Version: 200. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: 200 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Calcined Soda Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Basic substance with not specified application. Industrial application Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 H319 Cat.: 2 Classification according to EC Regulation No. 67/548 or No. 1999/45 Irritating (Xi) R36 Eye irritation, category 2 Causes serious eye irritation. Irritating to eyes. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: GHS07-1 Signal word: Warning Hazard designation: 2

2 H319 Causes serious eye irritation. Page 2 Safety designation: P264 P280 P305+P351+P338 P337+P313 Wash thoroughly after handling. Wear protective gloves/ clothing/ eye/ face protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses and continue rinsing. If eye irritation persists: Get medical advice/ attention Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Hazardous Ingredients: Sodium carbonate (anhydrous sodium carbonate) (GHS07-1, H319); REACH Reg. No CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Remove contaminated clothes immediately. Supply fresh air and seek medical advice in case of complaints. Remove contaminated clothing immediately. Wash off immediately with plenty of water and soap. Rinse open eyes with plenty of water for at least 15 minutes. Consult physician After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with water and drink plenty of water. Do NOT induce vomiting. Consult a doctor. Symptoms: No further information available Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: No further information available. 3

3 5. Fire-Fighting Measures Extinguishing Media Page 3 Suitable extinguishing media: Product itself does not burn. Use extinguishing media for surrounding fire Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Special hazards: Advice for Firefighters Protective equipment: In case of fire: formation of carbon oxides. Wear suitable protective clothing. Wear self-contained respiratory protective device Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Provide adequate ventilation. Keep away from sources of ignition. Together with water product causes slippery surfaces. Avoid contact with acids: formation of carbon dioxide gases Environmental precautions: Methods and Material for Containment and Cleaning Up Use water spray when very dusty Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Avoid dust formation. For information for safe handling see Section 7. Protective clothing, see Section 8. Dispose of contaminated material according to Section 13. Keep containers tightly closed. Avoid formation of dust Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Keep away from foodstuffs and drinks. Storage conditions: Store in tightly sealed containers in a cool and well ventilated 4

4 location. Page Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Further Information: Specific End Use(s) Storage: In the original container. Observe official regulations on storage and handling of water hazardous substances. Product is not combustible. Do not store together with: acids. 13; Non combustible solids Product is hygroscopic Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): none known Parameters to be controlled: Derived No-Effect Level (DNEL): 10 mg/m3 (worker, inhalation, long-term exposition - local effects) 10 mg/m3 (consumer, inhalation, short-term exposition - local effects) Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation in case of dust formation. Personal Protection General protective measures: Respiratory protection: Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Do not inhale dust. Avoid contact with eyes and skin. In case of formation of dust. Dust mask recommended when very dusty: with particle filter P2. Hand protection: Chemical protective gloves (EN 374 (Europe), F739 (US)). 5

5 Protective glove material: Natural latex. Neoprene Page 5 Eye protection: Body protection: Tightly fitting safety goggles (EN 166). Face-shield. Chemical resistant safety shoes Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: Color: Odor: Odor threshold: ph-value: powder white odorless 11.5 (50 g/l; 20 C) Melting temperature: 850 C Boiling temperature: not determined Flash point: not combustible Evaporation rate: Flammability (solid, gas): Upper explosion limit: no information available Lower explosion limit: no information available Vapor pressure: Vapor density: Density: 2.53 g/cm3 (20 C) Solubility in water: 210 g/l Coefficient of variation (n- Octanol/Water): no information available Auto-ignition temperature: 6

6 Decomposition temperature: > 400 C Page Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Product is not explosive. not oxidizing kg/m3 No further information. Stable if used according to specifications. Stable if used according to specifications. Reacts with acids. No further information available. Strong acids, alkaline earth and heavy metal salts, aluminium, organic nitrocompounds, non-metal oxides / heat, conc. sulfuric acid. Formation of carbon dioxide after reaction with acids. The aqueous solution of this product is strongly alkaline. Sodium carbonate binds the water and carbon dioxide from the air. Acute Toxicity 7

7 LD50, oral: 2800 mg/kg (rat) Page 7 LD50, dermal: LC50, inhalation: > 2000 mg/kg (rat); > 2000 mg/kg (rabbit) 2.3 mg/l (2h; rat) Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Slight irritant effect. Prolonged skin contact may defat the skin and produce dermatitis. Causes serious eye irritation. No information available No sensitizing effects known. No data available. No data available. No data available. No data available. This product shows strong alkaline reactions in contact with water / humidity. For this reason, local irratating reactions are possble on skin, eyes and mucous membrane. Soda degreases the skin. LC50: 300 mg/l (96h, Lepomis macrohirus) EC50: mg/l (48h, Ceriodaphnia Dubia) Algae toxicity: Persistency and Degradability Inorganic substance, biologically non-degradable. Abiotic degradation: hydrolysis in water. 8

8 Bioaccumulation No bioaccumulation Mobility Results of PBT- und vpvp Assessment Not applicable Other Adverse Effects Page 8 Water hazard class: Behaviour in sewage systems: Further ecological effects: 1, slightly hazardous Do not let run into surface waters, waste water or soil. The product is an inorganic material and thus does not cause a biological oxygen depletion. After neutralization only a relatively low adverse effect of the formed salts is present. The ph value has to be taken into consideration if no neutralisation is carried out. The toxic effect for fish and bacteria is below ph 6 and above ph AOX Value: Disposal Considerations Waste Treatment Methods Product: Must not be disposed together with household garbage. Do not let product enter water systems. If product cannot be reused or recycled, it has to be disposed of according to current local regulations. European Waste Code (EWC): Uncleaned packaging: Dispose of according to official local regulations Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. Hazard no.: 9

9 Classification code: Page 9 Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards None Special Precautions for User Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Not classified as a dangerous good under transport regulations. Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 1, slightly hazardous for water Local regulations on chemical accidents: Employment restrictions: The employment restrictions for young workers in accordance with the Youth Employment Protection Law (94/33/EC) are to be observed Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product 10

10 Page 10 from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.