January 30, Harry Makridakis, Plant Manager Viskase Companies, Inc East State Highway 198 Osceola, AR 72370

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1 January 30, 2014 Harry Makridakis, Plant Manager Viskase Companies, Inc East State Highway 198 Osceola, AR RE: Viskase Companies, Inc. Inspection AFIN: Permit No.: AR & ARR Dear Mr. Makridakis: On November 19 and 20, 2013, Jason Bolenbaugh and I performed compliance sampling and industrial stormwater inspections of the above referenced facility in accordance with the provisions of the Federal Clean Water Act, the Arkansas Water and Air Pollution Control Act, and the regulations promulgated thereunder. Copies of the inspection reports are enclosed for your records. Please refer to the Summary of Findings sections of the attached inspection reports and provide a written response for each violation that was noted. This response should be mailed to the attention of the Water Division Inspection Branch at the address at the bottom of this letter or e- mailed to Water-Inspection-Report@adeq.state.ar.us. This response should contain documentation describing the course of action taken to correct each item noted. This corrective action should be completed as soon as possible, and the written response with all necessary documentation (i.e. photos) is due by February 13, If I can be of any assistance, please contact me at walker@adeq.state.ar.us or ext.-12. Sincerely, Brent L. Walker District 3 Field Inspector Water Division Page 1 of 8

2 Inspection Report: Viskase Companies, Inc., AFIN: , Permit #: AR FACILITY INFORMATION NAME: Viskase Companies, Inc. LOCATION: 2221 East State Hwy. 198 CITY: Osceola RESPONSIBLE OFFICIAL NAME: / TITLE Harry Makridakis / Plant Manager COMPANY: Viskase Companies, Inc. MAILING ADDRESS: 2221 East State Highway 198 CITY, STATE, ZIP: Osceola AR PHONE & EXT: / FAX: / WATER DIVISION INSPECTION REPORT AFIN: PERMIT #: AR DATE: 11/19/2013 COUNTY: 47 Mississippi PDS #: MEDIA: WN GPS LAT: LONG: LOCATION: Entrance FACILITY TYPE: 2 - Industrial FACILITY EVALUATION RATING: 2 - Marginal INSPECTION INFORMATION INSPECTOR ID#: S - State DATE(S): ENTRY TIME: EXIT TIME: 11/19/ :15 16:40 11/20/ :00 10:45 FAYETTEVILLE SHALE RELATED: N INSPECTION TYPE: Compliance Sampling PERMIT EFFECTIVE DATE: 6/1/2012 PERMIT EXPIRATION DATE: 5/31/2017 FAYETTEVILLE SHALE VIOLATIONS: N INSPECTION PARTICIPANTS NAME/TITLE/PHONE/FAX/ /ETC.: Harry Makridakis/Plant Manager Andy Stickler/Env. Coord ext Dwayne Lucius/Assistant Plant Manager Larry Sanders/Technical Assistance Manager harry.makridakis@viskase.com CONTACTED DURING INSPECTION: Yes AREA EVALUATIONS (S=Satisfactory, M=Marginal, U=Unsatisfactory, N=Not Applicable/Evaluated) S PERMIT S FLOW MEASUREMENT N STORMWATER M RECORDS/REPORTS S LABORATORY S FACILITY SITE REVIEW M OPERATION & MAINTENANCE S EFFLUENT/RECEIVING WATER M SELF-MONITORING PROGRAM M SAMPLING S SLUDGE HANDLING/DISPOSAL N PRETREATMENT N OTHER: SUMMARY OF FINDINGS 1. A review of the laboratory data and associated spreadsheets used to calculate the values reported on the DMRs (Discharge Monitoring Reports) revealed the formula used to calculate the monthly average concentrations for BOD5, TSS and NH3-N was incorrect. A review of all affected data should be performed to determine the significance of this error. 2. A calibrated thermometer was not being used in the drying oven for TSS analysis to insure that the proper temperature is used when drying samples as required by 40 CFR Part 136. Inspection Report Page 2 of 8

