Revision Date 31-Jan IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING. No information available

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1 SAFETY DATA SHEET Issuing Date 05-v-2013 Revision Number 1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING GHS product identifier Product Name Great Wipes Other means of identification Product Code(s) Synonyms ne Recommended use of the chemical and restrictions on use Recommended Use Uses advised against Hand cleaner information available Supplier's details Supplier Address Nu-Calgon 2611 Schuetz Road St. Louis, MO Phone: / Emergency telephone number Emergency Telephone Number Classification Chemtrec HAZARDS IDENTIFICATION This chemical is not considered hazardous according to the OSHA Hazard Communication Standard 2012 (29 CFR ). GHS Label elements, including precautionary statements Emergency Overview Signal Word ne The product contains no substances which at their given concentration are considered to be hazardous to health Appearance Colorless Physical State Liquid. Odor Citrus Precautionary Statements Prevention ne Page 1 / 8

2 General Advice ne Storage ne Disposal ne Hazard t Otherwise Classified (HNOC) t applicable Other information Harmful to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS- Weight % Alcohols, C12-15, ethoxylated D-Limonene *The exact percentage (concentration) of composition has been withheld as a trade secret. Trade secret * * 4. FIRST AID MEASURES Description of necessary first-aid measures Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a physician. Skin Contact Inhalation Ingestion ne normally required. Material is designed for skin cleansing. Get medical attention if irritation develops and/or persists. Move to fresh air. If symptoms persist, call a physician. t an expected route of exposure. If large quantities of this material are swallowed, call a physician immediately. Most important symptoms/effects, acute and delayed Most Important Symptoms/Effects t expected to give rise to an acute hazard under normal condition of use. Indication of immediate medical attention and special treatment needed, if necessary tes to Physician Treat symptomatically. Suitable Extinguishing Media Dry chemical. Carbon dioxide (CO 2 ). Foam. Water spray or fog. Unsuitable Extinguishing Media ne Specific Hazards Arising from the Chemical ne in particular 5. FIRE-FIGHTING MEASURES Page 2 / 8

3 Hazardous Combustion Products Carbon dioxide (CO 2 ). Carbon monoxide. Hydrocarbons. Hydrogen sulfide. Sulfur dioxide. Soot. Explosion Data Sensitivity to Mechanical Impact Sensitivity to Static Discharge ne. ne. Protective Equipment and Precautions for Firefighters Use water spray to cool surrounding containers. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment. Environmental Precautions Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas. Avoid release to the environment. See Section 12 for additional Ecological Information Dispose of contents/container to an approved waste disposal plant. Methods and materials for containment and cleaning up Methods for Containment Methods for Cleaning Up Prevent further leakage or spillage if safe to do so. Small spillage: Wipe up with absorbent material (e.g. cloth, fleece). Large spillage: Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. 7. HANDLING AND STORAGE Precautions for safe handling Handling Avoid contact with eyes. Do not smoke. Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage, including any incompatibilities Storage Incompatible Products Keep container closed when not in use. Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Do not contaminate food or feed stuffs. Keep out of the reach of children. Strong oxidizing agents. Strong acids. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Glycerin TWA: 10 mg/m 3 mist Appropriate engineering controls Engineering Measures Eyewash stations. Page 3 / 8

4 Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Hygiene Measures special protective equipment required. special protective equipment required. ne required under normal usage. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Handle in accordance with good industrial hygiene and safety practice. Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Odor Liquid Citrus Appearance Odor Threshold Colorless information available Property Values ph 6 Melting Point/Range Boiling Point/Boiling Range 100 C / 212 F Flash Point ne to boiling Evaporation rate Flammability (solid, gas) Flammability Limits in Air upper flammability limit lower flammability limit Vapor Pressure Vapor Density > 1 (air = 1) Relative Density Specific Gravity Water Solubility Solubility in other solvents Partition coefficient: n-octanol/water Autoignition Temperature Decomposition Temperature Viscosity Remarks/ - Method Flammable Properties Explosive Properties Oxidizing Properties t flammable Other information VOC Content (%) 0% 10. STABILITY AND REACTIVITY Reactivity t reactive under normal conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions ne under normal processing. Page 4 / 8

