Version: 1. Hauptstr , Aichstetten, Germany. Tel./Fax.: Tel , Fax

Transcription

1 Revised edition: Version: 1 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Vine Black, German Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Pigment for the coloration of paint, paper, polymers or zementbound building materials Uses advised against: Details of the Supplier of the Safety Data Sheet Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: Emergency No. info@kremer-pigmente.de Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product is not classified as hazardous according to the CLP/GHS Directive. The material is not subject to classification according to EC lists Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: Signal word: Hazard designation: Safety designation: See Section 12. This product does not require classification and labelling as hazardous according to CLP/GHS. Not applicable. Hazardous components for labelling: Other Hazards 2

2 Composition/Information on Ingredients Substance Mixture Page 2 Chemical Characterization: Pigment Black 8, C.I Hazardous Ingredients: Anthracite CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Natural product: exempted from the mandatory REACH Registration (Annex V). Seek medical attention in case of complaints. Supply fresh air and seek medical advice in case of complaints. Remove contaminated clothing. Wash off immediately with plenty of water and soap. Rinse open eyes with plenty of water for at least 15 minutes. Consult a physician After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with plenty of water. If symptoms persist consult physician. Symptoms: No further information available Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Use extinguishing media for surrounding fire. Unsuitable extinguishing media: Water with full jet. 3

3 5. 2. Special Hazards arising from the Substance or Mixture Page Special hazards: Advice for Firefighters Protective equipment: Danger of dust explosion. When heated or in case of fire: formation of hazard fumes possible. Wear self-contained respiratory protective device Further information: Do not inhale smoke. Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Wear protective clothing. Avoid contact with eyes and skin Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soil, drains and surface waters Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Collect powder using a special dust vacuum cleaner with particle filter. See Section 13 for information on disposal. Provide adequate ventilation. Avoid formation of dust. Do not inhale dust Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Store in tightly sealed containers in a dry room. No special measures necessary. Do not store together with ignitable sources, heat and fire. 4

4 Storage class (VCI): Page Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): TWA-Value: 3 mg/m3 air-borne fraction (general dust limit; 8h) TWA-Value: 10 mg/m3 general dust limit inhalable fraction (8h) Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): No values available. No values available Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation in case of dust formation. Personal Protection General protective measures: Respiratory protection: Hand protection: Remove contaminated clothing. Wash hands after work. Keep away from foodstuffs, beverages and feed. Respiratory equipment required in case of insufficient ventilation, filter type P2. Protective gloves (EN 374) Protective glove material: Eye protection: Body protection: Tightly fitting safety goggles (EN 166). Protective clothing Environmental precautions: No special measures required. Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: powder 5

5 Color: black Page 5 Odor: Odor threshold: none ph-value: 9 Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: not available not available not available not available no information available no information available ca. 1.5 g/cm3 insoluble No data available. Product is not explosive; however, an explosive dust/air mixture can be formed. ca. 500 g/l 6

6 9. 2. Further Information Page Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: No further information. Stable if used according to specifications. Stable if used according to specifications. The product is not dust explosive when delivered. The accumulation of fine dust can however increase the risk of dust explosion. Avoid heat, open fire and other ignition sources. No further information available. In case of fire: formation of carbon oxides and other toxic gases and vapors. No information available Irritant effect on eyes: 7

7 Page Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability No information available Industrial carbon black cannot be tested in bacterial and in vitro systems (insoluble inorganic compound). No data available. No data available. Epidemiological and clinical studies did not show any significant health hazards in workers exposed to industrial carbon black. The scientific discussions over the tumorigenic effect of insoluble, inorganic particles (fine dust) - such as carbon black - are still ongoing. According to many inhalation toxicologists, the tumors observed in the rat experiments result from a species-specific mechanism due to an overstressing of the rat lung (overload phenomena). No corresponding finding have been found following the exposition to humans. The IARC, however, assesses the present rat studies in the Monograph 65 as sufficient evidence for the cancerogenicity of carbon black in animal studies. According to the IARC, there is no evidence for the carcinogenic effect of carbon black for humans. The overall assessment of carbon black: "probably carcinogenic to humans" (group 2B) results from the IARC evaluation scheme. The PAH (polycyclic aromatic hydrocarbons) content of the Degussa Industrial Carbon Blacks are below 0.1 %. Pigment is not soluble in water and biologically not degradable. 8

8 Bioaccumulation Moblity Results of PBT- und vpvp Assessment No data available Other Adverse Effects Page 8 Water hazard class: Not hazardous. Behaviour in sewage systems: Further ecological effects: No special effects or hazards known AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: In accordance with current regulations, product may be taken to a waste disposal site or incineration plant, after consultation with site operator and/or with the responsible authority. The waste code must be determined with the regional disposal service. Packaging that may not are to be disposed of in the same manner as the product Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. IMDG Class (sea): 9

9 Page 9 Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards Special Precautions for User None Not classified as a dangerous good under transport regulations Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Not classified as a dangerous good under transport regulations Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 0, not hazardous (self-assessment) Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information Exempted from the mandatory REACH Registration (Annex V). This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.