3 Inspection Report: Viskase Companies, Inc., AFIN: , Permit #: AR GENERAL COMMENTS Sample Results from Inspection ADEQ Lab Facility Lab Limits (lbs./day) Parameter [Conc] lbs./day [Conc] lbs./day Mon. Avg. Daily Max BOD5 (mg/l) TSS (mg/l) NH3-N (mg/l) FCB (CFU/100 ml)* 9 N/A <10 N/A DO (mg/l)** 2.45 N/A 3.3 N/A 2.0 Inst. Min ph (SU)** 7.06 N/A 6.6 N/A *Grab samples collected on different days. **Grab samples collected at different times on the same day. Needed improvements to laboratory records were discussed. Sampling and analysis dates/times as well as specific sample ID s were not readily discernable in the laboratory data. The potential foaming/solids problem that was noted in the October 29, 2013, reconnaissance inspection of the outfall structure was discussed. The facility is going to investigate further and provide their findings with the response to this inspection. The age of the wastewater treatment plant (specifically the process clarifier and sanitary plant) was discussed. Although the plant appears to be functioning adequately at the present time, it is showing extensive signs of aging and deterioration. It was suggested that both short-term and long-term plans for overhaul, repair and/or replacement be considered to insure the proper treatment of wastewater without unnecessary interruptions in plant operation. An Industrial Stormwater Inspection (ARR00876) was also performed on this date and is documented in a separate inspection report. INSPECTOR S SIGNATURE: Brent L. Walker DATE: 1/27/2014 SUPERVISOR S SIGNATURE: Jason Bolenbaugh DATE: 1/29/2014 Inspection Report Page 3 of 8

4 Inspection Report: Viskase Companies, Inc., AFIN: , Permit #: AR SECTION A: PERMIT VERIFICATION PERMIT SATISFACTORILY ADDRESSES OBSERVATIONS S M U NA NE DETAILS: 1. CORRECT NAME AND MAILING ADDRESS OF PERMITTEE: Y N NA NE 2. NOTIFICATION GIVEN TO EPA/STATE OF NEW DIFFERENT OR INCREASED DISCHARGES: Y N NA NE 3. NUMBER AND LOCATION OF DISCHARGE POINTS AS DESCRIBED IN PERMIT: Y N NA NE 4. ALL DISCHARGES ARE PERMITTED: Y N NA NE SECTION B: RECORDKEEPING AND REPORTING EVALUATION RECORDS AND REPORTS MAINTAINED AS REQUIRED BY PERMIT S M U NA NE DETAILS: Error in spreadsheet used to report average concentrations. 1. ANALYTICAL RESULTS CONSISTENT WITH DATA REPORTED ON DMRS: Y N NA NE 2. SAMPLING AND ANALYSES DATA ADEQUATE AND INCLUDE: Difficult to trace improvements suggested. S M U NA NE a. DATES AND TIME(S) OF SAMPLING: Y N NA NE b. EXACT LOCATION(S) OF SAMPLING: Y N NA NE c. NAME OF INDIVIDUAL PERFORMING SAMPLING: Y N NA NE d. ANALYTICAL METHODS AND TECHNIQUES: Y N NA NE e. RESULTS OF CALIBRATIONS: Y N NA NE f. RESULTS OF ANALYSES: Y N NA NE g. DATES AND TIMES OF ANALYSES: Y N NA NE h. NAME OF PERSON(S) PERFORMING ANALYSES: Y N NA NE 3. LABORATORY EQUIPMENT CALIBRATION AND MAINTENANCE RECORDS ADEQUATE: S M U NA NE 4. PLANT RECORDS INCLUDE SCHEDULES, DATES OF EQUIPMENT MAINTENANCE AND REPAIR: S M U NA NE 5. EFFLUENT LOADINGS CALCULATED USING DAILY EFFLUENT FLOW AND DAILY ANALYTICAL DATA: Y N NA NE SECTION C: OPERATIONS AND MAINTENANCE TREATMENT FACILITY PROPERLY OPERATED AND MAINTAINED S M U NA NE DETAILS: 1. TREATMENT UNITS PROPERLY OPERATED: S M U NA NE 2. TREATMENT UNITS PROPERLY MAINTAINED: Plant is showing signs of aging and deterioration S M U NA NE 3. STANDBY POWER OR OTHER EQUIVALENT PROVIDED: S M U NA NE 4. ADEQUATE ALARM SYSTEM FOR POWER OR EQUIPMENT FAILURES AVAILABLE: S M U NA NE 5. ALL NEEDED TREATMENT UNITS IN SERVICE: S M U NA NE 6. ADEQUATE NUMBER OF QUALIFIED OPERATORS PROVIDED: S M U NA NE 7. SPARE PARTS AND SUPPLIES INVENTORY MAINTAINED: S M U NA NE 8. OPERATION AND MAINTENANCE MANUAL AVAILABLE: Y N NA NE 9. STANDARD OPERATING PROCEDURES AND SCHEDULES ESTABLISHED: Y N NA NE 10. PROCEDURES FOR EMERGENCY TREATMENT CONTROL ESTABLISHED: Emergency pond Y N NA NE 11. HAVE BYPASSES/OVERFLOWS OCCURRED AT THE PLANT OR IN THE COLLECTION SYSTEM IN THE LAST YEAR: Y N NA NE 12. IF SO, HAS THE REGULATORY AGENCY BEEN NOTIFIED: Y N NA NE 13. HAS CORRECTIVE ACTION BEEN TAKEN TO PREVENT ADDITIONAL BYPASSES/OVERFLOWS: Y N NA NE 14. HAVE ANY HYDRAULIC OVERLOADS OCCURRED AT THE TREATMENT PLANT: Y N NA NE 15. IF SO, DID PERMIT VIOLATIONS OCCUR AS A RESULT: Y N NA NE Inspection Report Page 4 of 8

