1. IDENTIFICATION OF THE PREPARATION AND OF THE COMPANY/UNDERTAKING

Transcription

1 1. IDENTIFICATION OF THE PREPARATION AND OF THE COMPANY/UNDERTAKING 1.1 Product name Imidasect 1.2. Relevant identified uses of the substance or Non crop insecticide for pest control in industrial mixture and uses advised against: and private buildings, warehouses, and food stores 1.3. Identification of MSDS supplier Sharda Worldwide Exports Pvt. Ltd. Domnic Holm, 29th Road, Bandra (West), Mumbai India Tel.: Fax: Emergency telephone: (8 16h) 2. HAZARDS IDENTIFICATION 2.1 Classification of the mixture: EU directive. 2001/59/EC EU Regulation 1272/2008 R52/53 S2 S13 S20/21 S29 S60 S61 Aquatic Chronic 3 H412 P273 P Label elements: EU regulation 2001/59/EC Regulation EU 1272/2008 R52/53: Harmful to aquatic organisms/ May cause long-term adverse effects in the aquatic environment S2: Keep out of the reach of children. S13: Keep away from food, drink and animal feeding stuffs. S20/21: When using do not eat, drink or smoke S29: Do not empty into drains. S60: This material and its container must be disposed of as hazardous waste. S61: Avoid release to the environment. Refer to special instructions/safety data sheet. H412: Harmful to aquatic life with long lasting effects P273: Avoid release to the environment P501 Dispose of contents/container via a licensed hazardous waste manager. 3. COMPOSITION/INFORMATION ON INGREDIENTS

2 Hazardous components Chemical Name CAS-No. / Concentration Classification EINECS-No. [% w/w] EC_1272/2008 Imidacloprid SGH07,SGH09 Ac.Tox cat.4; H302 Ac. Aqua. Cat.1; H400 Chron. Aqua. Cat.1; H410 Classification EEC/67/548 Xn, N R22 R50/53 Sodium hydroxide < 0.5 Skin corr cat 1; H314 C, R35 4. FIRST AID MEASURES 4.1. First aid General advice Skin contact Eye contact Ingestion Notes to Physician Treatment Move out of dangerous area. If the patient is likely to become unconscious, place and transport in stable sideways position. Remove soiled or soaked clothing immediately. Wash off immediately with soap and plenty of water. Take medical treatment. In case of contact with eyes rinse thoroughly with water. Call a physician immediately. Do not induce vomiting. Wash out mouth with water. Call a physician immediately. Treat symptomatically. Monitoring of respiratory and cardiac functions. Gastric lavage, then charcoal (carbo medicalis) and sodium sulfate. 4.2 : Most important symptoms and effects, both acute and delayed: 4.3 : Indication of any immediate medical attention and special treatment needed: 5. FIRE-FIGHTING MEASURES 5.1 Suitable Extinguishing Media Dry chemical powder. Carbon dioxide. Foam, water fog or spray. Fight larger fires preferably with water fog or alcohol-resistant foam. Avoid pressure water jets.

3 5.2 Specific hazards during fire fighting If the product comes in combustion, for example as a result of a fire may cause toxic fumes and vapors. of carbon monoxide (CO) 5.3 Special protective equipment for fire-fighters Use standard protective clothing for firefighting boots, overalls, gloves, eye protection and face and breathing apparatus. In the event of fire and/or explosion do not breathe fumes. 5.4 Further information Contain the spread of the fire-fighting media. Do not allow run-off from firefighting to enter drains or water courses. Move containers from fire area if possible without risk. With water spray to cool containers. Prevent choking waters reach drains or waterways. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Keep people away and isolate spill area. Avoid contact with spilled product or contaminated surfaces. Use personal protective equipment: gloves, boots, protective clothing, eye protection, respiratory protection. Caution: spilled on the floor may be slippery Environmental Precautions Prevent product from entering the environment (surface and groundwater), sewerage, drainage... with the construction of protective barriers and closing drains. Inform the competent authorities uncontrolled leaks or spills to water courses, drains, sewers Methods for Cleaning Up Take up with absorbent material (e.g. sand, diatomaceous earth or a proprietary absorbent material). Pack spilled material in suitable containers for recovery or disposal. Clean contaminated floors and objects thoroughly, observing environmental regulations. 6.4 Additional Advice Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section HANDLING AND STORAGE 7.1 Handling Precautions for safe handling:: Do not eat, drink or smoke while handling. Wash hands after handling. Wearing gloves, protection. Work in well ventilated conditions. Avoid product contact with eyes / skin. Shedding clothing and contaminated protective equipment before entering eating areas..

