPNA. CHEMICAL REACTION M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

111 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

112 7.2 PRODUCT: 2, 4, 6 TCA BRIEF MANUFACTURING PROCESS Aniline reacts with Chlorine and Hydrochloric acid in the presence of MCB to form 2, 4, 6 Tri Chloro Aniline. CHEMICAL REACTION M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

113 MATERIAL BALANCE M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

114 2.5 DETAILS OF SOLVENT RECOVERY SYSTEM & ITS MANAGEMENT Toluene, Acetone, Xylene, MCB and MIBK are the solvent to be used in the process. TABLE: 2.5 DETAILS OF SOLVENT RECOVERY Sr. No. Product Name of Solvent Condenser Details Primary service Secondary service M2 M2 1 QP ACETONE 6 chill water 1.5 chill water 2 QP XYLENE 12 cooling water 8 chill water 3 DCBH TOLUENE 30 cooling water 20 chill water 4 DCPNA MCB 20 cooling water 10 chill water 5 PFP MIBK 15 cooling water 10 chill water 2.6 RESOURCE REQUIREMENT INFRASTRUCTURE FACILITIES (LAND) Expansion will be carried out at existing plot no. 902,923, Phase-III, GIDC Estate, Vapi , Dist. Valsad, Gujarat. The land possession document is attached as annexure XII. The total plot area of the unit is 26,271 sq. m. The green belt area is sq. m. The photograph of existing plant area and proposed plant area are attached as annexure- XIII. The plant layout is attached as annexure- IX. Details of infrastructures is covered under following table no. 2.6 Details of breakup of plot area are covered under following Table no M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

115 TABLE: 2.6 DETAILS OF INFRASTRUCTURE Sr. Particular Land Area Nos. No. (sq. m.) 1. Watchman Cabin Office building D.G. set room Godown Driver room Sanitary block Labour room Engineering work shop 9. Ware house Work shop DCS Control room TABLE: 2.7 LAND USE BREAK UP OF TOTAL PLOT AREA Sr. Particular Land Area Land Area in % No. (sq. m.) 1. Watchman Cabin Office building Bromo plant A. Tank farm B. Storage yard QP & 2HQ Plant A. QP Godown Flouro plant M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

116 Sr. Particular Land Area Land Area in % No. (sq. m.) 6. Storage yard Petroleum storage tank farm 8. D.G. set room D.C.B.H.-II U/G Tank D.C.B.H.-IV D.C.B.H.-III DCBH Godown Godown Spin flash dryer Hydrogenation Plant DCP-DCNB Plant DFB Plant Tank Farm Residue ST.Yard ST. Tank Farm Catalyst incinerator Hydrogen shed Driver room Sanitary block Salt Solution Plant ETP A. ETP Labour room M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

117 Sr. Particular Land Area Land Area in % No. (sq. m.) 29. Engineering work shop 30. Ware house Work shop MEE Plant DCS Control room Green Belt Area Open Area Total WATER REQUIREMENT Water consumption is primarily for processing, washing, boiler, cooling, DM plant, gardening and domestic purpose. The existing fresh water requirement for domestic and industrial purpose is met through GIDC water supply. GIDC has its own water reservoir and distribution network throughout the GIDC Estate. A letter from GIDC stating that the proposed additional quantity of water will be provided is attached as annexure-xii The unit will also use recovered water from R.O. system and MEE plant as the unit has proposed zero liquid discharge unit. Average daily fresh water consumption of the unit is about 404 KL/day. The unit will use additional fresh water of 195 KL/day for proposed expansion. Unit will also use recovered water of 268 KL/day. So, total water consumption will be 867 KL/day (599 KL/day of fresh water KL/day of recycled water) after proposed expansion. Stream wise bifurcation of water consumption is covered in following Table M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

118 TABLE: 2.8 DETAILS OF WATER CONSUMPTION Sr. No. Section Water Consumption KL/Day Existing Water as per Consumption as CCA per Proposed no.awh- Expansion Domestic Industrial 2.1 Process (Fresh) + 20(Recovered) 2.2 Washing DM plant Cooling (Fresh) (Recovered) 2.5 Gardening Total (Industrial) (Fresh) Total( Domestic+ Industrial) (Recovered) (Fresh) (Recovered) Total 327 (Fresh) + 20(Recovered) 157 (Fresh) + 268(Recovered) 529 (Fresh) + 288(Recovered) 599 (Fresh) (Recovered) M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

119 FIGURE: 2.1 WATER BALANCE DIAGRAM (EXISTING) Water from Reaction & Raw material KL/Day GIDC supply 404 KL/Day Process 129 KL/Day Effluent KL/Day Water going to spent Sulphuric acid KL/Day Washing 10 KL/Day Cooling tower 215 KL/Day Gardening 20 KL/Day Domestic 30 KL/Day To Incinerator 2.44 KL/Day KL/Day Neutralization KL/Day Effluent From washing 10 KL/Day Cooling tower Blow down 6.7 KL/Day Sewage 20 KL/Day Neutral 62.3 KL/Day ETP 99 KL/Day Treated effluent is sent to CETP 99 KL/Day M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

120 FIGURE: 2.2 WATER BALANCE DIAGRAM (PROPOSED EXPANSION) Recovered Water from Process 20 KL/Day GIDC supply 599 KL/Day KL/Day recovered water = 867KL/Day Process 347 KL/Day ( ) Washing Cooling tower DM Plant Domestic 30 KL/Day 425 KL/Day 15 KL/Day 70 KL/Day 268 KL/Day Effluent to Incinerator 11.7 KL/Day Effluent 149 KL/Day Water going to spent Sulphuric acid KL/Day Effluent 137 KL/Day Effluent From washing 30 KL/Day Cooling tower Blow down 70 KL/Day DM Plant 5 KL/Day Sewage 60 KL/Day STP 30 KL/Day ETP 167 KL/Day RO KL/Day 30 KL/Day Use for gardening purpose 238 KL/Day Treated effluent Send to RO KL/Day RO Reject 72 KL/Day MEE 72 KL/Day RO-2 Permeate 53 KL/Day Recovered 68 KL/Day 4 KL/Day Rejected Solid will be send to TSDF RO-1 Permeate M/s. JYOTI OM CHEMICAL RESEARCH 117KL/Day CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

121 2.6.3 ENERGY REQUIREMENT The energy requirement in terms of power and fuel for proposed unit is shown in following Table 2.9. TABLE: 2.9 FUEL CONSUMPTION REQUIREMENT Sr. Name of Requirement Source No. Fuel Existing Quantity As Proposed Quantity Total Quantity Per Consent No AWH Diesel 100 Lit/Hr 150Lit/Hr 250 Lit/Hr Local supplier 2. Furnace 425 Lit/Hr -425 Lit/Hr 000 Lit/Hr Local supplier Oil 3. Energy - Electricity 1200 KVA 800 KVA 2000 KVA DGVCL DETAILS OF ENERGY DISTRIBUTION/UTILISATION Details of energy distribution are covered in below table no TABLE: 2.10 ENERGY REQUIREMENT Sr. No. Name of Equipment Existing Connected Energy in HP Proposed Connected Energy in HP 1. Reactor Cooling Tower Boiler Dryer Nutch Filter Centrifuge Pump & Motor Pulvariser Compressor Blender Lift Blower Reactor Total Total Connected Energy in HP M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

122 2.6.4 UTILITIES For the proposed expansion project the utilities to be installed will be Cooling tower, D.G set, etc. Details of utilities services required for the proposed project are given in following Table And Table TABLE: 2.11 DETAILS OF EXISTING UTILITIES Sr. No. Name of The Utilities Capacity Nos. MOC 1. Chilling Plant 75 TR 4 CI 2. Chilling Plant 35 TR 1 CI 3. Chilling Plant 150 TR 1 CI 4. Cooling Tower 400 TR 1 PPFRP 5. Cooling Tower 300 TR 5 PPFRP 6. Cooling Tower 300 TR 1 WOODEN 7. Cooling Tower 250 TR 6 PPFRP 8. Cooling Tower 150 TR 1 PPFRP 9. Cooling Tower 100 TR 4 PPFRP 10. Cooling Tower 30 TR 1 PPFRP 11. Air Compressor 60 CFM 2 CI 12. Air Compressor 80 CFM 2 CI TABLE: 2.12 DETAILS OF PROPOSED UTILITIES Sr. No. Name of the Utilities Capacity Nos. MOC 1. Chilling Plant 150 TR 1 CI 2. Cooling Tower PPFRP 3. Air Compressor 80 CFM 2 CI M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

123 2.6.5 MANPOWER The manpower required for the project as well as during the construction/ commissioning activities will be employed from the local area. TABLE: 2.13 MAN POWER REQUIREMENT Phase of project During construction During commissioning During operations Type of Labor No. of Workers (Existing) No. of Workers (Proposed Scenario) Contractual Contractual Managerial Skilled Un-skilled Total EQUIPMENTS/MACHINERIES No. of Workers (Total) Details of equipment and machineries are given in below table no 2.14.The list is quite comprehensive and provide overall image of the processing area. TABLE: 2.14 DETAILS OF EQUIPMENT AND MACHINERIES Sr. No. Existing Name of The Equipment MOC Capacity in KL Nos. 1. Autoclove SS Fanda Filter SS m Vessel SS Vent Tank MS Storage Tank SS Tank MS Sparkler Filter SS m Polosh Filter SS m Pump CI 200/ Pump SS316 20/ Cooling Tower PP/FRP 300 TR 5 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

124 Sr. No. Name of The Equipment MOC Capacity in KL Nos. 12. Reactor SS Reactor SS Reactor GLR Reactor GLR Tank SS Tank MS Tank MS Pump CI 100 / Pump SS316 20/ Pump CI 25/ Condenser GRP 15 m Column MS 300/6000 m Condenser SS m Ejector System SS316 5 TOR Cooling Tower PP/FRP 300 TR Reactor SS Reactor SS Reactor GLR Reactor GLR Tank SS Tank MS Tank MS Pump CI 100 / Pump SS316 20/ Column SS /5000 m Ejector System SS316 5 TOR Pump PP 20/ Reactor HDPE Reactor GLR Reactor GLR 16 2 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

125 Sr. No. Name of The Equipment MOC Capacity in KL Nos. 42. Reactor PP Pump CI 250/ Pump CI 100/ Pump PFA 25/ Pump PP 20/ Pump SS316 20/ Pump PVDF 50/ Storage Tank MS Storage Tank HDPE 20/ Cooling Tower PP/FRP Coloumn SS /7 m Condenser SS Condenser GRP m Scrubber HDEP 600/3000 m Reactor SS Condenser SS316 4 m Condenser MS I - 6 m Pump CI 20/ Pump SS316 20/ Tank MS Storage Tank MS Storage Tank PP/FRP Filter MS 5 m Filter MS 5 m Cooling Tower PP/FRP 250 TR Chilling Compressor CI 75 TR Chilling Compressor CI Chilling Compressor CI Chillier Condenser MS 48 m Cooling Tower PP/FRP 250 TR 3 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

126 Sr. No. Name of The Equipment MOC Capacity in KL Nos. 72. Cooling Tower WOODEN 300 TR Oil & Grease Tarp RCC Collection Tank RCC Equalisation Tank RCC Equalisation Tank RCC Equalisation Tank RCC Bioreactor RCC Bioreactor RCC Clarifier RCC Clarifier RCC Sand Filter MS/RL Carbon Filter MS/RL Pump SS316 20/ Pump CI 20/ Pump PP 20/ Tank HDPE MEE TI/SS 3 KL / HR Stripper SS316 3 KL /HR 1 Proposed 1. Reactor SS Reactor SS Reactor GLR Reactor GLR Ejector System SS316 5 TOR 1 6. Cooling Tower PP/FRP 250 TR 2 7. Pump SS m 3 /20 MH Pump CI 200 m 3 /30 MH 8 9. Pump CI 20 m 3 /25 MH Pump PP 30 m 3 /30 MH Pump PP 20 m 3 /20MH 10 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

