3 ADDITIONAL DOCCUMENTS

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1 3 ADDITIONAL DOCCUMENTS Annexure 1: Production Details Sr. No Name of Products CAS Number Type of Dye Production capacity MT/Month Existing Proposed Total 1 Turquoise Blue Reactive Vinyl Sulphone Intermediate Acetanilide Intermediate Synthetic Organic Dyes Reactive/ Disperse 1 Acid Black Acid Red Reactive Black Reactive Black Reactive Blue Reactive Blue Reactive Red Reactive Orange Reactive Blue Reactive Orange Reactive Red Reactive Red Reactive Blue Reactive Violet Reactive Yellow Reactive Yellow Reactive Black Reactive Blue 4 - REACTIVE Reactive Blue Reactive Blue Reactive Blue Reactive Blue Reactive Blue Reactive Green Reactive Violet Reactive Violet Reactive Orange Reactive Orange Reactive Red Reactive Violet Reactive Red Reactive Red Reactive Red Reactive Orange Reactive Yellow 86 - KADAM ENVIRONMENTAL CONSULTANTS JULY

2 Sr. No Name of Products CAS Number Type of Dye Production capacity MT/Month Existing Proposed Total 36 Reactive Yellow Reactive Orange Reactive Orange Reactive Yellow 145A Reactive Blue Reactive Blue Reactive Blue Reactive Brown Reactive Red 198 A Reactive Red 195A Reactive Red Reactive Blue Reactive Yellow Reactive Yellow Direct Orange Direct Blue Direct Blue BLACK BCH - 54 Yellow REACTIVE YELLOW C4G - 56 Reactive Orange Reactive Brilliant Blue Brilliant Blue JRF BLUE BLUE P5G BLACK MIX - 62 YELLOW 160A YELLOW YELLOW RED YELLOW MIX - 67 RED MIX - 68 BLUE MIX - 69 ORANGE MIX - Red 2BN / Red FB - CI Red Disperse Dye (Azo 60 Cynation) 71 Reactive Violet Flourescent Yellow 10GF - CI Disperse Flourescent Yellow 8GF - CI Disperse Disperse Dye (Yellow Methine) Flourescent Yellow 10GN - CI Disperse 232/ KADAM ENVIRONMENTAL CONSULTANTS JULY

3 Sr. No Name of Products CAS Number Type of Dye Production capacity MT/Month Existing Proposed Total 75 Brilliant Blue SR - CI Disperse Blue Disperse Dye (Blue Methine) Cyanine Red - 77 Cyanine Pink - 78 Cyanine Blue - 79 CI - Blue CI - Yellow Blue BG - CI - Blue Orange RL - CI Orange Yellow SG - CI Yell Yellow 4G CI Yell Scarlet BR - CI Red 74 - Disperse Dye (Cyanine Plant) Disperse Dye (Multi P Plant) Yellow C4G - C.I. Yellow Yellow SGL Yellow SG- C.I. Yellow Yellow Yellow Yellow Red Yellow M7G - 94 Yellow Yellow Yellow Yellow Orange Red Yellow Yellow 7GN Black Black Orange Disperse Dye (HCl- Nitrite Base Azo Dye) Navy Blue 3G - CI Blue 79.1 Dark Red 2B - CI Red Violet 3R - CI Violet Blue 2R - CI Blue Navy Blue Navy Blue Navy Blue Navy Blue Blue Blue 4R Disperse Dye (NSA Based Azo Dye) KADAM ENVIRONMENTAL CONSULTANTS JULY

4 Sr. No Name of Products CAS Number Type of Dye Production capacity MT/Month Existing Proposed Total 115 Blue 6GEF Blue 4RB Blue 4GEF Red BS Scarlet GS Red-XF2R Red Yellow Brown XF Brown XF Navy XF2R Navy XF2G Brown Brown Brown Orange Orange Scarlet 3R C.I. Red Scarlet 3R C.I. Red Blue Red List of By Product Sr. No. Name of By-Product Total Quantity in MT/Month Existing Proposed Total 1 HCL Sodium Bi Sulphide (SBS Sulrry) Total KADAM ENVIRONMENTAL CONSULTANTS JULY

5 Annexure 2: Existing Consent to Operate (CTO) Note: Jay chemical has applied to GPCB for amalgamation of unit-3/1 and unit-3/2 as unit-3. This application is in process hence details are given separately 1) Unit -3/1 KADAM ENVIRONMENTAL CONSULTANTS JULY

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10 2) Unit 3/2 KADAM ENVIRONMENTAL CONSULTANTS JULY

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15 SYNTHETIC ORGANIC DYES MFG. PLANT, AT Annexure 3: Site Location Map KADAM ENVIRONMENTAL CONSULTANTS JULY

16 SYNTHETIC ORGANIC DYES MFG. PLANT, AT Annexure 4: Project boundary on Google Image with co-ordinates KADAM ENVIRONMENTAL CONSULTANTS JULY

17 SYNTHETIC ORGANIC DYES MFG. PLANT, AT Annexure 5: Site Layout Map KADAM ENVIRONMENTAL CONSULTANTS JULY

18 Table 1: Area Break up at Site S. No. Title Area, m 2 Existing Proposed Total % of total Area 1 Processing Area Storage Area a Hazardous Chemicals b Other Non-hazardous chemicals c Hazardous Waste d Water Storage Effluent Treatment Plant Boiler Cooling tower DG Sets Roads Administrative Building Open Space Greenbelt Area Area for proposed Expansion 3697 Total KADAM ENVIRONMENTAL CONSULTANTS JULY

