Safety Data Sheet in accordance with Regulation (EU) No.453/2010 Savinyl Pink 6BLS Page 1(10)

Transcription

1 Savinyl Pink 6BLS Page 1(10) SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name Savinyl Pink 6BLS Material number: Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses of the substance or mixture Industry sector : Paints, lacquers and varnishes industry Type of use : dye for special industries 1.3. Details of the supplier of the safety data sheet Identification of the company Clariant Production (France) Usine de Huningue Avenue de Bâle Huningue Telephone no. : Information about the substance/mixture Division Pigments & Additives tel.: France.ProductSafety@clariant.com 1.4. Emergency telephone number (24 h) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according CLP regulation (Regulation (EC) No. 1272/2008, as amended) Hazard class Hazard category H-phrase Acute toxicity Category 4 Harmful if swallowed. Chronic aquatic toxicity Category 2 Toxic to aquatic life with long lasting effects. Classification according EC Directive (67/548/EEC or 1999/45/EC, as amended) Category of danger/category 2.2. Label elements Hazard symbol Harmful R - phrases May cause long-term adverse effects in the aquatic environment. Harmful if swallowed.

2 Savinyl Pink 6BLS Page 2(10) Labelling according CLP regulation (Regulation (EC) No. 1272/2008, as amended) Hazard pictograms Signal word Warning Hazard statements H302 H411 Harmful if swallowed. Toxic to aquatic life with long lasting effects. Precautionary statements P264.3 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P273 Avoid release to the environment. P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330 Rinse mouth. P391 Collect spillage Other hazards May cause long term adverse effects in the aquatic environment. Toxic to aquatic organisms. Harmful if swallowed. SECTION 3: Composition/information on ingredients 3.1. Substances Chemical characterization azo dyestuff/chromium complex, C.I. SOLVENT RED 127 EC number: SECTION 4: First aid measures 4.1. Description of first aid measures General information Seek medical assistance if discomfort continues After inhalation Remove from danger zone. Obtain medical advice. After contact with skin Remove contaminated clothing. Wash with water and soap.

3 Savinyl Pink 6BLS Page 3(10) After contact with eyes Immediately rinse eyes with running water and seek medical advice. After ingestion If swallowed, seek medical advice immediately Most important symptoms and effects, both acute and delayed Symptoms No symptoms known currently. Hazards No hazards known at this time Indication of any immediate medical attention and special treatment needed Treatment Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media all Extinguishing media that must not be used for safety reasons No restrictions 5.2. Special hazards arising from the substance or mixture carbon oxides chromium oxides nitrogen oxides sulfur oxides Under certain conditions of combustion traces of other toxic substances cannot be excluded 5.3. Advice for firefighters Special protective equipment for firefighting Use self-contained breathing apparatus Further information Cool container and metallic parts with a water spray jet SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with skin and eyes Environmental precautions Do not allow entry to drains,water courses or soil 6.3. Methods and material for containment and cleaning up

4 Savinyl Pink 6BLS Page 4(10) Take up with suitable equipment and if necessary collect in closed containers 6.4. Reference to other sections Additional information Information regarding Safe handling, see chapter 7. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Keep container tightly closed. Keep container in a well-ventilated place. Ensure efficient exhaust ventilation when using this product Store container in cool and dry place. Avoid dust formation. Advice on protection against fire and explosion Take precautionary measures against static discharges. Avoid formation of dust. Keep away from sources of ignition. Observe the usual precautionary measures required for chemicals with dust explosive properties (Observe national regulations) Conditions for safe storage, including any incompatibilities Further information on storage conditions Keep container tightly closed and dry in a cool, well-ventilated place 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure limit values Exposure limit values are not available. DNEL/DMEL values DNEL/DMEL values are not available. PNEC values PNEC values are not available Exposure controls General protective measures Observe the usual precautions for handling chemicals.

5 Savinyl Pink 6BLS Page 5(10) Hygiene measures Keep away from food, drink and animal feedingstuffs. Work in an adequately ventilated room. When using do not eat or drink. Do not breathe dust. Avoid contact with skin and eyes. Observe the usual precautionary measures required for chemicals. Respiratory protection : Hand protection : Eye protection : Body protection : dust mask Nitrile rubber gloves. tightly fitting safety goggles protective clothing SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Form : Colour : Odour : ph value : Melting point : Boiling point : Boiling point : Flash point : Evaporation rate : Flammability Lower explosion limit : Upper explosive limit : Combustion number : Vapour pressure : Vapour density relative to air : Solubility in water : Soluble in... : Octanol/water partition coefficient (log Pow) : powder red not specified app. 5 (20 C, 10 g/l) not applicable ( hpa) not applicable not determined not applicable (20 C) not applicable (20 C) insoluble fat unknown ( 20 C)

