APPENDIX B. Soil Sample Certificate of Analysis

Transcription

1 APPENDIX B Soil Sample Certificate of Analysis

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3 5 SHOREHAM DR DOWNSVIEW, ON M3N1S4 SOIL ANALYSIS REVIEWED BY: Mike Muneswar, BSc (Chem), Senior Inorganic Analyst TRACE ORGANICS REVIEWED BY: Jacky Takeuchi, BScH (Chem Eng), BSc (Bio), C.Chem, Laboratory Manager DATE REPORTED: Apr 20, 2011 PAGES (INCLUDING COVER): 13 VERSION*: 1 Should you require any information regarding this analysis please contact your client services representative at (905) , or at *NOTES All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time. Laboratories (V1) Page 1 of 13 Member of: Association of Professional Engineers, Geologists and Geophysicists of Alberta (APEGGA) Western Enviro-Agricultural Laboratory Association (WEALA) Environmental Services Association of Alberta (ESAA) AGAT Laboratories is accredited to ISO/IEC by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from and/or The tests in this report may not necessarily be included in the scope of accreditation.

4 DATE SAMPLED: Apr 12, 2011 Antimony Arsenic Barium Beryllium Boron WEC 1-1 WEC 1-2 WEC 1-3 WEC 2-1 WEC 2-2 WEC 2-3 WEC 2-4 Parameter Unit G / S RDL Boron (Hot Water Extractable) Cadmium Chromium Cobalt Copper Lead Molybdenum Nickel Selenium Silver Thallium Uranium Vanadium Zinc Chromium, Hexavalent Cyanide, Free Mercury Electrical Conductivity (2:1) Sodium Adsorption Ratio (2:1) ph, 2:1 CaCl2 Extraction Chloride (2:1) Nitrate + Nitrite Comments: µg/g <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 <0.8 µg/g µg/g µg/g <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 µg/g µg/g µg/g <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 µg/g µg/g µg/g µg/g µg/g µg/g µg/g <0.4 <0.4 < <0.4 <0.4 µg/g <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 µg/g <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 <0.4 ug/g 0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 <0.5 µg/g µg/g µg/g <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 µg/g <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 <0.05 µg/g ms/cm N/A DATE RECEIVED: Apr 12, N/A ph Units µg/g µg/g RDL - Reported Detection Limit; G / S - Guideline / Standard: Refers to T1(All) Certificate of Analysis O. Reg. 153 Metals & Inorganics in Soil - Table 1 DATE REPORTED: Apr 20, EC, SAR, Chloride & Nitrate/Nitrite were determined on the extract obtained from the 2:1 leaching procedure (2 parts DI water:1 part soil). ph was determined on the extract obtained from the 2:1 leaching procedure (2 parts 0.01M CaCl2:1 part soil). SAMPLE TYPE: Soil CERTIFICATE OF ANALYSIS (V1) Certified By: Page 2 of 13

5 DATE SAMPLED: Apr 12, 2011 Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane Trichlorofluoromethane Acetone 1,1-Dichloroethylene Methylene Chloride WEC 1-1 WEC 1-2 WEC 1-3 WEC 2-1 WEC 2-2 WEC 2-3 WEC 2-4 Parameter Unit G / S RDL TRANS-1,2-Dichloroethylene Methyl tert-butyl Ether 1,1-Dichloroethane Methyl Ethyl Ketone CIS 1,2-Dichloroethylene Chloroform 1,2- Dichloroethane 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloropropane Trichloroethylene Bromodichloromethane CIS-1,3-Dichloropropene Methyl Isobutyl Ketone TRANS-1,3-Dichloropropene 1,1,2-Trichloroethane Toluene 2-Hexanone Dibromochloromethane Ethylene Dibromide Tetrachloroethylene 1,1,1,2-Tetrachloroethane Chlorobenzene DATE RECEIVED: Apr 12, 2011 Certificate of Analysis O. Reg Volatile Organic Compounds in Soil DATE REPORTED: Apr 20, 2011 SAMPLE TYPE: Soil µg/g <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 µg/g <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 µg/g <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 µg/g <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 µg/g <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 µg/g <0.004 <0.004 <0.004 <0.004 <0.004 <0.004 <0.004 µg/g <0.130 <0.130 <0.130 <0.130 <0.130 <0.130 <0.130 µg/g <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 µg/g <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 µg/g <0.004 <0.004 <0.004 <0.004 <0.004 <0.004 <0.004 µg/g 0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 µg/g <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 µg/g <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 µg/g <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 µg/g <0.004 <0.004 <0.004 <0.004 <0.004 <0.004 <0.004 µg/g <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 µg/g <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 µg/g 0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 µg/g <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 µg/g <0.470 <0.470 <0.470 <0.470 <0.470 <0.470 <0.470 µg/g <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 <0.003 µg/g <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 µg/g <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 CERTIFICATE OF ANALYSIS (V1) Certified By: Page 3 of 13