127 Sr. No. Name of The Equipment MOC Capacity in KL Nos. 12. Storage tank MS Storage Tank MS Storage Tank MS Storage Tank SS Storage Tank SS Storage Tank SS Storage Tank SS Storage Tank HDPE Storage Tank HDPE Storage Tank HDPE Storage Tank HDPE Scrubber (Water Cir) HDPE 600 DIA * 3000 H 24. Scrubber (Caustic Cir) HDPE 600 DIA * 3000 H 2.7 POLLUTION POTENTIAL SCENARIO The details of pollution generation in terms of effluent generation, sewage generation, and flue gas emission, process emission and hazardous waste generation is covered in this section EFFLUENT AND SEWAGE GENERATION As per consent, the industrial effluent generation is 79 KL/Day and sewage generation is 20 KL/Day. Concentrated & toxic effluent stream of 11.7 KL/Day is sent for inhouse incineration. Existing effluent is treated in ETP having primary, secondary and tertiary treatment. Treated water is sent to CETP. After proposed expansion, total industrial effluent generation will be 242KL/Day (79 KL/Day KL/Day).After expansion sewage generation will be 60 KL/Day (20 KL/Day + 40 KL/Day).After proposed expansion, concentrated & toxic effluent stream of 11.7 KL/Day is sent to common incineration facility for incineration. Remaining water will be treated in unit s own treatment plant and recycled back using RO and MEE system. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

128 The details of waste water generation are given in following Table.2.15 TABLE: 2.15 DETAILS OF WASTE WATER GENERATION Sr. No. Section Waste Water Generation KL/Day Existing Quantity As per Consent No AWH Waste water Generation As Per Proposed Expansion Total 1. Domestic Industrial 2.1 Process Washing DM plant Cooling Total (Industrial) Total ( Domestic + Industrial) * * Unit will become zero liquid discharge GASEOUS EMISSION The sources of flue gas emission are two D.G. sets (emergency use only). There will be one additional D.G. stack due to proposed expansion. Process emission is from one stack attached to reactor of 2-Bromo 4 Flouro Acetanilide/Di Chloro Bromo Benzene. There will be one additional stack attached to chlorinator reactor, one stack of SFD Dryer and one stack attached to Dizo vessels due to proposed expansion. Details of stack height, fuel consumption, air pollution control system etc. are shown in below Table TABLE: 2.16 DETAILS OF FLUE GAS EMISSION Stack. No. Stack Attached To Stack Height (Meter) Type of Fuel Parameter Permissible Limit 150mg/Nm 3 As Per Consent No. AWH DG Set (450 KVA) L/Hr Particulate Matter SO PPM M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

129 Stack. No. Stack Attached To Stack Height (Meter) Type of Fuel Parameter NOx 2. DG Set L/Hr Particulate (380 KVA) Matter SO 2 NOx As Per Proposed Expansion 3. DG Set Particulate (750 KVA) L/Hr Matter SO 2 NOx Permissible Limit 50 PPM 150mg/Nm PPM 50 PPM 150mg/Nm PPM 50 PPM TABLE: 2.17 DETAILS OF PROCESS EMISSION Stack No. Stack Attached To As Per Consent 1. Reactor of 2- Bromo 4Flouro Acetanilide/ Di Chloro Bromo Benzene Stack Height (Meter) APCM 16 Water Scrubber followed by Alkali Scrubber As Per Proposed Expansion 2. Chlorinator 11 Water Scrubber followed by Alkali Scrubber Probable Pollutants Br 2 HBr Cl 2 HCl Permissible Limit 09mg/Nm 3 20 mg/nm 3 09 mg/nm 3 20 mg/nm 3 3. SFD dryer 11 Water scrubber PM 150 mg/nm 3 4. Dizo vessels 11 Water Scrubber followed by Alkali Scrubber NOx HCl 25mg/Nm 3 20 mg/nm 3 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

130 TABLE: 2.18 DETAILS OF PROCESS GASES SEND TO SCRUBBER Sr. No. Gases Come out from process Quantity in MT/Day 1. HBr Gas-( Di Chloro Bromo Benzene) 2. HCl Gas (2,4,6 TCA)/OR HCl Gas (DCPNA) /OR HAZARDOUS WASTE GENERATION The following type of hazardous waste will be generated from the operational activities. All the waste will be stored separately in a designated storage area. TABLE: 2.19 DETAILS OF HAZARDOUS WASTE GENERATION Sr. Type of Cat. Quantity Quantity Treatment And Disposal No. Hazardous Waste No. as Per Consent (MT/Year) as Per Proposed Expansion (MT/Year) 1. ETP Waste Collection, Storage, transportation, disposal at TSDF site. 2. MEE Salt Collection, Storage, transportation, disposal at TSDF site. 3. Distillation Residue Collection, storage, Transportation, disposal by sending to Common Incineration. /co processing site. 4. Discarded Containers Collection, Storage, Decontamination and reuse M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

131 Sr. No. Type of Cat. Quantity Quantity Treatment And Disposal Hazardous Waste No. as Per Consent (MT/Year) as Per Proposed Expansion (MT/Year) Bags/ Liners or sold to actual reuses. 5. Used Oil KL/Year 2.4 KL/Year Collection,storage, Transportation, Disposal by selling registered re processors 6. Spent Catalyst Collection, Storage, Transportation, disposal at registered regenerators. 7. Spent Solvent Collection, storage, Transportation, disposal by sending to Common Incineration./ co processing site. 8. Spent Filter Cloth Nos./Year 1500 Nos./Year Collection, Storage, Transportation, disposal at TSDF site. 9. Date Expired Pesticide Collection, storage, Transportation, disposal by sending to Common Incineration. / Co processing site. 10. Spent Carbon Collection, storage, Transportation, disposal by sending to Common Incineration. / Co processing site. 11. Gypsum Collection, Storage, Transportation, disposal at M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

132 Sr. Type of Cat. Quantity Quantity Treatment And Disposal No. Hazardous No. as Per as Per Waste Consent Proposed (MT/Year) Expansion (MT/Year) TSDF site/cement industry. 12. Insulation Waste Collection, Storage, Transportation, disposal at TSDF site. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR PDF compression, OCR, web optimization using a watermarked evaluation copy of CVISION PDFCompressor

133 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Chapter 3 BASELINE ENVIRONMENT STATUS 3.1 INTRODUCTION It is essential to monitor the environment quality prevailing in the surrounding area before implementation of the proposed project for assessing the environmental impacts from proposed project. The Environment status within the study area could be used for identification of significant environmental issues to be addressed in the impact assessment study. The impact from an existing industrial project on its surrounding environment are mainly regulated by, The nature of the pollutants, Their quantities discharged to the environment, Existing environment quality Assimilative capacity of the surrounding environment and Topography and terrain of the project site. In order to identify and establish the extent of likely impacts, it is necessary to gather information on existing environmental quality relating to various components of the environment. Primary data were collected for baseline collection. Secondary data were also gathered for remaining information like meteorological data, Socio-economic data, Ecological data and Land use data. For the purpose of collection of primary data, study area was selected within 10 km radius taking as project site as a center which also included towns and villages. The main factor of local, sub-regional and regional meteorology that influence the air quality in area of the proposed project are diurnal and seasonal wind pattern and wind direction, humidity,temperature etc. Vapi is a very important industrial center having the advantage of close proximity to Mumbai, the commercial capital of India. Due to NH-8 and Vapi railway station, GIDC is well connected by road and rail to rest parts of the country. Communication facility available in the area is good. Water is available from GIDC. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.1

134 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Vapi is large industrial estate with a number of chemical plants, paper mill, textile processing plants and other allied industries totaling to about more than 705 units. Lists of major industries in the Vapi are given in Table no. 3.1 TABLE: 3.1 LIST OF MAJOR INDUSTRIES IN THE VAPI Sr. No. Name Of The Company Type Of Industry 1. K.V. Arochem Limited Organic chemicals 2. Aegis Chemicals Limited Chemical 3. Amantech Chemicals Pvt. Limited Chemical 4. Arochem Industries Chemical 5. Bhageria Dye-Chem Limited Chemical 6. Brighton Inorganic Pvt. Limited Chemical 7. Manglam organics Limited Chemical 8. Phthalo colours & chemicals Pvt. Limited (Unit-1) Pigment 9. Sarna Chemicals Pvt. Limited Dye intermediates 10. Hindustan inks and organics pigments Limited 11. Phthalo Colours & Chemicals (I) Pvt. Limited (Unit II) Chemicals Pigments 12. Mangalam drugs Limited Bulk drugs and intermediated 13. Dhiraj Intermediates Pvt. Limited (Unit II) Dyes Intermediates 14. Dhiraj Intermediates Pvt. Limited(Unit I) Pigments 15. Makwell Plasticizer Pvt. Limited Chemical 16. Makwell Organics Pvt. Limited Chemical 17. Mitsu Limited Agrochemicals 18. Nascent Chemicals Limited Chemical 19. Nath Industrial hem Limited Chemical 20. Numet Industries Chemical 21. Pidilite Industries Chemical M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.2

135 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. No. Name Of The Company Type Of Industry 22. Rishiroop Organics Pvt. Limited Chemical 23. Supreet Chemicals Pvt. Limited Chemical 24. United Phosphorous Limited Agrochemicals 25. Vadilal Chemicals Chemical 26. Perstorp Aegis Limited Chemical 27. Amoli Organics Limited Bulk drugs 28. Essel Mining and industries Chemicals 29. Duphar interfran Limited Pharmaceutical 30. MM Labs Pharmaceutical 31. Sun Pharmaceuticals Ind. Ltd. Pharmaceutical 32. Umedica Laboratories Limited Pharmaceutical 33. Supreme Non wovens Limited Roof liners 34. Daman Ganga Boards Limited Paper 35. Nathani Paper Mills Limited Paper 36. NR Paper Mills Limited Paper 37. Ruby Macons Limited Paper 38. Shah Paper Mills Limited Paper 39. Prayag tex prints Limited Textiles 40. Navin Chemicals Dyes 41. Techno Colour Corporation Dyes 42. Pramanik tex fab Pvt. Ltd. Textile 43. Gujarat Axles and forgins pvt. Ltd. Engineering 44. Gujarat Electromag Industries Pvt. Ltd. Engineering 45. Kabra Extru- Technics Limited Engineering 46. Pragati Engineering Engineering 47. Bilag Industries Agrochemicals 48. Micro Inks Inks & Organic Pigments 49. Themis Medicare Limited. Pharmaceutical 50. Ritcher Themis Ltd. Pharmaceutical M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.3

136 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. No. Name Of The Company Type Of Industry 51. Perstrop Industries Ltd. Agrochemicals 52. Heranba Industries Ltd. Agrochemicals 53. Rotam India Ltd. Agrochemicals M/s. Aarti Industries Ltd. (Alchemie Organics Division) is located in GIDC Estate, Vapi. The location aspects of the site are provided in Table no.1.5 in Chapter 1. For Baseline Study, the monthly meteorological data for study period from March 2014 to May 2014 is shown at below Table no.3.2. Meteorological data like hourly wind speed, hourly wind direction, hourly temperature, hourly relative humidity and monthly rainfall of Valsad station are attached as annexure-xv. 3.2 WINDROSE Based on the meteorological data, wind rose have been prepared for the summer season period between the March 2014 to May The wind rose prepared from same data is shown at Figure 3.1 TABLE: 3.2 METEOROLOGICAL DATA (Data from Indian Meteorological Department, Ahmadabad, Station:-VALSAD) Month -- Temp. ( C) Relative Humidity (%) Wind Speed km/hr March-14 Min Max Average Apr-14 Min Max Average May-14 Min Max Average Rainfall mm M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.4

137 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. FIGURE: 3.1 WIND ROSE DIAGARM FOR PEROID OF MARCH TO MAY 2014 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.5

138 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. FIGURE: 3.2 WIND CLASS FREQUENCY DISRTIBUTION 3.3. AIR ENVIRONMENT AMBIENT AIR QUALITY (AAQ) The basic objective of collection of base line data for air environment is to identify project specific air pollutants being released into atmosphere, which will have significant impact on air environment of immediate locality of the proposed project site. For assessment of the baseline data it is important to specify the study area in respect of the location of the proposed project. It was decided to the study ambient air quality at 8 locations in the different direction in probable impact zone including the project site LOCATION OF AAQ MONITORING STATIONS Ambient air quality stations were chosen considering the various factors like the most prevailing wind direction, pockets of habitation, available infrastructure facilities like power supply, accessibility etc. The location of AAQ monitoring stations are shown in Figure no.3.3 and Table no M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.6