5 Conditions to avoid Incompatible products. Incompatible materials Strong oxidizing agents. Strong acids. Hazardous decomposition products Carbon dioxide (CO2). Carbon monoxide (CO). Hydrocarbons. Hydrogen sulfide. Sulfur dioxide. Soot. Information on likely routes of exposure 11. TOXICOLOGICAL INFORMATION Product Information Inhalation Eye Contact Skin Contact Ingestion t an expected route of exposure Contact with eyes may cause irritation. May cause mild skin irritation. t an expected route of exposure. Symptoms related to the physical, chemical and toxicological characteristics Symptoms Delayed and immediate effects and also chronic effects from short and long term exposure Sensitization Mutagenic Effects Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA D-Limonene Group IARC: (International Agency for Research on Cancer) Group 3: t Classifiable as to its Carcinogenicity to Humans Reproductive Toxicity STOT - single exposure STOT - repeated exposure Aspiration Hazard Numerical measures of toxicity - Product The following values are calculated based on chapter 3.1 of the GHS document: LD50 Oral mg/kg; Acute toxicity estimate LD50 Dermal mg/kg; Acute toxicity estimate Ecotoxicity Harmful to aquatic life with long lasting effects. 12. ECOLOGICAL INFORMATION Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Isoparaffinic Hydrocarbon LC50 96 h: = 45 mg/l flow-through (Pimephales promelas) LC50 96 h: = 2.2 mg/l static (Lepomis macrochirus) LC50 96 h: = 2.4 mg/l static (Oncorhynchus mykiss) Daphnia Magna (Water Flea) LC50 96 h: = 4720 mg/l (Den-dronereides heteropoda) Page 5 / 8

6 Sodium dioctyl sulfosuccinate D-Limonene Dimethyl glutarate Phenoxyethanol ,3-Propanediol, 2,2-dimethyl Isopropyl myristate Propylene glycol Glycerin Iodopropynyl butylcarbamate Persistence and Degradability EC50 72 h: > 500 mg/l (Desmodesmus subspicatus) EC50 72 h: > 1000 mg/l (Pseudokirchneriella subcapitata) EC50 72 h: > 500 mg/l (Desmodesmus subspicatus) EC50 72 h: > 100 mg/l (Desmodesmus subspicatus) EC50 96 h: = mg/l (Pseudokirchneriella subcapitata) LC50 96 h: mg/l semi-static (Oncorhynchus mykiss) LC50 96 h: < 24 mg/l static (Oncorhynchus mykiss) LC50 96 h: = 37 mg/l static (Lepomis macrochirus) LC50 96 h: mg/l flow-through (Pimephales promelas) LC50 96 h: = 35 mg/l (Oncorhynchus mykiss) LC50 96 h: mg/l static (Pimephales promelas) LC50 96 h: mg/l flow-through (Pimephales promelas) LC50 96 h: = 366 mg/l static (Pimephales promelas) LC50 96 h: mg/l static (Leuciscus idus) LC50 96 h: > 1000 mg/l semi-static (Oryzias latipes) LC50 96 h: = 8400 mg/l (Brachydanio rerio) LC50 96 h: = 8400 mg/l semi-static (Brachydanio rerio) LC50 96 h: = mg/l static (Oncorhynchus mykiss) LC50 96 h: ml/l static (Oncorhynchus mykiss) LC50 96 h: = mg/l static (Pimephales promelas) LC50 96 h: = 710 mg/l (Pimephales promelas) - LC50 96 h: ml/l static (Oncorhynchus mykiss) LC50 96 h: mg/l flow-through (Oncorhynchus mykiss) LC50 96 h: mg/l (Oncorhynchus mykiss) LC50 96 h: mg/l flow-through (Lepomis macrochirus) LC50 96 h: mg/l flow-through (Pimephales promelas) EC50 = 32.4 mg/l 5 min EC50 = 880 mg/l 17 h EC50 48 h: = 36 mg/l EC50 48 h: mg/l EC50 48 h: > 500 mg/l EC50 24 h: > 1000 mg/l - EC50 48 h: = 100 mg/l EC50 = 710 mg/l 30 min EC50 24 h: > mg/l EC50 48 h: > 1000 mg/l Static - EC50 24 h: > 500 mg/l Bioaccumulation Other Adverse Effects 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods Contaminated Packaging Dispose of in accordance with federal, state, and local regulations Do not re-use empty containers. Page 6 / 8

7 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name D-Limonene California Hazardous Waste Toxic 14. TRANSPORT INFORMATION DOT t regulated International Inventories 15. REGULATORY INFORMATION Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/n-Domestic Substances List U.S. Federal Regulations Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ). CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations "X" designates that the ingredients are listed on the state right to know list. U.S. EPA Label Information Page 7 / 8

8 EPA Pesticide Registration Number t applicable 16. OTHER INFORMATION NFPA Health Hazard 0 Flammability 1 Instability 0 HMIS Health Hazard 0 Flammability 1 Physical Hazard 0 Physical and Chemical Hazards - Personal Protection X Prepared By Issuing Date Revision Date Revision te Product Stewardship 23 British American Blvd. Latham, NY v Jan-2018 Initial Release. General Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of Safety Data Sheet Page 8 / 8