6 DATE SAMPLED: Apr 12, 2011 Ethylbenzene m & p-xylene Bromoform Styrene WEC 1-1 WEC 1-2 WEC 1-3 WEC 2-1 WEC 2-2 WEC 2-3 WEC 2-4 Parameter Unit G / S RDL ,1,2,2- Tetrachloroethane o-xylene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 1,2-Dichlorobenzene 1,2,4-Trichlorobenzene Xylene Mixture (Total) 1,3-Dichloropropene (Cis + Trans) n-hexane Surrogate µg/g <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 µg/g <0.004 <0.004 <0.004 <0.004 <0.004 <0.004 <0.004 µg/g <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 µg/g <0.007 <0.007 <0.007 <0.007 <0.007 <0.007 <0.007 µg/g <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 <0.002 µg/g <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 <0.005 Unit Toluene-d8 % Recovery Bromofluorobenzene % Recovery Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard: Refers to T1(All) Results are based on the dry weight of the soil. DATE RECEIVED: Apr 12, 2011 Certificate of Analysis O. Reg Volatile Organic Compounds in Soil DATE REPORTED: Apr 20, 2011 SAMPLE TYPE: Soil CERTIFICATE OF ANALYSIS (V1) Certified By: Page 4 of 13

7 DATE SAMPLED: Apr 12, 2011 Naphthalene Acenaphthylene Acenaphthene Fluorene Phenanthrene Anthracene Fluoranthene Pyrene Benzo(a)anthracene Chrysene Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene Indeno(1,2,3-cd)pyrene Dibenz(a,h)anthracene Benzo(g,h,i)perylene WEC 1-1 WEC 1-2 WEC 1-3 WEC 2-1 WEC 2-2 WEC 2-3 WEC 2-4 Parameter Unit G / S RDL and 1-methyl Naphthalene Surrogate µg/g µg/g <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 µg/g <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 <0.03 µg/g <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 µg/g µg/g < µg/g µg/g µg/g µg/g µg/g µg/g µg/g µg/g µg/g < < µg/g µg/g Unit Chrysene-d12 % Comments: RDL - Reported Detection Limit; G / S - Guideline / Standard: Refers to T1(All) Results are based on the dry weight of the soil. DATE RECEIVED: Apr 12, 2011 Certificate of Analysis O. Reg PAHs in Soil DATE REPORTED: Apr 20, 2011 SAMPLE TYPE: Soil CERTIFICATE OF ANALYSIS (V1) Certified By: Page 5 of 13

8 DATE SAMPLED: Apr 12, 2011 C6 - C10 (F1) WEC 1-1 WEC 1-2 WEC 1-3 WEC 2-1 WEC 2-2 WEC 2-3 WEC 2-4 Parameter Unit G / S RDL C6 - C10 (F1 minus BTEX) C>10 - C16 (F2) C>10 - C16 (F2 minus Naphthalene) C>16 - C34 (F3) C>16 - C34 (F3 minus PAHs) C>34 - C50 (F4) Gravimetric Heavy Hydrocarbons Moisture Content Comments: DATE RECEIVED: Apr 12, 2011 µg/g 5 <5 <5 <5 <5 <5 <5 <5 µg/g 5 <5 <5 <5 <5 <5 <5 <5 µg/g 10 <10 <10 <10 <10 <10 <10 <10 µg/g 10 <10 <10 <10 <10 <10 <10 <10 µg/g <50 < µg/g <50 < µg/g <50 < µg/g 50 NA NA NA NA NA NA NA % RDL - Reported Detection Limit; G / S - Guideline / Standard: Refers to T1(All) Certificate of Analysis O. Reg Petroleum Hydrocarbons F1 - F4 (C6 - C50) in Soil (PAHs Incl.) DATE REPORTED: Apr 20, 2011 SAMPLE TYPE: Soil Results are based on sample dry weight. The C6-C10 fraction is calculated using toluene response factor. The C10 - C16, C16 - C34, and C34 - C50 fractions are calculated using the average response factor for n-c10, n-c16, and n-c34. Gravimetric Heavy Hydrocarbons are not included in the Total C16-C50 and are only determined if the chromatogram of the C34 - C50 hydrocarbons indicates that hydrocarbons >C50 are present. Total C6 - C50 results are corrected for BTEX and PAH contributions. This method complies with the Reference Method for the CWS PHC and is validated for use in the laboratory. nc6 and nc10 response factors are within 30% of Toluene response factor. nc10, nc16 and nc34 response factors are within 10% of their average. C50 response factor is within 70% of nc10 + nc16 + nc34 average. Linearity is within 15%. Extraction and holding times were met for this sample. CERTIFICATE OF ANALYSIS (V1) Certified By: Page 6 of 13