139 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. TABLE: 3.3 DETAILS OF SAMPLING LOCATION OF AMBIENT AIR QUALITY MONITORING Sr. Location Direction from the Distance in District No. site Km 1. Project Site (A1) Valsad 2. Karvad (A2) SE 1.59 Valsad 3. Khacharva (A3) ENE 2.72 Valsad 4. Chanod (A4) SW 2.24 Valsad 5. Dungrifalia (A5) S 1.61 Valsad 6. Chharwada (A6) NNW 2.5 Valsad 7. Rata (A7) NE 2.8 Valsad 8. Balitha(A8) NW 3.93 Valsad 9. Vankachi(A9) ESE 4.04 Valsad FIGURE: 3.3 LOCATION OF AMBIENT AIR QUALITY MONITORING STATIONS N M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.7

140 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI BASE LINE DATA The ambient air quality monitoring was carried out during period of March, 2015 to May, Monitoring details like location, monitoring date, concentration of pollutants are attached as annexure-xvi. The frequency of monitoring was twice in a week for a period of 12 weeks to assess the existing the sub regional air quality status. All the sampling locations were monitored for PM 2.5, PM 10, SO 2 and NO x, HCl, HBr and Br 2 on 24 hr basis to enable the comparison with ambient air quality standards prescribed by the Central Pollution Control Board (CPCB). Based on the data obtained through ambient air quality survey statement showing maximum, minimum average concentration values of different monitoring location in the study area have been computed and presented at Table no.3.4. TABLE: 3.4 AMBIENT AIR QUALITY STATUS OF STUDY AREA PM 10 µg/m 3 (Permissible Limit : 100 µg/m 3 ) Location Min. Value Max. Value Avg. Value Project Site (A1) Karvad(A2) Khacharva(A3) Chanod(A4) Dungrifalia(A5) Chharwada(A6) Rata(A7) Balitha(A8) Vankachi(A9) PM 2.5 µg/m 3 (Permissible Limit : 60 µg/m 3 ) Location Min. Value Max. Value Avg. Value Project Site (A1) Karvad(A2) Khacharva(A3) M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.8

141 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Location Min. Value Max. Value Avg. Value Chanod(A4) Dungrifalia(A5) Chharwada(A6) Rata(A7) Balitha(A8) Vankachi(A9) SO 2 µg/m 3 (Permissible Limit :80 µg/m 3 ) Location Min. Value Max. Value Avg. Value Project Site (A1) Karvad(A2) Khacharva(A3) Chanod(A4) Dungrifalia(A5) Chharwada(A6) Rata(A7) Balitha(A8) Vankachi(A9) NO X µg/m 3 (Permissible Limit : 80 µg/m 3 ) Location Min. Value Max. Value Avg. Value Project Site (A1) Karvad(A2) Khacharva(A3) Chanod(A4) Dungrifalia(A5) Chharwada(A6) Rata(A7) Balitha(A8) M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.9

142 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Location Min. Value Max. Value Avg. Value Vankachi(A9) HCl µg/m 3 Location Min. Value Max. Value Avg. Value Project Site (A1) BDL BDL BDL Karvad(A2) BDL BDL BDL Khacharva(A3) BDL BDL BDL Chanod(A4) BDL BDL BDL Dungrifalia(A5) BDL BDL BDL Chharwada(A6) BDL BDL BDL Rata(A7) BDL BDL BDL Balitha(A8) BDL BDL BDL Vankachi(A9) BDL BDL BDL VOC Location Min. Value Max. Value Avg. Value Project Site (A1) Karvad(A2) Khacharva(A3) Chanod(A4) Dungrifalia(A5) Chharwada(A6) Rata(A7) <1 <1 <1 Balitha(A8) Vankachi(A9) NH 3 (µg/m 3 ) Location Min. Value Max. Value Avg. Value Project Site (A1) Karvad(A2) Khacharva(A3) Chanod(A4) Dungrifalia(A5) M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.10

143 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Location Min. Value Max. Value Avg. Value Chharwada(A6) Rata(A7) Balitha(A8) Vankachi(A9) Chlorine Location Min. Value Max. Value Avg. Value Project Site (A1) <0.1 <0.1 <0.1 Karvad(A2) <0.1 <0.1 <0.1 Khacharva(A3) <0.1 <0.1 <0.1 Chanod(A4) <0.1 <0.1 <0.1 Dungrifalia(A5) <0.1 <0.1 <0.1 Chharwada(A6) <0.1 <0.1 <0.1 Rata(A7) <0.1 <0.1 <0.1 Balitha(A8) <0.1 <0.1 <0.1 Vankachi(A9) <0.1 <0.1 <0.1 CO (mg/m 3 ) Location Min. Value Max. Value Avg. Value Project Site (A1) Karvad(A2) Khacharva(A3) Chanod(A4) Dungrifalia(A5) Chharwada(A6) Rata(A7) Balitha(A8) Vankachi(A9) HBr Location Min. Value Max. Value Avg. Value Project Site (A1) BDL BDL BDL Karvad(A2) BDL BDL BDL M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.11

144 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Location Min. Value Max. Value Avg. Value Khacharva(A3) BDL BDL BDL Chanod(A4) BDL BDL BDL Dungrifalia(A5) BDL BDL BDL Chharwada(A6) BDL BDL BDL Rata(A7) BDL BDL BDL Balitha(A8) BDL BDL BDL Vankachi(A9) BDL BDL BDL Br 2 Location Min. Value Max. Value Avg. Value Project Site (A1) BDL BDL BDL Karvad(A2) BDL BDL BDL Khacharva(A3) BDL BDL BDL Chanod(A4) BDL BDL BDL Dungrifalia(A5) BDL BDL BDL Chharwada(A6) BDL BDL BDL Rata(A7) BDL BDL BDL Balitha(A8) BDL BDL BDL Vankachi(A9) BDL BDL BDL *BDL: Below Detectable Limit Based on data obtained, it could be stated that, during the study period the value of PM 10 at monitored locations is ranged between μg/m 3 while the value PM 2.5 fluctuates in the range of μg/m 3. The value of SO 2 and NO x were observed to be in the range of μg/m 3 and μg/m 3 respectively. The values of HCl, HBr and Br 2 were found Below Detectable Limit. The average concentration of PM 10, PM 2.5, SO 2 and NO x are within prescribed limit at all locations. These concentrations at all AAQM locations were primarily caused by local phenomena including vehicular movement and natural dusting due to human activities and wind movement. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.12

145 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. 3.4 WATER ENVIRONMENT There are two categories of water environment: 1) Ground water: - accumulation in deeper strata of ground and 2) Surface water: - river, drains, canals, ponds etc. Five locations were selected for ground water sampling and eight locations were selected for surface water sampling. Collected samples were analyzed for drinking water quality parameters like physic-chemical parameters and heavy metals. During study period, the sampling was done for one time. The map viewing location for sampling points is shown at Figure 3.4 and Figure 3.5. The analysis results are presented at Table no.3.8 and Table no.3.9. FIGURE: 3.4 LOCATION OF GROUND WATER QUALITY MONITORING STATIONS M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.13

146 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. TABLE: 3.5 DETAILS OF GROUND WATER MONITORING LOCATIONS Sr. No. Sampling locations 1. GIDC water supply (Project Site) Sample ID Distance & Direction w.r.t project site Type of Area GW1 -- Industrial 2. Khacharva GW Km, ENE Residential Area 3. Chanod GW Km, SW Residential Area 4. Rata GW4 2.8 Km, NE Residential Area 5. Balitha GW Km, NW Residential Area FIGURE: 3.5 LOCATION OF SURFACE WATER QUALITY MONITORING STATIONS M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.14

147 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. TABLE: 3.6 DETAILS OF SURFACE WATER MONITORING LOCATIONS Sr. No. Sampling locations Sample 1. GIDC water supply (Project Site) ID Distance & Direction w.r.t project site Type of Area SW1 -- Industrial 2. Khacharva SW Km, ENE Residential Area 3. Chanod SW Km, SW Residential Area 4. Rata SW4 2.8 Km, NE Residential Area 5. Balitha SW Km, NW Residential Area Sampling Method The samples were collected as per Indian standard (IS: 3025 (part-1) for ground water and surface water quality assessment. Analysis Method The analysis method followed for the measuring different parameters to evaluate water quality is given in Table no TABLE: 3.7 METHOD OF ANALYSIS Sr. No. Parameters Applicable Standard Method of Analysis 1. Color in Pt. Co. Sc. APH (22 nd Edition) Spectrophotometer (analogous to APHA 2120 C) (Platinum Cobalt Method) 2. ph APHA(22 nd Edition) 4500 H + B Electrometric Method 3. Total hardness APHA(22 nd Edition) 2340 C: Page 2 37 (as CaCO 3 ) in mg/l EDTA Titrimetric Method 4. Chloride (as Cl) in APHA(22 nd Edition) 4500-Cl-Bmg/l Argentometric method 5. TDS in mg/l APHA (22 nd Edition) 2540 C Total Dissolved Solid Dried at 180 C Detection Limit M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.15

148 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. No. Parameters Applicable Standard Method of Analysis Detection Limit 6. TSS in mg/l APHA (22 nd Edition) 2540-D-Total 4 Suspended Solids Dried at C 7. Calcium (as Ca) in APHA (22 nd Edition) Ca : B Page 3 2 mg/l 65 EDTA Titrimetric Method 8. Magnesium(as Mg) in APHA(22 nd Edition) Mg : B 2 mg/l Page 3 84 Calculation Method 9. Sulphate (as SO 4 ) in APHA (22 nd Edition) 4500 SO4-2 E: Page 1 mg/l Turbid metric Method/ IS 3025 (Part 24) 1986 (Reaffirmed 1986) Gravimetric Method 10. Alkalinity (as CaCO 3 ) APHA (22 nd Edition) 2320 B: Page 2 2 in mg/l 27 Titration Method 11. COD in mg/l APHA(22 nd Edition) 5220 B Open 4 Reflux Method 12. BOD in mg/l IS: 3025 (Part 44) (Reaffirmed 1999) 13. MPN Coliform APHA C -- Count 14. E.coli APHA D (Presence Absence Test) Nitrate in mg/l Spectrophotometer Iron (as Fe) in mg/l By NOVA 60 spectrophotometer (Triazine) Fluoride (as F) in mg/l By NOVA 60 spectrophotometer Residual Free Iodometric method 1 Chlorine in mg/l 19. Sodium in mg/l Flame photo meter Potassium in mg/l Flame photo meter Ammonical Nitrogen in mg/l APHA-4500 N ORGBnC macro and semi-micro KJELDHAL 2.8 M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.16

149 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. TABLE: 3.8 WATER QUALITY PARAMETERS (GROUNDWATER SOURCES) Parameter Unit IS : 1991 Desirable Limit Permissible Limit Project site (GW1) Khacharva (GW2) Chanod (GW3) Rata (GW4) Balitha (GW5) ph Color Pt co.sc TDS mg/l Total hardness mg/l (as CaCO 3 ) Chloride (as Cl) mg/l Calcium mg/l (as Ca) Magnesium mg/l (as Mg) Iron (as Fe) mg/l Fluoride (as F) mg/l Sodium (as Na) mg/l Potassium (as K) mg/l Sulphate mg/l (as SO 4 ) Nitrate mg/l Alkalinity(as mg/l CaCO 3 ) COD mg/l <4 <4 <4 <4 <4 BOD mg/l <4 <4 <4 <4 <4 Free Residual Chlorine mg/l ND ND ND ND ND M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.17

150 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Parameter Unit IS : 1991 Desirable Limit Permissible Limit Project site (GW1) Khacharva (GW2) Chanod (GW3) Rata (GW4) Balitha (GW5) MPN Coli mg/l 1 10 ND ND ND ND ND form Count E. coli mg/l Absent -- Absent Absent Absent Absent Absent *ND-Not Detected Detectable limit for COD- 4 mg/l BOD- 1 mg/l Free Residual Chlorine- 1 mg/l M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.18