19 Annexure 6: Manufacturing Processes 1) Turquoise Blue Process Description: The Chlorosulphonic acid is charged into Sulphonation vessel and CPC is slowly charged at 50OC. The reaction mass is sulphonated at 120C, whereas the HCl generated is scrubbed. The reaction mass is maintained for 3 hrs. Thereafter the sulphonated mass is drowned under ice, the mass is filtered and the filtrate is collected separately and taken into treatment. The filtered cake is charged with Vinyl Sulphone, Pyridine is added, and the mass is condensed. The condensed mass is then checked for the required quality and salt is added as per the required strength. The condensed slurry is then spray dried. The final product is blended and packed. Flow Diagram: 2) Vinyl Sulphone Process Description: (1) SULPHONATION Take Chlorosulphonic Acid and Thionyl Chloride into the sulphonation vessel and charge the Acetanilide flakes, with regular stirring of sulphomass for 4 hrs, maintain temperature between C, where in by addition of water to sulphomass, the HCl gas is scrubbed to recover Hydrochloric Acid. (2) DUMPING & FILTERATION The sulphomass is then dumped into ice to maintain temperature between C for 3 hrs, whereby ASC gets crystalized out. Crystalized ASC is then filtered through vacuumneutch. The filtrate obtained is mainly Sulphuric Acid and Sulfanilic Acid. Sulfanilic Acid is separated from Sulphuric Acid by cooling the filtrate for 24 hrs. (3) REDUCTION ASC is then charged into reduction vessel with Sodium Bisulphite and Caustic Soda lye at temperature between C, maintaining ph between for 4 hrs. After 4 hrs, temperature is increased to 55 to 60 C and transferred to ethoxilation vessel. KADAM ENVIRONMENTAL CONSULTANTS JULY

20 (4) ETHOXILATION Once the temperature of reduction mass is maintained between 55 to 60 C, mass is transferred for ethoxylation where Ethyle Oxide IS charged with Sulphuric Acid, maintaining ph between for 14 hrs with regular stirring. (5) NEUTCH FILTERATION The condensed mass is then filtered through vacuumneutch with 2 water washes. The filtered cake is then centrifuged and dried by flash dryer. (6) ESTERIFICATION The dried condense obtained is then esterified in esterification vessel with addition of Sulphuric Acid, maintaining temperature at 150 C with regular stirring for 5 hrs. Wherein Acetic Acid is recovered Vinyl Sulphone is obtained is pulverized. (7) PULVERIZING & PACKING The pulverized Vinyl Sulphone powder is filled and packed in the HDPE bags. The pulverized Vinyl Sulphone powder is filled and packed in the HDPE bags. Flow Diagram: KADAM ENVIRONMENTAL CONSULTANTS JULY

21 3) Acetanilide Process Description: Process for Acetanilide Flakes Aniline oil and Acetic Acid are charged into reaction vessel and temperature is maintained to 119 C, where acetic acid is recovered and collected. Temperature then raised to 140 C and acetic anhydride is charged into vessel with regular stirring for 2 hrs., temperature is then again raised to 190 C and mass is then flakered and Acetanilide flakes obtained and packed. Flow Diagram: KADAM ENVIRONMENTAL CONSULTANTS JULY

22 RECOVERY (ACETIC ACID) 4) Synthetic Organic Dyes 4.1 Reactive Dyes Process Discription: 1) Vinyl Sulphone base Reactive Dyes Manufacturing Process Vinyl sulphone ester of aniline (amine) charged into water and 30% hydrochloric acid added. Mass is stirred for 4 hours and then cooled by ice to 0-5 degree C. Sodium nitrite solution added to this amine below 5 degree C and completely diazotised. Mass stirred SI positive for 1 hour and then made SI negative with sulphamic acid solution. To this diazo H Acid powder ( coupler ) added below 5 degree C and stirred for 4 hours without temperature control. When acidic coupling completed ph adjusted to 4.5 by sodium carbonate and further maintained for 2 hours. Dyes produced transferred to holding reactor for shade and strength adjustment and transferred to spray dryer for drying and directly packed. Flow Diagram: KADAM ENVIRONMENTAL CONSULTANTS JULY

23 (2) Cold Brand Reactive Dyes Manufacturing Process K Acid ( amine ) charged into water and 30% hydrochloric acid added to it. Mass stirred for 2 hours and then cooled by ice to 5 Degree C. To this sodium nitrite solution added slowly and diazo prepared. Diazo stirred for 2 hours and then made SI negative by Sulphamic acid solution. To this diazo added meta uredo aniline ( coupler ) powder and simultaneously ph adjusted to 6.5 by sodium bi carbonate. When coupling completed again it is cooled to 0 degree C by Ice and charged cyanuric chloride and stirred. When reaction completed ph adjusted to 6.5 If required dye is isolated by adding salt and filtered in filter press and mother liquor goes to ETP. Press cake thus obtained charged into cold water, slurry transferred to spray dryer for shade, strength adjustment and Spray powder directly packed. Flow Diagram: KADAM ENVIRONMENTAL CONSULTANTS JULY

24 (3) Hot Brand Reactive Dyes Manufacturing Process 6 CAPSA ( amine) charged into water and 30% hydrochloric acid added to it. Mass is colled to 0 degree C by ice and then sodium nitrite solution added to it. When diazotisation completed, made SI negative with sulphamic acid solution and H Acid (coupler) clear solution added for coupling. Ph adjusted to 6.5 by soda ash and when coupling complted charged copper sulphate solution for metallization. When reaction completed again cooled to 0 degree C by ice and cyanuric chloride powder charged. Ph adjusted to 6.5 by soda solution. After reaction completion added Metanilic acid powder for condensation and ph adjusted to 6.5. Dye produced transferred to spray dryer for drying and packing. Flow Diagram: KADAM ENVIRONMENTAL CONSULTANTS JULY

25 (4) Bifunctional Reactive Dyes Manufacturing Process Vinyl sulphone ester of aniline is charged into water and ph adjusted to 4.5 by soda bi carbonate. This is cooled to 0 degree C and cyanuric chloride powder added. Mass is stirred for 6 hours and when reaction completed charged H Acid powder and ph adjusted to 5.5 by soda bi carb. Mass is stirred till reaction completed and then coled by ice. Seperately Sulpho Tobias acid diazo prepared by charging Sulpho tobias acid in water, adding hydrochloric acid and at 5 degree C sodium nitrite solution added. When diazo ready made SI negtive and transferred to condensed mass prepared in 1st step and ph adjusted to 6.5. Dye solution transferred to spray dryer and powder directly packed. Flow Diagram: KADAM ENVIRONMENTAL CONSULTANTS JULY

