SAFETY DATA SHEET: UNICER 25

Transcription

1 SECTION 1: CHEMICAL PRODUCT & COMPANY INFORMATION APPLICABLE PART #: BA2025, BA2025NS IDENTITY: Unicer 25 SUPPLIER: Universal Photonics, Inc. FOR INFORMATION CALL 85 Jetson Lane CUSTOMER SERVICE (516) Central Islip, NY DATE PREPARED: October 12, 2015 EMERGENCY TELEPHONE NUMBER: E COMPANY - ACCT # 3665 SECTION 2: HAZARDS IDENTIFICATION Although OSHA has not adopted the environmental portion of the GHS regulations, this document may include information on environmental effects. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE HCS 2012 (29 CFR ): Not a hazardous product according to the OSHA Globally Harmonized System (GHS). LABEL ELEMENTS HCS 2012 (29 CFR ): OTHER HAZARDS WHICH DO NOT RESULT IN CLASSIFICATION: Not a hazardous product according to the OSHA Globally Harmonized System (GHS). Slightly irritating to eyes. NO particular fire or explosion hazard. SECTION 3: COMPOSITION INFORMATION SUBSTANCE: Not applicable, this product is a mixture. MIXTURE CHEMICAL NATURE: Mixture based on rare earth(s) compound(s) HAZARDOUS INGREDIENTS AND IMPURITIES CHEMICAL NAME IDENTIFICATION NUMBER CAS-NO. CONCENTRATION (%) Lanthanum fluoride (LaF3) The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. NON-HAZARDOUS INGREDIENTS AND IMPURITIES CHEMICAL NAME IDENTIFICATION NUMBER CAS-NO. CONCENTRATION (%) Cerium Oxide (CeO2) > 60 Lanthanum oxide (La2O3) < 40 Phosphoric acid, lanthanum (3+) salt (1:1) < 40 1

2 SECTION 4: FIRST AID MEASURES DESCRIPTION OF FIRST-AID MEASURES GENERAL ADVICE: IN CASE OF INHALATION: IN CASE OF SKIN CONTACT: Show this material safety data sheet to the doctor in attendance. If breathed in, move person into fresh air. If symptoms persist, call a physician. Wash off with soap and water. If skin irritation persists, call a physician. IN CASE OF EYE CONTACT: Rinse with running water while keeping the eyes wide open (at least 15 minutes). If eye irritation persists, consult a physician. IN CASE OF INGESTION: If swallowed, do NOT induce vomiting. Rinse mouth with water, seek medical advice. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED: SECTION 5: FIRE FIGHTING MEASURES FLASH POINT: AUTOIGNITION TEMPERATURE: FLAMMABILITY / EXPLOSIVE LIMIT: EXTINGUISHING MEDIA SUITABLE EXTINGUISHING MEDIA: UNSUITABLE EXTINGUISHING MEDIA: Not applicable, mineral product. Lower flammability/explosion limit: Not applicable, solid Upper flammability/explosion limit: Not applicable, solid Water, foam, collect contaminated fire extinguishing water separately. This must not be discharged into drains. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE: Not combustible. ADVICE FOR FIREFIGHTERS SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS: Gloves. In the case of respirable dust and/or fumes, use self-contained breathing apparatus and dust impervious protective suit. 2