151 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. TABLE: 3.9 WATER QUALITY PARAMETERS (SURFACE WATER SOURCES) Parameter Unit IS 10500: 1991 Sampling location Desirabl e Limit Permissibl e Limit SW1 Khacha rva SW2 Rata Colour Pt.co. sc Odour --- Unobject ionable SW3 Karvad SW4 Balitha Unobject ionable Unobje ctionabl e Unobjec tionable Unobject ionable ph Total mg/l hardness (as CaCO 3 ) Chloride mg/l (as Cl) TDS mg/l Calcium mg/l (as Ca) Magnesium mg/l (as Mg) Iron mg/l Fluoride mg/l Na mg/l K mg/l Sulphate mg/l (as SO 4 ) Nitrate mg/l Alkalinity mg/l (as CaCO 3 ) COD mg/l BOD mg/l MPN Coli form Count mg/l 1 10 <1.8 CFU/100 ML E. coli mg/l Absent -- Abse nt Absent Absent Absent M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.19

152 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. 3.5 NOISE ENVIRONMENT To estimation of background noise level, noise measurement was done within the study area using the sound level meter. The locations where noise level measurements were done are shown at Figure 3.6. FIGURE: 3.6 LOCATION OF NOISE MONITORING STATIONS TABLE: 3.10 CPCB RECOMMENDATIONS FOR COMMUNITY NOISE EXPOSURE (1989) Category of area Leq. (dba) (Day time) (06:00 to 21:00 hrs.) Industrial area Commercial Area Residential Area Silence Zone Leq. (dba) (Night time) (21:00 to 06:00 hrs.) M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.20

153 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. TABLE: 3.11 NOISE LEVEL DATA Sr. Location Area Category LEQ (db (A)) No. Day Time Night Time 1. Project Site (A1) Industrial Karvad(A2) Residential Kocharva(A3) Residential Chanod(A4) Residential Dungrifalia(a5) Residential Chharwada(A6) Residential Rata(A7) Residential Balitha(A8) Residential Vankachh(A9) Residential OBSERVATION & DISCUSSION The noise levels during daytime varied from db (A)Leq to db (A) Leq in the study area. The noise level in the study area is within the permissible Limits as per Noise rules The night time noise level in the study area is in the range of db (A) Leq to db (A) Leq. The night time noise was also within stipulated standards of CPCB. 3.6 SOIL BASELINE DATA Description of soil environment has become vital particularly when the treated effluent is to be discharge on land for disposal or treatment. The soil environment is usually described by determining the physical and chemical characteristics of soil samples collected from site with the help of auger/spade. The composite soil sample was collected from project site and the villages Within 10 km radius. The samples were collected to determine physical and chemical characteristic of soil. The selected soil sampling locations are given in Table no and shown in Figure no M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.21

154 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. TABLE: 3.12 LOCATIONS OF SOIL QUALITY MONITORING WITH RESPECT TO THE PROJECT SITE Sr. No. Location Direction from the site Distance in Km District 1. Project Site (S1) Valsad 2. Vapi (S2) WNW 4.4 Valsad 3. Chirri (S3) NE 3.9 Valsad 4. Karwad (S4) E 4 Valsad 5. Dungri falia (S5) E 4.53 Valsad 6. Chandor (S6) WS 1.32 Valsad FIGURE: 3.7 LOCATION OF SOIL MONITORING STATIONS M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.22

155 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. TABLE: 3.13 PARTICLE SIZE DISTRIBUTION OF SOIL SAMPLES Sr. No. Parameters Unit Sampling Locations Project site (S1) Vapi (S2) Chirri (S3) Karwad (S4) Dungra (S5) Chand or(s6) 1. ph (5%) EC Us Sodium ppm Potassium ppm Nitrogen mg/100g m LAND USE PATTERNS The land use pattern of the study area has been studied by satellite imaginary picture of National Remote Sensing Centre, Govt. of India. Details are covered in Table No TABLE: 3.14 LAND USE STATISTICS OF THE STUDY AREA Sr. Class Name Area Area(Sq. m) Area (%) No. (Hectares) 1. Water Body Open/Barren Land Agriculture Land Fallow Land Open/Degraded vegetation Vegetation Medium Density 7. Vegetation High density 8. Plantation/orchards Grass Land Scrubs Ravenous/Gullied Land River & Canal Marshy Land M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.23

156 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. Class Name Area Area(Sq. m) Area (%) No. (Hectares) 14. Salt affected Land Settlement & Habitation 16. Mud flat Sand/Beach Jetty Salt pans Mangrove (Sparse) Mangrove (Dense) Marshy Vegetation Mines Stony waste/rocky Area 25 Industrial Area Miscellaneous Sea Snow River Bed Seasonal Water Body Total M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.24

157 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. FIGURE: 3.8 LAND COVER MAP WITH VILLAGE LOCATION M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.25

158 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. 3.8 BIOLOGICAL ENVIRONMENT & SOCIO ECONOMIC ENVIRONMENT ECOLOGICAL INFORMATION The study of the environmental components like flora and fauna is required to assess the biological diversity of the region. Flora and fauna can be used for biological surveillance in assessing the environmental status. The ecological interpretation of study area is based on secondary sources of information. Water is the basic and essential resource for the survival of flora and fauna. The flora being the primary producer influences the fauna of the region. The characteristic flora existing in a region depends upon the existing conditions such as intensity of sunlight, type of soil, quality of air, including the quality and quantity of water available, etc FOREST There are patches of reserved forest and protected forests within 10 kms radial periphery of the study area. The map of reserved forest is shown in Figure No.3.8. The entire zone of Valsad district that comprises of maritime coastal environment and also the upland forest in the North-East has been classified as Tropical Moist Deciduous Forest. The reserved forest is having also maritime climate and the habitat serves as an ecological niche several plant species of terrestrial realm, and form important nature conservation sites FLORA The list of flora found during field survey is given in Table no TABLE: 3.15 LIST OF FLORA Sr. Scientific Name Common Name No. 1. Psilostachya seriea Lannea coromandelica Wodier 3. Mangifera indica Aam 4. Calotropis procera Ak 5. Nerium indicum Kaner 6. Rauvolfia tetrafylla Bara Chand 7. Tabernaemontana coronaria Tagar M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.26

159 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. Scientific Name Common Name No. 8. Vernonia anthelmintica Kaliziri 9. Millingtonia hortensis Akashneem 10. Bombax ceiba Silk cotton 11. Casuarina equisetifolia Saru 12. Garcinia xanthochymus Bottle brush 13. Anogeissus latifolia Axle wood 14. Terminalia arjuna Arjun 15. Terminalia bellerica Behda 16. Terminalia catappa Desshibadam 17. Terminalia tomentosa Terminalia paniculata Flowering murdah 19. Cyperus esculentus Yellow nustsedge 20. Diospyros chloroxylon Ninai 21. Diospyros melanoxylum Tendu 22. Ricinus communis Eranda 23. Acacia auriculiformis Australian acacia 24. Acacia catechu Khair 25. Acacia nilotica Babul 26. Alibizia lebbeck Shirish 27. Bauhinita tomentosa Kachnar 28. Cassia fistula Amaltash 29. Cassia siamea Karamala 30. Dalbergia latifolia Pahari sheesham 31. Dalbergia sissoo Sheesham 32. Delonix elata Gamhar 33. Desmodium heterocarpum Ougeinia dalbergioides Tiwas 35. Pithecellobium Saman Raintree 36. Pongamia pinnata Kanji 37. Prosopis juliflora Vilayati babul 38. Pterocarpus marsupium Indian Kino tree 39. Saraca indica Asoka 40. Tamarindus indica Imli 41. Vitex nequndo Shivarii 42. Parkinsonia aculeata Keerar 43. Lagerstroemia parviflora Dhuara 44. Hibiscus sabdariffa Lalambadi 45. Hibiscus schizopetalus Jaswand 46. Thespesia populnea Jaswand 47. Azadirachta indica Neem 48. Mimosa hamata Pithacellobium duice Jangli Jilebi 50. Artocarpus heterophyllus Jacktree 51. Ficus bengalensis Bargad 52. Ficus religiosa Peepal M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.27

160 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. Scientific Name Common Name No. 53. Moringa oleifera Shevga 54. Eucalyptus Nilgiri 55. Syzygium cumini Jamun 56. Boerhavia diffusa Lalsata 57. Bougainvillea glabra Bougainvillea 58. Oxalis corniculata Nalvari 59. Emblica officinalis Amla 60. Bambusa arundinaceae Bamboo 61. Dendro calamus strictus Bans 62. Zizyphus mauritiana Ber 63. Adina cordifolia Haldu 64. Mitragyna parvifolia Phaldu 65. Madhuca indica Mahua 66. Lindernia hyssopioides Ailanthus excels Ajan 68. Physalis longifolia Tamarix trupii Jhavnujhada 70. Typha angustata Patera 71. Gmelina arborea Shivan 72. Tectona grandis Sagwan 73. Borassus sp. Tad/Asian Palmyra palm 74. Phoenix sp. Khajoori/Date Palm M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.28

161 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. FIGURE: 3.9 MAP OF RESERVED FOREST Reference: - EIA report of Vertellus Specialty Materials (India) Pvt. Ltd., Vapi, Gujarat. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.29

162 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI FAUNA Some of the fauna found in study area is listed in Table no TABLE: 3.16 LIST OF FAUNA Sr. Common Name Scientific Name Family No. Reptiles 1. Common cobra Naja naja Elapidae 2. Common Krait Bungarus caeruleus Elapidae 3. Land monitor Varanus albigularis Varanidae 4. Python Python molrus bivittatus Pythonidae 5. Russell s viper Daboia russelii Viperidae 6. Saw scaled viper Echis carinatus Viperidae 7. Garden lizard Catotes versicolor Agamidae 8. Rat snake Zamenis longissimus Colubridae 9. Indian chameleon Chameleon zeylanicus Chamaeleonidae 10. House qecko Hemidactylus frenatus Gekkonidae Aves 11. Cattle egret Bubulcus ibis Ardeidae 12. Common crane Gruidae Gruiformes Common peafowl Pavo cristatus Phasianidae 14. Crow pheasant Centropus sinensis Cuculidae 15. House Sparrow Passer domesticus Passeridae 16. Gold backed Brachypternus aurantius Picidae woodpecker 17. Green pigeon Treron phoenicoptera Columbidae 18. Grey partridge Perdix perdix Phasianhdae 19. Hoopoo Upupa epops Upupidae 20. Inian myna Acridotheres tristis Sturnidae 21. Jungle bush quail Perdicula asiatica Phasianidae 22. Jungle crow Corvus macrohynchos Corvidae 23. Red vented bulbul Red wattled lapwing Pycnonotidae 24. Red wattled lapwing Vanellus Indicus Charadriidae 25. Small Green Bee- Merops orientalis Meropidae eater 26. Spotted dove Streptopelia chinensis Corvidae 27. Spotted owlet Athene brama Strigidae 28. Jungle owlet Glaucidium radiatum Strigidae 29. Large egret Ardea Alba Ardeidae 30. Little egret Egretta garzetta Ardeidae 31. Pond heron Ardeola grayii Ardeidae 32. Whitenecked stork Cicinia episcopus Ciconiidae 33. Black ibis Pseudibis papillosa Threskiornithidae 34. Common barbbler Turdoides caudata Timaliidae 35. Marsh harrier Circus aeruginosus Acciptridae M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.30

163 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. Common Name Scientific Name Family No. 36. Pied crested cuckoo Clamator jacobinus Cuculidae 37. Sugari/Tailor Bird Ortotomus sutorius Sylviidae 38. Vulture Diurnilis Neophron Accipitridae 39. Samadi Milvus migrans Accipitridae 40. Duck Anatidae Anseriformes Anatidae 41. Barking deer Muntiacus Cervidae 42. Langur Semnopithecus entellus Cercopithecidae 43. Jackal Canis aures Canidae 44. Panther Panthera Pardus Felidae 45. Porcupine Hystrix indicus Hystricidae 46. Sambar Rusa unicolor Cervidae 47. Wild Boar Sus scrofa Suidae 48. Wild dog Lycaon pictus Canidae 49. Fox Vulpes vulpes Canidae 50. Bonnet macaque Macaca radiata Cercopithecidae 51. Common Mongoose Herpestes edwardsii Herpestinae 52. Squirrel Rodentia Sciurus Sciuridae 53. Rat Rattus Muridae 54. Indian hare Lepus nigricollis Leporidae 55. Indian bush rat Golunda ellioti Muridae 56. Indian field mouse Mus booduga Muridae 3.9 SOCIO-ECONOMIC ENVIRONMENT As assessment of socio-economic environment forms an integral part of an EIA study, baseline information for the same was collected during the study period. The baseline socio-economic data collected for the study region, before the proposed expansion is operational, has been identified for the four major indicators viz. demography,civic amenities, economy and social culture. The baseline status of the above indicators is compiled in forthcoming sections. SETTLEMENTS AND DEMOGRAPHIC PATTERN 3.9.1DEMOGRAPHIC DATA WITHIN THE REGION OF INTEREST Demography covers the information related to population density sex ratio and literacy level of the public in the study area. Table no.3.17 provides the data on inhabitations of the Pardi Taluka. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.31