26 4.2 Disperse Dyes Azo Cynation Yellow Methine KADAM ENVIRONMENTAL CONSULTANTS JULY

27 4.1.3 Blue Methine Cyanine Plant KADAM ENVIRONMENTAL CONSULTANTS JULY

28 4.1.5 Multi P Plant HCl- Nitrite Base Azo Dye KADAM ENVIRONMENTAL CONSULTANTS JULY

29 4.1.7 NSA Based Azo Dye KADAM ENVIRONMENTAL CONSULTANTS JULY

30 Annexure 7: Raw Material & Product Storage Details Sr. No. Raw Materials CAS Number Physical State Means of Storage Capacity of storage Means Total Capacity Safety Measures Pressure Temperature Existing Dike Dimension / Storage Area 1 Acetanilide - SOLID Bag 50 Kg 50 MT - Atm Amb 50 Sq. Mt RM Store Domestic By Road 2 Caustic Lye LIQUID TANK 40 MT 40 MT Isolated Area with All Safety Measure Place of Storage Source of Supply Means of Transportation Atm Amb 50 Sq. Mt Tank Farm Domestic By Road 3 Chloro Sulfonic acid LIQUID TANK 51 MT 51 MT Isolated Area with All Atm Amb 50 Sq. Mt Tank Farm Domestic By Road 4 Chlorosulfonic acid LIQUID TANK 43 MT 43 MT Safety Measure Atm Amb 50 Sq. Mt Tank Farm Domestic By Road 5 Copper Phthalocyanine POWDER Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 6 Ethylene Oxide GAS TANK FARM 7.5 MT 7.5 MT Isolated Flame Proof Area 3.5 Kg (By Nitrogen) 10oC (Chilling System) 50 Sq. Mt Tank Farm Domestic By Road 7 SODA ASH SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 8 Sodium Bi Sulphate SOLID Bag 50 Kg 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 9 Sulphuric Acid LIQUID TANK FARM 54 MT 54 MT Atm Amb 50 Sq. Mt Tank Farm Domestic By Road Isolated Area with All 10 THIONIYL CHLORIDE LIQUID TANK FARM Atm Amb Tank Farm Domestic By Road 25 MT 25 MT Safety Measure 25 Sq. Mt 11 THIONIYL CHLORIDE LIQUID TANK FARM Atm Amb Tank Farm Domestic By Road 12 VINYL SULPHONE SOLID Bag 50 Kg 25 MT - Atm Amb 25 Sq. Mt RM Store Domestic By Road Proposed 13 2Amino P Crisol SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 14 2-Pyridone SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 15 3-methoxy propyl amine LIQUID CARBOY 50 Liter 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 16 4 Sulpho Hydrazone SOLID Bag 50 Kg 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 17 4-Aamino 2 Sulpho Di phenyl Amine SOLOD Bag 50 KG 02 MT - Atm Amb 2 Sq. Mt RM Store Domestic By Road 18 4Chloro Amino Phenol SOLID Bag 50 Kg 01MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 19 5 Sulho anthranilic acid SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 20 5 Sulpho Hydrazone SOLID Bag 50 Kg 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 21 6 Acetyl OAPSA SOLID Bag 50 Kg 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 22 6 Chloro 2:4 DNA - SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 23 6 Nitro Amino Phenol 2 Sulphonic Acid SOLID Bag 25 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 24 Acetic acid LIQUID Tank 10 MT 10 MT Isolated Area with All Safety Measure Atm Amb 10 Sq. Mt Tank Form Domestic By Road 25 Acetic Anhydride LIQUID CARBOY 50 KG 15 MT - Atm Amb 15 Sq. Mt RM Store Domestic By Road 26 Acetyl MPDSA POWDER Bag 50 Kg 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 27 Amino Di Chloro carbamide SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 28 Ammonia solution (23%) (Added) LIQUID Tank 20 KL 20 KL 29 Ammonia GAS CYLINDER 10 Nos 10 Nos 30 Ammonia solution LIQUID Carboy 50 Liter 05 MT Isolated Area with All Safety Measure Isolated Area with All Safety Measure Isolated Area with All Safety Measure Atm Amb 10 Sq. Mt Tank Farm Domestic By Road Atm Amb 5 Sq. Mt ICE Plant Domestic By Road Atm Amb 5 Sq. Mt RM Store Domestic By Road 31 AMONIUM SULPHATE SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 32 Aniline - 2,5 Di Sulphonic Acid SOLOD Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 33 Anthanilic Acid SOLID Bag 50 Kg 02 MT - Atm Amb 2 Sq. Mt RM Store Domestic By Road 34 2-(1,1- dioxidobenzo[b]thiophen- 3(2H)-ylidene) malono nitrile (Aqone) SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road KADAM ENVIRONMENTAL CONSULTANTS JUNE

