NITTY-GRITTY S.R.L. Fit - INOX FIT

Transcription

1 Page n / 05 Safety Data Sheet Substances INHALATION: Specific Possibility end in Candidate of remove use(s). hazardous to List open (Art. reactions. air. 59 If REACH). respiration is difficult, administer artificial respiration and seek medical advice. INGESTION: Information The vapours not may seek available. also medical form attention. explosive Induce mixtures vomiting with the only air. if indicated by the doctor. Never give anything by mouth to an unconscious person. EYES and SKIN: wash with plenty of water; if the irritation persists, seek medical advice. 1. Identification of the substance/mixture and of the company/undertaking 8. Exposure controls/personal protection Substances Most Conditions important subject to avoid. symptoms authorisarion and (Annex effects, XIV both REACH) Product identifier acute and delayed Avoid Control episodes overheating, parameters. of damage electrostatic to health discharge ascribable and to all the sources product of have ignition. been reported. Code: Fit 4.3. Name Product Indication nameof any immediate medical attention and INOX special Type FIT treatment CountryTWA/8h needed. STEL/15min Healthcare Information Incompatible controls. not available. materials. mg/m3 ppm mg/m3 ppm 1.2. Relevant identified uses of the substance or mixture and uses advised against 5. ETHANOL Firefighting measures. TLV-ACGIH Chemical Hazardous safety decomposition assessment. Intended use products. Degreasing, OEL neutralizer IRL for stainless steel In Extinguishing the event of thermal media. decomposition or fire, vapours potentially WEL dangerous UKto health may be released No SUITABLE chemical EXTINGUISHING safety assessment MEDIA has been processed for the mixture and the substances it contains Details of the supplier of the safety data sheet 11. The Toxicological extinction equipment information. should be of the conventional kind: carbon dioxide, foam, powder and nebulised water EXTINGUISHING Other Exposure information. controls. MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONS According Name None particular. to currently available data, this product NITTY-GRITTY has not yet S.R.L. produced health damages. Anyway, it must be handled carefully according to Full Observance good address industrial of safety practices. measures This used product in handling may have chemical VIA slight DEI substances. health MARMORARI effects 36 on sensitive people, by inhalation and/or cutaneous absorption and/or 5.2. GERAL District RESPIRATORY contact Special and with hazards BIBLIOGRAPHY Country eyes PROTECTION and/or arising ingestion. from the substance or mixture SPILAMBERTO (MO) 1. If HAZARDS Directive the threshold CAUSED 1999/45/EC value BY (if and EXPOSURE available) following amendments IN for THE one EVT or more OF of FIRE the ITALIA substances present in the preparation for daily exposure in the workplace or to a Do fraction Directive Information not breathe established 67/548/EEC combustion on toxicological by and the products following company s effects. (carbon amendments prevention oxide, toxic Tel. and and adjustments pyrolysis protection products, service etc). is exceeded, wear a mask with an B or universal filter, the class (1, 2 3. Information Regulation 3) of which not (EC) must available. 1907/2006 be chosen (REACH) according of to the European limit Fax concentration Parliament of use (ref. standard 141) EYE Advice Regulation PROTECTION address for firefighters. (EC) of the 1272/2008 competent (CLP) person of the European Parliament responsible GERAL None Regulation Ecological required. INFORMATION for (EC) information. the 790/2009 Safety Data (I Atp. Sheet CLP) of the European info@nitty-gritty.it Parliament 6. Use HAND Regulation jets PROTECTION of water (EC) 453/2010 to cool the of the containers European to Parliament prevent product decomposition and the development of substances potentially hazardous for health. None Emergency The specific required. Merck Always data Index. telephone wear are - 10th full available number fire Edition prevention for this product. gear. Collect Handle extinguishing it according to water good to working prevent practices. it from Avoid draining littering. into Do the not sewer contaminate system. soil, Dispose sewers of and 8. contaminated SKIN Handling waterways. PROTECTION Chemical water Inform used Safety the for extinction competent and authorities, the remains should of the the fire according product reach to applicable waterways regulations. or sewers or contaminate soil or vegetation. Please take For 9. SPECIAL None Niosh urgent all required. the - PROTECTIVE Registry inquiries proper measures of refer Toxic to EQUIPMT Effects to reduce of Chemical harmful FOR FIRE-FIGHTERS effects Substances on aquifers Hardhat Toxicity. INRS with - Fiche visor, Toxicologique fireproof clothing (toxicological (fireproof sheet) jacket and trousers with straps around arms, legs and waist), work gloves (fireproof, cut proof and antistatic), a depressurised mask with facemask covering the whole of the operator s face or a self-respirator (self-protector) in the event 9. Information 11. Patty - Industrial Physical and not available. Hygiene and Toxicology 2. Hazards identification. chemical properties. 