Issue Date: 23-Apr-1997 Revision Date: 08-Nov-2013 Version 1 1. IDENTIFICATION. Mark 360 Red Dish Machine Detergent. Dish machine detergent.

Transcription

1 Safety Data Sheet Issue Date: 23-Apr-1997 Version 1 1. IDENTIFICATION Product Identifier Product Name Other means of identification SDS # UN/ID No Mark 360 Red Dish Machine Detergent CMH-003 UN1760 Recommended use of the chemical and restrictions on use Recommended Use Dish machine detergent. Details of the supplier of the safety data sheet Manufacturer Address ChemMark of Houston, Inc Petro Park Houston, TX Emergency Telephone Number Company Phone Number Emergency Telephone (24 hr) INFOTRAC (International) (North America) 2. HAZARDS IDENTIFICATION Appearance Red liquid Physical State Liquid Classification Skin corrosion/irritation Category 1 Sub-category B Serious eye damage/eye irritation Category 1 Signal Word Danger Hazard Statements Causes severe skin burns and eye damage Precautionary Statements - Prevention Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Page 1 / 8

2 Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a POISON CENTER or doctor/physician IF SWALLOWED: rinse mouth. Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other Hazards Harmful to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Proprietary Sodium metasilicate Proprietary Trade Secret Proprietary 0-10% Trade Secret Proprietary 0-10% **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** First Aid Measures 4. FIRST-AID MEASURES Eye Contact Skin Contact Inhalation Ingestion Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek immediate medical attention/advice. Wash off immediately with plenty of water for at least 15 minutes. Take off contaminated clothing. Wash contaminated clothing before reuse. If skin irritation persists, call a physician. Remove to fresh air. Oxygen or artificial respiration if needed. Seek immediate medical attention/advice. Drink plenty of water or milk immediately. Do not induce vomiting. Seek medical attention. Most important symptoms and effects Symptoms Burning and/or irritation to eyes and skin. Inhalation may cause irritation or burning to mucous membranes. May cause eye burns and permanent eye damage. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. Page 2 / 8

3 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media. Specific Hazards Arising from the Chemical Closed containers may explode due to buildup of pressure when exposed to extreme heat. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Cool containers exposed to fire with water. Approach fire from upwind side. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Methods and material for containment and cleaning up Methods for Containment Methods for Clean-Up Prevent further leakage or spillage if safe to do so. Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Wash thoroughly after handling. Use personal protection recommended in Section 8. Do not breathe dust/fume/gas/mist/vapors/spray. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible Materials Keep containers tightly closed in a dry, cool and well-ventilated place. Keep separate from food items. Store locked up. Acids. Oxidizers. Oxidizing materials. Page 3 / 8

4 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Ceiling: 2 mg/m 3 (vacated) Ceiling: 2 mg/m 3 Ceiling: 2 mg/m 3 Sodium metasilicate 2 mg/m 3 2 mg/m Sodium Tripolyphosphate mg/m 3 15 mg/m 3 - Appropriate engineering controls Engineering Controls Local exhaust and mechanical ventilations are recommended to be used as engineering controls. Eyewash stations. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Splash proof chemical safety goggles. PVC, Neoprene, or Nitrile gloves are recommended. Ensure adequate ventilation, especially in confined areas. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Appearance Red liquid Odor Color Red Odor Threshold Property Values Remarks Method ph 12.5 Melting Point/Freezing Point Boiling Point/Boiling Range > 100 C / >212 F Flash Point Water solution, will not burn Evaporation Rate > 1 (butyl acetate = 1) Flammability (Solid, Gas) n/a-liquid Upper Flammability Limits Lower Flammability Limit Vapor Pressure Not available Vapor Density >1 Specific Gravity 1.16 (1=Water) Water Solubility Completely soluble Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties Page 4 / 8

5 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to Avoid Contact with incompatible materials. Incompatible Materials Acids. Oxidizers. Oxidizing materials. Hazardous Decomposition Products Carbon oxides. Phosphorous oxides. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Skin Contact Inhalation Ingestion Causes severe eye damage. Causes severe skin burns. Avoid breathing vapors or mists. Do not taste or swallow. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 = 214 mg/kg ( Rat ) - - Sodium metasilicate = 600 mg/kg ( Rat ) Sodium Tripolyphosphate = 3100 mg/kg ( Rat ) > 7940 mg/kg ( Rabbit ) Trade Secret - > 4640 mg/kg ( Rabbit ) - Trade Secret = 10 g/kg ( Rat ) - - Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Numerical measures of toxicity Page 5 / 8

6 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects. Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms 80: 96 h Gambusia affinis mg/l LC50 static Sodium metasilicate 210: 96 h Brachydanio rerio mg/l LC50 semi-static 210: 96 h Brachydanio rerio mg/l LC50 Sodium Tripolyphosphate 1650: 48 h Leuciscus idus mg/l LC50 Trade Secret 100: 96 h Oncorhynchus mykiss mg/l LC50 Trade Secret 1.01: 72 h Desmodesmus subspicatus mg/l EC50 41: 96 h Lepomis macrochirus mg/l LC50 static 59.8: 96 h Pimephales promelas mg/l LC50 static Crustacea 216: 96 h Daphnia magna mg/l EC50 100: 48 h water flea mg/l EC50 610: 24 h Daphnia magna mg/l EC50 Persistence/Degradability. Bioaccumulation. Mobility Chemical Name Partition Coefficient 0.83 Other Adverse Effects 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status Chemical Name California Hazardous Waste Status Toxic Corrosive Page 6 / 8

7 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT UN/ID No UN1760 Proper Shipping Name Corrosive liquids, n.o.s. (, Sodium metasilicate) Hazard Class 8 Packing Group II IATA UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (, Sodium metasilicate) Hazard Class 8 Packing Group II IMDG UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (, Sodium metasilicate) Hazard Class 8 Packing Group II Marine Pollutant This material may meet the definition of a marine pollutant International Inventories US Federal Regulations CERCLA 15. REGULATORY INFORMATION Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ SARA 313 CWA (Clean Water Act) Component ( Proprietary ) CWA - Reportable CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Quantities Substances 1000 lb X US State Regulations U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania X X X Sodium Tripolyphosphate X X Page 7 / 8

8 16. OTHER INFORMATION NFPA HMIS Health Hazards 3 Health Hazards 3 Flammability 0 Flammability 0 Instability 0 Physical Hazards 0 Special Hazards Personal Protection Issue Date: Revision Date: Revision Note: 23-Apr Nov-2013 New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 8 / 8