6022- 生物可分解母粒 名言塑膠顏料有限公司桃園縣楊梅市民豐路 505 號. Website: 電話 :(03) ( 代表號 ) 傳真 :(03)

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1 6022- 生物可分解母粒 名言塑膠顏料有限公司桃園縣楊梅市民豐路 505 號 Website: 電話 :(03) ( 代表號 ) 傳真 :(03)

2 生物可分解母粒 6022 生物可分解劑粒 6022 是一種新型生質材料, 添加後的產品, 掩埋於土壤後, 該產品之分子結構會逐漸崩壞, 變成脆弱而成碎片, 進而被微生物細菌消化成二氧化碳及水 6022 用法簡便, 不需增設加工設備, 不必改變加工條件,PE 樹脂直接拌合使用即可, 而且成品之機械性質 ( 如 : 抗張強度, 延伸率, 撕裂強度 ) 幾乎與原未添加者一致 分解性 PE 膜之分解速度可由 6022 之添加量予以控制 用途說明 : 6022 是以聚乙烯樹脂加上可分解性觸媒製成, 用於混合各種聚烯烴類原料, 經吹膜 射出 押出等不同加工方式, 可製造各種生物分解性產品, 諸如 : 農業用膜 垃圾袋 包裝袋 背心袋 漁網等 添加量 : 由 2%~10% 不等特性說明 : 1. 具有很好的攙混性與加工性, 無論在吹膜 射出或擠押加工上, 像添加色母一般的攙混使用, 即能得到均勻的分散效果 2. 焚化時不會產生有毒的物質, 完全分解後, 殘留於土壤中不會造成污染 3. 與聚烯烴類樹脂攙合所有加工的製品, 埋入土中後, 約數月後會逐漸分解 4. 需儲存於陰良通風的地方, 勿受陽光直接照射 本司有更詳細之電子檔資料, 歡迎來電索取 名言塑膠顏料有限公司桃園縣楊梅市民豐路 505 號 minyen.plastic@msa.hinet.net Website: 電話 :(03) ( 代表號 ) 傳真 :(03)

3 生物可分解母粒 A Patented technology based on US Pat. No.6,482,872 Process for Manufacturing a Biodegradable Polymeric Composition Additive A Specially formulated proprietary mixture of catalysts (fatty acids derived from palm tree oils) with following features. Dosage Level: 2~10% against let down Polyolefin Polymers (PE, PP). Blending: Blended directly with resin pellets in a converting stage. Ingredients: Registered in FDA, Complies with Rohs Directive. 2

4 生物可分解母粒 6022 成分 % FDA 脂肪酸金屬塩 CFR 稀有金屬氧化合成物 CFR 滑劑 CFR 母粒 產品編號外觀顏色融點每包重量 6022 母粒狀淡米黃 C 25kg/ 包 3

5 Properties of 6022 FDA Migration 測試 Testing Items 結果 (%) 通過標準 Remarks Extractable fraction in N-hexane 2.2% 6.4% 通過 Extractable fraction in Xylene 5.2% 9.8% 通過 Test Sample: 添加 6022 之 PE 薄膜 Test Standard: FDA 21CFR (Substances used as single or repeated use of food contact surfaces) Testing Body: Hong Kong Productivity Council 4

6 Properties of Dosed PE Film Properties 測試項目添加 6022 HDPE 100% HDPE Tensile Strength at Break (kg/cm 2 ) MD Elongation at Break (%) MD Dart Impact (g) Tear Strength (g) MD Thickness of films: 0.015mm, Blowing Temperature: 190C 5

7 Degradation of Polymers (Chemical Change in Polymers causing disintegration) Thermo-Oxidative Degradation (Thermal) Photo-Oxidative Degradation (Sun-light, UV) Hydrolysis Degradation (Water) Bio-Degradation (living micro-organism, fungi etc) 6

8 Degradation Path of Polymers A. Bio-polyesters, PLA, thermo plastic starch B. Polyolefin Polymers Group (PE, PP) Hydrolysis degradation (Water) (Low-molecular weight products) Oxidative degradation (Thermo, Photo) (Oxidative low-molecular weight products) Biodegradation CO 2, H 2 O, Biomass 7

9 Oxo-Biodegradation of Polyolefin Polymers by 6022 Technology (Mechanism) A specially formulated proprietary mixture of catalysts (6022) dosed into Polyolefin Polymers Oxidant (catalysts) leads chain scission of polymers and the production of low-molecular mass oxidation products such as carboxylic acids etc. (Step1) The living organisms bio-assimilate the low molecular oxidation products. (Step2) CO 2, H 2 O, Biomass 8