9 Guideline Violation SAMPLEID SAMPLE TITLE GUIDELINE ANALYSIS PACKAGE PARAMETER GUIDEVALUE RESULT WEC 1-1 T1(All) O. Reg PAHs in Soil Naphthalene WEC 1-2 T1(All) O. Reg. 153 Metals & Inorganics in Soil - Table 1 Sodium Adsorption Ratio (2:1) WEC 1-3 T1(All) O. Reg PAHs in Soil Naphthalene WEC 1-3 T1(All) O. Reg. 153 Metals & Inorganics in Soil - Table 1 Sodium Adsorption Ratio (2:1) WEC 2-1 T1(All) O. Reg. 153 Metals & Inorganics in Soil - Table 1 Sodium Adsorption Ratio (2:1) WEC 2-2 T1(All) O. Reg. 153 Metals & Inorganics in Soil - Table 1 Sodium Adsorption Ratio (2:1) WEC 2-3 T1(All) O. Reg PAHs in Soil Naphthalene WEC 2-4 T1(All) O. Reg. 153 Metals & Inorganics in Soil - Table 1 Sodium Adsorption Ratio (2:1) GUIDELINE VIOLATION (V1) Page 7 of 13

10 Quality Assurance Soil Analysis RPT Date: Apr 20, 2011 DUPLICATE REFERENCE MATERIAL METHOD BLANK SPIKE MATRIX SPIKE PARAMETER Batch Sample Id Dup #1 Dup #2 RPD Method Blank Measured Value Recovery Recovery O. Reg. 153 Metals & Inorganics in Soil - Table 1 Antimony < 0.8 < % < % 80% 120% 101% 90% 110% 101% 70% 130% Arsenic % < 1 99% 90% 110% 99% 90% 110% 101% 70% 130% Barium % < 2 100% 90% 110% 101% 90% 110% 100% 70% 130% Beryllium < 0.5 < % < % 90% 110% 120% 80% 120% 106% 70% 130% Boron % < 5 95% 90% 110% 118% 80% 120% 102% 70% 130% Boron (Hot Water Extractable) % < % 80% 120% 116% 80% 120% 98% 70% 130% Cadmium < 0.5 < % < % 90% 110% 100% 90% 110% 102% 70% 130% Chromium % < 2 95% 90% 110% 102% 90% 110% 85% 70% 130% Cobalt % < % 90% 110% 95% 90% 110% 95% 70% 130% Copper % < 1 101% 90% 110% 104% 90% 110% 92% 70% 130% Lead % < 1 108% 90% 110% 103% 90% 110% 96% 70% 130% Molybdenum % < % 90% 110% 98% 90% 110% 104% 70% 130% Nickel % < 1 101% 90% 110% 97% 90% 110% 93% 70% 130% Selenium < 0.4 < % < % 90% 110% 98% 90% 110% 97% 70% 130% Silver < 0.2 < % < % 90% 110% 107% 90% 110% 106% 70% 130% Thallium < 0.4 < % < % 80% 120% 100% 90% 110% 96% 70% 130% Uranium < 0.5 < % < % 90% 110% 104% 90% 110% 99% 70% 130% Vanadium % < 1 97% 90% 110% 97% 90% 110% 96% 70% 130% Zinc % < 5 101% 80% 120% 106% 90% 110% 93% 70% 130% Chromium, Hexavalent < 0.2 < % < % 80% 120% 104% 90% 110% 97% 70% 130% Cyanide, Free < 0.05 < % < % 80% 120% 110% 90% 110% 97% 70% 130% Mercury % < % 80% 120% 103% 90% 110% 104% 70% 130% Electrical Conductivity (2:1) % < % 80% 120% Sodium Adsorption Ratio (2:1) % N/A ph, 2:1 CaCl2 Extraction % < 100% 90% 110% Chloride (2:1) % < 2 92% 90% 110% 95% 90% 110% 91% 70% 130% Comments: Mercury Analysis: The average for the sample and duplicate is less than 5X RDL, thus,lab's RPD acceptance criteria is not applicable. Certified By: QUALITY ASSURANCE REPORT (V1) Page 8 of 13 AGAT Laboratories is accredited to ISO/IEC by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from and/or The tests in this report may not necessarily be included in the scope of accreditation.