12. of large N.I. Sax quantities - Dangerous of fume. properties of Industrial Materials-7, 1989 Edition Information Persistence ECHA website on and basic degradability. physical and chemical properties Appearance Information Accidental Classification not release available. of the measures. substance or mixture. liquid Colour pink Note Odour Personal Bioaccumulative for users: The product precautions, is not classified potential. protective as hazardous equipment pursuant and mild to emergency the provisions procedures. set forth in Directives 67/548/EEC and 1999/45/EC and/or EC Information Eliminate The Odour information threshold. sources not available. contained of ignition in (cigarettes, the present flames, sheet are Not sparks, available. based etc.) on from our own the air knowledge in which the on leak the occurred. date of the If there last are version. no contraindications, Users must verify spray the Regulation 1272/2008 (CLP)(and subsequent amendments and supplements). solid suitability ph. products and thoroughness with water to of provided prevent the information formation 10 according of dust. to Use each breathing specific use equipment of the product if fumes. or powders are released into the air. Block the leakage This Melting Mobility document or if freezing there soil. must is point. not be hazard. regarded Do as not a guarantee handle damaged Not on available. any specific containers product or leaked property Label elements. product before donning appropriate protective gear. Send away Information individuals The Initial use boiling of who not point. this available. are product not suitably is not subject equipped. to our For direct information Not control; available. therefore, on risks users for the must, environmental under their and own health, responsibility, respiratory comply tract with protection, the current ventilation health and Boiling safety personal range. laws protection and regulations. equipment, The producer refer to is the relieved Not other available. from sections any liability of this arising sheet. from These improper indications uses. Hazard pictograms: -- apply for both processing staff and those involved Flash Results point. emergency of PBT and procedures. vpvb assessment. > 60 C. Information Signal Evaporation words: not Rate available Flammability Environmental of solids precautions. and gases Not flammable The Hazard Lower Other product inflammability statements: adverse must not effects. limit. penetrate the --sewers, surface Not water, available. ground water and neighbouring areas. Information Upper inflammability not available. limit Precautionary Lower Methods explosive and statements: material limit. for containment -- and cleaning up. 13. For Upper Disposal liquid explosive products, considerations. limit. suck into a suitable container Not (made available. of material not incompatible with the product) and soak up any leaked product with 2.3. absorbent Vapour Other pressure. hazards. inert material (sand, vermiculite, diatomeous earth, Kieselguhr, etc). Collect the majority of the remaining material and deposit in containers Vapour Waste density treatment for disposal. methods. For solid products, use Not spark available. proof mechanical tools to collect the leaked product and place in plastic containers. If there Reuse, Information Specific are when gravity. no not possible. contraindications, available. Neat product use residues jets of should water 960 be to considered eliminate Kg/l product special non-hazardous residues. Make waste. sure the leakage site is well aired. Contaminated material Disposal Solubilityshould must be be performed disposed of through in compliance authorised with the waste soluble provisions management in water set forth firm, in point compliance 13. with national and local regulations. Partition coefficient: n-octanol/water 3. CONTAMINATED Composition/information PACKAGING on ingredients Ignition Contaminated Reference temperature. to packaging other sections. must be recovered or disposed of in compliance with national waste management regulations Any Decomposition Substances. information temperature. on personal protection and disposal Not is given available. in sections 8 and 13. Viscosity 14. Transport information. 7. Information Reactive Handling Properties and not relevant. storage. The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail (RID), Precautions Mixtures. Other of information. the International safe handling. Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. Avoid the accumulation of electrostatic charges. Vapours Information may not available. ignite with explosion, it is therefore necessary to avoid accumulation keeping the windows and doors open, ensuring 15. The Regulatory product does information. not contain substances classified as being hazardous to human health or the environment pursuant to the provisions set crossventilation. forth in Directives Without 67/548/EEC adequate and/or ventilation, EC Regulation the 1272/2008 vapours may (CLP) accumulate (and subsequent at the bottom amendments and ignite and at a supplements). distance, if triggered off, with the risk 10. of Stability flashback. and Keep reactivity. far away from sources of heat, sparks and bright flames. Do not smoke, use matches or lighters. Keep the containers earthed while decanting and wear antistatic boots. 