4 7.2 Conditions for safe storage, including any incompatibilities: The product should be stored in tightly closed original container in a cool, dry, well ventilated area. Avoid high temperatures and direct action of sunlight. Protect from moisture. The containers must be placed in such a way as to allow free circulation of air. Do not store together with oxidizing agents, alkalis (caustic solutions), and acids. Keep away from foodstuffs, beverages and feed. Check stocks regularly for damage. 7.3 specific to end use Product biocide: Insect pest control environmental health and food industry. Carefully read the label before using the product. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION Control parameters Information not available Exposure Controls General Hygiene Measures: Avoid contact with eyes, skin, clothing. Keep work clothes separate from the rest of the costume. Do not eat, drink or smoke while handling. a) Respiratory protection Handle in well ventilated areas. b) Hand Protection Wear protective gloves (PVC, rubber, nitrile) chemical resistant. Always wash hands immediately after handling the product. c) Eye protection Wear safety goggles or face shield. d) Skin protection Use appropriate protective clothing. e) Control of environmental exposure Avoid direct discharge to sewer systems and / or surface water. Do not contaminate water bodies or courses with the product or its packaging. The spills or uncontrolled discharges into surface waters must be reported to the competent authorities, in accordance with current legislation. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Form Colour Odour Gel (viscous liquid) Brown light, specific odour Density 1.25 x 10³ 20ºC Water Solubility completely miscible Impact Sensitivity not impact-sensitive Surface tension 60mN/m Other Information Not flammable, not auto-flammable, not explosive,

5 not oxidizing 10. STABILITY AND REACTIVITY 10.1 Reactivity No reactivity 10.2 Chemical stability Handled and stored under conditions described in Section 7, the product is stable at least for 2 years Conditions to avoid Avoid extreme temperatures. Avoid exposure to direct sunlight Incompatible materials Strong acids and bases, strong oxidizing agents Hazardous Reactions No hazardous reactions when stored and handled according to prescribed instructions Hazardous decomposition products If the product comes in combustion, for example as a result of a fire may cause toxic fumes and vapors (see Section 5). 11. TOXICOLOGICAL INFORMATION 11.1 Acute toxicity (Imidasect mixture) Acute Oral Toxicity Acute Dermal Toxicity Skin Irritation Eye Irritation Skin sensitization LD50 (rat) > 5,000 mg/kg LD50 (rat) > 2,000 mg/kg Mild irritant Mild irritant Non-sensitizing 11.2 Subchronic/chronic toxicity (substance) Non Mutagenic, non carsinogenic & non teratogenic (imidacloprid) 12. ECOLOGICAL INFORMATION 12.1 Toxicity (substance) Toxicity to Fish (trout) Toxicity to daphnia Toxicity to algae (Desmodesmus subspicatus) 96-h LC mg/l (imidacloprid). 48-h EC50 85 mg/l (imidacloprid). 72-h EC50 > 10 mg/l (imidacloprid) Persistence/biodegradability: persistent in soil

6 12.3 Bioaccumulation potential: Low 12.4 Soil mobility: moderate 12.5 PBT, vpvb: Not available 12.6 Other effect: none known 13. DISPOSAL CONSIDERATIONS Product Contaminated packaging Dispose of by incineration in an authorized hazardous waste incineration plant. Comply with local legislation. For larger quantities contact manufacturer. Completely empty packaging can be recycled or landfilled together with domestic waste. Regulations concerning reuse or disposal of used packaging materials must be observed. 14. TRANSPORT INFORMATION ADNR ADR IATA IMDG RID 15. REGULATORY INFORMATION Classification: Exceptional labelling Further information National legislation Water contamination class (Germany) Hazard warning labelling not compulsory To avoid risks to man and the environment, comply with the instructions for use WHO-classification: III (Slightly hazardous) WGK 1 slightly water endangering 16. OTHER INFORMATION Further information

7 R22 harmful if swallowed R35 corrosive to skin R50/53 harmful to aquatic organisms; may cause long-term cause adverse effect in the aquatic envirpnment R52/53: Harmful to aquatic organisms/ May cause long-term adverse effects in the aquatic environment S2: Keep out of the reach of children. S13: Keep away from food, drink and animal feeding stuffs. S20/21: When using do not eat, drink or smoke S29: Do not empty into drains. S60: This material and its container must be disposed of as hazardous waste. S61: Avoid release to the environment. Refer to special instructions/safety data sheet. H302 hartmful if swallowed H314 causes severe skin burns and eye damage H410 very toxic to aquatic life with long-lasting effects The information given in this Data Sheet has been included in accordance with the guidelines established by Regulation EC 1907/2006 and Annex II of Regulation 453/2010. This data sheet complements the user's instructions, but does not replace them. The information it contains is based on the knowledge available about the product concerned at the time it was compiled. Users are further reminded of the possible risks of using a product for purposes other than those for which it was intended. The required information complies with current EU legislation. Addressees are requested to observe any additional national requirements. This information is based on our present state of knowledge. It should not therefore be construed as guaranteeing specific properties of the products described or their suitability for a particular application.