Safety Data Sheet Attached

Transcription

1 Canada Colors and Chemicals Limited 152 Kennedy Road South Brampton, Ontario Canada L6W 3G4 General Inquiry Number: (905) Attached

2 1. PRODUCT AND COMPANY IDENTIFICATION TOMAMINE Q-C-15 SURFACTANT Product name : Product Use Description Manufacturer/Importer/Distribu tor : Surfactant : - Division PMD 299 Jefferson Road Parsippany, NJ Telephone Emergency telephone number (24h) : Corporate Chemicals Cust Serv Gases/Electronics Cust Serv : USA International 2. HAZARDS IDENTIFICATION GHS classification Serious Eye Damage - Category 1 GHS label elements Hazard pictograms/symbols Signal Word: Danger Hazard Statements: H318:Causes serious eye damage. Precautionary Statements: Prevention : P280:Wear eye protection/face protection. 1/9

3 Response : P305+P351+P338 :IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 :Immediately call a POISON CENTRE/doctor. Hazards not otherwise classified Irritating to eyes. Moderate respiratory irritant. Moderate skin irritant. Risk of serious damage to eyes. 3. COMPOSITION/INFORMATION ON INGREDIENTS Components CAS Number Concentration Quaternary ammonium compounds, coco % alkylbis(hydroxyethyl)methyl, ethoxylated, chlorides CHEMICAL FAMILY: Quaternary ammonium chloride 4. FIRST AID MEASURES General advice : Seek medical advice. If breathing has stopped or is labored, give assisted respirations. Supplemental oxygen may be indicated. If the heart has stopped, trained personnel should begin cardiopulmonary resuscitation immediately. Eye contact : Rinse immediately with plenty of water also under the eyelids for at least 20 minutes. Remove contact lenses. Skin contact Ingestion Inhalation Most important symptoms/effects - acute and delayed : Wash off immediately with plenty of water for at least 20 minutes. Immediately remove contaminated clothing, and any extraneous chemical, if possible to do so without delay. : Never give anything by mouth to an unconscious person. If a person vomits when lying on his back, place him in the recovery position. Prevent aspiration of vomit. Turn victim's head to the side. : If breathing has stopped or is labored, give assisted respirations. Supplemental oxygen may be indicated. If the heart has stopped, trained personnel should begin cardiopulmonary resuscitation immediately. Move to fresh air. : Repeated and/or prolonged exposure to low concentrations of vapors and/or aerosols may cause: Sore throat.eye disease. Asthma. Skin disorders and Allergies. 5. FIRE-FIGHTING MEASURES 2/9

4 Suitable extinguishing media Specific hazards Special protective equipment for fire-fighters : Alcohol-resistant foam. Carbon dioxide (CO2). Dry chemical. Dry sand. Limestone powder. : Incomplete combustion may form carbon monoxide. May generate ammonia gas. May generate toxic nitrogen oxide gases. Burning produces noxious and toxic fumes. Downwind personnel must be evacuated. : Use personal protective equipment. Wear self contained breathing apparatus for fire fighting if necessary. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment, and Emergency Procedures Environmental precautions Methods for cleaning up Additional advice : Wear suitable protective clothing, gloves and eye/face protection. Use selfcontained breathing apparatus and chemically protective clothing. Evacuate personnel to safe areas. : Construct a dike to prevent spreading. Construct a dike to prevent spreading. : Call Emergency Response number for advice. Approach suspected leak areas with caution. Place in appropriate chemical waste container. : Open enclosed spaces to outside atmosphere. If possible, stop flow of product. 7. HANDLING AND STORAGE Handling Emergency showers and eye wash stations should be readily accessible. Adhere to work practice rules established by government regulations. Use only in well-ventilated areas. Avoid contact with eyes. Avoid breathing vapors and/or aerosols. Use personal protective equipment. When using, do not eat, drink or smoke. Storage Do not store near acids. Store in steel containers preferably located outdoors, above ground, and surrounded by dikes to contain spills or leaks. Keep containers tightly closed in a dry, cool and well-ventilated place. Storage Temperature : < 160 F (< 71.1 C) 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures Provide readily accessible eye wash stations and safety showers. Provide natural or explosion-proof ventilation adequate to ensure concentrations are kept below exposure limits. Personal protective equipment 3/9

5 Respiratory protection Hand protection Eye protection : Wear appropriate respirator when ventilation is inadequate. : Butyl-rubber Nitrile rubber. Neoprene gloves. Impervious gloves. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. : Chemical resistant goggles must be worn. Skin and body protection : Long sleeve shirts and trousers without cuffs. Environmental exposure controls Special instructions for protection and hygiene : Construct a dike to prevent spreading. : Discard contaminated leather articles. Provide readily accessible eye wash stations and safety showers. Wash hands at the end of each workshift and before eating, smoking or using the toilet. Provide readily accessible eye wash stations and safety showers. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Odor Odor threshold ph Melting point/range Boiling point/range Flash point Evaporation rate Flammability (solid, gas) Upper/lower explosion/flammability limit Vapor pressure : Liquid. Amber. : Mild. : 41 F (5 C) : > 220 F (> C) : > 212 F (> 100 C) : Not applicable. : Not applicable. 4/9

