Material Safety Data Sheet

Transcription

1 Page: 1 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER FOSTER SEALFAS Product Name Company Name Address Emergency Tel. Telephone/Fax Number Recommended Use Other Information 2. HAZARDS IDENTIFICATION Hazard Classification H.B. FULLER COMPANY (ABN ) Red Gum Drive Dandenong South Victoria 3175 Australia AUS: (or IDD ), NZ: (Or IDD ) Tel: Customer Service Toll Free Numbers: Australia ; Breather coat for use over polyurethane and fibreglass insulation. Applied by spray or trowel. This MSDS summarises at the date issue our best knowledge the health and safety hazard information the product, and in particular, how to safely handle and use the product in the workplace. Since H.B. Fuller Company Australia Pty Ltd cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, review this MSDS in the context how the user intends to handle and use the product in the workplace. If clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact this company. Our responsibility for the products sold is subject to our standard terms and conditions, a copy which is sent to our customers and is also available on request. Classified as Hazardous according to criteria National Occupational Health & Safety Commission, Australia (NOHSC). Not classified as Dangerous Goods according to the Australian Code for the Transport Dangerous Goods by Road and Rail. (7th edition) Classified as Hazardous according to the Hazardous Substances (Minimum Degrees Hazard) Regulations 2001, New Zealand. Classified as Dangerous Goods for transport according to the New Zealand Standard NZS 5433:2012 Transport Dangerous Goods on Land. HSNO Classification: 6.7B - Substance that is a suspected human carcinogen 6.C - Substance that produces toxic human reproductive or developmental effects on or via lactation 9.1B - Substance that is ecotoxic in the aquatic environment Hazard statement codes: H351 Suspected causing cancer. H362 May cause harm to breast-fed children. H411 Toxic to aquatic life with long lasting effects. Precautionary statement codes - Prevention: P103 Read label before use. P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P263 Avoid contact during pregnancy/while nursing. P264 Wash contaminated skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment. P21 Use personal protective equipment as required. Precautionary statement codes - Response: Print Date: 3/02/2014

2 Page: 2 Risk Phrase(s) Safety Phrase(s) P30+P313 IF exposed or concerned: Get medical advice/ attention. P391 Collect spillage. Precautionary statement codes - Storage: P405 Store locked up. Precautionary statement codes - Disposal: P501 In the case a substance that is in compliance with a HSNO approval other than a Part 6A (Group Standards) approval, a label must provide a description one or more appropriate and achievable methods for the disposal a substance in accordance with the Hazardous Substances (Disposal) Regulations This may also include any method disposal that must be avoided. See Section 13 for disposal details R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R64 May cause harm to breastfed babies. S53 Avoid exposure - obtain special instructions before use. S61 Avoid release to the environment. Refer to special instructions/safety data sheet. 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients 4. FIRST AID MEASURES Inhalation Ingestion Skin Eye First Aid Facilities Advice to Doctor Other Information Name CAS Proportion Hazard Symbol Risk Phrase Alkanes, C14-17, chloro <25 % Crystalline Silica <10 % Ethanol <10 % T, Xi, F Antimony Oxide <1 % Ingredients determined not to be hazardous, including water. Balance R10, R11, R20, R21, R22, R36, R37, R3, R41, R45(2), R4, R52, R53 If inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms persist seek medical attention. Do not induce vomiting. Wash out mouth thoroughly with water. Seek medical attention. Wash affected area thoroughly with soap and water. If symptoms develop seek medical attention. If in eyes, hold eyelids apart and flush the eyes continuously with running water. Remove contact lenses. Continue flushing for several minutes until all contaminants are washed out completely. If symptoms develop and persist seek medical attention. Eyewash and normal washroom facilities. Treat symptomatically. 5. FIRE FIGHTING MEASURES Suitable Extinguishing Media Hazards from Combustion Products For advice in an emergency, contact a Poisons Information Centre (Phone Australia ; New Zealand 000 POISON / ) or a doctor at once. Use appropriate fire extinguisher for surrounding environment. Under fire conditions this product may emit toxic and/or irritating fumes and gases including carbon monoxide and carbon dioxide. Print Date: 3/02/2014

