MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name Version # 01 Revision date CAS # Manufacturer information 2. Hazards Identification Mixture Material Interface, Inc. N73W22301 Willowview Drive Sussex, WI info@materialinterface.com General information: Contact person: Susan J. Kerber, Ph.D. 24-Hour Emergency Assistance: Physical state Appearance Emergency overview OSHA regulatory status Potential health effects Routes of exposure Eyes Skin Inhalation Ingestion Liquid. Hazy white liquid Health injuries are not known or expected under normal use. May be harmful if swallowed. Keep out of reach of children. This product is considered not hazardous under 29 CFR (Hazard Communication). Eye contact. Skin contact. Ingestion. May irritate eyes. May be slightly irritating to skin. Health injuries are not known or expected under normal use. Health injuries are not known or expected under normal use. However, may be harmful if swallowed. 3. Composition / Information on Ingredients The manufacturer lists no ingredients as hazardous according to OSHA 29 CFR Composition comments 4. First Aid Measures The manufacturer has claimed one or more hazardous ingredients as trade secret under the OSHA Hazard Communication Standard. The hazards of this (these) ingredient(s) are given on this MSDS. First aid procedures Eye contact Skin contact Inhalation Ingestion tes to physician General advice Flush eyes with water as a precaution. Get medical attention if irritation develops or persists. Rinse skin with water/shower. Get medical attention if irritation develops or persists. If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms develop or persist. Have victim rinse mouth thoroughly with water. If ingestion of a large amount does occur, call a poison control center immediately. Treat symptomatically. Get medical attention if any discomfort develops. 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Fire fighting equipment/instructions t a fire hazard. The product is not flammable. Water. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Move containers from fire area if you can do it without risk. Use water spray to cool unopened containers. Cool containers with flooding quantities of water until well after fire is out. 1 / 6

2 Specific methods Hazardous combustion products In the event of fire, cool tanks with water spray. Use water spray to cool unopened containers. ne known. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Local authorities should be advised if significant spillages cannot be contained. Keep unnecessary personnel away. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Should not be released into the environment. Large Spills: Dike far ahead of liquid spill for later disposal. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated surface thoroughly. After removal flush contaminated area thoroughly with water. Other information 7. Handling and Storage Handling Storage Never return spills to original containers for re-use. Clean up in accordance with all applicable regulations. Use only with adequate ventilation. Wash thoroughly after handling. Avoid release to the environment. Handle and open container with care. Use care in handling/storage. 8. Exposure Controls / Personal Protection Occupational exposure limits US. ACGIH Threshold Limit Values Acetic acid ( ) STEL US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Acetic acid ( ) PEL Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) Acetic acid ( ) STEL Canada. Ontario OELs. (Ministry of Labor - Control of Exposure to Biological or Chemical Agents) 2 / 6

3 Canada. Ontario OELs. (Ministry of Labor - Control of Exposure to Biological or Chemical Agents) Canada. Quebec OELS. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Mexico. Occupational Exposure Limit Values Engineering controls Personal protective equipment Eye / face protection Skin protection Respiratory protection General hygiene considerations 9. Physical & Chemical Properties Appearance Color Odor Odor threshold Physical state Form Ensure adequate ventilation, especially in confined areas. If risk of splashing, wear safety goggles or face shield. special protective equipment required. personal respiratory protective equipment normally required. Handle in accordance with good industrial hygiene and safety practice. Hazy white liquid Clear. ph 6.9 Melting point Freezing point Boiling point Flash point Evaporation rate Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Vapor pressure Vapor density Specific gravity 1.1 Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Odorless. Liquid. Nanoparticles in suspension. 3 / 6

4 Decomposition temperature 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions Stable for six weeks at 25 C (77 F). ne known. May include oxides of nitrogen. Hazardous polymerization does not occur. 11. Toxicological Information Toxicological data Product (Mixture) Components Acetic acid ( ) Sensitization Chronic effects Carcinogenicity Epidemiology Mutagenicity Neurological effects Reproductive effects Teratogenicity Further information Acute Oral LD50 Rat: 1034 g/kg estimated Acute Dermal LD50 Rabbit: 1060 mg/kg Acute Inhalation LC50 Rat: 11.4 mg/l 4 Hours Acute Oral LD50 Rat: 3.31 g/kg This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. This product has no known adverse effect on human health. 12. Ecological Information Ecotoxicological data Product (Mixture) Components Acetic acid ( ) Proprietary Surfactant Ecotoxicity Environmental effects Persistence and degradability Bioaccumulation / Accumulation Partition coefficient (n-octanol/water) Mobility in environmental media EC50 Daphnia: mg/l 48 hours estimated EC50 Water flea (Daphnia magna): 65 mg/l 48 hours LC50 Bluegill (Lepomis macrochirus): 75 mg/l 96 hours LC50 Fathead minnow (Pimephales promelas): 79 mg/l 96 Hours LC50 Bluegill (Lepomis macrochirus): mg/l 96 hours Components of this product have been identified as having potential environmental concerns. An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. ne known. data available. The product is soluble in water. 4 / 6

5 13. Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging 14. Transport Information DOT IATA IMDG TDG 15. Regulatory Information US federal regulations Do not allow this material to drain into sewers/water supplies. This product, in its present state, when discarded or disposed of, is not a hazardous waste according to Federal regulations (40 CFR (b)(4)). Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the product meets RCRA criteria for hazardous waste. Dispose in accordance with all applicable regulations. t applicable. CERCLA (Superfund) reportable quantity (lbs) ne Offer rinsed packaging material to local recycling facilities. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - Section 302 extremely hazardous substance Section 311 hazardous chemical Drug Enforcement Agency (DEA) Canadian regulations WHMIS status Inventory status This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR All components are on the U.S. EPA TSCA Inventory List. t controlled This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. n-controlled Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) 5 / 6

6 Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US - California Hazardous Substances (Director's): Listed substance (CAS Proprietary) 16. Other Information Further information Other information Listed. This product contains a Proprietary Surfactant. HMIS is a registered trade and service mark of the NPCA. Contains: Proprietary Surfactant HMIS ratings Health: 1 Flammability: 0 Physical hazard: 0 NFPA ratings Health: 1 Flammability: 0 Instability: 0 Disclaimer Issue date The information in the sheet was written based on the best knowledge and experience currently available. This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment. 6 / 6