10 Oxo-Biodegradation of Polyolefin Polymers by 6022 Technology (Image) 1. Blend with Polymers by extrusion H H H H H H H H H H H H C-C-C-C-C-C- -C-C-C-C-C-C- H H H H H H 6022 H H H H H H 2. Oxidative Degradation Sun-light (energy) O 2 -C-C-C-C-C-C- O 2 -C-C-C=O C-C-C-C=O 6022 Thermo (energy) 6022 (Carboxylic Acids, Ketons, Alcohol) 9

11 Oxo-Biodegradation of Polyolefin Polymers by 6022 Technology (Image) 2. Oxidative Degradation Sun-light (energy) O 2 -C-C-C-C-C-C- O 2 -C-C-C=O C-C-C-C=O 6022 Thermo (energy) 6022 (Carboxylic Acids, Ketons, Alcohol) 3. Bio-Degradation Micro-organisms C-C-C=O -C-C-C-C=O CO 2 + H 2 O + Biomass 6022 Micro-organisms 1

12 Oxo-Biodegradation of Polyolefin Polymers by 6022 Technology (Technical Explanation) Polyolefins contain small amounts of alkyl radicals react very fast with oxygen: R + O 2 ROO This peroxyradical attacks a polymer chain as follows: ROO + RH ROOH + R This new alkyl radical reacts with oxygen. The hydroperoxide is quite stable but under the catalytic action of 6022, it is decomposed as follows: M n+ + ROOH M (n+1) + RO + HO - - M (n+1) + ROOH M n+ + ROO + H + The new radicals formed can also attack polymer chains as follows: RO + RH ROH + R ROO + RH ROOH + R 1

13 Evaluation of 6022 Oxo-Biodegradable Plastic Products(Oxidative-Degradation) ASTM Standards for Testing of Degradable Polymers: Oxidative-Degradation Testing: D5510 Heat Aging of Oxidatively Degradable Plastic Photo-Degradation Testing: G154 Operating Fluorescent Light Apparatus for UV Exposure of Non- metallic Materials Tensile Testing: D3826 Degradation End Point Using a Tensile Test 1

14 80 C 熱照光實驗 ASTM D (Elongation, %): Control 延展率 (%) 照光天數 6022 薄膜 : 10% % HDPE, 對照組薄膜 : 100% HDPE 1

15 紫外線光照測試 ASTM G154 ( 延展率, %): Control 延展率 (%) 照光日數 6022 薄膜 : 10% % HDPE, 對照組薄膜 : 100% HDPE 1

16 Photos of Actual Tested Samples: 經過 6 天的加溫熱光照測試後 加溫熱光照測試前 經過 14 天的 UV 光照測試後 1

17 野外實地測試照 (1) ( 實驗地點 : 馬來西亞 ) Test Sample: 添加 6022 的 PE 袋 (0.05mm) 16

18 Photos of Field Testing (2) (Testing site: KYOTANGO CITY, JAPAN)

19 GPC Analysis for Molecular Weight Test Sample: *6022 dosed LDPE Film (0.03mm) Test Method: GPC (Gel Permeation Chromatography) Analysis Testing Body: Chemicals Evaluation and Research Institute, Japan (CERI) Table4. GPC Analysis Test Results Sample *Mw *Mn PDI* 6022 LDPE Film 2,020 1, *Mw: Weight average molecular weight *Mn: Number average of molecular weight *PDI: Mw/Mn *6022 dosed LDPE Film was thermally treated at 60C for 28 days. 18

20 GPC Analysis for Molecular Weight Table5. Molecular Weight Change in Oxidative Degradation Thermal Exposure Mw Mn PDI at 60C 0day 113,280 16, days 2,020 1, *Mw: Weight average molecular weight *Mn: Number average of molecular weight *PDI: Mw/Mn *6022 dosed LDPE Film was thermally treated at 60C for 28 days. 19

21 Evaluation of 6022 Oxo-Biodegradable Plastic Products (Bio-Degradability) Testing Standards; ISO14855 (JIS K6953, EN13432): Determination of the ultimate aerobic biodegradability and disintegration of plastic materials under controlled composting conditions Method by analysis of evolved carbon dioxide ASTM D6954: Exposing and Testing Plastics that Degrade in the Environment by a Combination of Oxidation and Biodegradation 20

22 Evaluation of 6022 Oxo-Biodegradable Plastic Products (Bio-Degradability) Chemicals Evaluation and Research Institute, Japan (CERI) accredited as an Authorized Testing Body in Japan conducted the biodegradability testing with 6022 LDPE Film according to JIS K6953. The test result showed that the degree of biodegradability was 30% after 144days and it was still increasing. This investigation has shown that when the 6022 dosed plastics are degraded into low molecular mass products, the plastics are certainly bio-assimilated. 21