3 Page: 3 Specific Hazards Precautions in connection with Fire This product is non-combustible. However, following evaporation aqueous component under fire conditions, the non-aqueous component may decompose and/or burn. Fire fighters should wear Self-Contained Breathing Apparatus (SCBA) operated in positive pressure mode and full protective clothing to prevent exposure to vapours or fumes. Water spray may be used to cool down heat-exposed containers. Fight fire from safe location. This product should be prevented from entering drains and watercourses. 6. ACCIDENTAL RELEASE MEASURES Emergency Procedures 7. HANDLING AND STORAGE Precautions for Safe Handling Conditions for Safe Storage Wear appropriate personal protective equipment and clothing to minimise exposure. Increase ventilation. If possible contain the spill. Place inert absorbent material onto spillage. Collect the material and place into a suitable labelled container. Do not dilute material but contain. Dispose waste according to the applicable local and national regulations. If contamination sewers or waterways occurs inform the local water and waste management authorities in accordance with local regulations. Use only in a well ventilated area. Keep containers sealed when not in use. Prevent the build up mists or vapours in the work atmosphere. Avoid inhalation vapours and mists, and skin or eye contact. Maintain high standards personal hygiene i.e. Washing hands prior to eating, drinking, smoking or using toilet facilities. Avoid exposure. Do not handle until all safety precautions have been read and understood. It is recommended that pregnant or breastfeeding women should not handle this product unless adequate exposure protection can be assured at all times. Female personnel planning pregnancy should be made aware the potential risks. Store in a cool, dry, well-ventilated area, out direct sunlight. Store in suitable, labelled containers. Keep containers closed when not in use. Ensure that storage conditions comply with applicable local and national regulations.. EXPOSURE CONTROLS/PERSONAL PROTECTION National Exposure Standards No exposure value assigned for this material by Safe Work, Australia or the Occupational Safety and Health Service (OSH) the New Zealand Department Labour. However, the available exposure limits for ingredients are listed below: Safe Work, Australia Exposure Standards: Substance TWA STEL NOTICES ppm mg/m³ ppm mg/m³ Crystalline Silica Antimony trioxide Ethanol New Zealand Occupational Safety and Health Service (OSH) Workplace Exposure Standards: Substance TWA STEL NOTICES ppm mg/m³ ppm mg/m³ Crystalline Silica(quartz) Respirable dust Antimony trioxide Ethanol TWA (Time Weighted Average): The average airborne concentration a particular substance when calculated over a normal eight-hour working day, for a five-day week. STEL (Short Term Exposure Limit): The average airborne concentration over a 15 minute period which should not be exceeded at any time during a normal eight-hour workday. Print Date: 3/02/2014

4 Page: 4 Biological Limit Values Engineering Controls Respiratory Protection Eye Protection Hand Protection Body Protection No biological limits allocated. Provide sufficient ventilation to keep airborne levels below the exposure limits. Where vapours or mists are generated, particularly in enclosed areas, and natural ventilation is inadequate, a local exhaust ventilation system is required. If engineering controls are not effective in controlling airborne exposure then an approved respirator with a replaceable mist filter should be used. Reference should be made to Australian/New Zealand Standards AS/NZS 1715, Selection, Use and Maintenance Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices, in order to make any necessary changes for individual circumstances. Safety glasses with side shields or chemical goggles should be worn. Final choice appropriate eye/face protection will vary according to individual circumstances. Eye protection devices should conform with Australian/New Zealand Standard AS/NZS Eye Protectors for Industrial Applications. Wear gloves impervious material. Final choice appropriate gloves will vary according to individual circumstances i.e. methods handling or according to risk assessments undertaken. Reference should be made to AS/NZS : Occupational protective gloves - Selection, use and maintenance. Suitable protective work wear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron is recommended where large quantities are handled. 9. PHYSICAL AND CHEMICAL PROPERTIES White viscous liquid Appearance Odour Melting Point Boiling Point Solubility in Water Specific Gravity ph Value Vapour Pressure Vapour Density (Air=1) Evaporation Rate Viscosity Volatile Component Octanol/Water Partition Coefficient Flash Point Flammability Auto-Ignition Temperature Flammable Limits - Lower Flammable Limits - Upper Explosion Properties Oxidising Properties Characteristic Fully miscible 1.29 (approximate) VOC content: 2 g/l (Californian south coast air quality management rule 116) Not applicable Non-combustible Not applicable Not applicable Not applicable Print Date: 3/02/2014