3 SECTION 6: ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: ENVIRONMENTAL PRECAUTIONS: Wear respiratory protection. Wear suitable gloves. Tightly fitting safety goggles No harmful effect to the environment is known or expected under normal conditions of use. METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP RECOVERY: DECONTAMINATION / CLEANING: DISPOSAL: METHODS FOR CONTAINMENT: REFERENCE TO OTHER SECTIONS: Sweep up and shovel into suitable containers for disposal. Keep in properly labeled containers. Wash off with plenty of water. Dispose of contents/ container to an approved waste disposal plant. Dam up. SECTION 7: HANDLING & STORAGE PRECAUTIONS FOR SAFE HANDLING: HYGIENE MEASURES: Provide sufficient air exchange and/or exhaust in work rooms. Dust must be extracted directly at the point of origin. Avoid contact with skin and eyes. Do not breathe vapors/dust. Routine housekeeping should be instituted to ensure that dusts do not accumulate on surfaces. Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES TECHNICAL MEASURES/STORAGE CONDITIONS: PACKAGING MATERIAL SUITABLE MATERIAL: UNSUITABLE MATERIAL: REMARKS: REQUIREMENTS FOR STORAGE ROOMS AND VESSELS: SPECIFIC END USE(S): Keep in properly labeled containers. Stable under normal conditions. To guarantee the quality and properties of the product. Keep container tightly closed and dry. Keep away from: No special restrictions on storage with other products. Plastic materials (polyethylene). None known. Store in original container. Stable under recommended storage conditions. 3

4 SECTION 8: PERSONAL PROTECTION AND EXPOSURE CONTROLS Introductory Remarks: These recommendations provide general guidance for handling this product. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application. Assistance with selection, use and maintenance of worker protection equipment is generally available from equipment manufacturers. CONTROL PARAMETERS COMPONENTS WITH WORKPLACE OCCUPATIONAL EXPOSURE LIMITS INGREDIENTS VALUE TYPE VALUE BASIS Lanthanum Fluoride (LaF3) TWA 2.5 mg/m3 Occupational Safety and Health Administration - Table Z-1 Limits for Air Contaminants American Conference of Governmental Industrial Hygienists NIOSH IDLH (IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONCENTRATIONS) INGREDIENTS CAS-NO. CONCENTRATION Lanthanum fluoride (LaF3) mg/m3 BIOLOGICAL EXPOSURE INDICES INGREDIENTS VALUE TYPE VALUE BASIS Lanthanum fluoride (LaF3) Lanthanum fluoride (LaF3) BEI 2 mg/l Fluoride Urine Prior to shift (16 hours after exposure ceases) 3 mg/l Fluoride Urine End of shift (As soon as possible after exposure ceases) American Conference of Governmental Industrial Hygienists American Conference of Governmental Industrial Hygienists EXPOSURE CONTROLS CONTROL MEASURES ENGINEERING MEASURES: INDIVIDUAL PROTECTION MEASURES RESPIRATORY PROTECTION: Apply technical measures to comply with the occupational exposure limits. Local exhaust. Dust must be extracted directly at the point of origin. When respirators are required, select NIOSH/MSHA approved equipment based on actual or potential airborne concentrations and in accordance 4

5 with the appropriate regulatory standards and/or industrial recommendations. Respirator with a dust filter. HAND PROTECTION: EYE PROTECTION: SKIN AND BODY PROTECTION: HYGIENE MEASURES: PROTECTIVE MEASURES: For prolonged or repeated contact use protective gloves. In case of contact through splashing: safety glasses Long sleeved clothing Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. The protective equipment must be selected in accordance with current CEN standards and in co-operation with the supplier of the protective equipment. Selection of appropriate personal protective equipment should be based on an evaluation of the performance characteristics of the protective equipment relative to the task(s) to be performed, conditions present, duration of use, and the potential hazards, and/or risks that may occur during use. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical properties here represent typical properties of this product. Contact the business area using the Product information phone number in Section 1 for its exact specifications. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE FORM: PHYSICAL STATE: COLOR: PARTICLE SIZE: ODOR: ODOR THRESHOLD: PH: MELTING POINT/RANGE: BOILING POINT/BOILING RANGE: FLASH POINT: EVAPORATION RATE (BUTYLACETATE = 1): FLAMMABILITY (SOLID, GAS): Powder Solid Light cream < 5 μm None Not applicable, insoluble product 4,712 F (2,600 C) Not applicable, mineral product Not applicable 5

