Safety Data Sheet Dispers Blue Revision date : 2015/02/13 Page: 1/7

Transcription

1 Revision date : 2015/02/13 Page: 1/7 1. Product and Company Identification Company BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA 24 Hour Emergency Response Information CANUTEC (reverse charges): (613) BASF HOTLINE: (800) 454-COPE (2673) Chemical family: Synonyms: copper-phthalocyanine pigment C.I. Pigment Blue 15:3 preparation 2. Hazards Identification Emergency overview No particular hazards known. State of matter: liquid Colour: blue Odour: product specific Potential health effects Acute toxicity: Virtually nontoxic after a single ingestion. Irritation / corrosion: Not irritating to eyes and skin. Assessment other acute effects: Based on the available information there is no specific target organ toxicity to be expected after a single exposure. Sensitization: No reliable data was available concerning sensizitation. The product has not been tested. The statement has been derived from the properties of the individual Chronic toxicity: Carcinogenicity: Based on our experience and the information available, no adverse health effects are expected if handled as recommended with suitable precautions for designated uses. The product has not been tested. The statement has been derived from the properties of the individual Repeated dose toxicity: No data available.

2 Revision date : 2015/02/13 Page: 2/7 Reproductive toxicity: The data available for an assessment of the effect of the substance on reproduction are not sufficient for a proper evaluation. Teratogenicity: The data available for an assessment of the effect of the substance on developmental toxicity are not sufficient for a proper evaluation. Genotoxicity: The chemical structure does not suggest a specific alert for such an effect. The product has not been tested. The statement has been derived from the properties of the individual Signs and symptoms of overexposure: No significant reaction of the human body to the product known. Potential environmental effects Aquatic toxicity: No data can be given due to the product's insolubility in water. 3. Composition / Information on Ingredients Not WHMIS controlled. 4. First-Aid Measures General advice: Immediately remove contaminated clothing. If inhaled: Remove the affected individual into fresh air and keep the person calm. Seek medical attention. If on skin: Wash affected areas thoroughly with soap and water. Seek medical attention. If in eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open. If irritation develops, seek medical attention. If swallowed: Rinse mouth and then drink plenty of water. Do not induce vomiting. Seek medical attention if necessary. Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Flash point: > 100 C (DIN 51758) Autoignition: > 200 C (DIN 51794) Lower explosion limit: As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use.

3 Revision date : 2015/02/13 Page: 3/7 Upper explosion limit: Flammability: Self-ignition temperature: Suitable extinguishing media: water spray, dry powder, foam As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use. not self-igniting Hazards during fire-fighting: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Protective equipment for fire-fighting: Firefighters should be equipped with self-contained breathing apparatus and turn-out gear. 6. Accidental release measures Personal precautions: Use personal protective clothing. Environmental precautions: Do not discharge into drains/surface waters/groundwater. Cleanup: Spills should be contained, solidified, and placed in suitable containers for disposal. For small amounts: Pick up with absorbent material (e.g. sand, sawdust, general-purpose binder). Dispose of absorbed material in accordance with regulations. For large amounts: Pump off product. 7. Handling and Storage Handling General advice: No special measures necessary provided product is used correctly. Protection against fire and explosion: No special precautions necessary. Storage General advice: Keep container tightly closed and in a cool place. Temperature tolerance Protect from temperatures below: 0 C Characteristics of the product are irreversibly changed below the limit temperature. Protect from temperatures above: 60 C 8. Exposure Controls and Personal Protection Advice on system design: Provide local exhaust ventilation to control vapours/mists.

4 Revision date : 2015/02/13 Page: 4/7 Personal protective equipment Respiratory protection: Wear respiratory protection if ventilation is inadequate. Respiratory protection in case of vapour/aerosol release. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. Hand protection: Chemical resistant protective gloves Eye protection: Safety glasses with side-shields. Wear face shield if splashing hazard exists. Body protection: Impermeable protective clothing General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wash soiled clothing immediately. 9. Physical and Chemical Properties Form: liquid Odour: product specific Odour threshold: No data available. Colour: blue ph value: 8-9 ( 20 C) Freezing point: 0 C ( 1,013 hpa) boiling temperature: 100 C Vapour pressure: Density: 1.06 g/cm3 ( 20 C) Relative density: 1.06 Vapour density: Partitioning coefficient n- not applicable octanol/water (log Pow): Solubility in water: miscible 10. Stability and Reactivity Conditions to avoid: See MSDS section 7 - Handling and storage. Substances to avoid: No substances known that should be avoided. Hazardous reactions: No hazardous reactions when stored and handled according to instructions. The product is chemically stable. Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition: Oxidizing properties: not fire-propagating 11. Toxicological information

5 Revision date : 2015/02/13 Page: 5/7 Acute toxicity Oral: Type of value: LD50 Species: rat Value: > 5,000 mg/kg Inhalation: Type of value: LC50 Species: rat Exposure time: 4 h Dermal: Type of value: LD50 Species: rat Irritation / corrosion Skin: Species: rabbit Result: non-irritant Eye: Species: rabbit Result: non-irritant Aspiration Hazard: No aspiration hazard expected. The product has not been fully tested. The statements have been derived in parts from products of a similar structure or composition. 12. Ecological Information Fish Acute: Leuciscus idus/lc50 (96 h): > 100 mg/l Chronic: No data available. Aquatic invertebrates Acute: daphnia/lc50 (48 h): Chronic: No data available. Aquatic plants

6 Revision date : 2015/02/13 Page: 6/7 Toxicity to aquatic plants: algae/ec50 (72 h): Degradability / Persistence Biological / Abiological Degradation Evaluation: The colourant is insoluble in water and can thus be separated from water mechanically in suitable effluent treatment plant Other adverse effects: The product contains: copper The heavy metals mentioned are present in complex bound form as substantial constituent of the colourant. 13. Disposal considerations Waste disposal of substance: Dispose of in accordance with national, state and local regulations. It is the waste generator's responsibility to determine if a particular waste is hazardous under RCRA. Container disposal: Dispose of in a licensed facility. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers. 14. Transport Information Land transport TDG Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations 15. Regulatory Information Federal Regulations Registration status: Chemical DSL, CA released / listed Not WHMIS controlled. THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR.

7 Revision date : 2015/02/13 Page: 7/7 16. Other Information Recommended use: pigment Suitable for use in industrial sector: chemical industry; We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. SDS Prepared by: BASF NA Product Regulations BASF HOTLINE (800) 454 COPE (2673) SDS Prepared on: 2015/02/13 END OF DATA SHEET