Issue Date: 13-Jul-2011 Revision Date: 14-Oct-2014 Version 1 1. IDENTIFICATION 2. HAZARDS IDENTIFICATION

Transcription

1 Safety Data Sheet Issue Date: 13-Jul-2011 Version 1 1. IDENTIFICATION Product Identifier Product Name Other means of identification SDS # Product Code UN/ID No Enviro-Sep CARROLL-182 B76 UN1950 Recommended use of the chemical and restrictions on use Recommended Use Disinfectant. Details of the supplier of the safety data sheet Supplier Address Carroll Co W. Kingsley Road Garland, TX Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr) INFOTRAC (International) (North America) 2. HAZARDS IDENTIFICATION Appearance Colorless aerosol spray Physical State Aerosol Odor Lysol type, ammonia Classification Flammable Aerosols Category 1 Signal Word Danger Hazard Statements Extremely flammable aerosol Precautionary Statements - Prevention Keep away from heat/sparks/open flames/hot surfaces. No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Page 1 / 8

2 Precautionary Statements - Storage Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F Other Hazards Toxic to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Propane Isobutane Trade Secret Proprietary <1 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** First Aid Measures 4. FIRST-AID MEASURES Eye Contact Skin Contact Inhalation Ingestion Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists: Get medical advice/attention. Wash skin with soap and water. If irritation persists, seek medical attention. Remove to fresh air. Get medical attention if symptoms occur. Give large volumes of water. Do not induce vomiting. Get medical attention. Most important symptoms and effects Symptoms Prolonged or repeated skin contact may cause irritation. Eye contact may be slightly irritating. Inhalation of vapor or mist may be irritating. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Carbon dioxide (CO2). Dry chemical. Foam. Unsuitable Extinguishing Media. Specific Hazards Arising from the Chemical Product is an extremely flammable aerosol. Aerosol cans may rupture in severe heat. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Page 2 / 8

3 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protection recommended in Section 8. Environmental Precautions Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS. Methods and material for containment and cleaning up Methods for Containment Methods for Clean-Up Prevent further leakage or spillage if safe to do so. Flood area with water and then mop up. Dispose of in accordance with federal, state and local regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Use personal protection recommended in Section 8. Avoid contact with skin, eyes or clothing. Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not destroy or deface the label. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible Materials Keep container tightly closed and store in a cool, dry and well-ventilated place. Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F. Store containers upright. None known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH STEL: 1000 ppm Propane Isobutane Appropriate engineering controls TWA: 1900 mg/m 3 (vacated) (vacated) TWA: 1900 mg/m 3 IDLH: 3300 ppm TWA: 1900 mg/m 3 TWA: 1800 mg/m 3 (vacated) (vacated) TWA: 1800 mg/m 3 IDLH: 2100 ppm TWA: 1800 mg/m 3 - TWA: 800 ppm TWA: 1900 mg/m 3 Engineering Controls Ensure adequate ventilation, especially in confined areas. Eyewash stations. Showers. Individual protection measures, such as personal protective equipment Eye/Face Protection Goggles. Skin and Body Protection Wear suitable protective clothing. Respiratory Protection Use in well-ventilated area. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Page 3 / 8

4 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Aerosol Appearance Colorless aerosol spray Odor Lysol type, ammonia Color Colorless Odor Threshold Property Values Remarks Method ph 11.0 Melting Point/Freezing Point Not applicable Boiling Point/Boiling Range Flash Point 35.2 C / 95 F Evaporation Rate Flammability (Solid, Gas) Liquid-Not applicable Upper Flammability Limits Lower Flammability Limit Vapor Pressure Not applicable Vapor Density Specific Gravity (Liquid Concentrate) (Water = 1) Water Solubility Completely soluble Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to Avoid Avoid contact with heat. Keep out of reach of children. Incompatible Materials None known based on information supplied. Hazardous Decomposition Products None known based on information supplied. Information on likely routes of exposure Product Information 10. STABILITY AND REACTIVITY 11. TOXICOLOGICAL INFORMATION Eye Contact Skin Contact Inhalation Avoid contact with eyes. Avoid contact with skin. Avoid breathing vapors or mists. Page 4 / 8

5 Ingestion Do not ingest. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 = 7060 mg/kg ( Rat ) - = mg/l ( Rat ) 4 h Propane - - = 658 mg/l ( Rat ) 4 h Isobutane - - = 658 mg/l ( Rat ) 4 h Trade Secret = 85 mg/kg ( Rat ) - = 5.5 mg/l ( Rat ) 4 h Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Nitrate or nitrite (ingested) under conditions that result in endogenous nitrosation are considered IARC group 2A carcinogens. The ingredient in this product is only classified as a carcinogen when consumed as an alcoholic beverage in long-term studies. Chemical Name ACGIH IARC NTP OSHA A3 Group 1 Known X Trade Secret Group 2A X Legend ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2A - Probably Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Numerical measures of toxicity Ecotoxicity Toxic to aquatic life with long lasting effects. Component Information 12. ECOLOGICAL INFORMATION Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Crustacea Page 5 / 8

6 : 96 h Oncorhynchus mykiss ml/l LC50 static 100: 96 h Pimephales promelas mg/l LC50 static : 96 h Pimephales promelas mg/l LC50 flow-through EC50 = mg/l 30 min EC50 = mg/l 5 min : 48 h Daphnia magna mg/l LC : 24 h Daphnia magna mg/l EC50 2: 48 h Daphnia magna mg/l EC50 Static Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Trade Secret 0.19: 96 h Oncorhynchus mykiss mg/l LC50 flowthrough : 96 h Oncorhynchus mykiss mg/l LC50 flow-through : 96 h Oncorhynchus mykiss mg/l LC50 semi-static : 96 h Oncorhynchus mykiss mg/l LC50 static 2.3: 96 h Pimephales promelas mg/l LC50 flow-through 20: 96 h Pimephales promelas mg/l LC50 static Crustacea Persistence/Degradability. Bioaccumulation. Mobility Chemical Name Partition Coefficient Propane Isobutane Trade Secret -3.7 Other Adverse Effects Waste Treatment Methods 13. DISPOSAL CONSIDERATIONS Disposal of Wastes Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status Page 6 / 8

7 Chemical Name Trade Secret California Hazardous Waste Status Toxic Ignitable Toxic Ignitable Reactive 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT UN/ID No UN1950 Proper Shipping Name Aerosols Hazard Class 2.1 IATA UN/ID No UN1950 Proper Shipping Name Aerosols, flammable Hazard Class 2.1 IMDG UN/ID No UN1950 Proper Shipping Name Aerosols Hazard Class 2.1 Marine Pollutant This material may meet the definition of a marine pollutant International Inventories 15. REGULATORY INFORMATION TSCA Listed Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory US Federal Regulations CERCLA SARA 313 Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Trade Secret 100 lb RQ 100 lb final RQ RQ 45.4 kg final RQ Chemical Name CAS No Weight-% SARA Threshold Values % Trade Secret - <1 1.0 CWA (Clean Water Act) Page 7 / 8

8 Chemical Name CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Quantities Substances Trade Secret 100 lb X US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania X X X Propane X X X Isobutane X X X Trade Secret X X X 16. OTHER INFORMATION NFPA HMIS Health Hazards Health Hazards 2 Flammability Flammability 3 Instability Physical Hazards 0 Special Hazards Personal Protection A = Goggles Issue Date: Revision Date: Revision Note: 13-Jul Oct-2014 New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 8 / 8