5 Page: STABILITY AND REACTIVITY Stable under normal conditions storage and handling. Chemical Stability Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Hazardous Polymerization Extremes temperature and direct sunlight. Thermal decomposition may result in the release toxic and/or irritating fumes including carbon monoxide and carbon dioxide. Will not occur. 11. TOXICOLOGICAL INFORMATION Toxicology Information Inhalation Ingestion Skin Eye Chronic Effects Reproductive Toxicity Carcinogenicity No toxicity data available for this product. Inhalation product vapours may cause irritation the nose, throat and respiratory system. Ingestion this product may irritate the gastric tract causing nausea and vomiting. May be irritating to skin. The symptoms may include redness, itching and swelling. May be irritating to eyes. The symptoms may include redness, itching and tearing. Repeated exposure may cause skin dryness and cracking. May cause harm to breast-fed children. Classified as a substance that produces toxic human reproductive or developmental effects on or via lactation. This product contains crystalline silica. No exposure to free respirable crystalline silica is anticipated during normal use this product as silica is bound in the liquid/paste. It should be noted, however, that respirable crystalline silica has been listed as a Group 1 human carcinogen by the IARC. Inhalation respirable silica may cause cancer, silicosis or other serious delayed lung injury. Grinding or machining coated materials may release silica. Use approved dust respirator when grinding, sanding or machining the dried items. Antimony trioxide is listed as a Group 2B: Possibly carcinogenic to humans according to International Agency for Research on Cancer (IARC). Chlorinated hydrocarbon has been identified as an animal carcinogen in feeding studies with laboratory animals. Overexposure may create cancer risk. 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence / Degradability Mobility Bioaccumulative Potential Environ. Protection Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 13. DISPOSAL CONSIDERATIONS Disposal Considerations Do not discharge this material into waterways, drains and sewers. Dispose waste according to applicable local and national regulations. Do not allow into drains or watercourses or dispose where ground or surface waters may be affected. Wastes including emptied containers are controlled wastes and should be disposed in accordance with all applicable local and national regulations. Print Date: 3/02/2014

6 Page: TRANSPORT INFORMATION Transport Information Product Disposal: Product wastes are controlled wastes and should be disposed in accordance with all applicable local and national regulations. This product can be disposed through a licensed commercial waste collection service. This is a water-based/water-soluble product and therefore can be sent through a Waste Water Treatment Plant and after treatment can be discharged into environment through the sewerage or drainage systems as authorized. Personal protective clothing and equipment as specified in Section this SDS must be worn during handling and disposal this product. The ventilation requirements as specified in the same section must also be followed, and the precautions given in Section 7 this SDS regarding handling must also be followed. Do not dispose into the sewerage system. Do not discharge into drains or watercourses or dispose where ground or surface waters may be affected. In New Zealand, the disposal agency or contractor must comply with the New Zealand Hazardous Substances (Disposal) Regulations Further details regarding disposal can be obtained on the EPA New Zealand website under specific group standards. Container Disposal: The container or packaging must be cleaned and rendered incapable holding any substance. It can then be disposed in a manner consistent with that the substance it contained. In this instance the packaging can be disposed through a commercial waste collection service. Alternatively, the container or packaging can be recycled if the hazardous residues have been thoroughly cleaned or rendered non-hazardous. In New Zealand, the packaging (that may or may not hold any residual substance) that is lawfully disposed by householders or other consumers through a public or commercial waste collection service is a means compliance with regulations. This material is exempted from Class 9 - Miscellaneous Substances Dangerous Goods classification according to The Australian Code for the Transport Dangerous Goods by Road and Rail (7th edition) since Special Provision AU01 applies for this product Special Provision AU01 Environmentally Hazardous Substances meeting the descriptions UN 3077 or UN 302 are not subject to this Code when transported by road or rail in; (a) packagings that do not incorporate a receptacle exceeding 500 kg(l); or (b) IBCs. This material is classified as a Class 9 - Miscellaneous Substances according to NZS 5433:2012 Transport Dangerous Goods on Land. UN No.: 302 Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Contains Alkanes, C14-17, chloro) DG Class: 9 Packaging Group: III Hazchem: 3Z Must not be loaded in the same freight container or on the same vehicle with: - Class 1, Explosives Class 9 dangerous goods that contain organic matter must not be loaded in the same bulk container or tankwagon with dangerous goods Division 5.1 unless the Class 9 and Division 5.1 dangerous goods are in separate compartments a bulk container or tankwagon. Print Date: 3/02/2014

7 Page: 7 IMDG Marine Pollutant (MP) Goods packing group II or III may be loaded in the same freight container or on the same vehicle if transported in segregation devices. Segregation devices may be used to segregate Dangerous goods Class 9 when the nature those dangerous goods requires them to be segregated from dangerous goods Class 3, 4, 5, 6 or or from food items. Marine Transport (IMO/IMDG): Classified as Dangerous Goods by the criteria the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea. UN No.: 302 Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Contains Alkanes, C14-17, chloro) DG Class: 9 Packaging Group: III EMS No.: F-A, S-F Special provision(s): Air Transport (ICAO/IATA): Classified as Dangerous Goods by the criteria the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air. UN No: 302 Proper Shipping Name: : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Contains Alkanes, C14-17, chloro) Class: 9 Packing Group: III Label: Miscellaneous Packing Instruction: 964 (For passenger and cargo aircraft) Packing Instruction: 964 (For cargo aircraft only) Special provision(s): A97 A15 Yes 15. REGULATORY INFORMATION Regulatory Information Poisons Schedule National and or International Regulatory Information HSNO Approval Number Hazard Category AICS (Australia) 16. OTHER INFORMATION Date preparation or last revision MSDS Contact Person/Point Classified as Hazardous according to criteria National Occupational Health & Safety Commission (NOHSC), Australia. Not classified as a Scheduled Poison according to the Standard for the Uniform Scheduling Medicines and Poisons (SUSMP). Not Scheduled Classified as Hazardous according to the New Zealand Hazardous Substances (Minimum Degrees Hazard) Regulations Group Standard: Surface Coatings and Colourants (Toxic [6.7]) Group Standard 2006 HSR Harmful,Dangerous for the environment All components this product are listed on the Australian Inventory Chemical Substances (AICS) or exempted. SDS Reviewed: January 2014, Supersedes: July 2009 For advice in an emergency contact: (or IDD ) (or IDD ) Print Date: 3/02/2014

8 Page: Literature References Standard for the Uniform Scheduling Medicines and Poisons. Approved criteria for classifying hazardous substances [NOHSC:100(2004)]. National Code Practice for the Preparation s [NOHSC:2011(2003)]. Australian Code for the Transport Dangerous Goods by Road & Rail. Model Work Health and Safety Regulations, Schedule 10: Prohibited carcinogens, restricted carcinogens and restricted hazardous chemicals. Workplace exposure standards for airborne contaminants, Safe work Australia. American Conference Industrial Hygienists (ACGIH). Workplace Exposure Standards and Biological Exposure Indices, Department Labour, Health & Safety. Transport Dangerous goods on land NZS Preparation Safety Data Sheets - Approved Code Practice Under the HSNO Act 1996 (HSNO CoP ). Assigning a hazardous substance to a group standard. American Conference Industrial Hygienists (ACGIH)....End Of MSDS... Copyright ACOHS Pty Ltd Copyright in the source code the HTML, PDF, XML, XFO and any other electronic files rendered by an Infosafe system for Infosafe MSDS displayed is the intellectual property Acohs Pty Ltd. Copyright in the layout, presentation and appearance each Infosafe MSDS displayed is the intellectual property Acohs Pty Ltd. The compilation MSDS's displayed is the intellectual property Acohs Pty Ltd. Copying any MSDS displayed is permitted for personal use only and otherwise is not permitted. In particular the MSDS's displayed cannot be copied for the purpose sale or licence or for inclusion as part a collection MSDS without the express written consent Acohs Pty Ltd. Print Date: 3/02/2014