Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] and GHS

Transcription

1 A safety data sheet is not required for this product under. This Product Safety Information Sheet has been created on a voluntary basis. Date of issue: 4/30/2018 Revision date: 6/18/2018 Supersedes: 4/30/2018 Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name Type of product : Mixture : : Fertilizer Other means of identification : Plantacote 4M Top K Plantacote 6M Top K Plantacote 8M Top K Plantacote 12M Top K Plantacote 4M Top K Plantacote 6M Top K Plantacote 8M Top K Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category : Professional use Uses advised against 1.3. Details of the supplier of the safety data sheet Plantacote N.V. Autrichehavenweg 10 Haven MB Westdorpe infonl@plantacote.com 1.4. Emergency telephone number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Australian GHS criteriamixtures/substances: SDS EU 2015: According to Regulation (EU) 2015/830 (REACH Annex II) Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Australian GHS criteriaextra labelling to displayextra classification(s) to display No labelling applicable 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] and GHS Ammonium nitrate (AN) (CAS-No.) (EC-No.) (REACH-no) XXXX Calcium sulphate substance with national workplace exposure limit(s) (CAS-No.) (EC-No.) (REACH-no) Ox. Sol. 3, H272 Eye Irrit. 2, H Not classified 6/18/2018 EN (English) SDS Ref.: Plantacote 1/6

2 Specific concentration limits: Name Product identifier Specific concentration limits Ammonium nitrate (AN) (CAS-No.) (EC-No.) (REACH-no) XXXX Full text of H-statements: see section 16 ( 80 <C <= 100) Eye Irrit. 2, H319 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Get medical advice/attention if you feel unwell. In all cases of doubt, or when symptoms persist, seek medical attention. : Remove person to fresh air and keep comfortable for breathing. Respiratory problems: consult a doctor/medical service. : Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. : Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth out with water. If you feel unwell, seek medical advice. Do not induce vomiting without medical advice Most important symptoms and effects, both acute and delayed Symptoms/effects 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Special hazards arising from the substance or mixture Fire hazard Hazardous decomposition products in case of fire 5.3. Advice for firefighters Precautionary measures fire Firefighting instructions : Not expected to present a significant hazard under anticipated conditions of normal use. : Flood fire area with water from a distance. : earth, sand, dry chemical powder or foam. : Not expected to be a fire/explosion hazard under normal conditions of use. : Nitrogen oxides. Ammonia. Phosphorus oxides. Sulphur oxides. Metal oxides. : Evacuate unnecessary personnel. : Do not allow run-off from fire fighting to enter drains or water courses. Protection during firefighting : Use self-contained breathing apparatus and chemically protective clothing. EN 469. Other information SECTION 6: Accidental release measures : Symptoms may be delayed Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment : See Heading 8. Emergency procedures Measures in case of dust release For emergency responders : Evacuate unnecessary personnel. Do not touch or walk on the spilled product. Ventilate spillage area. : Provide adequate ventilation. Protective equipment : See Heading Environmental precautions Do not allow to enter drains or water courses. May cause long lasting harmful effects to aquatic life. Notify authorities if product enters sewers or public waters Methods and material for containment and cleaning up For containment Other information 6.4. Reference to other sections See Heading 8. For further information refer to section 13. : Take up mechanically (sweeping, shovelling) and collect in suitable container for disposal. : Dispose of materials or solid residues at an authorized site. 6/18/2018 EN (English) SDS Ref.: Plantacote 2/6

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Avoid contact with skin, eyes and clothing. For further information refer to section 8: "Exposure controls/personal protection". : Keep container tight closed. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace Conditions for safe storage, including any incompatibilities Technical measures Information on mixed storage Storage area 7.3. Specific end use(s) Read label before use. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Comply with applicable regulations. : Do not store with: Organic materials. oxidizing materials. Acids. Alkali. : Store tightly closed in a dry, cool and well-ventilated place. Keep only in the original container. Keep out of direct sunlight. TWA 10 mg/m³ 8.2. Exposure controls Appropriate engineering controls: Ensure good ventilation of the work station. Local exhaust and general ventilation must be adequate to meet exposure standards. Hand protection: In case of repeated or prolonged contact wear gloves Type Material Permeation Thickness (mm) Penetration Standard Nitrile rubber (NBR) >0.35 EN 374 Eye protection: In case of dust production: protective goggles. EN 166 Skin and body protection: Handle in accordance with good industrial hygiene and safety practice Respiratory protection: No respiratory protection needed under normal use conditions Environmental exposure controls: Prevent entry to sewers and public waters. Other information: After contact with skin, wash immediately and thoroughly with plenty of water. Do not eat, drink or smoke when using this product. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Colour : Beige. Odour : characteristic. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point : Not determined Flash point : Auto-ignition temperature : Not determined Decomposition temperature Flammability (solid, gas) 6/18/2018 EN (English) SDS Ref.: Plantacote 3/6

4 Vapour pressure Relative vapour density at 20 C Relative density : Density : 1 g/cm³ at 20 C Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Lower explosive limit (LEL) Upper explosive limit (UEL) : Water: Very soluble : : : 9.2. Other information Additional information : SECTION 10: Stability and reactivity Reactivity Stable under normal conditions Chemical stability Stable under normal conditions of use Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid Water, humidity. metals. Organic Substances. Dust Incompatible materials Acids. Combustible materials. Reducing agents. Organic materials. Alkali. Oxidizing agent Hazardous decomposition products No hazardous decomposition products known at room temperature. Thermal decomposition generates : Metal oxides. Sulphur oxides. Phosphorus oxides. Ammonia. Nitrogen oxides. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) LD50 oral rat LD50 dermal rat LC50 inhalation rat (mg/l) LD50 oral rat Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity 2950 mg/kg bodyweight (OECD 401 method) > 5000 mg/kg bodyweight (OECD 402 method) > 88.8 mg/l 4h > 2000 mg/kg STOT-single exposure STOT-repeated exposure Aspiration hazard 6/18/2018 EN (English) SDS Ref.: Plantacote 4/6

5 SECTION 12: Ecological information Toxicity Acute aquatic toxicity Chronic aquatic toxicity LC50 fish mg/l 48h EC50 Daphnia mg/l IUCLID 5 LC50 fish mg/l IUCLID Persistence and degradability Persistence and degradability Persistence and degradability. Not relevant Bioaccumulative potential Bioaccumulative potential Bioaccumulative potential No data available. No data available Mobility in soil Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Product/Packaging disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with ADR / IMDG / ADN / RID : This material and its container must be disposed of in a safe way. : Recycle the material as far as possible. : Avoid release to the environment. ADR IMDG ADN RID UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No supplementary information available Special precautions for user - Overland transport - Transport by sea - Inland waterway transport - Rail transport 6/18/2018 EN (English) SDS Ref.: Plantacote 5/6

6 14.7. Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Listed on the Australian Inventory of Chemical Substances (AICS): Tier I Human Health Assessments Listed on the Australian Inventory of Chemical Substances (AICS): Tier II Human Health Assessments Chemical safety assessment SECTION 16: Other information Indication of changes: Section Changed item Change Comments 1.1 Other means of identification Modified Full text of H- statements: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Ox. Sol. 3 Oxidising Solids, Category 3 H272 May intensify fire; oxidiser. H319 Causes serious eye irritation. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 6/18/2018 EN (English) SDS Ref.: Plantacote 6/6