31 Sr. No. Raw Materials CAS Number Physical State Means of Storage Capacity of storage Means Total Capacity Safety Measures Pressure Temperature Dike Dimension / Storage Area Place of Storage Source of Supply Means of Transportation Existing 35 Basic Chromium Sulphate SOLID Bag 50 Kg 03 MT - Atm Amb 3 Sq. Mt RM Store Domestic By Road 36 Benzanilide VS Ester SOLID Bag 50 Kg 03 MT - Atm Amb 3 Sq. Mt RM Store Domestic By Road 37 6 Bromo 2:4 dinitro anoline (Br DNA) SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 38 Bromamine acid SOLID Bag 50 Kg 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 39 C Acid SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 40 Calcium Carbonate SOLID Bag 50 Kg 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 41 Calsolene oil LIQUID CARBOY 50 Liter 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 42 Caustic flake SOLID Bag 50 Kg 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 43 Caustic Lye LIQUID TANK 20 MT 40 MT Isolated Area with All Safety Measure Atm Amb 40 Sq. Mt TANK FARM Domestic By Road 44 Chloranil condensate POWDER Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 45 Chlorosulfonic acid LIQUID TANK FARM 41 MT 41 MT Isolated Area with All Safety Measure Atm Amb 5 Sq. Mt 46 6 Chloro 2:4 DNA (ClDNA) SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 47 Copper Powder Powder Bag 50 Kg 03 MT - Atm Amb 3 Sq. Mt RM Store Domestic By Road 48 Copper Phthalo cyanine SOLID Bag 50 Kg 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 49 Copper Sulfate SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 50 Cuprous Chloride SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 51 Cyano Bromo PNA SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 52 Cyano PNA - SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 53 Cyanuric Chloride SOLID Bag 50 Kg 50 MT - Atm Amb 25 Sq. Mt RM Store EXPORT By Road 54 2-Cyano Bromo PNA (CyBrPNA) TANK FARM (Already Existing) SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 55 DASA SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 56 DASDA SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road Dihexyl-m-toluidine -paldehyde (DBM) Dibromo-p-toluidine (DBPT) Dichloro diamino anthraquinone (DCDAQ) Di hydroxy diamino anthraquinone (DHDA) LIQUID Carboy 50 Liter 02 MT - Atm Amb 2 Sq. Mt RM Store Domestic By Road SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 61 DMAVS SOLID Bag 50 KG 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 62 Dimethyl pyridone (DMP ) - LIQUID Carboy 50 Liter 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 63 Di Methyl Formamide LIQUID Tanker 20 KL 20 KL - Atm Amb 10 Sq. Mt 64 Methyl acetoacetate (Ester derivatives) - LIQUID Carboy 50 Liter 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 65 Ethylene Di Amine LIQUID Barrel 200 Liter 15 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 66 Gamma Acid SOLID Bag 50 KG 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 67 GS (Sodium Sulphate) SOLID Bag 50 Kg 50 MT - Atm Amb 50 Sq. Mt RM Store Domestic By Road 68 H Acid SOLID Bag 50 Kg 20 MT - Atm Amb 15 Sq. Mt RM Store Domestic By Road Domestic By Road 69 HCl 30% LIQUID TANK FARM 20 KL 20 KL 70 Hydrogen Peroxide LIQUID CARBOY 35 Kg 05 MT Isolated Area with All Safety Measure Isolated Area with All Safety Measure Atm Amb 10 Sq. Mt Tank Farm Domestic By Road Atm Amb 5 Sq. Mt RM Store Domestic By Road KADAM ENVIRONMENTAL CONSULTANTS JUNE

32 Sr. No. Raw Materials CAS Number Physical State Means of Storage Capacity of storage Means Total Capacity Safety Measures Pressure Temperature Dike Dimension / Storage Area Place of Storage Source of Supply Means of Transportation Existing 71 Hyflow SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 72 Ice SOLID - 50 MT - Atm 0 C 25 Sq. Mt Ice Plant Domestic By Road 73 J Acid SOLID Bag 50 Kg 10 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 74 Jacko dust Oil - LIQUID CARBOY 50 Kg 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road N:N Diethyl p-methoxy - m amino acetanilide (JD10) N:N Diethyl - m amino acetanilide (JD12) 2-((3-Acetamidophenyl) (2-cyanoethyl) amino) ethylacetate (JD14) N:N allyl p-methoxy - m amino acetanilide (JD24) N:N Dibutyl amino thizole (JD33) N:N Dibutyl amino thizole aldehyde (JD36) N ethyl N cyanoethyl -mtoluidinr (JD37) SOLID Bag 50 Kg 1 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road SOLID Bag 50 Kg 5 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road - LIQUID CARBOY 50 Kg 1 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road SOLID bag 50 Kg 5 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road - LIQUID CARBOY 50 Kg 1 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road - LIQUID CARBOY 50 Kg 1 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road - LIQUID CARBOY 50 Kg 1 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 82 Pyridone aldehyde (JD44) SOLID Bag 50 Kg 1 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road N:N Diacetoxy - p-methoxy - m amino acetanilide (JD5) N ethyl N cyanoethyl aniliner (JD8) N:N Diethyl - m amino propanilide (JD9) LIQUID CARBOY 50 Kg 10 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road LIQUID CARBOY 50 Kg 5 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road SOLID Bag 50 Kg 1 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 86 K ACID SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 87 Liq. Bromine (Fresh+ Recycled) LIQUID Glass Bottle 500 Liter 0.5 KL - Atm Amb 1 Sq. Mt Plant Domestic By Road 88 M Acid SOLID Bags 50 Kg 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 89 MBVS Cond SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 90 Metanilic acid SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 91 Methanol LIQUID TANK FARM 20 KL 20 KL Atm Amb 20 Sq. Mt Tank Farm Domestic By Road (Phenylsulfonyl)benzenami ne (MHA) 4-amino-Nbutylbenzenesulfonamide (MHAL) m-phenylene diamine (MPD) - SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 95 MPDDSA SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 96 Meta Ureado Aniline (MUA) SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 97 Sodium Hydroxide (15%) LIQUID Carboy 50 Kg 02 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 98 NaNO SOLID Bag 50 Kg 25 MT - Atm Amb 20 Sq. Mt RM Store Domestic By Road 99 N-Ethyl MBVS SOLID Bag 50 Kg 03 Mt - Atm Amb 3 Sq. Mt RM Store Domestic By Road 100 NMJ acid SOLID Bag 50 Kg 05 Mt - Atm Amb 5 Sq. Mt RM Store Domestic By Road 101 Ortho Anisidine Vinyl Sulphone (OAVS) SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 102 o-chloro - p nitroaniline SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road KADAM ENVIRONMENTAL CONSULTANTS JUNE