5 Inspection Report: Viskase Companies, Inc., AFIN: , Permit #: AR SECTION D: SAMPLING PERMITTEE SAMPLING MEETS PERMIT REQUIREMENTS S M U NA NE DETAILS: DO was being performed on composite due to incorrect instructions now being performed on grab sample. 1. SAMPLES TAKEN AT SITE(S) SPECIFIED IN PERMIT: Y N NA NE 2. LOCATIONS ADEQUATE FOR REPRESENTATIVE SAMPLES: Y N NA NE 3. FLOW PROPORTIONED SAMPLES OBTAINED WHEN REQUIRED BY PERMIT: Y N NA NE 4. SAMPLING AND ANALYSES COMPLETED ON PARAMETERS SPECIFIED IN PERMIT: Y N NA NE 5. SAMPLING AND ANALYSES PERFORMED AT FREQUENCY SPECIFIED IN PERMIT: Y N NA NE 6. SAMPLE COLLECTION PROCEDURES ADEQUATE: Y N NA NE a. SAMPLES REFRIGERATED DURING COMPOSITING: Y N NA NE b. PROPER PRESERVATION TECHNIQUES USED: Y N NA NE c. CONTAINERS AND SAMPLE HOLDING TIMES CONFORM TO 40 CFR 136: Y N NA NE 7. IF MONITORING IS PERFORMED MORE OFTEN THAN REQUIRED ARE RESULTS REPORTED ON THE DMR: Y N NA NE SECTION E: FLOW MEASUREMENT PERMITTEE FLOW MEASUREMENT MEETS PERMIT REQUIREMENTS S M U NA NE DETAILS: 1. PRIMARY FLOW MEASUREMENT DEVICE PROPERLY INSTALLED AND MAINTAINED: TYPE OF DEVICE: Mag Meter Y N NA NE 2. FLOW MEASURED AT EACH OUTFALL AS REQUIRED: Y N NA NE 3. SECONDARY INSTRUMENTS (TOTALIZERS, RECORDERS, ETC.) PROPERLY OPERATED AND MAINTAINED: Y N NA NE 4. CALIBRATION FREQUENCY ADEQUATE: Y N NA NE 5. RECORDS MAINTAINED OF CALIBRATION PROCEDURES: Y N NA NE 6. CALIBRATION CHECKS DONE TO ASSURE CONTINUED COMPLIANCE: Y N NA NE 7. FLOW ENTERING DEVICE WELL DISTRIBUTED ACROSS THE CHANNEL AND FREE OF TURBULENCE: Y N NA NE 8. FLOW MEASUREMENT EQUIPMENT ADEQUATE TO HANDLE EXPECTED RANGE OF FLOW RATES: Y N NA NE 9. HEAD MEASURED AT PROPER LOCATION: Y N NA NE SECTION F: LABORATORY PERMITTEE LABORATORY PROCEDURES MEET PERMIT REQUIREMENTS S M U NA NE DETAILS: 1. EPA APPROVED ANALYTICAL PROCEDURES USED (40 CFR FOR LIQUIDS, 503.8(B) FOR SLUDGES) : Y N NA NE 2. IF ALTERNATIVE ANALYTICAL PROCEDURES ARE USED, PROPER APPROVAL HAS BEEN OBTAINED: Y N NA NE 3. SATISFACTORY CALIBRATION AND MAINTENANCE OF INSTRUMENTS AND EQUIPMENT: Y N NA NE 4. QUALITY CONTROL PROCEDURES ADEQUATE: DMRQA results reviewed very little deviation noted Y N NA NE 5. DUPLICATE SAMPLES ARE ANALYZED >10% OF THE TIME: Y N NA NE 6. SPIKED SAMPLES ARE ANALYZED >10% OF THE TIME: Y N NA NE 7. COMMERCIAL LABORATORY USED: Y N NA NE a. LAB NAME: ETC b. LAB ADDRESS: Memphis, TN c. PARAMETERS PERFORMED: Biomonitoring, FCB 8. BIOMONITORING PROCEDURES ADEQUATE: Y N NA NE a. PROPER ORGANISMS USED: Y N NA NE b. PROPER DILUTION SERIES FOLLOWED: Y N NA NE c. PROPER TEST METHODS AND DURATION: Y N NA NE d. RETESTS AND/OR TRE PERFORMED AS REQUIRED: Y N NA NE Inspection Report Page 5 of 8

