MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name Version # 01 Issue date Revision date - Supersedes date - CAS # Product code Product use Manufacturer/Supplier General Information: Mixture D20 Industrial Strength Drain Opener. Scot Laboratories Park Circle Dr. Chagrin Falls, OH US Emergency 24 Hour Emergency: Hazards Identification Physical state Appearance Emergency overview Liquid. Clear yellow liquid. DANGER! Causes skin and eye burns. Causes digestive tract burns. Causes respiratory tract irritation. OSHA regulatory status This product is hazardous according to OSHA 29 CFR Potential health effects Eyes Skin Inhalation Ingestion Potential environmental effects Causes eye burns. Causes skin burns. Causes respiratory tract irritation. Causes digestive tract burns. 3. Composition / Information on Ingredients The product may affect the acidity (ph-factor) in water with risk of harmful effects to aquatic organisms. CAS # Percent Sodium hydroxide Potassium hydroxide Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First Aid Measures First aid procedures Eye contact Skin contact Inhalation Ingestion Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Call a physician or poison control center immediately. In case of irritation from airborne exposure, move to fresh air. Get medical attention if symptoms persist. Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician or poison control center immediately. Wash contaminated clothing before reuse. Destroy or thoroughly clean contaminated shoes. Move to fresh air. Treat symptomatically. Get medical attention if symptoms persist. Call a physician or poison control center immediately. DO NOT induce vomiting. If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person. If vomiting occurs, keep head lower than the hips to help prevent aspiration. 1 / 6

2 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Fire fighting equipment/instructions Hazardous combustion products 6. Accidental Release Measures Personal precautions Methods for cleaning up 7. Handling and Storage Handling Storage unusual fire or explosion hazards noted. Water. Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Sodium oxides. Potassium oxides. 8. Exposure Controls / Personal Protection Occupational exposure limits US. ACGIH Threshold Limit s Avoid contact with skin and eyes. Wear protective clothing as described in Section 8 of this MSDS. Absorb spill with vermiculite or other inert material, then place in a container for chemical waste. Large Spills: Flush area with water. Prevent runoff from entering drains, sewers, or streams. Dike for later disposal. Do not get in eyes, on skin, on clothing. Avoid breathing mist or vapor. Do not taste or swallow. Use only with adequate ventilation. Wash thoroughly after handling. If frozen, allow to thaw to room temperature. Mix before using. Keep container closed. Do not store near heat. Store in polyethylene containers. Do not store in glass. Store away from incompatible materials. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) PEL Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) 2 / 6

3 Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Mexico. Occupational Exposure Limit s Engineering controls Personal protective equipment Eye / face protection Skin protection Respiratory protection General hygiene considerations 9. Physical & Chemical Properties Appearance Physical state Form Color Odor ph 13 Vapor density Solubility (water) Ensure adequate ventilation, especially in confined areas. Wear safety glasses with side shields (or goggles). Wear chemical-resistant gloves, footwear and protective clothing appropriate for risk of exposure. Contact glove manufacturer for specific information. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be worn. Respirator type: Air-purifying respirator with an appropriate, government approved (where applicable), air-purifying filter, cartridge or canister. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Clear yellow liquid. Liquid. Liquid. Clear yellow. ne. Specific gravity 1.11 Flash point Heavier than air. Complete. > 200 F (> 93.3 C) Evaporation rate < 1 (Butyl acetate = 1) 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions 11. Toxicological Information Sensitization Acute effects Carcinogenicity 12. Ecological Information Ecotoxicity Persistence and degradability Material is stable under normal conditions. Contact with incompatible materials. Strong acids. Strong oxidizing agents. Do not mix with other chemicals or household cleaners. hazardous decomposition products are known. Hazardous polymerization does not occur. Causes eye and skin burns. Causes digestive tract burns. Causes respiratory tract irritation. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Large amounts of the product may affect the acidity (ph-factor) in water with possible risk of harmful effects to aquatic organisms. 3 / 6

4 Bioaccumulation / Accumulation Partition coefficient Mobility in environmental media 13. Disposal Considerations Disposal instructions Contaminated packaging 14. Transport Information Dispose of contents/container in accordance with local/regional/national/internat ional regulations. Since emptied containers may retain product residue, follow label warnings even after container is emptied. DOT Basic shipping requirements: Proper shipping name Corrosive liquid, basic, inorganic, n.o.s. (Potassium hydroxide RQ = LBS, Sodium hydroxide RQ = LBS) Hazard class 8 Additional information: Special provisions B2, IB2, T11, TP2, TP27 Packaging exceptions 154 Packaging non bulk 202 Packaging bulk 242 IATA UN proper shipping name Corrosive liquid, basic, inorganic, n.o.s. (Potassium hydroxide, Sodium hydroxide) Transport hazard class(es) 8 ERG code 8L IMDG UN proper shipping name CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (Potassium hydroxide, Sodium hydroxide) Transport hazard class(es) 8 EmS. F-A, S-B TDG Proper shipping name CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (Potassium hydroxide, Sodium hydroxide) Hazard class 8 Marine pollutant Special provisions Regulatory Information US federal regulations This product is hazardous according to OSHA 29 CFR TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) t regulated. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List t regulated. CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4) Sodium hydroxide: 1000 Potassium hydroxide: 1000 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Pressure Hazard - Reactivity Hazard - 4 / 6

5 Section 302 extremely hazardous substance (40 CFR 355, Appendix A) Section 311/312 (40 CFR 370) Drug Enforcement Administration (DEA) (21 CFR ) Canadian regulations WHMIS status WHMIS classification WHMIS labeling Yes t controlled This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. Controlled D2B - Other Toxic Effects-TOXIC E - Corrosive Inventory status Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s) State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US - California Hazardous Substances (Director's): Listed substance US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance t listed. US - New Jersey RTK - Substances: Listed substance US. Massachusetts RTK - Substance List US. New Jersey Worker and Community Right-to-Know Act t regulated. US. Pennsylvania RTK - Hazardous Substances Mexico regulations 16. Other Information Further information This safety data sheet was prepared in accordance with the Official Mexican Standard (NOM-018-STPS-2000). HMIS is a registered trade and service mark of the NPCA. Yes Yes 5 / 6

6 HMIS ratings Health: 3 Flammability: 1 Physical hazard: 0 NFPA ratings Health: 3 Flammability: 1 Instability: 0 Disclaimer The information contained herein was obtained from current and reliable sources. However, the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since the conditions for use, handling, storage and disposal of this product are beyond Scot Laboratories' control, it is the user's responsibility both to determine safe conditions for use of this product and to assume liability for loss, injury, damage or expense arising from the product's improper use. warranty, expressed or implied, regarding the product described herein shall be created by or inferred from any statement or omission in this MSDS. Various government agencies (e.g., DOT, EPA, FDA) may have specific regulations concerning the transportation, handling, storage, use or disposal of this product which may not be reflected in this MSDS. The user should review these regulations to ensure full compliance. 6 / 6