6 Savinyl Pink 6BLS Page 6(10) Ignition temperature : Self-ignition temperature : 470 C Method : BAM (fluidized dust) Thermal decomposition : 150 C Method : isoperibolic decomposition test Thermal decomposition : 170 C Method : dynamic decomposition test Viscosity (dynamic) : Oxidizing properties : (20 C) not applicable 9.2. Other information Density : 1,31 g/cm3 (20 C, hpa) SECTION 10: Stability and reactivity Reactivity Chemical stability Stable Possibility of hazardous reactions Conditions to avoid None known Incompatible materials not known Hazardous decomposition products poisonous gases/vapors carbon oxides nitrogen oxides sulfur oxides SECTION 11: Toxicological information Information on toxicological effects Acute oral toxicity : LD mg/kg (rat) Acute dermal toxicity : Acute inhalation toxicity : Irritant effect on skin : non-irritant (rabbit)

7 Savinyl Pink 6BLS Page 7(10) Irritant effect on eyes : Sensitization : Repeated dose toxicity: non-irritant (rabbit) Genetic toxicity in vitro : Assesment of mutagenicity : Assessment of carcinogenicity : Assessment of toxicity to reproduction : Test type : Ames test Metabolic activation : with and without Result : Negative with and without metabolic activation Method : OECD 471 The substance may be absorbed through the skin. SECTION 12: Ecological information Toxicity Fish toxicity : Daphnia toxicity : Algae toxicity : Bacteria toxicity : LC50 1,45 mg/l (96 h, rainbow trout (salmo gairdneri, oncorhynchus mykiss)) Persistence and degradability Biodegradability : < 70 % (28 d) not degradable in biol. waste water treatment plant Method : EEC L251,C * mod. Sturm Chemical oxygen demand (COD) : 500 mg/g Method : SANDOZ internal test Bioaccumulative potential Bioaccumulation: Mobility in soil Behaviour in environmental compartments No known data Results of PBT and vpvb assessment

8 Savinyl Pink 6BLS Page 8(10) Other adverse effects Additional ecotoxicological remarks No data available. SECTION 13: Disposal considerations Waste treatment methods Product Incineration in an approved, controlled furnace with combustion gas scrubbing and emission gas control. Uncleaned packaging For disposal local regulation is binding. SECTION 14: Transport information Section to ADR UN no. UN 3077 Proper shipping name: Environmentally hazardous substance, solid, n.o.s. Hazard inducer(s): Azo dye / complex chromium containing Class: 9 Primary risk: 9 Packing group: III Hazard no. : 90 Environmental hazards: Special marking provision: environmentally hazardous Shipment permitted ADNR UN no. UN 3077 Proper shipping name: Environmentally hazardous substance, solid, n.o.s. Hazard inducer(s): Azo dye / complex chromium containing Class: 9 Primary risk: 9 Packing group: III Environmental hazards: Special marking provision: environmentally hazardous Shipment permitted RID UN no. UN 3077 Proper shipping name: Environmentally hazardous substance, solid, n.o.s. Hazard inducer(s): Azo dye / complex chromium containing Class: 9 Primary risk: 9 Packing group: III Hazard no. : 90 Environmental hazards: Special marking provision: environmentally hazardous Shipment permitted

9 Savinyl Pink 6BLS Page 9(10) IATA UN no. UN 3077 Proper shipping name: Environmentally hazardous substance, solid, n.o.s. Hazard inducer(s): Azo dye / complex chromium containing Class: 9 Primary risk: 9 Packing group: III Environmental hazards: Special marking provision: environmentally hazardous Shipment permitted IMDG UN no. UN 3077 Proper shipping name: Environmentally hazardous substance, solid, n.o.s. Hazard inducer(s): Azo dye / complex chromium containing Class: 9 Primary risk: 9 Packing group: III Shipment permitted Marine pollutant: Marine Pollutant EmS : F-A S-F Special precautions for user See sections 6 to 8 of this Safety Data Sheet Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code No transport as bulk according IBC - Code. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical safety assessment No Chemical Safety Assessment (CSA) is yet available for the substance, or for the component substances, contained in this product. SECTION 16: Other information Decimal notation: "thousands" places are identified with a dot (for example, "2.000 mg/kg" means "two thousand mg/kg"). Decimal places are identified with a comma (for example, "1,35 g/cm3" means "one point three five g/cm3"). This information corresponds to the present state of our knowledge and is intended as a general description of our products and their possible applications. Clariant makes no warranties, express or implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and assumes no liability in connection with any use of this information. Any user of this product is responsible for determining the suitability of Clariant's products for its particular application. Nothing included in this information waives any of Clariant's

10 Savinyl Pink 6BLS Page 10(10) General Terms and Conditions of Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial property rights must be observed. Due to possible changes in our products and applicable national and international regulations and laws, the status of our products could change. Material Safety Data Sheets providing safety precautions, that should be observed when handling or storing Clariant products, are available upon request and are provided in compliance with applicable law. You should obtain and review the applicable Material Safety Data Sheet information before handling any of these products. For additional information, please contact Clariant.