164 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. TABLE: 3.17 DEMOGRAPHIC DATA Sr.N o. Rural /Urban Area Name of area of Pardi Taluka No. of Households Total Population Total Male Total Female 1. Rural Pardi (M) Rural Umarsadi Rural Balda Rural Kumbhariya Rural Sondhalwada Rural Parvasa Rural Kachwal Rural Mota Waghchhipa 9. Rural Nana Waghchhipa 10. Rural Sukhesh Rural Borlai Rural Sukhlav Rural Velparva Rural Khadki Rural Motiwada Rural Palsana Rural Kalsar Rural Udwada Rural Kolak Rural Kikarla Rural Rentlav Rural Dungri Rural Dashwada Rural Amli Rural Sonwada Rural Varai Rural Nimkhal Rural Panchlai Rural Lakhmapor Rural Nevri Rural Rabdi Rural Asma Rural Tarmaliya Rural Khuntej Rural Sarodhi Rural Tarakpardi M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.32

165 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr.N o. Rural /Urban Area Name of area of Pardi Taluka No. of Households Total Population Total Male Total Female 37. Rural Saran Rural Vatar Rural Kunta Rural Morai Rural Bagwada Rural Tighara Rural Paria Rural Rohina Rural Samarpada Rural Dhagadmal Rural Daheli Rural Chival Rural Arnala Rural Pati Rural Goima Rural Barai Rural Dumalav Rural Tukwada Rural Ambach Rural Kherlav Rural Pandor Rural Rata Rural Chharwada Rural Chandor Rural Kocharva Rural Vankachh Rural Koparli Rural Kaval Rural Karaya Rural Nani Tambadi Rural Degam Rural Moti Tambadi Rural Karamkhal Rural Chibhad Kachchh 71. Urban Pardi (M) Urban Pardi (M) ward no M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.33

166 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr.N o. Rural /Urban Area Name of area of Pardi Taluka 73. Urban Pardi (M) WARD NO Urban Pardi (M) WARD NO Urban Pardi (M) WARD NO Urban Pardi (M) ward no Urban Pardi (M) WARD NO Urban Pardi (M) WARD NO No. of Households Total Population Total Male Total Female Urban Vapi (M) Urban Vapi (M) WARD NO Urban Vapi (M) WARD NO Urban Vapi (M) WARD NO Urban Vapi (M) WARD NO Urban Vapi (M) WARD NO Urban Vapi (M) WARD NO Urban Vapi (M) WARD NO Urban Vapi (M) WARD NO Urban Vapi (M) WARD NO M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.34

167 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr.N o. Rural /Urban Area Name of area of Pardi Taluka 89. Urban Vapi (M) WARD NO Urban Vapi (M) WARD NO Urban Vapi (M) WARD NO No. of Households Total Population Total Male Total Female Urban Vapi (M) ward no Urban Vapi (M) ward no Urban Vapi (INA) Urban Vapi (INA) WARD NO Urban Orvad (CT) Urban Orvad (CT) WARD NO Urban Balitha (CT) Urban Balitha (CT) WARD NO Urban Salvav (CT) Urban Salvav (CT) WARD NO Urban Chhiri (CT) Urban Chhiri (CT) WARD NO Urban Chanod (CT) Urban Chanod (CT) WARD NO Urban Karvad (CT) Urban Karvad (CT) WARD NO Urban Lavachha (CT) 109. Urban Lavachha M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.35

168 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr.N o. Rural /Urban Area Name of area of Pardi Taluka (CT) WARD NO No. of Households Total Population Total Male Total Female (Source: Census-2011 for Valsad District) LITERACY RATE The literacy rate is a major factor, which influences the socio-cultural condition of a particular place. Details of literacy rate in percentage in district Valsad and Taluka Pardi are given in Table no TABLE: 3.18 LITERACY RATE WITHIN 10 KM RADIAL DISTANCE OF STUDY AREA Sr. No. Village Name CD Block Name Total Population Population < 06 Years Populatio n Literate Literacy (%) 1. Umarsadi Pardi Balda Pardi Kumbhariya Pardi Sondhalwaa Pardi Parvasa Pardi Kachwal Pardi Mota Pardi Waghchhipa 8. Nana Pardi Waghchhipa 9. Sukhesh Pardi Borlai Pardi Sukhlav Pardi Velparva Pardi Khadki Pardi Motiwada Pardi Palsana Pardi Kalsar Pardi Udwada Pardi Kolak Pardi Kikarla Pardi Rentlav Pardi Dungri Pardi Dashwada Pardi Amli Pardi Sonwada Pardi M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.36

169 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. No. Village Name CD Block Name Total Population Population < 06 Years Populatio n Literate Literacy (%) 25. Varai Pardi Nimkhal Pardi Panchlai Pardi Lakhmapor Pardi Nevri Pardi Rabdi Pardi Asma Pardi Tarmaliya Pardi Khuntej Pardi Sarodhi Pardi Saran Pardi Tarakpardi Pardi Vatar Pardi Kunta Pardi Morai Pardi Bagwada Pardi Tighara Pardi Paria Pardi Rohina Pardi Samarpada Pardi Dhagadmal Pardi Daheli Pardi Chival Pardi Arnala Pardi Pati Pardi Goima Pardi Barai Pardi Dumalav Pardi Tukwada Pardi Ambach Pardi Kherlav Pardi Pandor Pardi Rata Pardi Chharwada Pardi Namdha Pardi Chandor Pardi Kocharva Pardi Vankachh Pardi Koparli Pardi Kaval Pardi Karaya Pardi M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.37

170 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. No. Village Name CD Block Name Total Population Population < 06 Years Populatio n Literate Literacy (%) 66. Nani Tambadi Pardi Degam Pardi Moti Tambadi Pardi Karamkhal Pardi Chibhad Pardi Kachchh 71. Pardi (M) Pardi Pardi (M) Pardi WARD NO Pardi (M) Pardi WARD NO Pardi (M) Pardi WARD NO Pardi (M) Pardi WARD NO Pardi (M) Pardi WARD NO Pardi (M) Pardi WARD NO Pardi (M) Pardi WARD NO Vapi (M) Pardi Vapi (M) Pardi WARD NO Vapi (M) Pardi WARD NO Vapi (M) Pardi WARD NO Vapi (M) Pardi WARD NO Vapi (M) WARD NO Pardi M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.38

171 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. No. Village Name CD Block Name 85. Vapi (M) WARD NO Vapi (M) WARD NO Vapi (M) WARD NO Vapi (M) WARD NO Vapi (M) WARD NO Total Population Population < 06 Years Populatio n Literate Literacy (%) Pardi Pardi Pardi Pardi Pardi Vapi (M) Pardi WARD NO Vapi (M) Pardi WARD NO Vapi (M) Pardi WARD NO Vapi (M) Pardi WARD NO Vapi (INA) Pardi Vapi (INA) Pardi WARD NO Orvad (CT) Pardi Orvad (CT) Pardi WARD NO Balitha (CT) Pardi Balitha (CT) Pardi WARD NO Salvav (CT) Pardi Salvav (CT) Pardi WARD NO Chhiri (CT) Pardi M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.39

172 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. No. Village Name CD Block Name 103. Chhiri (CT) WARD NO Total Population Population < 06 Years Populatio n Literate Literacy (%) Pardi Chanod (CT) Pardi Chanod (CT) WARD NO Pardi Karvad (CT) Pardi (Source: Census-2011 for Valsad District) OCCUPATIONAL STRUCTURE In economic development of the region its geographical location, natural resources, business and employment, industries and manpower play vital role. Table no.3.19 provides the occupational patterns in all villages of Pardi Taluka. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.40

173 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. TABLE: 3.19 OCCUPATIONAL STRUCTURE Sr. No. Name of Area Total Populati on Worker Population Total Main Marginal Worke Worke Worker r r Total Non worker populati on Employm ent Ratio% 1. Pardi Taluka Umarsadi Balda Kumbhariya Sondhalwada Parvasa Kachwal Mota Waghchhipa Nana Waghchhipa 10. Sukhesh Borlai Sukhlav Velparva Khadki Motiwada Palsana Kalsar Udwada Kolak Kikarla Rentlav Dungri Dashwada Amli Sonwada Varai Nimkhal Panchlai Lakhmapor Nevri Rabdi M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.41

174 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. No. Name of Area Total Populati on Total Worke r Worker Population Main Worke r Marginal Worker Total Non worker populati on Employm ent Ratio% \32. Asma Tarmaliya Khuntej Sarodhi Saran Tarakpardi Vatar Kunta Morai Bagwada Tighara Paria Rohina Samarpada Dhagadmal Daheli Chival Arnala Pati Goima Barai Dumalav Tukwada Ambach Kherlav Pandor Rata Chharwada Namdha Chandor Kocharva Vankachh Koparli Kaval Karaya Nani Tambadi Degam Moti Tambadi M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.42

175 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. No. Name of Area Total Populati on Total Worke r Worker Population Main Worke r Marginal Worker Total Non worker populati on Employm ent Ratio% 70. Karamkhal Chibhad Kachchh 72. Pardi (M) Pardi (M) WARD NO Pardi (M) WARD NO Pardi (M) WARD NO Pardi (M) WARD NO Pardi (M) WARD NO Pardi (M) WARD NO Pardi (M) WARD NO Vapi (M) Vapi (M) WARD NO Vapi (M) WARD NO Vapi (M) WARD NO Pardi (M) ward no Pardi (M) ward no Vapi (M) Vapi (M) WARD NO M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.43

176 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. No. Name of Area 88. Vapi (M) WARD NO Vapi (M) WARD NO Vapi (M) WARD NO Vapi (M) WARD NO Vapi (M) WARD NO Vapi (M) WARD NO Total Populati on Total Worke r Worker Population Main Worke r Marginal Worker Total Non worker populati on Employm ent Ratio% Vapi (M) WARD NO Vapi (M) WARD NO Vapi (M) WARD NO Vapi (M) WARD NO Vapi (M) WARD NO Vapi (M) WARD NO Vapi (INA) Vapi (INA) WARD NO Orvad (CT) Orvad (CT) WARD NO M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.44

177 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI Balitha (CT) Sr. No. Name of area Worker Population 106. Balitha (CT) WARD NO Total Populati on Total Worke r Main Worke r Marginal Worker Total Non worker populati on 114. Karvad (CT) WARD NO Lavachha (CT) Lavachha (CT) WARD NO Kaprada Umbergaon (Source: Census-2011 for Valsad District) Main worker: Who has worked last year for six month or more? Marginal worker: Who has worked last year for less than six months? Non-worker: Who did not work at all during the reference period of one year? Distribution of main worker and marginal worker into further following four categories are shown in Table no Cultivators Agricultural labors Household industry Others worker Employm ent Ratio% Salvav (CT) Salvav (CT) WARD NO Chhiri (CT) Chhiri (CT) WARD NO Chanod (CT) Chanod (CT) WARD NO Karvad (CT) M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.45

178 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. TABLE: 3.19 DISTRIBUTION OF WORKERS Sr. No. Area Name Main worker Cultiv ators Agricultural Labours Household Industry Others Marginal worker Cultivators Agricultural Labours Household Industry Others Pardi Taluka 1. Pardi Umarsadi Badla Kumbhariya Sondhalwada Parvasa Kachwal Mota Waghchhipa 9. Nana Waghchhipa 10. Sukhesh Borlai Sukhlav Velparva Khadki Motiwada Palsana Kalsar Udwada Kolak M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.46