33 Sr. No. Raw Materials CAS Number Physical State Means of Storage Capacity of storage Means Total Capacity Safety Measures Pressure Temperature Dike Dimension / Storage Area Place of Storage Source of Supply Means of Transportation Existing (OCPNA) 103 OLIUM (23%) LIQUID TANK FARM 15 MT 15 MT (Existing) Isolated Area with all safety measure Atm Amb 15 Sq. Mt Tank Farm Domestic By Road 104 o-nitro aniline (ONA) SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 105 o-phenylene diamine (OPDA) SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 106 Formic acid (Organic Acid) - LIQUID Carboy 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 107 Orthanilic Acid SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 108 p-amino azo benzene (PAAB) SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 109 P-Anisidine SOLID Bag 50 Kg 02 MT - Atm Amb 2 Sq. Mt RM Store Domestic By Road 110 Para Toluidine SOLID Bag 50 Kg 02 MT - Atm Amb 2 Sq. Mt RM Store Domestic By Road 111 p-chloro aniline (PCA) SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 112 p-chloro-o-nitro aniline (PCONA) SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 113 P-Cresidine SOLID Bag 50 Kg 02 MT - Atm Amb 2 Sq. Mt RM Store Domestic By Road 114 Para Crisidine Vinyl Sulphone (PCVS) SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 115 Phenol LIQUID TANK FARM 20 KL 20 KL amino 2 bromo 4 hydroxy anthraquinone (Pink Bromide) Isolated Area with Flame Proof safety measure Atm Amb 10 Sq. Mt Tank Farm Domestic By Road SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 117 PMP SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 118 PMPVS SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 119 PNA POWDER Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 120 PNAOSA SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 121 Potassium Carbonate SOLID Bag 50 Kg 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 122 Para Phenylene Di Amine (PPD) SOLID Bag 50 Kg 03 MT - Atm Amb 3 Sq. Mt RM Store Domestic By Road 123 PPDDSA SOLID Bag 50 Kg 03 MT - Atm Amb 3 Sq. Mt RM Store Domestic By Road 124 Sodium acetate anhydrous (SAA) SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 125 Salicylic Acid SOLID Bag 50 Kg 50 MT - Atm Amb 30 Sq. Mt RM Store Domestic By Road 126 Sodium Chloride (Salt) SOLID Bag 50 Kg 25 MT - Atm Amb 25 Sq. Mt RM Store Domestic By Road N:N Diethyl - m amino acetanilide (SD12) Diethyl-m-amino salicyldehyde (SD35) N:N Diacetoxy - - m amino acetanilide (SD3A) N:N hydroxy - p-methoxy - m amino acetanilide (SD5) N ethyl N cyanoethyl aniliner (SD8) N:N Diethyl - m amino propanilide (SD9) Soda Carbonate (Soda Ash) - SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road SOLID bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road - LIQUID CARBOY 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road - SOLID bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road - LIQUID CARBOY 50 Kg 01 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road - SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road SOLID Bag 50 Kg 20 MT - Atm Amb 20 Sq. Mt RM Store Domestic By Road 134 Soda bi carbonate SOLID Bag 50 Kg 20 MT - Atm Amb 20 Sq. Mt RM Store Domestic By Road KADAM ENVIRONMENTAL CONSULTANTS JUNE

34 Sr. No. Raw Materials CAS Number Physical State Means of Storage Capacity of storage Means Total Capacity Safety Measures Pressure Temperature Dike Dimension / Storage Area Place of Storage Source of Supply Means of Transportation Existing 135 Sodium per sulfate SOLID Bag 50 Kg 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 136 Sodium Sulphide SOLID Bag 50 Kg 03 MT - Atm Amb 3 Sq. Mt RM Store Domestic By Road 137 SPCP SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 138 SPMP SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 139 Sulpho Tobias Acid (STA) SOLID Bag 50 Kg 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 140 Sulfamic Acid SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 141 Sulphanilic acid - SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 142 Sulpho J acid SOLID Bag 50 Kg 02 MT - Atm Amb 2 Sq. Mt RM Store Domestic By Road 143 Sulpho OAVS SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 144 Sulpho Tobias Acid SOLID Bag 50 Kg 10 MT - Atm Amb 10 Sq. Mt RM Store Domestic By Road 145 Sulpho VS SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 146 Sulphuric acid LIQUID TANK FARM 54 MT 54 MT Isolated Area with all Safety Meaures Atm Amb 50 Sq. Mt Tank Farm Domestic By Road 147 Trimethyl indoline (TMI) LIQUID CARBOY 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 148 Tobias acid SOLID Bag 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 149 Vinyl Sulphone Ester of Aniline (VSA) SOLID Bag 50 Kg 25 MT - Atm Amb 25 Sq. Mt RM Store Domestic By Road 150 Dibromo butyl pta (DBBP) SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road dimethyl 2,2'-((5- acetamidophenyl)azanediyl )diacetate (JD26) N:N Dihydroxy - - m amino acetanilide (JD3) N:N Dihydroxy aniline (JD4) N;N diacetoxy aniline (JD4A) dimethyl 2,2'-((5- acetamido-2- methoxyphenyl)azanediyl) diacetate (JD52) LIQUID CARBOY 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road LIQUID CARBOY 50 Kg 01 MT - Atm Amb 5 Sq. Mt LIQUID CARBOY 50 Kg 01 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road LIQUID CARBOY 50 Kg 01 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road 156 Disperse Yellow SOLID Bag 50 Kg 01 MT - Atm Amb 1 Sq. Mt RM Store Domestic By Road 157 N-cyano ethyl N-acetoxy ethyl aniline (JD7) LIQUID CARBOY 50 Kg 05 MT - Atm Amb 5 Sq. Mt RM Store Domestic By Road KADAM ENVIRONMENTAL CONSULTANTS JUNE