6 Inspection Report: Viskase Companies, Inc., AFIN: , Permit #: AR SECTION G: EFFLUENT/RECEIVING WATERS OBSERVATIONS BASED ON VISUAL OBSERVATIONS ONLY S M U NA NE DETAILS: *Foam previously noted at outfall to Mississippi River; Observations below made at sample point. OUTFALL #: OIL SHEEN GREASE TURBIDITY VISIBLE FOAM FLOATING SOLIDS COLOR OTHER 001 None None Low None* None Clear -- SECTION H: SLUDGE DISPOSAL SLUDGE DISPOSAL MEETS PERMIT REQUIREMENTS S M U NA NE DETAILS: 1. SLUDGE MANAGEMENT ADEQUATE TO MAINTAIN EFFLUENT QUALITY: S M U NA NE 2. SLUDGE RECORDS MAINTAINED AS REQUIRED BY 40 CFR 503: S M U NA NE 3. FOR LAND APPLIED SLUDGE, TYPE OF LAND APPLIED TO: (E.G., FOREST, AGRICULTURAL, PUBLIC CONTACT SITE): Mississippi Co. Landfill SECTION I: SAMPLING INSPECTION PROCEDURES SAMPLE RESULTS WITHIN PERMIT REQUIREMENTS S M U NA NE DETAILS: 1. SAMPLES OBTAINED THIS INSPECTION: Y N NA NE 2. TYPE OF SAMPLE: GRAB: ph, DO, FCB COMPOSITE: BOD5, TSS, NH3-N METHOD: Autosampler FREQUENCY: Varied by flow 3. SAMPLES PRESERVED: Y N NA NE 4. FLOW PROPORTIONED SAMPLES OBTAINED: Y N NA NE 5. SAMPLE OBTAINED FROM FACILITY'S SAMPLING DEVICE: Y N NA NE 6. SAMPLE REPRESENTATIVE OF VOLUME AND NATURE OF DISCHARGE: Y N NA NE 7. SAMPLE SPLIT WITH PERMITTEE: Y N NA NE 8. CHAIN-OF-CUSTODY PROCEDURES EMPLOYED: Y N NA NE 9. SAMPLES COLLECTED IN ACCORDANCE WITH PERMIT: Y N NA NE SECTION J: STORM WATER POLLUTION PREVENTION PLAN STORM WATER MANAGEMENT MEETS PERMIT REQUIREMENTS S M U NA NE DETAILS: Separate permit coverage under ARR SWPPP UPDATED AS NEEDED: DATE OF LAST UPDATE: Y N NA NE 2. SITE MAP INCLUDING ALL DISCHARGES AND SURFACE WATERS: Y N NA NE 3. POLLUTION PREVENTION TEAM IDENTIFIED: Y N NA NE 4. POLLUTION PREVENTION TEAM PROPERLY TRAINED: Y N NA NE 5. LIST OF POTENTIAL POLLUTANT SOURCES: Y N NA NE 6. LIST OF POTENTIAL SOURCES AND PAST SPILLS AND LEAKS: Y N NA NE 7. ALL NON-STORM WATER DISCHARGES ARE AUTHORIZED: Y N NA NE 8. LIST OF STRUCTURAL BMPS: Y N NA NE 9. LIST OF NON-STRUCTURAL BMPS: Y N NA NE 10. BMPS PROPERLY OPERATED AND MAINTAINED: Y N NA NE 11. INSPECTIONS CONDUCTED AS REQUIRED: Y N NA NE Inspection Report Page 6 of 8

7 Inspection Report: Viskase Companies, Inc., AFIN: , Permit #: AR DMR Calculation Check Reporting Period: From To Year Month Day Year Month Day Parameter Checked: TSS Loading Concentration Mass Monthly Avg./Max - lbs/day Mo. Avg. - mg/l Max. - mg/l Reported Value: 251/ * 31.5 Calculated Value: 251/ * 31.5 Permit Value: 314/627 Report Report If calculated value does not equal reported value, explain: *Difference appears to be due to an incorrect formula in the facility s spreadsheet. Inspection Report Page 7 of 8