6 Water solubility Relative vapor density : Not applicable. Relative density : 1.08 Partition coefficient (noctanol/water) Auto-ignition temperature Decomposition temperature Viscosity Molecular Weight 10. STABILITY AND REACTIVITY Chemical Stability Conditions to avoid Materials to avoid Hazardous decomposition products Possibility of hazardous Reactions/Reactivity : Stable under normal conditions. : Organic acids (i.e. acetic acid, citric acid etc.). Mineral acids. Sodium hypochlorite. Product slowly corrodes copper, aluminum, zinc and galvanized surfaces. Reaction with peroxides may result in violent decomposition of peroxide possibly creating an explosion. Oxidizing agents. Alkali and alkaline earth metals - powdered aluminum, zinc, etc. Reacts with water to form corrosive acids. : Nitric acid. Ammonia Nitrogen oxides (NOx). Nitrogen oxide can react with water vapors to form corrosive nitric acid. Carbon monoxide. Carbon dioxide (CO2). 11. TOXICOLOGICAL INFORMATION Information on toxicological effects Likely routes of exposure Effects on Eye : Contact with eyes may cause irritation. 5/9

7 Effects on Skin Inhalation Effects Ingestion Effects Symptoms : Causes skin irritation. : Harmful if inhaled and may cause delayed lung injury. May cause nose, throat, and lung irritation. Inhalation of vapors and/or aerosols in high concentration may cause irritation of respiratory system. : Repeated and/or prolonged exposure to low concentrations of vapors and/or aerosols may cause: Sore throat. Eye disease., Asthma., Skin disorders and Allergies. Acute toxicity Acute Oral Toxicity Inhalation Acute Dermal Toxicity Skin corrosion/irritation Serious eye damage/eye irritation Sensitization. : LD50 : > 2,000 mg/kg Species : Rat. : No data is available on the product itself. : No data is available on the product itself. : Skin irritation. : Eye irritation. Chronic toxicity or effects from long term exposures Carcinogenicity Reproductive toxicity Germ cell mutagenicity Specific target organ systemic toxicity (single exposure) Specific target organ systemic toxicity (repeated exposure) Aspiration hazard : No data is available on the product itself. : No data is available on the product itself. Delayed and Immediate Effects and Chronic Effects from Short and Long Term Exposure This product contains no listed carcinogens according to IARC, ACGIH, NTP and/or OSHA in concentrations of 0.1 percent or greater.eye disease., Asthma., Skin disorders and Allergies. 6/9

8 12. ECOLOGICAL INFORMATION Ecotoxicity effects Aquatic toxicity Toxicity to other organisms : (96 h) : mg/l Species : Fathead minnow (Pimephales promelas). EC50 (96 h) : 1-5 mg/l Species : Algae. Persistence and degradability Biodegradability : Not biodegradable. Mobility Bioaccumulation : No data is available on the product itself. 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products Contaminated packaging : Contact supplier if guidance is required. : Dispose of container and unused contents in accordance with federal, state, and local requirements. 14. TRANSPORT INFORMATION DOT Not dangerous goods IATA UN/ID No. : UN3082 Proper shipping name : Environmentally hazardous substance, liquid, n.o.s., (Quaternary ammonium compounds, coco alkylbis(hydroxyethyl)methyl, ethoxylated, chlorides) Class or Division : 9 Packing group : III Label(s) : 9 Marine Pollutant : Yes ** NOTE: This product contains a substance that: 1) is regulated as a Marine Pollutant, or 2) meets the 7/9

9 IMDG definition of toxic to the aquatic environment. UN/ID No. : UN3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (Quaternary ammonium compounds, coco alkylbis(hydroxyethyl)methyl, ethoxylated, chlorides) Class or Division : 9 Packing group : III Label(s) : 9 Marine Pollutant : Yes TDG ** NOTE: This product contains a substance that: 1) is regulated as a Marine Pollutant, or 2) meets the definition of toxic to the aquatic environment. UN/ID No. : UN3082 Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (Quaternary ammonium compounds, coco alkylbis(hydroxyethyl)methyl, ethoxylated, chlorides) Class or Division : 9 Packing group : III Label(s) : 9 Marine Pollutant : Yes ** NOTE: This product contains a substance that: 1) is regulated as a Marine Pollutant, or 2) meets the definition of toxic to the aquatic environment. Further Information The transportation information is not intended to convey all specific regulatory data relating to this material. For complete transportation information, contact customer service. 15. REGULATORY INFORMATION Toxic Substance Control Act (TSCA) 12(b) Component(s): None. Country Regulatory list Notification USA TSCA Included on Inventory. EU EINECS Included on EINECS inventory or polymer substance, monomers included on EINECS inventory or no longer polymer. Canada DSL Included on Inventory. Australia AICS Included on Inventory. 8/9

10 Japan ENCS Not on Inventory. South Korea ECL Included on Inventory. China SEPA Included on Inventory. Philippines PICCS Included on Inventory. EPA SARA Title III Section 312 (40 CFR 370) Hazard Classification Acute Health Hazard EPA SARA Title III Section 313 (40 CFR 372) Component(s) above 'de minimus' level None. US. California Safe Drinking Water & Toxic Enforcement Act (Proposition 65) WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm. Chloromethane Ethylene oxide 16. OTHER INFORMATION HMIS Rating Health : 2 Flammability : 1 Physical hazard : 0 Prepared by : Evonik, Product Regulatory Department Telephone : Corporate Chemicals Cust Serv Gases/Electronics Cust Serv Preparation Date : 01/21/ /9