35 SYNTHETIC ORGANIC DYES MFG. PLANT, AT VATVA GIDC, PHASE III, A BAD Annexure 8: Water Consumption and Waste Water Generation Details Existing water is sourced from Borewell and its NOC application has already been done to CGWA. For proposed expansion, source of water is GIDC water supply. Existing water demand is KLD and proposed water demand will be 1782 KLD. So after expansion total water consumption will be KLD. Table 2: Water Consumption Details S. No. Area of Consumption Fresh Water Quantity, KLD Existing UNIT - 3/1* UNIT - 3/2* Proposed Total 1 Domestic Gardening Processing Washing (Reactor and Floor) Boiler Cooling Tower Total Recycle Total water consumption Total Industrial Remark Borewell + GIDC fresh water KLD GIDC fresh water, 190 KLD RO permeate and 178 KLD MEE condensate Borewell + GIDC fresh water 190 KLD RO permeate and 178 KLD MEE condensate * Note: Jay chemical has applied to GPCB for amalgamation of unit-3/1 and unit-3/2 as unit-3. This application is in process hence details are given separately. Existing wastewater generation is 112 KLD. Proposed wastewater generation will be 406 KLD. From that 33 KLD domestic sewage will be going to soak pit and 485 KLD will be going to ETP. After ETP treatment, 105 KLD going to CETP and 380 KLD will be sent to MEE followed by RO. CETP Membership Certificate is given as Figure 5. Table 3: Effluent Generation Details S. No. Area of Consumption Effluent Generation, KLD Existing Total Proposed UNIT - 3/1 UNIT - 3/2 UNIT - 3 Disposal mode 1 Domestic SOAK-PIT 2 Processing Washing (Reactor and Floor) Boiler Cooling Tower Total Total Industrial To ETP followed by Ro & MEE / CETP From that 33 KLD domestic sewage will be going to soak pit and 485 KLD will be going to ETP After ETP treatment, 105 KLD going to CETP and 380 KLD will be sent to MEE followed by RO. KADAM ENVIRONMENTAL CONSULTANTS JUNE

36 SYNTHETIC ORGANIC DYES MFG. PLANT, AT Figure 1: Existing Water Balance Raw water from GIDC Process Boiler Cooling Tower Washing Domestic Unit-1 10 Unit Unit Unit-2 13 Unit Unit-2 2 Unit Unit Unit Unit Soak - pit ETP KADAM ENVIRONMENTAL CONSULTANTS JUNE

37 SYNTHETIC ORGANIC DYES MFG. PLANT, AT Figure 2: Proposed Water Balance Process Raw water from GIDC 1782 Boiler Cooling Tower Washing Domestic Gardening 5 Reactive 300 Disperse 1006 Ammonium Chloride solution (Sell to authorised vendor) Reactive 80 Disperse 167 Reactive 20 Disperse 25 Reactive Disperse 300 Gupsm Solution (Sell to cement industry) 26 Soak - pit ETP RO permeate 190 Condensate 178 RO 380 RO reject 190 MEE 12 MEE salt to TSDF KADAM ENVIRONMENTAL CONSULTANTS JUNE

38 SYNTHETIC ORGANIC DYES MFG. PLANT, AT Figure 3: Water Balance after Proposed Expansion Raw water from GIDC Process Boiler Cooling Tower Washing Domestic Gardening Ammonium Chloride solution (Sell to Gupsm Solution (Sell to cement industry) Soak - pit ETP 105 RO permeate 190 Condensate 178 RO 380 RO reject 190 MEE 12 CETP MEE salt to TSDF KADAM ENVIRONMENTAL CONSULTANTS JUNE

39 Figure 4: NOC letter for water permission to GIDC (VIEIDL) KADAM ENVIRONMENTAL CONSULTANTS JUNE

40 Figure 5: Existing Membership Certificate of M/s. The Green Environment Services Co-op. Society Ltd. For Effluent Treatment: KADAM ENVIRONMENTAL CONSULTANTS JUNE

41 Annexure 9: Details of Effluent Treatment Plant In the Unit effluent generated from various areas such as: Washing water Domestic Wastewater Utility Blow-Down The total wastewater generation from the plant is 518 KLD including Domestic Sewage. The industrial effluent is treated in ETP of capacity 250 KLD & treated water is going to CETP for further treatment. For Domestic sewage Soak-pit is provided. ETP Description The unit is provided common ETP to treat effluent from M/s Jay Chemical Industries Ltd (Unit-3/1) and Jay Chemical Industries Ltd (Unit-3/2). The unit is segregating the concentrated stream as per CCA and concentrated stream sending to spray dryer for Glauber Salt Recovery to CETP. The diluted stream is first collected into Neutralization Tank, where Hydrated Lime is added and making neutral ph. Then the effluent is pumped into the Filter Press. From the Filter Press, the filtrate flows to Primary Clarifier then it goes to Biological treatment. The sludge from filter press is disposed to TSDF site through manifest system. Over flow from Aeration tank is going into Secondary clarifier. The settled sludge from Secondary clarifier collected into the Neutralization tank along with primary sludge. Then treated effluent send to CETP, Vatva through overhead tank for further treatment. Sludge from filter press packed and stored on impervious layer with leachate collection system under roof and send to TSDF site. Leachate generated from the Sludge storage area is taken back to Collection tank of ETP for further treatment and disposal. Design Inlet & Outlet characteristics of ETP ETP is designed for 250 KLD Capacity. The design base inlet and outlet characteristics of Existing ETP is presented in below table. Table 4: Design Inlet & Outlet Characteristics of Proposed ETP Sr. No. Parameters Unit ETP Inlet ETP Outlet (Norms of CETP Inlet) 1 ph TSS ppm <300 3 TDS ppm Ammonical Nitrogen ppm <50 5 COD ppm < BOD ppm <500 Sizing of ETP Units The list of ETP units with sizing is given in below table. Table 5: List of ETP Units with Sizing Process block diagram of existing ETP is given in below figure. Sr. No. Name of Unit Quantity Size in m with SWD (m) Design Flow (250 m3/d) 1 Storage Tank dia. x 2.1 D.T. = 2.85 h KADAM ENVIRONMENTAL CONSULTANTS JUNE