11 Quality Assurance Trace Organics Analysis RPT Date: Apr 20, 2011 DUPLICATE REFERENCE MATERIAL METHOD BLANK SPIKE MATRIX SPIKE PARAMETER Batch Sample Id Dup #1 Dup #2 RPD Method Blank Measured Value Recovery Recovery O. Reg Petroleum Hydrocarbons F1 - F4 (C6 - C50) in Soil (PAHs Incl.) C6 - C10 (F1) < 5 < 5 0.0% < 5 112% 60% 130% 90% 60% 130% 85% 60% 130% C>10 - C16 (F2) 1 < 10 < % < % 70% 130% 91% 70% 130% 95% 70% 130% C>16 - C34 (F3) 1 < 50 < % < % 70% 130% 113% 70% 130% 118% 70% 130% C>34 - C50 (F4) 1 < 50 < % < % 70% 130% 103% 70% 130% 105% 70% 130% O. Reg PAHs in Soil Naphthalene % < % 60% 130% 76% 60% 130% 64% 60% 130% Acenaphthylene 1 < 0.02 < % < % 60% 130% 76% 60% 130% 60% 60% 130% Acenaphthene 1 < 0.03 < % < % 60% 130% 79% 60% 130% 67% 60% 130% Fluorene 1 < 0.02 < % < % 60% 130% 80% 60% 130% 74% 60% 130% Phenanthrene 1 < 0.02 < % < % 60% 130% 78% 60% 130% 80% 60% 130% Anthracene 1 < 0.02 < % < % 60% 130% 87% 60% 130% 80% 60% 130% Fluoranthene 1 < 0.02 < % < % 60% 130% 89% 60% 130% 93% 60% 130% Pyrene 1 < 0.02 < % < % 60% 130% 91% 60% 130% 93% 60% 130% Benzo(a)anthracene 1 < 0.02 < % < % 60% 130% 91% 60% 130% 92% 60% 130% Chrysene % < % 60% 130% 94% 60% 130% 96% 60% 130% Benzo(b)fluoranthene 1 < 0.02 < % < % 60% 130% 89% 60% 130% 76% 60% 130% Benzo(k)fluoranthene 1 < 0.02 < % < % 60% 130% 85% 60% 130% 80% 60% 130% Benzo(a)pyrene 1 < 0.02 < % < % 60% 130% 84% 60% 130% 79% 60% 130% Indeno(1,2,3-cd)pyrene 1 < 0.02 < % < % 60% 130% 95% 60% 130% 79% 60% 130% Dibenz(a,h)anthracene 1 < 0.02 < % < % 60% 130% 93% 60% 130% 80% 60% 130% Benzo(g,h,i)perylene 1 < 0.02 < % < % 60% 130% 94% 60% 130% 79% 60% 130% 2-and 1-methyl Naphthalene % < % 60% 130% 84% 60% 130% 77% 60% 130% O. Reg Volatile Organic Compounds in Soil Dichlorodifluoromethane < < % < % 60% 130% 83% 60% 130% 95% 60% 130% Chloromethane < < % < % 60% 130% 90% 60% 130% 86% 60% 130% Vinyl Chloride < < % < % 60% 130% 90% 60% 130% 102% 60% 130% Bromomethane < < % < % 60% 130% 102% 60% 130% 92% 60% 130% Chloroethane < < % < % 60% 130% 88% 60% 130% 101% 60% 130% Trichlorofluoromethane < < % < % 60% 130% 86% 60% 130% 98% 60% 130% Acetone < < % < % 60% 130% 89% 60% 130% 100% 60% 130% 1,1-Dichloroethylene < < % < % 60% 130% 84% 60% 130% 102% 60% 130% Methylene Chloride < < % < % 60% 130% 82% 60% 130% 97% 60% 130% TRANS-1,2-Dichloroethylene < < % < % 60% 130% 80% 60% 130% 98% 60% 130% Methyl tert-butyl Ether < < % < % 60% 130% 85% 60% 130% 98% 60% 130% 1,1-Dichloroethane < < % < % 60% 130% 81% 60% 130% 102% 60% 130% Methyl Ethyl Ketone < 0.10 < % < % 60% 130% 86% 60% 130% 88% 60% 130% CIS 1,2-Dichloroethylene < < % < % 60% 130% 87% 60% 130% 100% 60% 130% Chloroform < < % < % 60% 130% 88% 60% 130% 99% 60% 130% QUALITY ASSURANCE REPORT (V1) Page 9 of 13 AGAT Laboratories is accredited to ISO/IEC by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from and/or The tests in this report may not necessarily be included in the scope of accreditation.