8 Inspection Report: Viskase Companies, Inc., AFIN: , Permit #: AR DMR Calculation Check Reporting Period: From To Year Month Day Year Month Day Parameter Checked: BOD5 Loading Concentration Mass Monthly Avg./Max - lbs/day Mo. Avg. - mg/l Max. - mg/l Reported Value: 301.3/ * 33.7 Calculated Value: 301.3/ * 33.7 Permit Value: 400/800 Report Report If calculated value does not equal reported value, explain: *Difference appears to be due to an incorrect formula in the facility s spreadsheet. Inspection Report Page 8 of 8

9 From: To: Cc: Subject: Date: Attachments: Andy Stickler Water-Inspection-Report Walker, Brent Viskase Corporation - AFIN / NPDES Permit #"s AR & ARR Response to January 30th, 2014 Inspection Report Wednesday, February 12, :46:40 PM Viskase Corporation Response to ADEQ Inspection of Nov. 19&20, 2013.pdf To Whom It May Concern: Attached above, is our official response to a compliance sampling / industrial wastewater inspection conducted by Mr. Brent Walker and Mr. Jason Bolenbaugh (ADEQ Water Division staff) on November 19 th and 20 th, For reference purposes, the formal Inspection Report is posted on the ADEQ website (under the above referenced company name / AFIN# / NPDES Permit Number), and has the following identifying file name: insp.pdf, dated 1/20/2014. Please reference this inspection report when reviewing our formal response. Finally, to ensure that we cover all bases on our end, we are also putting a copy of this response document in the mail to ADEQ this afternoon, to the following address: Arkansas Department of Environmental Quality Water Division Inspection Branch 5301 Northshore Drive North Little Rock, AR As always, please don t hesitate to contact me should you have questions, or need additional information. We appreciate your continued support and consideration. Andy Stickler CASING SOLUTIONS WORLDWIDE Andy Stickler Plant Environmental Coordinator Viskase Companies, Inc East State Highway 198 Osceola, AR Work Phone - (870) , ext Cell Phone - (870) andy.stickler@viskase.com

10 From: To: Cc: Subject: Date: Attachments: Andy Stickler Water-Inspection-Report Walker, Brent Viskase Corporation - AFIN / NPDES Permit #"s AR & ARR Response to January 30th, 2014 Inspection Report Wednesday, February 12, :46:40 PM Viskase Corporation Response to ADEQ Inspection of Nov. 19&20, 2013.pdf To Whom It May Concern: Attached above, is our official response to a compliance sampling / industrial wastewater inspection conducted by Mr. Brent Walker and Mr. Jason Bolenbaugh (ADEQ Water Division staff) on November 19 th and 20 th, For reference purposes, the formal Inspection Report is posted on the ADEQ website (under the above referenced company name / AFIN# / NPDES Permit Number), and has the following identifying file name: insp.pdf, dated 1/20/2014. Please reference this inspection report when reviewing our formal response. Finally, to ensure that we cover all bases on our end, we are also putting a copy of this response document in the mail to ADEQ this afternoon, to the following address: Arkansas Department of Environmental Quality Water Division Inspection Branch 5301 Northshore Drive North Little Rock, AR As always, please don t hesitate to contact me should you have questions, or need additional information. We appreciate your continued support and consideration. Andy Stickler CASING SOLUTIONS WORLDWIDE Andy Stickler Plant Environmental Coordinator Viskase Companies, Inc East State Highway 198 Osceola, AR Work Phone - (870) , ext Cell Phone - (870) andy.stickler@viskase.com

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24 February 21, 2014 Harry Makridakis, Plant Manager Viskase Companies, Inc East State Highway 198 Osceola, AR RE: Viskase Companies, Inc. Inspection Response AFIN: Permit No.: AR & ARR Dear Mr. Makridakis: I have reviewed the response pertaining to my November 19 and 20, 2013, inspections of the above referenced facility. Based on the information provided, you should submit corrected DMRs for at least the 2013 calendar year, even if the changes were minor and did not result in any exceedances. Corrected copies should be submitted as follows: Highlight each parameter value that has been corrected, Write Corrected Copy on each DMR, Re-sign and re-date each copy, Submit the corrected DMRs to Enforcement as you would a regular DMR. The information provided in your response sufficiently addresses the other violations referenced in my inspection report. At this time the Department has no further comment concerning this particular inspection. Acceptance of this response by the Department does not preclude any future enforcement action deemed necessary at this site or any other site. If we need further information concerning this matter, we will contact you. Thank you for your attention to this matter. Should you have any questions, feel free to contact me at ext.-12 or you may me at walker@adeq.state.ar.us. Sincerely, Brent L. Walker District 3 Field Inspector Water Division cc: Kevin Suel, Water Division Enforcement Branch

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