42 Sr. No. Name of Unit Quantity Size in m with SWD (m) Design Flow (250 m3/d) 2 Neutralization Tank x 7.0 x 2.1 D.T. = 3.81 h 3 Holding Tank x 3.0 x 1.0 D.T. = 0.86 h 4 Collection Tank 1 5 x 7 x5 D.T. = 16.8 h 5 Plate and Frame Filter Press Equalization Tank x 5.2 x 4.5 D.T. = 11.6 h 7 Clariflocculator Dia x 2.5 SWD D.T. = 4.71 h SOR = m3/m2.d 8 1st Aeration Tank x 20.6 x 3.5 D.T. = h 9 Secondary Clarifier dia. x 2.5 SWD D.T. = 4.71 h SOR= m3/m2.d 10 2nd Aeration Tank x 5.0 x 2.5 D.T. = 6 h 11 Hopper Bottom Settling Tank x 3.0 x 4.5 D.T. = 3.89 h 12 Treated Effluent Storage Tank x 2.0 x 2.0 D.T. = 1.15 h 13 Discharge over Head Tank x 1.3 x KADAM ENVIRONMENTAL CONSULTANTS JUNE

43 SYNTHETIC ORGANIC DYES MFG. PLANT, AT Process Block diagram of ETP- 250KLD KADAM ENVIRONMENTAL CONSULTANTS JUNE

44 Annexure 10: Fuel Consumption Table 6: Fuel Consumption Sr. No. Unit Stack Attached to Capacity Type of Fuel used Fuel consumptio n in Hr Stac k No. Stack Height Existing 1 Unit - Steam Boiler 600 KG/HR KL/Hr /1 HAG 800 lit/hr 0.07KL/Hr 1 20 Thermic Fluid Heater Lac K Cal NATURAL 10 SCM/Hr Thermic Fluid Heater - GAS 4 2 Lac K Cal 1 30 Unit - 2 3/2 5 Steam Boiler 600 KG/HR 25 SCM/Hr HAG (GS Recovery) 800 lit/hr 110 SCM/Hr D.G.Set 250 KVA Diesel 40 lit/hr Unit - 3 HAG - 1 (Reactive Plant) HAG - 2 (Reactive Plant) HAG - 3 (Reactive Plant) 20 Lac K Cal Proposed NATURAL GAS 320 SCM/Hr Lac K Cal 240 SCM/Hr Lac K Cal 240 SCM/Hr Boiler (Reactive Plant) 4 TPH 150 SCM/Hr HAG - 1 (Disperse Plant) HAG - 2 (Disperse Plant) HAG - 3 (Disperse Plant) HAG - 4 (Disperse Plant) HAG - 5 (Disperse Plant) Boiler (Common) (Disperse Plant) 7.5 Lac K Cal 7.5 Lac K Cal 120 SCM/Hr SCM/Hr Lac K Cal 240 SCM/Hr Lac K Cal 240 SCM/Hr Lac K Cal 240 SCM/Hr TPH x 02 Nos 300 SCM/Hr 1 20 (Common ) 17 D.G.Set 500 KVA Diesel 80 lit/hr KADAM ENVIRONMENTAL CONSULTANTS JUNE

45 SYNTHETIC ORGANIC DYES MFG. PLANT, AT Annexure 11: Hazardous Waste Generation Table 7: Hazardous Waste Generation and Disposal S. No. Type of Waste Hazardous Waste Category Unit Existing Quantity per Year UNIT - 3/1 UNIT - 3/2 Proposed Total Source Method of Collection Treatment / Disposal 1 ETP Sludge 35.3 MT/Yr ETP 2 Gypsum Sludge 26.1 MT/Yr Pre- 3 Ammonium Chloride 35.3 MT/Yr treatment plant 4 Distillation Residue 36.1 MT/Yr Evaporation Packed in HDPE Bags Packed in HDPE Bags Packed in HDPE Bags Packed in HDPE Bags Packed in HDPE Bags, and Dispose to TSDF Packed in HDPE Bags, and Dispose to Cement Industry Reused in plant Packed in HDPE Bags, and Dispose to TSDF 5 Spray Dry Salt 37.3 MT/Yr Evaporation Packed in HDPE Bags 6 Used Oil 5.1 MT/Yr Machinrary Drums 7 8 Discarded Container Discarded Liners/Bags 33.1 MT/Yr Production Scrap Yard 33.1 MT/Yr Production Scrap Yard Packed in HDPE Bags, and Dispose to TSDF Disposal by selling to register recycler Disposal by selling to register recycler Disposal by selling to register recycler 9 10 Spent Acid (Spent Sulphuric Acid) Spent Acid (Spent Hydrochloric Acid) 26.3 MT/Yr Production HDPE Tank 26.3 MT/Yr Production HDPE Tank Disposal by selling to NOVEL, Ecocare, Arvind and Aarvee denim and Actual end user KADAM ENVIRONMENTAL CONSULTANTS JUNE

46 Figure 6: Existing Provisional Membership Certificate of M/s. Saurastra Enviro Projects Pvt. Ltd. For Hazardous Waste KADAM ENVIRONMENTAL CONSULTANTS JUNE