6 FLAMMABILITY (LIQUIDS): FLAMMABILITY / EXPLOSIVE LIMIT LOWER FLAMMABILITY/EXPLOSION LIMIT: UPPER FLAMMABILITY/EXPLOSION LIMIT: AUTOIGNITION TEMPERATURE: VAPOR PRESSURE: VAPOR DENSITY: DENSITY: Not applicable, solid Not applicable, solid Not applicable Not applicable SOLUBILITY WATER SOLUBILITY: Practically insoluble SOLUBILITY IN OTHER SOLVENTS COMMON ORGANIC SOLVENTS: PARTITION COEFFICIENT: N-OCTANOL/WATER: THERMAL DECOMPOSITION: Insoluble VISCOSITY VISCOSITY, DYNAMIC: VISCOSITY, KINEMATIC: EXPLOSIVE PROPERTIES: OXIDIZING PROPERTIES: OTHER INFORMATION: Not applicable, solid Not applicable, solid No information available SECTION 10: STABILITY & REACTIVITY REACTIVITY: CHEMICAL STABILITY: POSSIBILITY OF HAZARDOUS REACTIONS: CONDITIONS TO AVOID: INCOMPATIBLE MATERIALS: Stable under recommended storage conditions. Stable under normal conditions. Difficult to dissolve in acids. Carry out with caution (consult us). No dangerous reaction known under conditions of normal use. Avoid dust formation. No dangerous reaction known with common products. Strong acids 6

7 HAZARDOUS DECOMPOSITION PRODUCTS: SECTION 11: TOXICOLOGICAL INFORMATION INFORMATION ON TOXICOLOGICAL EFFECTS ACUTE TOXICITY ACUTE ORAL TOXICITY: ACUTE INHALATION TOXICITY: ACUTE DERMAL TOXICITY: Not classified as harmful if swallowed according to the data on the components. ACUTE TOXICITY (OTHER ROUTES OF ADMINISTRATION): SKIN CORROSION/IRRITATION: According to the data on the components, not classified as irritating to skin. SERIOUS EYE DAMAGE/EYE IRRITATION: RESPIRATORY OR SKIN SENSITIZATION: According to the data on the components, not classified as irritating to eyes. MUTAGENICITY: CARCINOGENICITY: GENOTOXICITY IN VITRO: GENOTOXICITY IN VIVO: THIS PRODUCT DOES NOT CONTAIN ANY INGREDIENT DESIGNATED AS PROBABLE OR SUSPECTED HUMAN CARCINOGENS BY: NTP IARC OSHA ACGIH TOXICITY FOR REPRODUCTION AND DEVELOPMENT TOXICITY TO REPRODUCTION / FERTILITY: DEVELOPMENTAL TOXICITY/TERATOGENICITY: STOT STOT-SINGLE EXPOSURE: STOT-REPEATED EXPOSURE: 7

8 ASPIRATION TOXICITY: SECTION 12: ECOLOGICAL INFORMATION TOXICITY: PERSISTENCE AND DEGRADABILITY BIODEGRADATION BIOACCUMULATIVE POTENTIAL: BIODEGRADABILITY: Not applicable, mineral product MOBILITY IN SOIL KNOWN DISTRIBUTION TO ENVIRONMENTAL COMPARTMENTS: RESULTS OF PBT AND VPVB ASSESSMENT: OTHER ADVERSE EFFECTS: Ultimate destination of the product: Soil Ultimate destination of the product: Sediment ECOTOXICITY ASSESSMENT ACUTE AQUATIC TOXICITY: According to the data on the components The product does not have any known adverse effects on the aquatic organisms tested Unpublished internal reports. SECTION 13: DISPOSAL INFORMATION WASTE TREATMENT METHODS WASTE CODE: PRODUCT DISPOSAL: ADVICE ON CLEANING AND DISPOSAL OF PACKAGING: Dispose of in accordance with local regulations. Environmental Protection Agency; Hazardous Waste NO Clean with cold water. Dispose of in accordance with local regulations. SECTION 14: TRANSPORTATION INFORMATION DOT: TDG: NOM: IMDG: Not regulated Not regulated Not regulated Not regulated 8