4. First Safety, aid measures. health and environmental regulations/legislation specific for the substance or mixture Vigorous Reactivity. stirring and flow through the pipings and equipment may cause the formation and accumulation of electrostatic charges due to the 4.1. Seveso low There Description conductivity are category. no particular of of first the aid product. risks measures. of reaction In order with to avoid other the substances risk of fire in outbreak normal conditions and explosion of use. never use compressed air during movement. No harm to the staff authorised to use has been reported. However, in case of contact, inhalation or ingestion, the following general measures Restrictions provided Conditions Chemical for relating a stability. for first safe aid to the shall storage, product be taken. including or contained any substances incompatibilities. pursuant to Annex XVII to EC Regulation 1907/2006. The Store product the containers is stable sealed in normal and conditions in a well ventilated of use and place. storage.

2 Page n. 2 / 5 INHALATION: remove to open air. If respiration is difficult, administer artificial respiration and seek medical advice. INGESTION: seek medical attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious person. EYES and SKIN: wash with plenty of water; if the irritation persists, seek medical advice Most important symptoms and effects, both acute and delayed. No episodes of damage to health ascribable to the product have been reported Indication of any immediate medical attention and special treatment needed. 5. Firefighting measures Extinguishing media. SUITABLE EXTINGUISHING MEDIA The extinction equipment should be of the conventional kind: carbon dioxide, foam, powder and nebulised water. EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONS None in particular Special hazards arising from the substance or mixture. HAZARDS CAUSED BY EXPOSURE IN THE EVT OF FIRE Do not breathe combustion products (carbon oxide, toxic pyrolysis products, etc) Advice for firefighters. GERAL INFORMATION Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations. SPECIAL PROTECTIVE EQUIPMT FOR FIRE-FIGHTERS Hardhat with visor, fireproof clothing (fireproof jacket and trousers with straps around arms, legs and waist), work gloves (fireproof, cut proof and antistatic), a depressurised mask with facemask covering the whole of the operator s face or a self-respirator (self-protector) in the event of large quantities of fume. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures. Eliminate sources of ignition (cigarettes, flames, sparks, etc.) from the air in which the leak occurred. If there are no contraindications, spray solid products with water to prevent the formation of dust. Use breathing equipment if fumes or powders are released into the air. Block the leakage if there is no hazard. Do not handle damaged containers or leaked product before donning appropriate protective gear. Send away individuals who are not suitably equipped. For information on risks for the environmental and health, respiratory tract protection, ventilation and personal protection equipment, refer to the other sections of this sheet. These indications apply for both processing staff and those involved in emergency procedures Environmental precautions. The product must not penetrate the sewers, surface water, ground water and neighbouring areas Methods and material for containment and cleaning up. For liquid products, suck into a suitable container (made of material not incompatible with the product) and soak up any leaked product with absorbent inert material (sand, vermiculite, diatomeous earth, Kieselguhr, etc). Collect the majority of the remaining material and deposit in containers for disposal. For solid products, use spark proof mechanical tools to collect the leaked product and place in plastic containers. If there are no contraindications, use jets of water to eliminate product residues. Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point Reference to other sections. Any information on personal protection and disposal is given in sections 8 and Handling and storage Precautions for safe handling. Avoid the accumulation of electrostatic charges. Vapours may ignite with explosion, it is therefore necessary to avoid accumulation keeping the windows and doors open, ensuring crossventilation. Without adequate ventilation, the vapours may accumulate at the bottom and ignite at a distance, if triggered off, with the risk of flashback. Keep far away from sources of heat, sparks and bright flames. Do not smoke, use matches or lighters. Keep the containers earthed while decanting and wear antistatic boots. Vigorous stirring and flow through the pipings and equipment may cause the formation and accumulation of electrostatic charges due to the low conductivity of the product. In order to avoid the risk of fire outbreak and explosion never use compressed air during movement Conditions for safe storage, including any incompatibilities. Store the containers sealed and in a well ventilated place.