179 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. Area Main worker Marginal worker No. Name Cultiv ators Agricultural Labours Household Industry Others Cultivators Agricultural Labours Household Industry Others 20. Kilkara Rentlav Dungri Dashwada Amli Sonwada Varai Nimkhal Panchlai Lakhmapor Nevri Rabdi Asma Tarmaliya Khuntej Sarodhi Saran Tarakpardi Vatar Kunta Morai Bagwada Tighara Paria Rohina M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.47

180 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. Area Main worker Marginal worker No. Name Cultiv ators Agricultural Labours Household Industry Others Cultivators Agricultural Labours Household Industry Others 45. Samarpada Dhagadmal Daheli Chival Arnala Pati Goima Barai Dumalav Tukwada Ambach Kherlav Pandor Rata Chharwada Namdha Chandor Kocharva Vankachh Kaval Karaya Nani Tambadi Degam Moti Tambadi Karamkhal M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.48

181 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. Area Main worker Marginal worker No. Name Cultiv ators Agricultural Labours Household Industry Others Cultivators Agricultural Labours Household Industry Others 71. Chibhad Kachchh Pardi (M) Pardi (M) WARD NO Pardi (M) WARD NO Pardi (M) WARD NO Pardi (M) WARD NO Pardi (M) WARD NO Pardi (M) WARD NO Pardi (M) WARD NO Vapi (M) Vapi (M) WARD NO Vapi (M) WARD NO Vapi (M) WARD NO Vapi (M) WARD NO Vapi (M) WARD NO M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.49

182 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. Sr. No. Area Name 86. Vapi (M) WARD NO Vapi (M) Ward no Main worker Marginal worker Cultiv ators Agricultural Labours Household Industry Others Cultivators Agricultural Labours Household Industry Others (Source: Census-2011 for Valsad District) M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.50

183 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI EARTHQUAKE VULNERABILITY Map of Earthquake vulnerability is shown in below figure FIGURE: 3.10 EARTHQUAKE VULNERABILITY MAP 3.11 WIND AND CYCLONE VULNERABILITY Map of Wind and cyclone vulnerability is shown in below figure FIGURE: 3.11 WIND AND CYCLONE VULNERABILITY MAP M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.51

184 M/s. AARTI INDUSTRIES LTD. (ALCHEMIE ORGANICS DIVISION), GIDC,VAPI. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD.,ANKLESHWAR. 3.52

185 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. Chapter - 4 IDENTIFICATION & ASSESSMENT OF IMPACT 4.1 IDENTIFICATION OF IMPACT The proposed expansion project will result in environmental consequences during d manufacturing activities alone. The unit has proposed to install additional machinery into existing building only. There will not be any additional construction activity. This chapter covers identification of impacts, quantification and evaluation of impacts during operation phase. The network method (Cause - effect) is adopted to identify potential impact of the proposed activity. It includes step wise study of relationship between an activity and its environmental parameters. This method involves in the Road Map type of approach to the identification of second and third order effect. The basic idea is to account for the project activity and identify the type of impact that could initially occur followed by the identification of secondary and tertiary impact. The type of identified potential impacts on various environmental components i.e. Air, Noise, Water and Land are presented in Figure no. 4.1 to Figure no It should be noted that in these illustration the lines are to be read as might have an effect on. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 4. 1

186 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. FIGURE: 4.1 IMPACT NETWORK ON AIR ENVIRONMENT Project Activity Operational Phase Release of Air Pollutants Release of Heat Primary Impact Secondary Impact Change in Air Quality Impact on Human, flora & fauna Impact on Visibility Aesthetic Impact Particulates Deposition on Water, Land Impact on Agricultural produce Climatic Changes Impact on Human, Flora and Fauna Tertiary Impact Impact on Economic Output Impact on Socio Cultural Environment M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 4. 2

187 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. FIGURE: 4.2 IMPACT NETWORK ON NOISE ENVIRONMENT Project Activity Operational Phase Noise Emission Primary Impact Change in Ambient Noise Level Secondary Impact Health Risks Impact on Work Output & Efficiency Impact on fauna & population Tertiary Impact Impact on Economic Output Impact on Socio-cultural Environment M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 4. 3

188 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. FIGURE: 4.3 IMPACT NETWORK ON WATER ENVIRONMENT Project Operation Phase Activity Abstraction of Water Release of wastewater Primary Impact Impact on Hydraulics of Water Courses Environmental health Cost of Water Treatment Secondary Impact Tertiary Impact Impact on Hydraulic Water Courses Impact on Economic Output Impact on Aquatic Life Impact on Amenity / Recreation Impact on Socio-Cultural Environment M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 4. 4

189 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. FIGURE: 4.4 IMPACT NETWORK ON GROUND WATER ENVIRONMENT Project Operation Phase Activity Abstraction of water Disturbance of soil Release of wastewater on land Primary Impact Change in Ground water Regime: Soil Moisture / water level/ Flow Pattern/ Salt water instruction Change in structure of Soil: Ground level Addition /Removal of substances or Heat to /form the soil Secondary Impact Impact on Soil Impact on agricultural production Impact on Flora and Fauna Impact on livestock Impact on landscape Tertiary Impact Impact on Economic Output Impact on Socio-Cultural Environment M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 4. 5

190 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. FIGURE: 4.5 IMPACT NETWORK ON SOCIO-ECONOMIC AND CULTURAL ENVIRONMENT Project Activity Operational Phase Primary Impact Economic input Capital/O&M Cost Net Income output Economic output Product Cost Secondary Impact Change in Economic Base of the region Development of Ancillary Industries Better product availability Air, Water, Land, Noise pollution Employment opportunity Aesthetic Risk Tertiary Impact Saving foreign Exchange Effect on Human Health Effect on Agriculture & fisheries Effect on visual Environment Effect on Buildings Materials Monuments M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 4. 6

191 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. FIGURE: 4.6 IMPACT NETWORK ON LAND ENVIRONMENT Project Activity Operational Phase Primary Impact Disturbance of land Abstraction of water Disposal of waste water & Sludge on Land Change in soil Texture & Permeability Change in ground Water Regime /Salt Water intrusion Toxic Substances on Land, Particulate Deposition on Land Secondary Impact Impact on Landscape Soil Salinity Impact on Agricultural Produce Impact on flora & fauna Impact on Live stock Tertiary Impact Impact on Economic Output Impact on Socio-Cultural Environment M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 4. 7

192 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. 4.2 PREDICTION AND ASSESSMENT OF IMPACT The predication and assessment of impact on the environmental parameters have been carried out. For assessing the impact, the baseline data of environmental status were considered. The change in the environmental parameters due to manufacturing activities of the industry has been superimposed on the status data WATER ENVIRONMENT OPERATIONAL PHASE IMPACTS The average daily water requirements after proposed expansion will be 404 KL/Day. The unit will use 195 KL/day of fresh water and 268 KL/day of recovered water. Fresh water will be met by GIDC water supply scheme. There will be no extraction of ground water, so that no direct impact is found on ground water availability. Existing effluent generation is KL/day. After proposed expansion, total effluent generation will be 99 KL/day from different sources i.e. process, washing, boiler, cooling, DM plant and domestic at full production capacity. Mitigative measures The unit has ETP having primary, secondary and tertiary treatment. The effluent is treated inept. Treated water will be further treated in R.O. followed by MEE. The condensate water from MEE and permeate water from RO is reused and the residue from MEE is send to TSDF site. The unit will be zero liquid discharge for industrial effluent. Sewage will be treated separately in STP and treated water will be used for gardening purpose and reused in cooling tower AIR ENVIRONMENT OPERATION PHASE IMPACTS There is already flue gas emission from two D.G. stacks. There will be increase in flue gas emission due to two D.G stacks. Diesel, Furnace oil and Energy- Electricity are used as fuel in two existing D.G.set. For proposed D.G. set also diesel, Furnace oil and Energy- Electricity will be used as fuel. There is process emission from one stack attached to Reactor of Bromo 4 Flouro Acetanilide/Di Chloro Bromo Benzene, one stack attached to Chlorinator, one stack attached to SFD dryer and one stack attached to Dizo vessels. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 4. 8

193 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. Mitigative measure The unit is using Diesel as fuel in stack and adequate stack height is provided. There is provision of Water scrubber followed by alkali scrubber to control emission of HBr and Br 2 from stack attached to Reactor of 2-Bromo 4 Flouro acetanilide/ Di Chloro Bromo Benzene. There is provision of water scrubbers followed by alkali scrubber to control emission of HCl and Cl 2 from stack attached to Chlorinator. There is provision of Water scrubber followed by alkali scrubber to control emission of PM from stack attached to the SFD dryer. There is provision of Water scrubber followed by alkali scrubber to control emission of NOx and HCl from stack attached to Dizo vessels. The air quality impacts of source are evaluated by use of model. The model stimulates the relationship between air pollutants emission, meteorology and air chemistry, all of which are determined by formulating impact scenario. MODELING DETAILS The dispersion of pollutants in the atmosphere is a function of several meteorological parameters like temperature, wind speed and direction, mixing depths, inversion level etc. The air quality impacts of source or collection of sources is evaluated by use of models. The model stimulates the relationship between air pollutants emission, meteorology and air chemistry, all of which are determined by formulating impact scenario. Estimation of emissions from the plant has been made by Industrial Source Complex Short Term (ISC-ST3) model developed by United States Environment Protection Agency (USEPA). ISC-ST is based on a modified steady state Gaussian Plume equation, and it has been recommended for use in EIA studies by Ministry of Environment & Forests (MoEF) in EIA manual. Maximum GPCB permissible limits were used for carrying out atmospheric dispersion modeling studies. Based on the modeling results, the concentration of PM summarized in the Table no. 4.2., concentration of NOx summarized in the Table no And concentration of HCl & HBr is summarized in the Table no. 4.4 & Table no.4.5. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 4. 9

194 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. DISPERSION MODEL TABLE: 4.1 DETAILS OF PROCESS EMISSION Sources Of Gaseous Emissions Reactor Of 2- Bromo 4 Flouro Acetanilide/Di Chloro Bromo Benzene Chlorinator SFD Dryer Dizo Vessels Fuel used Quantity of fuel Type of HBr, Br 2 HCl, Cl 2 PM NO X, HCl emissions Stack height 16 m 11 m 11 m 11 m Stack diameter at 150 mm 150 mm 800 mm 250 mm the top Stack gas exit 40 o C 50 o C 55 o C 50 o C temperature Stack gas exit 6.5 m/s 6.5 m/s 6.5 m/s 6.5 m/s velocity APCM Water scrubber followed by Alkali scrubber Water scrubber followed by Alkali scrubber Water scrubber followed by Alkali scrubber Water scrubber followed by Alkali scrubber Emissions: PM Concentration NOx Concentration HCl Concentration Cl 2 Concentration HBr Concentration Br 2 Concentration < 150 mg/nm < 25 mg/nm 3 -- <20 mg/nm 3 -- < 20 mg/nm 3 -- < 09 mg/nm <20 mg/nm < 09 mg/nm M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

195 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. TABLE: 4.2 CONCENTRATION OF PM Highest Values Incremental Increase In Concentration (µg/m 3 ) X Co-Ord ( mts) Y Co-Ord (mts) PM TABLE: 4.3 CONCENTRATION OF NOx Highest Values Incremental Increase In Concentration (µg/m 3 ) X Co-Ord (mts) Y Co-Ord (mts) NOx M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

196 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. TABLE: 4.4 CONCENTRATION OF HCl AND Cl 2 Highest Values Incremental Increase In Concentration (µg/m 3 ) X Co-ord (mts) Y Co-ord (mts) HCL Cl TABLE: 4.5 CONCENTRATION OF HBr AND Br Highest Values Incremental Increase In Concentration (µg/m 3 ) X Co-ord (mts) Y Co-ord (mts) HBr Br Based on the modeling results, isopleths for incremental increase in concentrations isopleths were drawn and were superimposed on an aerial view of the site using maps from Google Earth which are shown below: M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

197 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. FIGURE: 4.7 ISOPLETHS OF NOx (SITE COORDINATES 0, 0) M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

198 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. FIGURE: 4.8 ISOPLETHS OF PM (SITE COORDINATES 0, 0) M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

199 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. FIGURE: 4.9 ISOPLETHS OF HCL (SITE COORDINATES 0, 0) M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

200 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. FIGURE: 4.10 ISOPLETHS OF CL 2 (SITE COORDINATES 0, 0) M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