12 Quality Assurance Trace Organics Analysis (Continued) RPT Date: Apr 20, 2011 DUPLICATE REFERENCE MATERIAL METHOD BLANK SPIKE MATRIX SPIKE PARAMETER Batch Sample Id Dup #1 Dup #2 RPD Method Blank Measured Value Recovery Recovery 1,2- Dichloroethane < < % < % 60% 130% 94% 60% 130% 97% 60% 130% 1,1,1-Trichloroethane < < % < % 60% 130% 82% 60% 130% 86% 60% 130% Carbon Tetrachloride < < % < % 60% 130% 92% 60% 130% 98% 60% 130% Benzene < < % < % 60% 130% 101% 60% 130% 105% 60% 130% 1,2-Dichloropropane < < % < % 60% 130% 87% 60% 130% 91% 60% 130% Trichloroethylene < < % < % 60% 130% 89% 60% 130% 113% 60% 130% Bromodichloromethane < < % < % 60% 130% 87% 60% 130% 92% 60% 130% CIS-1,3-Dichloropropene < < % < % 60% 130% 85% 60% 130% 89% 60% 130% Methyl Isobutyl Ketone < 0.10 < % < % 60% 130% 99% 60% 130% 105% 60% 130% TRANS-1,3-Dichloropropene < < % < % 60% 130% 100% 60% 130% 105% 60% 130% 1,1,2-Trichloroethane < < % < % 60% 130% 94% 60% 130% 101% 60% 130% Toluene < < % < % 60% 130% 99% 60% 130% 111% 60% 130% 2-Hexanone < < % < % 60% 130% 96% 60% 130% 101% 60% 130% Dibromochloromethane < < % < % 60% 130% 95% 60% 130% 95% 60% 130% Ethylene Dibromide < < % < % 60% 130% 97% 60% 130% 101% 60% 130% Tetrachloroethylene < < % < % 60% 130% 97% 60% 130% 104% 60% 130% 1,1,1,2-Tetrachloroethane < < % < % 130% 99% 60% 130% 102% 60% 130% Chlorobenzene < < % < % 60% 130% 97% 60% 130% 102% 60% 130% Ethylbenzene < < % < % 60% 130% 96% 60% 130% 104% 60% 130% m & p-xylene < < % < % 60% 130% 100% 60% 130% 105% 60% 130% Bromoform < < % < % 60% 130% 97% 60% 130% 103% 60% 130% Styrene < < % < % 60% 130% 98% 60% 130% 107% 60% 130% 1,1,2,2- Tetrachloroethane < < % < % 130% 93% 60% 130% 99% 60% 130% o-xylene < < % < % 60% 130% 97% 60% 130% 104% 60% 130% 1,3-Dichlorobenzene < < % < % 60% 130% 97% 60% 130% 99% 60% 130% 1,4-Dichlorobenzene < < % < % 60% 130% 98% 60% 130% 101% 60% 130% 1,2-Dichlorobenzene < < % < % 60% 130% 99% 60% 130% 105% 60% 130% 1,2,4-Trichlorobenzene < < % < % 60% 130% 91% 60% 130% 92% 60% 130% Xylene Mixture (Total) < < % < % 60% 130% 97% 60% 130% 104% 60% 130% 1,3-Dichloropropene (Cis + Trans) < < % < % 60% 130% 100% 60% 130% 105% 60% 130% n-hexane < < % < % 130% 90% 60% 130% 103% 60% 130% Certified By: QUALITY ASSURANCE REPORT (V1) Page 10 of 13 AGAT Laboratories is accredited to ISO/IEC by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from and/or The tests in this report may not necessarily be included in the scope of accreditation.