3 Page n. 3 / Specific end use(s). 8. Exposure controls/personal protection Control parameters. Name Type Country TWA/8h STEL/15min mg/m3 ppm mg/m3 ppm ETHANOL TLV-ACGIH 1000 OEL IRL 1000 WEL UK Exposure controls. Observance of safety measures used in handling chemical substances. RESPIRATORY PROTECTION If the threshold value (if available) for one or more of the substances present in the preparation for daily exposure in the workplace or to a fraction established by the company s prevention and protection service is exceeded, wear a mask with an B or universal filter, the class (1, 2 or 3) of which must be chosen according to the limit concentration of use (ref. standard 141). EYE PROTECTION HAND PROTECTION SKIN PROTECTION 9. Physical and chemical properties Information on basic physical and chemical properties. Appearance liquid Colour pink Odour mild Odour threshold. ph. 10 Melting or freezing point. Initial boiling point. Boiling range. Flash point. > 60 C. Evaporation Rate Flammability of solids and gases Not flammable Lower inflammability limit. Upper inflammability limit. Lower explosive limit. Upper explosive limit. Vapour pressure. Vapour density Specific gravity. 960 Kg/l Solubility soluble in water Partition coefficient: n-octanol/water Ignition temperature. Decomposition temperature. Viscosity Reactive Properties 9.2. Other information. 10. Stability and reactivity Reactivity. There are no particular risks of reaction with other substances in normal conditions of use Chemical stability. The product is stable in normal conditions of use and storage.

4 Page n. 4 / Possibility of hazardous reactions. The vapours may also form explosive mixtures with the air Conditions to avoid. Avoid overheating, electrostatic discharge and all sources of ignition Incompatible materials Hazardous decomposition products. In the event of thermal decomposition or fire, vapours potentially dangerous to health may be released. 11. Toxicological information. According to currently available data, this product has not yet produced health damages. Anyway, it must be handled carefully according to good industrial practices. This product may have slight health effects on sensitive people, by inhalation and/or cutaneous absorption and/or contact with eyes and/or ingestion Information on toxicological effects. 12. Ecological information. No specific data are available for this product. Handle it according to good working practices. Avoid littering. Do not contaminate soil, sewers and waterways. Inform the competent authorities, should the product reach waterways or sewers or contaminate soil or vegetation. Please take all the proper measures to reduce harmful effects on aquifers Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects. 13. Disposal considerations Waste treatment methods. Reuse, when possible. Neat product residues should be considered special non-hazardous waste. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. 14. Transport information. The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture. Seveso category. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006.

5 Page n. 5 / 5 Substances in Candidate List (Art. 59 REACH). Substances subject to authorisarion (Annex XIV REACH). Healthcare controls Chemical safety assessment. No chemical safety assessment has been processed for the mixture and the substances it contains. 16. Other information. GERAL BIBLIOGRAPHY 1. Directive 1999/45/EC and following amendments 2. Directive 67/548/EEC and following amendments and adjustments 3. Regulation (EC) 1907/2006 (REACH) of the European Parliament 4. Regulation (EC) 1272/2008 (CLP) of the European Parliament 5. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament 6. Regulation (EC) 453/2010 of the European Parliament 7. The Merck Index. - 10th Edition 8. Handling Chemical Safety 9. Niosh - Registry of Toxic Effects of Chemical Substances 10. INRS - Fiche Toxicologique (toxicological sheet) 11. Patty - Industrial Hygiene and Toxicology 12. N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition 13. ECHA website Note for users: The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product. This document must not be regarded as a guarantee on any specific product property. The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses.