Material Safety Data Sheet

Transcription

1 Conforms to ANSI Z Standard (United States). Material Safety Data Sheet 1. Product and company identification Common name Material uses Calcium and magnesium supplement for plants. Supplier/Manufacturer Technaflora Plant Products Ltd River Place, 11 Mission, B.C. Canada, V4S A3 Tel / In case of emergency CHEMTREC, U.S. (8) International (73) Physical state Hazards identification Odor Color Hazard status Emergency overview Routes of entry Potential acute health effects Potential chronic health effects Medical conditions aggravated by overexposure Liquid. See toxicological information (section 11) 3. Odorless. Gold. This material is classified as hazardous under OSHA regulations. WARNING! CAUSES EYE IRRITATION. MAY BE HARMFUL IF SWALLOWED. MAY CAUSE SKIN IRRITATION. Do not ingest. Avoid contact with skin and clothing. Avoid breathing vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Dermal contact. Eye contact... Irritating to eyes. Moderately irritating to the skin. No known significant effects or critical hazards. May be harmful if swallowed. Carcinogenic effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Mutagenic effects Not available. Teratogenic effects Not available. Repeated or prolonged contact with spray or mist may produce chronic eye irritation and severe skin irritation. Composition/information on ingredients Name United States CAS number % Magnesium Nitrate Date of issue 9/2/211 Page 1/5

2 4. Eye contact contact First aid measures Check for and remove any contact lenses. In case of contact with eyes, rinse immediately with plenty of water. Get medical attention if symptoms occur. Wash with soap and water. Get medical attention if symptoms occur. Notes to physician If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms appear. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if symptoms appear. No specific antidote. Medical staff must contact Poison Control Center. 5. Fire-fighting measures Flammability of the product Extinguishing media Suitable Not suitable Special exposure hazards Special protective equipment for fire-fighters 6. Non-flammable. Accidental release measures Use an extinguishing agent suitable for the surrounding fire. None known. No specific hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Personal precautions Use suitable protective equipment. Environmental precautions Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. Methods for cleaning up For small spills, add absorbent (soil may be used in the absence of other suitable materials), scoop up material and place in a sealable, liquid-proof container for disposal. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. 7. Handling Storage 8. Handling and storage Do not ingest. Avoid contact with eyes, skin and clothing. Keep container closed. Use only with adequate ventilation. Avoid breathing vapor or mist. Wash thoroughly after handling. Keep container tightly closed. Keep container in a cool, well-ventilated area. Exposure controls/personal protection Consult local authorities for acceptable exposure limits. Engineering measures Personal protection Respiratory Hands Use only with adequate ventilation. If user operations generate dust, fumes, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Safety glasses. Lab coat. A respirator is not needed under normal and intended conditions of use. Natural rubber (latex). Date of issue 9/2/211 Page 2/5

3 HMIS Code/Personal B protective equipment Personal protection in case Safety glasses, goggles or face shield. Impervious gloves. Full suit. Boots. Wear NIOSHapproved of a large spill Hygiene measures self-contained breathing apparatus or equivalent and full protective gear. Wash hands, forearms and face thoroughly after handling compounds and before eating, smoking and using the lavatory and at the end of the day. Follow good industrial hygiene practice. 9. Physical state Physical and chemical properties Color Odor ph Boiling/condensation point Melting/freezing point Relative density Vapor pressure Vapor density Evaporation rate Solubility 1. Liquid. Stability and reactivity Stability and reactivity Incompatibility with various substances Hazardous decomposition products Hazardous polymerization Conditions of reactivity 11. Gold. Odorless [Acidic.] The lowest known value is 1 C (212 F) (Water). May start to solidify at C (32 F) based on data for Water (Water = 1) The highest known value is 2.3 kpa (17.5 mm Hg) (at 2 C) (Water). The highest known value is.62 (Air = 1) (Water)..36 (Water) compared with Butyl acetate. Miscible in water. The product is stable. Reactive with acids, alkalis, oxidizing materials, reducing materials, organic materials and metals. These products are halogenated compounds, hydrogen chloride. Will not occur. None known. Toxicological information Toxicity data Product/ingredient name Test Result Route Species LD5 32 mg/kg Rat LD5 LD5 194 mg/kg 1 mg/kg Mouse Rat Acute Effects Potential chronic health effects Irritating to eyes. Moderately irritating to the skin. No known significant effects or critical hazards. May be harmful if swallowed. Carcinogenic effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Mutagenic effects Not available. Teratogenic effects Not available. Date of issue 9/2/211 Page 3/5

4 12. Ecological information Product/ingredient name Ecotoxicity data Species Pimephales promelas (LC5) Period Result 463 mg/l 95 mg/l 165 mg/l 113 mg/l Environmental precautions Products of degradation Toxicity of the products of biodegradation 13. Disposal considerations Waste disposal 14. Transport information NAERG Not applicable. Regulatory information 15. SARA 313 UN/ IMDG/ IATA DOT Regulatory information United States HCS Classification U.S. Federal regulations Form R - Reporting requirements Supplier notification No known significant effects or critical hazards. These products are carbon oxides and water, nitrogen oxides, halogenated compounds. Some metallic oxides. The products of degradation are as toxic as the product itself. The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional and local authority requirements. Not regulated. Irritating material TSCA All components listed. SARA 32/34/311/312 extremely hazardous substances No products were found. SARA 32/34 emergency planning and notification No products were found. SARA 32/34/311/312 hazardous chemicals Magnesium Nitrate; ; SARA 311/312 MSDS distribution - chemical inventory - hazard identification Magnesium Nitrate Fire hazard; Fire hazard; Immediate (acute) health hazard, Delayed (chronic) health hazard Clean Water Act (CWA) 37 No products were found. Clean Water Act (CWA) 311 No products were found. Clean Air Act (CAA) 112 accidental release prevention No products were found. Clean Air Act (CAA) 112 regulated flammable substances No products were found. Clean Air Act (CAA) 112 regulated toxic substances No products were found. Product name CAS number Concentration SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed. Date of issue 9/2/211 Page 4/5

5 State regulations International regulations International lists 16. Other information Label requirements (U.S.A.) Pennsylvania RTK Magnesium Nitrate (generic environmental hazard) Massachusetts RTK Magnesium Nitrate New Jersey Magnesium Nitrate; California prop. 65 No products were found. This product, (and its ingredients) is (are) listed on national inventories, or is (are) exempted from being listed, Australia (AICS), in Europe (EINECS/ELINCS), in Korea (TCCL), in Japan (METI), in the Philippines (RA6969). CAUSES EYE IRRITATION. MAY BE HARMFUL IF SWALLOWED. MAY CAUSE SKIN IRRITATION. Hazardous Material Information System (U.S.A.) HMIS RATING Health 1 Fire hazard Physical Hazard Personal protection B HAZARD RATINGS 4- Extreme 3- Serious 2- Moderate 1- Slight - Minimal See section 8 for more detailed information on personal protection. National Fire Protection Association (U.S.A.) Health 1 Flammability Reactivity Special References ANSI Z4.1, MSDS Standard, Manufacturer's Material Safety Data Sheet. - 29CFR Part OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping Names, PG. Date of issue 9/2/211 Date of previous issue 8/1/26 Version 2 Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue 9/2/211 Page 5/5