201 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. FIGURE: 4.11 ISOPLETHS OF HBr (SITE COORDINATES 0, 0) M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

202 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. FIGURE: 4.12 ISOPLETHS OF Br (SITE COORDINATES 0, 0) Observations from dispersion modeling studies From the dispersion modeling studies conducted, it was observed that the maximum ground level concentration occurs in the North & North east direction. The maximum incremental increase in concentration for PM and NOx is µg/m 3 and µg/m 3 respectively at a distance of about 1 km in the North direction. Whereas, the maximum incremental increase in concentration for HCl & Cl 2 is 0.806µg/m 3 & 0.235µg/m 3 respectively and for HBr & Br is 0.177µg/m 3 each at a distance of about 1 km in the North direction. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

203 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI NOISE ENVIRONMENT OPERATIONAL PHASE IMPACTS The sources of noise pollution will be D.G. sets and other noise generating units. Vehicular movements during operation phase for loading/unloading of raw materials and finished products and other transportation activity may also increase noise level. Mitigative measures Adequate noise control measures such as mufflers, silencers at the air inlet/outlet, anti vibration pad for equipment with high vibration etc. is already provided. Housing/casing shall be provided for all noise generating machines. Job rotation will reduce exposure to some extent. More ever, PPE like earmuff and ear plugs is provided to the operators/worker exposed to high noise. The green belt is further helpful in reducing the ambient noise level. The above control measures will be continuously followed after proposed expansion LAND ENVIRONMENT OPERATIONAL PHASE IMPACTS If the raw materials and hazardous wastes are not handled properly, it can pose danger of land contamination and can affect land system adversely. Transportation is one of the most important areas of concern associated with handling and spillage of raw materials and HW because of the packaging and method of transporting HW will prevent the likelihood that an accident or spill would occur. Mitigative measures The unit has closed hazardous waste storage area with impervious flooring. Transportation of hazardous waste to the TSDF site is governed as per the Hazardous Waste (Management, Handling and Transboundary Movement) Rules. Separate collection system is provided for collection of spillage material. Impervious layer, RCC roads and flooring is provided to area, where the chemical storage and handling activities will be involved. Separate storm water collection system is provided to prevent contamination of soil through contaminated water. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

204 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. Hence, there will be no significant adverse impact on land environment due to handling of hazardous solids waste. The unit is following Standard Operating Procedure (SOP) for storing and handling of hazardous wastes. SOP is attached as annexure-xvii ECOLOGICAL ENVIRONMENT The impact due to the proposed expansion on ecological parameters like natural vegetation, cropping pattern, fisheries and aquatic life, forest land species diversity are briefly summarized below: OPERATIONAL PHASE IMPACTS The green belt will be developed by the unit outside the premises having different species of flora, which will lead to beneficial impact on ecological environment. There is necessary environmental protection measures which have been planned under air pollution control system designed to take care of release of the gaseous pollutants like PM, Br, NOx, HCl & HBr. The waste water generated from the process and domestic activity will be properly treated and reused in cooling tower. There will be no impact on fisheries and aquatic life as it is zero discharge unit. Raw material and hazardous waste will be transported by road and will be stored in plant premises. Hence, no adverse impact on this account is anticipated INFRASTRUCTURE AND SERVICES OPERATION PHASE IMPACTS The plant is located in a GIDC, Vapi having all essential facilities such as water, power, post, and telecommunication. The GIDC Vapi has four lanes internal roads with separate parking areas at different locations. At present there are no traffic issues in the project area. Due to proposed expansion of MT/Month, there will be additional truck / tanker moments will be increase. This will not results in any traffic issues. Also, the unit has made parking arrangement of 50 Vehicles within the premises. The packing for staff and worker s vehicle is also available within the premises. This will have almost negligible impact on road network. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

205 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. The power requirement of proposed project of 800 KVA will be fulfilled from DGVCL. DGVCL is having large amount of electricity production thus due to extra consumption of electricity no adverse impact of electricity supply is predicted. The unit is using water from GIDC water supply scheme. Also, the treated water will be used for cooling tower to conserve fresh water. As a result of development of GIDC, Vapi, the neighboring areas will be developed for commercial use. The infrastructure services e.g. roads, post and telegraph, communication, medical facilities, education; housing will get improved in surrounding area SOCIO-ECONOMIC IMPACT OPERATION PHASE IMPACTS During operation phase some additional jobs for operation and maintenance of project and for operating and maintaining various facilities like water supply, power supply, roads, gardens, transportation etc will be available. The migration of employees in addition to the local ones will lead to a faster growth rate of economical and social status of the local area. Emission, if uncontrolled from process and utility stacks may cause discomfort to people in the down wind direction. This may be caused due to the failure of control equipment / process. Mitigative measure Provision of adequate APC and maintenance of APC will prevent any accidental emission from stacks and reduce risk to the health of the people in the vicinity of the project. As a result the project activities there will not be adverse impacts on sanitation, communication and community health as sufficient measures have been proposed in EMP. 4.3 IMPACT MATRIX The parameter discussed are presented in the form of a matrix in Table no. 4.6.There will be both construction and operation phases. The quantification of impact is done using numerical scores 0 to 5 as per the following criteria. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

206 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. Score Severity criteria 0 No Impact 1 No damage 2 Slight/short term effect 3 Occasional reversible effect 4 Irreversible /Long term effect 5 Permanent damage M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

207 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. TABLE : 4.6 ENVIRONMENT IMPACT MATRIX (WITH MITIGATION MEASURES) Activi ty Operation Phase Activities During Construction Phase Material Storage/handling/ Air Quality Water Quality Noise & Odour Land Quality Infra- Structure /Services Ecological Environment Transport Utilities Gaseous Emissions Fugitive Emissions Solid/hazardous Waste Disposal Spills & Leaks Plant Operations Equipment Failures/ Shutdown/ Startup Transport of workers/ Movement of vehicles Cumulative score Socio- Economic Status M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

208 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. TABLE: 4.7 CUMULATIVE IMPACT CHART Environmental Total Parameter Cumulative Air Quality 18 Water Quality 3 Noise and Odor 16 Land Quality 8 Infrastructure/ Service 13 Ecological environment 10 Socio Economic Status 13 Conclusion: Due to proposed expansion project, identified impacts are as under: The source of water is GIDC water supply scheme; there is no extraction of ground water. The unit is using recovered water for cooling tower. So, there will be no deterioration of surface and ground water quality. Even though after provision of APCM, there will be minor increase in ground level concentration of HCl & HBr in ambient air due to operational activities of proposed project. The unit will take adequate measure for storage, handling and disposal of hazardous waste. Hence, there will be no significant adverse impact on land environment. Engineering control, use of PPE, restriction of construction activity during 9 p.m. to 6 a.m., and green belt will reduce impact of noise pollution due to construction work, vehicular movement and noise generating equipment. There will be minor increase in ambient noise level and impact is insignificant. The unit is located in GIDC, Vapi. There will be not significant impact on crops & vegetation as the proposed APCM will take care of flue gas emission and process emission. There will be no discharge of effluent, so no impact on fisheries and aquatic life. Hence, no adverse impact on this account is anticipated. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

209 M/s. AARTI INDUSTRIES LTD.(ALCHEMIE ORGANICS DIVISION),GIDC,VAPI. This will be a beneficial impact on the local socio-economic environment as increase in demand for essential utilities and employment during both construction and operational phase. This will be no impact on the local infrastructure services. E.g. roads post and telegraph, communication, medical facilities, education, housing will be improved in surrounding area. There is a well laid down broad roads already existing in GIDC, Vapi. At the full capacity of production, there will be trucks per day for transportation of raw material and finished good products. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR

210 Chapter 5 ENVIRONMENTAL MONITORING PROGRAM 5.1 POLLUTION MONITORING AND SURVEILLANCE SYSTEM Regular monitoring of important parameters is of immense importance to assess the status of environment during plant operation. With the knowledge of baseline conditions, a properly planned monitoring program can serve as an indicator for assessment of any deterioration in environment conditions. This will facilitate undertaking suitable measures to mitigate adverse impact during the operation of the plant and further help to protect the environment in the area. The main attributes for which monitoring shall be carried out are: Ambient Air Quality Stack Emission Wastewater Quality Noise Level The characteristics of the ambient air, water, waste water and noise from the plant will be maintained so as to meet the requirements of the State Pollution Control Board. Details of emission monitoring plan is given in Table 5.1 TABLE: 5.1 EMISSION MONITORING PLAN Sr. Description Location Parameter To No. Be Monitored 1. Flue gas emission Two existing SO 2,NOx and PM monitoring plan 2. Process emission monitoring plan D.G. stacks, One proposed D.G. stacks, One existing stack attached to Reactor of Br 2 &HCl Frequency of Monitoring D.G set are available. Monitoring will be done by internal centralized facility. Whenever it will be in running condition. Quarterly by internal centralized monitoring facility. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 5. 1

211 Sr. No. Description Location Parameter To Be Monitored Bromo 3. Fugitive emission 4. monitoring plan Ambient air monitoring plan 5. Noise monitoring 6. Water quality monitoring 4Flouro Acetanilide/ Di Chloro Bromo Benzene One proposed stack attached to Chlorinator One proposed stack attached to SFD dryer One proposed stack attached to reactor Dizo vessels Process area & storage area ETP, Process area,storage area and one location in downwind direction Nine location within company premises Eight location for Ground water and Eight location for surface Water HCl &Cl 2 PM HCl & NOx Relevant solvent Acetone, Xylene, Toluene, MCB, MIBK PM 10,PM 2.5, SO 2, NO x, HCl, HBr, Br 2 - physic-chemical parameters and heavy metals Frequency of Monitoring Quarterly by internal centralized monitoring facility. Quarterly by internal centralized monitoring facility. Six monthly by selfanalytical facility During study period, the sampling was done for one time. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 5. 2

212 Sr. No. Description Location Parameter To Be Monitored 6.1 Effluent quality Primary TDS, ph, COD, TSS, ammonical after primary equalization nitrogen, treatment tank chlorides, sulphates, 6.2 Effluent quality after Secondary treatment 6.3 Effluent quality after R.O. treatment Secondary clarifier R.O. permeate TDS, ph, COD, TSS, ammonical nitrogen, chlorides, sulphates, For TDS, ph TDS, ph Frequency of Monitoring Daily by selfanalytical facility Daily by selfanalytical facility Daily by selfanalytical facility Daily by selfanalytical facility 7. Hazardous waste monitoring Sludge storage area ph, COD, Chloride Alkalinity, organic content Comprehensive analysis every 2 year. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 5. 3

213 Chapter 6: Risk Assessments and Disaster Management Plan Is Uploaded Separately.

214 Chapter 7 PROJECT BENEFITS The project has multiple benefits. The large number of product will be exported to various countries. These will results in foreign exchange earning. Also the proposed products are Dye/Dye intermediates & Pesticides. Thus new generation drugs will be available in India. The project will give direct employment to another around 168 people. Also there will be indirect/ supporting business development. Thus will results in increase social upliftman of the community. The company is committed for contribution of funds and provides the services for the upliftment of local community in the nearby villages. The different activities to be undertaken by the company are mentioned in this chapter. The unit is part of Aarti group. The group is known for several corporate social responsibility activities. It is already providing educational, medicinal and community welfare facilities. The group will discuss with local government administration and Vapi industries association for identifying various projects. The unit has planned to spend 5 % of the total cost of the project (Rs lacs) over a period of five years towards CSR activity. 7.1 SOCIO ECONOMIC ACTIVITIES Programs for environmental education and public participation shall be developed with the help of visual aids to create awareness about the activities. It has been planned to sponsor to the educational institutes. The proponents have also planned to provide training to the ladies for livelihood enhancement projects. Proper awareness campaign shall be organized by the project proponent for water conservation. Periodic health check up camps shall be organized by the project authority for workers families and surrounding localities. In order to increase the aesthetic environment, road side plantation program shall be carried out. M/s.JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 7. 1

