Version: 12. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: 12 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Dibasic Ester Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Solvent in industrial manufacturing processes. Coating agent. Chemical intermediate product Paint stripper Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product is not classified as hazardous according to the CLP/GHS Directive. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: No classification required according to the CLP/GHS guidelines. Not applicable. Signal word: Hazard designation: Safety designation: Hazardous components for labelling: 2

2 2. 3. Other Hazards 3. Composition/Information on Ingredients Substance Mixture Page 2 Chemical Characterization: REACH Reg. No XXXX Mixture of the following substances. Dimethyl glutarate (CAS No , EINECS ): % Dimethyl adipate (CAS No , EINECS ): % Hazardous Ingredients: Dimethyl succinate (Xi; R36; H319) % CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Stable side position in case of unconsciousness. Supply fresh air. If required give artificial respiration. In case of complaints or unconsiousness consult a physician. In case of unconsciousness place patient stable in side position for transportation. Remove contaminated clothing. Wash off immediately with plenty of water and soap. Rinse open eye for several minutes under running water. Should irritation continue, seek medical advice After ingestion: Most important Symptoms and Effects, both Acute and Delayed Do not induce vomiting. Consult physician immediately. Symptoms: No further information available Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media No further information available. Suitable extinguishing media: 3

3 Page 3 Fight larger fire with water jet or alcohol resistant foam. Foam, carbon dioxide (CO2), extinguishing powder, water jet Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Special hazards: Advice for Firefighters Protective equipment: In case of fire: formation of carbon monoxide. Wear self-contained respiratory protective device Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Ensure adequate ventilation Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water. Contact local authorities if product pollutes soil or vegetation Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Contain with absorbent material (sand, diatomaceous earth, acid binder, universal absorbent) and dispose accordingly. For information for safe handling see Section 7. Protective clothing, see Section 8. Dispose of contaminated material according to Section 13. No special measures required Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Storage conditions: Store in a cool and dry place. Requirements for storage areas and containers: No special measures necessary. Information on fire and explosion protection: No special measures necessary. 4

4 Storage class (VCI): Page Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): Dimethyl glutarate (CAS ): TLV: 8 mg/m3, 1,2 ml/m3, 2 (I); AGS, Y Dimethyl succinate (CAS ): TLV: 8 mg/m3, 1,2 ml/m3, 2 (I); AGS, Y Dimethyl adipate (CAS ): TLV: 8 mg/m3, 1,2 ml/m3, 2(I); AGS, Y Y: No teratogenic risk when the exposure limit values (ELV) and biological limit values (BLV) are adhered to. Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: Remove contaminated clothing. Wash hands after work. Keep away from foodstuffs, beverages and feed. Not required. Protective gloves (EN 374) Butyl rubber (480 min; 0.5 mm). Not suitalble material: chloroprene rubber, fluoro carbon rubber (Viton), nitrile rubber, PVC. Safety glasses (EN 166) Protective clothing. Environmental precautions: 9. Physical and Chemical Properties Information on Basic Physical and Chemical Properties 5

5 Form: liquid Page 5 Color: Odor: Odor threshold: ph-value: Melting temperature: colorless sweetish not available -20 C Boiling temperature: C Flash point: 103 C Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: < 0.1 (nbuac=1) not applicable 8.0 Vol.-% 0.8 Vol.-% 0.08 hpa (20 C) 1.09 g/cm3 (20 C) 5.3 g/l (20 C) 0.19 logpow Product is not auto-ignitable. not determined 2.6 mpa.s (25 C) Product is not explosive. no information available Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: 6

6 Particle size: Page Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: None known. Unknown. Strong oxidizing agents. Carbon monoxide. No irritant effect known. Can temporarily cause slight irritation of eyes. No permanent damage expected. No harmful effects expected after short-term, single exposure. No sensitizing effects known. No data available. Reproductive toxicity: No data available. 7

7 Cancerogenity: No data available. Page Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: No negative effects. When used and handled according to specifications, the product does not have any harmful effects. The product is not subject to classification according to latest version of the General EU Classification Guidelines for Preparations. Not applicable. 1, slightly hazardous. Must be treated as toxic waste according to local laws and regulations. Dispose of according to official local regulations. Waste Code No.: 8

8 Page Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: No hazardous goods according to ADR (land transportation) IMDG/IATA: Transport Hazard Classes ADR Class: not applicable Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: not applicable Hazard no.: Packaging Group ADR/RID: not applicable IMDG: IATA: Environmental Hazards None Special Precautions for User Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 1, slightly hazardous for water (self-assessment) Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: 9

9 Chemical Safety Assessment Further Information Other Information Page 9 A Chemical Safety Assessment has not been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.