13 Method Summary PARAMETER AGAT S.O.P LITERATURE REFERENCE ANALYTICAL TECHNIQUE Soil Analysis Antimony MET EPA SW B & 6020A ICP-MS Arsenic MET EPA SW B & 6020A ICP-MS Barium MET EPA SW B & 6020A ICP-MS Beryllium MET EPA SW B & 6020A ICP-MS Boron MET EPA SW B & 6020A ICP-MS Boron (Hot Water Extractable) MET EPA SW C; MSA, Part 3, Ch.21 ICP/OES Cadmium MET EPA SW B & 6020A ICP-MS Chromium MET EPA SW B & 6020A ICP-MS Cobalt MET EPA SW B & 6020A ICP-MS Copper MET EPA SW B & 6020A ICP-MS Lead MET EPA SW B & 6020A ICP-MS Molybdenum MET EPA SW B & 6020A ICP-MS Nickel MET EPA SW B & 6020A ICP-MS Selenium MET EPA SW B & 6020A ICP-MS Silver MET EPA SW B & 6020A ICP-MS Thallium MET EPA SW B & 6020A ICP-MS Uranium MET EPA SW B & 6020A ICP-MS Vanadium MET EPA SW B & 6020A ICP-MS Zinc MET EPA SW B & 6020A ICP-MS Chromium, Hexavalent INOR SM 3500 B; MSA Part 3, Ch. 25 SPECTROPHOTOMETER Cyanide, Free INOR MOE CN-3015 & E 3009 A;SM 4500 CN TECHNICON AUTO ANALYZER Mercury MET EPA SW A CVAAS Electrical Conductivity (2:1) INOR McKeague 4.12, SM 2510 B EC METER Sodium Adsorption Ratio (2:1) INOR McKeague 4.12 & 3.26 & EPA SW C ICP/OES ph, 2:1 CaCl2 Extraction INOR MSA part 3 & SM 4500-H+ B PH METER Chloride (2:1) INOR McKeague 4.12 & SM 4110 B ION CHROMATOGRAPH Nitrate + Nitrite INOR McKeague 4.12 & SM 4110 B ION CHROMATOGRAPH METHOD SUMMARY (V1) Page 11 of 13