215 Annual get together and rewards for school children from identified villages who have shown brilliance in education, sports, cultural activities etc. will be arranged. 7.2 OTHER TANGIBLE BENEFITS The unit does contribute towards improving their quality of life since the end users of products are industries ranging from agrochemicals and dyes to specialty chemicals and pharmaceuticals - markets that are critical to long-term sustainability. By supplying high quality and good value products to customers, the unit indirectly helps people to have access to better medicines, fertilizers and diverse items of daily use. 7.3 EMPLOYMENT POTENTIAL There will be increase in the employment facilities due to the upcoming project like There will be employment opportunity for local people during construction and operation phase. The Unit will use latest STATE OF ART technology. Thus man power will be exposed to new technology. There will be employment opportunity for local people during construction and operation phase. 7.4 ACTION PLAN TABLE: 7.1 ACTION PLAN Sr. No. Activity Fund Earmarked For Activity Time Schedule 1. Training to unskilled workers Rs. 20 Lacs 5 Years 2. Training to the ladies for livelihood Rs. 10 Lacs 5 Years enhancement projects. 3. Encouraging school children by way Rs. 15 Lacs 5 Years of rewards/scholarships& Sponsorship for Educational Institute s 4. Road side tree plantation and garden development Rs. 12 Lacs 5 Years M/s.JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 7. 2

216 5. Health awareness and support to needed people 6. Proper awareness campaign shall be organized by the project proponent for water conservation. 7.5 BUDGETARY ALLOCATION Rs. 13 Lacs Rs. 5 Lacs 5 Years 5 Years The budgetary allocation of 5 years for socio economic activity 1 st Year : 15 Lacs 2 nd Year : 15 Lacs 3 rd Year : 15 Lacs 4 th Year : 15 Lacs 5 th Year : 15 Lacs M/s.JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 7. 3

217 Chapter 8 ENVIRONMENTAL MANAGEMENT PLAN 8.1 INTRODUCTION Environmental protection is an issue that no organization can neglect and hope to survive. The key to the success of the integrated approach to pollution prevention and control is the management and operation of the organization. Effective committed management delivers a successful industry. A total commitment to the environment, not just for compliance with legal or regulatory compliance will be the essence of environment management of an industry. Many companies have recognized the benefits of implementing an effective environmental management system. 8.2 AIM AND OBJECTIVE The aim of environment management plan is to conserve natural resources and water, to prevent pollution of environment, to ensure effectiveness of control measures and monitoring programme, to ensure safety, welfare and good health of worker, to minimize generation of waste. The objectives of EMP are as under: Pollution will be prevented or reduced at the source, Pollution that can not be prevented will be recycled in to the system, Pollution that can not be prevented or recycled will be subjected for recovery of chemicals using best technologies, Pollution that can not be prevented or recycled or recovered will be treated in environmentally safe manner, and Disposal and other releases into the environment will be used only as a last resort and will be conducted in an environmentally safe manner. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 8. 1

218 8.3 ENVIRONMENTAL MANAGEMENT CELL M/s. Aarti Industries Ltd. (Alchemie Organics Division) has assigned responsibility to officers from various disciplines to co-ordinate the activities concerned with management and implementation of environmental control measures. Environment management cell is shown in below figure 8.1. FIGURE: 8.1 FLOW DIAGRAM OF ENVIRONMENTAL MANAGEMENT CELL Director (Technical) Vice President General Manager (EHS Corporate) Site head Manager (EHS) Shift supervisor (ETP) Officer (EHS) Shift operator (ETP) M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 8. 2

219 The unit has planned to revise environment policy based on following points to fulfill corporate environment responsibility. The copy of environment policy is attached as annexure XVIII. PROPOSED CORPORATE ENVIRONMENT POLICY: 1. We will abide by the conditions laid down in Environment Clearance. 2. We will follow regulatory frame work of environment rules and regulations. 3. The focus will be for sustainable development. This will be ensured by adopting cleaner production technology, recycling all waste water, conserving resources and utilization of Green operations. 4. The stack holders of the company- employees, suppliers, share holders, final product users, financial institutes and local residents will be regularly informed the environment performance of the company. Their suggestions and involvement in environment issues will be encouraged. 5. A manager level person will be employed to supervise day to day operations of pollution control equipments and related area. The manager will directly report to the Vice President. The daily performance report will be circulated amongst in charges of production, maintenance, quality control and HR department besides executive Director. Any deviations noticed will be immediately circulated with Red mark highlighted report. Prompt actions will be sought from all departments. 8.4 ENVIRONMENT MANAGEMENT PLAN Since there will not be any construction activity, the EMP for operational phase has been prepared OPERATIONAL PHASE M/s. Aarti Industries Ltd. (Alchemie Organic division) has proposed Environment Management Plan to keep the pollution potential to a minimum level in the operation phase (A) AIR ENVIRONMENT The sources of air pollution are in form of flue gas emission, process emission and fugitve emission. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 8. 3

220 FLUE AS EMISSION AND PROCESS EMISSION The sources of flue gas emission are two D.G. sets. (for emergency use only). The unit is getting steam from neighbouring industry namely M/s. Aarti industries Ltd., plot no 801/23, Phase-III, GIDC Estate, Vapi. The unit has proposed one additional D.G. sets for proposed expansion. The details are given in Table no.8.2 The source of existing process emission is one process stacks only. Old incinerator stack is dismantled. There will be three additional stacks of process emissions due to proposed expansion. Details of height, Air pollution control system, parameter etc. are given in Table no.8.2.a drawing of water scrubber followed by alkali scrubber is attached as annexure- XIX. The control measures of flue gas emission and process emission are as under. TABLE: 8.2 DETAILS OF CONTROL MEASURES FOR FLUE GAS EMISSION AND PROCESS EMISSION Sr. Source No. Existing Flue gas emission 1. Two stacks of two DG sets (Stand by) Proposed Flue gas emission 1. One stack of DG set (Stand by) Existing process emission 1. Stack attached to reactor of 2-Broromo 4 Flouro Acetanilide/Di Chloro Bromo Benzene Proposed process emission 1. Stack attached to chlorinator reactor 2. Stack attached to Dizo vessels 3. Stack attached to SFD dryer Waste Type/Pollution Air pollutant (PM, SOx, NOx) Air pollutant (PM, SOx, NOx) Br 2,HBr Cl 2,HCl NOx, HCl PM Control Measures Adequate stack height Adequate stack height Water scrubber followed by Alkali Scrubber Water scrubber followed by Alkali Scrubber Water scrubber followed by Alkali Scrubber Water scrubber M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 8. 4

221 Regular ambient air quality monitoring will be carried out within premises and near by area for PM 10, PM 2.5, SO X, NO 2, Cl 2, HCl, HBr, Br 2 and VOC in the downwind directions as well as where maximum ground level concentration are anticipated and record of the same shall be maintained. Work area ambient air quality monitoring will be carried out as per Gujarat Factories Rules. FUGITIVE EMISSION Now a day as industrial growth increases, concerns of fugitive emission also increases. Percentage of contribution of fugitive emission to air pollution and climate change will also increase. Probable source of fugitive emission are raw material handling, storage tank of acid, storage tank of solvent, leakage from valves, flange joints of pipeline, pump & motors, reactor, loading & unloading area etc. General control measures like routine & regular inspection to identify leakage, preventive maintenance and operational maintenance, provision of leak detection and repair system (LDAR) and potable instrument for measurement of VOC etc. are already implemented by the unit. The same with additional equipments will be continued. TABLE: 8.3 DETAILS OF CONTROL MEASURES FOR FUGITIVE EMISSION Sr. No. Source Waste Type/Pollution Control Measures 1. Storage tank of acid 2. Solvent storage tank 3. Solvent recovery system Air pollutant (Acid fumes) Air pollutant (VOC) Air pollutant (VOC) Close handling system Carry out work place monitoring to find out concentration level in ambient air Under ground MS storage tank for solvent having low boiling point Carry out work place area monitoring to find out concentration level in ambient air Close handling system Provision of breather valve cum flame arrester. There will be installations of new reactors with heat exchangers. At the M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 8. 5

222 Sr. No. Source 4. Handling of raw material bags in storage area 5. Flange joints of pipeline, pump & motors 6. Solid raw material transferring to reactor 7. Liquid raw material transferring to reactor 8. Loading /unloading at storage area Waste Type/Pollution Air pollutant (PM) Air pollutant (VOC) Air pollutant (PM) Air pollutant (VOC, acid fumes) Air pollutant (VOC) Control Measures reactors itself the solvent will be recovered. At the end of heat exchangers, the water scrubbers are provided to arrest pollutants. The same scrubbers will also stop VOC going into atmosphere. There will be recovery of more than 95% solvent. Provision of exhaust ventilation Provision of PPE Provision of Job rotation to reduce exposure Routine & periodic inspection to check leakage Preventive maintenance, follow SOP for maintenance Pumps & motors are mechanical seal type LDAR program is followed. Hopper are provided with powder transfer system Feeding of liquid raw material is carried out by closed pipeline and mechanical seal pump. Unloading through pipeline to tank in a close system (B) WATER ENVIRONMENT The unit will use 887 KL/Day water after proposed expansion. The unit will use 599 KL/Day of fresh water from GIDC water supply system and 288 KL/Day will be recycled water. Extra water required for the proposed expansion of project will be fulfilled by GIDC water supply system. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 8. 6

223 Total waste water generation will be 302 KL/Day. This waste water includes waste water coming out from process (137 KL/Day), washing (30 KL/Day), DM plant regeneration (5 KL/Day), cooling tower blow down (70 KL/Day), and sewage (60 KL/Day). Concentrated & Toxic effluent stream of 11.7 KL/Day will be sent to common incinerator facility. 137 KL/Day of effluent from process and 30 KL/Day effluent from washing will be sent to unit s own Effluent Treatment Plant comprising of primary, secondary & tertiary treatment facilities. Treated effluent from ETP will be sent to R.O. system-1. Cooling tower blow down of 70 KL/Day and 5 KL/Day DM plant will be subjected to R.O. system-2. This unit has proposed for zero liquid discharge for industrial effluent. To achieve zero liquid discharge, R.O. reject of 50 KL/Day from R.O. system-1 and R.O. reject of 22 KL/Day from R.O. system-2 will be subjected to MEE. R.O.permeate of 117 KL/Day from R.O. system-1, R.O.permeate of 53 KL/Day from R.O. system-2 and MEE condensate of 68 KL/Day will be reused. Residue from MEE of 4 KL/Day will be sent to landfill site. Sewage of 60 KL/Day will be treated in Sewage treatment plan and treated water will be used for gardening purpose and in cooling tower. The description of effluent treatment process is given as under DETAILS OF EFFLUENT TREATMENT PLANT Existing Effluent Treatment Scheme The company is generating two types of effluents i.e. highly concentrated effluent stream and dilute effluent stream. The concentrated effluent stream alkaline in nature is separately collected in collection tank and directly incinerated in incineration system of 500 liters per hour capacity. The dilute effluent from the process plant is collected in a collection sump from which it is taken to oil & grease trap for separation, oil and grease is skimmed off from the top. Effluent is then pumped to neutralization tank where ph is neutralized between 7 to 8 and compressed air is used for agitation. Then it is transferred to decanter for sludge dewatering then it is taken to equalization tank after that effluent is pumped to primary settling tank where suspended solids are settled and the sludge M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 8. 7

224 is taken into sludge drying bed. Leachate is collected and sent back to equalization cum neutralization tank. Dried sludge is stored in a sludge storage tank. Clear water from settling tank is taken into aeration tank no. 1. In this tank, extended type aeration system is adopted. Biological treatment is given to the effluent. Overflow is taken into primary lamella separator for excess sludge settling, Biomass is re circulated in aeration tank if required or sent to SDB. Then further it is taken into second stage bioreactor and second stage settling tank. Overflow from secondary settling tank is passed through two stage activated carbon filter and then drain into underground effluent drainage line to CETP, Vapi. Proposed Effluent Treatment Scheme The unit is having effluent treatment plant consisting of primary, secondary, and tertiary treatment. The effluent is treated in ETP. Treated water will be further treated in RO followed by MEE. The condensate water from MEE and permeate water from RO is reused and the residue from MEE is send to TSDF site. The unit will be zero liquid discharge for industrial effluent. Sewage will be treated separately in STP and treated water will be used for gardening purpose and reused in cooling tower. M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 8. 8

225 EXISTING EFFLUENT TREATMENT PLANT FLOW DIAGRAM M/s. JYOTI OM CHEMICAL RESEARCH CENTRE PVT. LTD., ANKLESHWAR. 8. 9