9 IATA: Not regulated Note: The above regulatory prescriptions are those valid on the date of publication of this sheet. Given the possible evolution of transportation regulations for hazardous materials, it would be advisable to check their validity with your sales office. SECTION 15: REGULATORY INFORMATION NOTIFICATION STATUS INVENTORY INFORMATION United States TSCA Inventory Canadian Domestic Substances List (DSL) Australia Inventory of Chemical Substances (AICS) Japan. CSCL - Inventory of Existing and New Chemical Substances Korea. Korean Existing Chemicals Inventory (KECI) China. Inventory of Existing Chemical Substances in China (IECSC) Philippines Inventory of Chemicals and Chemical Substances (PICCS) STATUS One or more components not listed on inventory FEDERAL REGULATIONS US EPA EPCRA SARA TITLE III SARA HAZARD DESIGNATION SECTIONS 311/312 Fire Hazard Reactivity Hazard Sudden Release of Pressure Hazard Acute Health Hazard Chronic Health Hazard No No No No No SECTION 313 TOXIC CHEMICALS (40 CFR ): SECTION 302 EMERGENCY PLANNING EXTREMELY HAZARDOUS SUBSTANCE THRESHOLD PLANNING QUANTITY (40 CFR 355): This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels stablished by SARA Title III, Section 313. No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SECTION 302 EMERGENCY PLANNING EXTREMELY HAZARDOUS SUBSTANCE REPORTABLE QUANTITY (40 CFR 355): This material does not contain any components with a SARA 302 RQ. SECTION 304 EMERGENCY RELEASE NOTIFICATION REPORTABLE QUANTITY (40 CFR 355): This material does not contain any components with a section 304 EHS RQ. US. EPA CERCLA HAZARDOUS SUBSTANCES AND REPORTABLE QUANTITIES (40 CFR 302.4) INGREDIENTS CAS-NO. REPORTABLE QUANTITY Metaphosphoric acid (H6P6O18), sodium salt (1:6) lb 9

10 STATE REGULATIONS US. CALIFORNIA SAFE DRINKING WATER & TOXIC ENFORCEMENT ACT (PROPOSITION 65): This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. SECTION 16: OTHER INFORMATION HMIS RATING: Health: 1 Flammability: 0 Reactivity: 0 Personal Protection: E NFPA RATING: Health: 1 Flammability: 0 Reactivity: 0 ABBREVIATIONS N/A Not available DOT Department of Transportation GHS The Globally Harmonized System of Classification and Labeling of Chemicals HMIS - Hazardous Materials Identification System NIOSH National Institute for Occupational Safety and Health NORM Natural Occurring Radioactive Materials IATA International Air Transportation Association IMO International Maritime Organization OSHA Occupational Safety & Health Administration TSCA Toxic Substance Control Act DISCLAIMER WHILE UNIVERSAL PHOTONICS, INC. BELIEVES THAT THE DATA AND INFORMATION CONTAINED HEREIN ARE FACTUAL AND THE OPINIONS ARE THOSE OF QUALIFIED EXPERTS, THEY ARE NOT TO BE TAKEN AS A WARRANTY OR REPRESENTATION FOR WHICH UNIVERSAL PHOTONICS, INC. ASSUMES ANY LEGAL RESPONSIBILITY. THEY ARE OFFERED SOLEY FOR THE CONSIDERATION, INVESTIGATION AND VERIFICATION BY THE USER. IT IS THE USER S RESPONSIBILITY TO DETERMINE THE SUITABILITY OF THIS PRODUCT, DATA AND INFORMATION WITH APPLICABLE LAWS AND REGULATIONS.unicer sds 10