23 For your note: ASTM D6954: Exposing and Testing Plastics that Degrade in the Environment by a Combination of Oxidation and Biodegradation Tier1: An abiotic degradation test shall simulate or accelerate the degradation processes likely to occur in a chosen application and disposal environment. Tier2: The abiotically degraded material is then examined for the ultimate biodegradability under optimal conditions in a simulated disposal environment such as in soil or in compost. Tire3: The residual solids from Tire 2 are subjected to the determination of toxicological effects in accordance with one of several possible test methods such as germination and growth tests with plants according to OECD guideline 208, and EN

24 CO 2 釋放曲線圖 40 CO2 Production(g) 35 The Vessel with 6022 dosed LDPE film 30 The Blank Vessel Days 23

25 *Biodegradability of Test Material 60 生物分解程度 (%) 添加 6022 的 LDPE 薄膜 天數 (*Biodegradability(%) = ((CO 2 )SML-(CO 2 )BK) / Theoretical amount of CO 2 x 100) 24

26 Summary 6022 Degradable Plastic Products (*Oxo-Biodegradable Plastics) FDA Migration Test according to FDA 21CFR : PASSED Food Sanitation Law in Japan, No.20 in 1982, No.370 in 1959: PASSED Sun Light, Heat and Oxygen (The Natural Environment) Step1 Oxidative Degradation (Production of low molecular mass oxidation products.) CONFIRMED through the various accelerated abiotic testing based on ASTM Standards. CONFIRMED through the GPC Analysis for Molecular Weight. Natural Soil or Composting Environment Step2 Bio-Degradation (Bioassimilation of low molecular mass oxidation products.) APPROVED by CERI Japan through the Biodegradability Testing according to JIS K6953 (ISO 14855). 25

27 General Comparison of Biodegradable Plastics(1) (Programmable Life Inc. USA) 2. PLA (Nature Works, USA) 3. MaterBi (Novamont, Italy) Dosage Composition FDA Biodegradability Disadvantage IP Cost of chemistry 2-10% Fatty Acid Approved JIS K6953 Beige coloring US 極具競爭力 Base 21CFR Biodegradability on the finished Pat chemicals CFR CFR of 6022 dosed products LDPE confirmed by CERI Japan 100% Lactic Acid Partly ISO Susceptible to - Expensive Approved Confirmed. alkyl, moisture (Restricted and high against temperature, Hot Food) Hard Texture 100% Starch Partly ISO14855 Susceptible to Over 50 Expensive PVA Approved OK Compost moisture and patents and (Restricted Confirmed. higher patent against temperature, applications Oily Food, Not Clear etc) (off-white color) 26

28 General Comparison of Biodegradable Plastics(2) (Programmable Life Inc. USA) 4. TDPA (EPI, Canada) 5. D2W (Symphony, UK) Dosage Composition of chemistry 2-10% Fatty Acid Base chemicals 2% Inorganic & Organic Chemicals such as Cobalt Stearate and CaCO3 etc 1% No Information Available FDA Biodegradability Disadvantage IP Cost Approved 21CFR JIS K6953 Biodegradability Beige coloring on the finished CFR of 6022 dosed products LDPE confirmed by CERI Japan 21CFR CFR Not confirmed. Product Life is uncontrollable. No Not confirmed. Product Life is Information uncontrollable. Available US Competitive Pat US Competitive Pat No IP Competitive related Information is available. 27

29 生物可分解母粒 - 產品應用 零售業 - 購物袋 - 垃圾袋 / Courier Bags - 廚餘袋 食物飲料業 - 便當盒 / 杯蓋 - 食物托盤 / 捲袋 -Cutlery / 吸管 Packaging -Loose Fills -Foamed Sheets -PP Straps -PP Ropes Others -Coin Bags -Stationery Goods -Non-woven Cloth -Plastic Sand Bags -Seedling Bags -Agricultural Films 28

30 Business References Retail: Harris Teeter, The Mall Group, Shoe Mart Supermarkets, Nuance Watson Hotel: Excelsior Hotel, Mandarin Oriental Group Bank: HSBC, Standard Chartered Bank Catering: Maxims, Fairwood, Arome Bakery, Saint Honor Cakes, Yamazaki Bakery Government: Hospital Authority, Airport Authority, Kyotango City Education: HK Professional Teachers Union Property: Jones Lang LaSalle, Discovery Bay Others: NIKE GOLF, TOYSRUS, IKEYA 29