14 PARAMETER Method Summary AGAT S.O.P Trace Organics Analysis Dichlorodifluoromethane VOL EPA SW & 8260 (P&T)GC/MS Chloromethane VOL EPA SW & 8260 (P&T)GC/MS Vinyl Chloride VOL EPA SW & 8260 (P&T)GC/MS Bromomethane VOL EPA SW & 8260 (P&T)GC/MS Chloroethane VOL EPA SW & 8260 (P&T)GC/MS Trichlorofluoromethane VOL EPA SW & 8260 (P&T)GC/MS Acetone VOL EPA SW & 8260 (P&T)GC/MS 1,1-Dichloroethylene VOL EPA SW & 8260 (P&T)GC/MS Methylene Chloride VOL EPA SW & 8260 (P&T)GC/MS TRANS-1,2-Dichloroethylene VOL EPA SW & 8260 (P&T)GC/MS Methyl tert-butyl Ether VOL EPA SW & 8260 (P&T)GC/MS 1,1-Dichloroethane VOL EPA SW & 8260 (P&T)GC/MS Methyl Ethyl Ketone VOL EPA SW & 8260 (P&T)GC/MS CIS 1,2-Dichloroethylene VOL EPA SW & 8260 (P&T)GC/MS Chloroform VOL EPA SW & 8260 (P&T)GC/MS 1,2- Dichloroethane VOL EPA SW & 8260 (P&T)GC/MS 1,1,1-Trichloroethane VOL EPA SW & 8260 (P&T)GC/MS Carbon Tetrachloride VOL EPA SW & 8260 (P&T)GC/MS Benzene VOL EPA SW & 8260 (P&T)GC/MS 1,2-Dichloropropane VOL EPA SW & 8260 (P&T)GC/MS Trichloroethylene VOL EPA SW & 8260 (P&T)GC/MS Bromodichloromethane VOL EPA SW & 8260 (P&T)GC/MS CIS-1,3-Dichloropropene VOL EPA SW & 8260 (P&T)GC/MS Methyl Isobutyl Ketone VOL EPA SW & 8260 (P&T)GC/MS TRANS-1,3-Dichloropropene VOL EPA SW & 8260 (P&T)GC/MS 1,1,2-Trichloroethane VOL EPA SW & 8260 (P&T)GC/MS Toluene VOL EPA SW & 8260 (P&T)GC/MS 2-Hexanone VOL EPA SW & 8260 (P&T)GC/MS Dibromochloromethane VOL EPA SW & 8260 (P&T)GC/MS Ethylene Dibromide VOL EPA SW & 8260 (P&T)GC/MS Tetrachloroethylene VOL EPA SW & 8260 (P&T)GC/MS 1,1,1,2-Tetrachloroethane VOL EPA SW & 8260 (P&T)GC/MS Chlorobenzene VOL EPA SW & 8260 (P&T)GC/MS Ethylbenzene VOL EPA SW & 8260 (P&T)GC/MS m & p-xylene VOL EPA SW & 8260 (P&T)GC/MS Bromoform VOL EPA SW & 8260 (P&T)GC/MS Styrene VOL EPA SW & 8260 (P&T)GC/MS 1,1,2,2- Tetrachloroethane VOL EPA SW & 8260 (P&T)GC/MS o-xylene VOL EPA SW & 8260 (P&T)GC/MS 1,3-Dichlorobenzene VOL EPA SW & 8260 (P&T)GC/MS 1,4-Dichlorobenzene VOL EPA SW & 8260 (P&T)GC/MS 1,2-Dichlorobenzene VOL EPA SW & 8260 (P&T)GC/MS 1,2,4-Trichlorobenzene VOL EPA SW & 8260 (P&T)GC/MS Xylene Mixture (Total) VOL EPA SW & 8260 (P&T)GC/MS 1,3-Dichloropropene (Cis + Trans) VOL EPA SW & 8260 (P&T)GC/MS n-hexane VOL EPA SW & 8260 (P&T)GC/MS Toluene-d8 VOL EPA SW & 8260 (P&T)GC/MS 4-Bromofluorobenzene VOL EPA SW & 8260 (P&T)GC/MS Naphthalene ORG EPA SW & 8270 GC/MS LITERATURE REFERENCE ANALYTICAL TECHNIQUE METHOD SUMMARY (V1) Page 12 of 13

15 PARAMETER Method Summary AGAT S.O.P LITERATURE REFERENCE ANALYTICAL TECHNIQUE Acenaphthylene ORG EPA SW & 8270 GC/MS Acenaphthene ORG EPA SW & 8270 GC/MS Fluorene ORG EPA SW & 8270 GC/MS Phenanthrene ORG EPA SW & 8270 GC/MS Anthracene ORG EPA SW & 8270 GC/MS Fluoranthene ORG EPA SW & 8270 GC/MS Pyrene ORG EPA SW & 8270 GC/MS Benzo(a)anthracene ORG EPA SW & 8270 GC/MS Chrysene ORG EPA SW & 8270 GC/MS Benzo(b)fluoranthene ORG EPA SW & 8270 GC/MS Benzo(k)fluoranthene ORG EPA SW & 8270 GC/MS Benzo(a)pyrene ORG EPA SW & 8270 GC/MS Indeno(1,2,3-cd)pyrene ORG EPA SW & 8270 GC/MS Dibenz(a,h)anthracene ORG EPA SW & 8270 GC/MS Benzo(g,h,i)perylene ORG EPA SW & 8270 GC/MS 2-and 1-methyl Naphthalene ORG EPA SW & 8270 GC/MS Chrysene-d12 ORG EPA SW & 8270 GC/MS C6 - C10 (F1) VOL CCME Tier 1 Method GC / FID C6 - C10 (F1 minus BTEX) VOL CCME Tier 1 Method GC / FID C>10 - C16 (F2) VOL CCME Tier 1 Method GC / FID C>10 - C16 (F2 minus Naphthalene) VOL CCME Tier 1 Method GC / FID C>16 - C34 (F3) VOL CCME Tier 1 Method GC / FID C>16 - C34 (F3 minus PAHs) VOL CCME Tier 1 Method GC / FID C>34 - C50 (F4) VOL CCME Tier 1 Method GC / FID Gravimetric Heavy Hydrocarbons VOL CCME Tier 1 Method GRAVIMETRIC ANALYSIS Moisture Content VOL CCME Tier 1 Method GRAVIMETRIC METHOD SUMMARY (V1) Page 13 of 13

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