47 Figure 7: Existing Membership Certificate from EcoCARE KADAM ENVIRONMENTAL CONSULTANTS JUNE

48 Figure 8: MOU with NOVEL for Spent Sulphuric acid KADAM ENVIRONMENTAL CONSULTANTS JUNE

49 Figure 9: MOU with Arvind Ltd. for spent acid KADAM ENVIRONMENTAL CONSULTANTS JUNE

50 KADAM ENVIRONMENTAL CONSULTANTS JUNE

51 Figure 10: MOU with Aarvee Denim for Spent acid KADAM ENVIRONMENTAL CONSULTANTS JUNE

52 KADAM ENVIRONMENTAL CONSULTANTS JUNE

53 Annexure 12: Stack Details Table 8: Details of Flue Gas Stacks Sr. No. Unit Stack Attached to Capacity Type of Fuel used Existing Fuel consumptio n Stac k No. Stack Height in m Stack Diamete r in m 1 Unit - Steam Boiler 600 KG/HR KL/Hr N/A 2 3/1 HAG 800 lit/hr 0.07KL/Hr N/A Thermic Fluid Heater Lac K Cal N/A 1 NATURAL 10 SCM/Hr GAS Unit - Thermic Fluid Heater Lac K Cal N/A 3/2 2 5 Steam Boiler 600 KG/HR 25 SCM/Hr N/A 6 HAG (GS Recovery) 800 lit/hr 110 SCM/Hr N/A 7 D.G.Set 250 KVA Diesel 40 lit/hr N/A Unit - 3 HAG - 1 (Reactive Plant) HAG - 2 (Reactive Plant) HAG - 3 (Reactive Plant) 20 Lac K Cal Proposed NATURAL GAS APC M 320 SCM/Hr N/A 15 Lac K Cal 240 SCM/Hr N/A 15 Lac K Cal 240 SCM/Hr N/A 11 Boiler (Reactive Plant) 4 TPH 150 SCM/Hr N/A HAG - 1 (Disperse Plant) HAG - 2 (Disperse Plant) HAG - 3 (Disperse Plant) HAG - 4 (Disperse Plant) HAG - 5 (Disperse Plant) Boiler (Common) (Disperse Plant) 7.5 Lac K Cal 7.5 Lac K Cal 120 SCM/Hr N/A 140 SCM/Hr N/A 15 Lac K Cal 240 SCM/Hr N/A 15 Lac K Cal 240 SCM/Hr N/A 15 Lac K Cal 240 SCM/Hr N/A 4 TPH x 02 Nos 300 SCM/Hr 1 20 (Common ) 0.2 N/A 17 D.G.Set 500 KVA Diesel 80 lit/hr N/A Table 9: Details of Process Vents Sr. No Unit Unit 3/1 Unit - 3/2 Stack Attached to Reaction Vessel (Sulphonation Vessel) Spray Dryer (800 Lit/Hr) (Product) Sulphonation Vessel - 1 Sulphonation Vessel - 2 Nos. of Stacks Stack Height in m Existing Pollutants Emitted 1 20 SO2, HCl, Cl PM 1 15 SO2, HCl, Cl SO2, HCl, Cl2 Air Pollution Control Measures Attached Water Ventury, Two Stage Water Scubber followed by Alkali Ventury, Two Stage Alakali Scrubber Cyclone Separator with Water Scrubber Water Ventury, Two Stage Water Scubber followed by Alkali Ventury, Two Stage Alakali Scrubber Water Ventury, Two Stage Water Scubber followed by Alkali Ventury, Two Stage Alakali Scrubber KADAM ENVIRONMENTAL CONSULTANTS JUNE

54 Sr. No Unit Unit - 3 Stack Attached to Dumping Vessel Spray Dryer (800 Lit/Hr)(GS - Recovery) HCl Scrubber-1 (Reactive Plant) HCl Scrubber-2 (Reactive Plant) HCl Scrubber-3 (Blue Plant) (Sulphonation Vessel-) Ammonia Scrubber Spray Dryer - 1 (Reavtive Plant) (2000 Lit/Hr) Spray Dryer - 2 (Reactive Plant) (1500 Lit/Hr) Spray Dryer - 3 (Reactive Plant) (1500 Lit/Hr) HCl Scrubber-4 (HCl - Nitrite Base Azo Disperse Plant) Spray Dryer - 1 (Disperse Plant) (750 Lit/Hr) Spray Dryer - 2 (Disperse Plant) (750 Lit/Hr) Spray Dryer - 3 (Disperse Plant) (1500 Lit/Hr) Spray Dryer - 4 (Disperse Plant) (1500 Lit/Hr) Spray Dryer - 5 (Disperse Plant) (1500 Lit/Hr) Nos. of Stacks Stack Height in m Pollutants Emitted 1 15 SO2, HCl, Cl PM Proposed 1 25 SO2, HCl, Cl SO2, HCl, Cl SO2, HCl, Cl NH PM 1 40 PM 1 40 PM 1 25 SO2, HCl, Cl PM 1 40 PM 1 40 PM 1 40 PM 1 40 PM Air Pollution Control Measures Attached Water Scubber followed by Alakali Scrubber Cyclone Separator + Water Scrubber Primary + Water Scrubber Secondary Packed/Demister Venturi Scrubber Water Scrubber-I + Alkali packed column-i + Alkali Venturi Scrubbing Alkali Packed Column-II Venturi Scrubber Water Scrubber-I + Alkali packed column-i + Alkali Venturi Scrubbing Alkali Packed Column-II Venturi Scrubber Water Scrubber-I + Alkali packed column-i + Alkali Venturi Scrubbing Alkali Packed Column-II Venturi Scrubber + Packed Column Dip Tank Cyclone Separator + Water Scrubber Primary + Water Scrubber Secondary Packed/Demister Cyclone Separator + Water Scrubber Primary + Water Scrubber Secondary Packed/Demister Cyclone Separator + Water Scrubber Primary + Water Scrubber Secondary Packed/Demister Venturi Scrubber Water Scrubber-I + Alkali packed column-i + Alkali Venturi Scrubbing Alkali Packed Column-II Cyclone Separator + Water Scrubber Primary + Water Scrubber Secondary Packed/Demister Cyclone Separator + Water Scrubber Primary + Water Scrubber Secondary Packed/Demister Cyclone Separator + Water Scrubber Primary + Water Scrubber Secondary Packed/Demister Cyclone Separator + Water Scrubber Primary + Water Scrubber Secondary Packed/Demister Cyclone Separator + Water Scrubber Primary + Water Scrubber Secondary Packed/Demister KADAM ENVIRONMENTAL CONSULTANTS JUNE

55 Kadam Environmental Consultants w w w. k a d a m e n v i r o. c o m E n vi r o n m e n t f o r D e v e l o p m en t CONTACT DETAILS Vadodara (Head Office) 871/B/3, GIDC Makarpura, Vadodara, India E: kadamenviro@kadamenviro.com; T: ; F: Delhi / NCR Spaze IT Park, Unit No. 1124, 11 th Floor, Tower B-3, Sector 49, Sohna Road, Gurgaon, India E: delhi@kadamenviro.com; T/F :