Safety data sheet according to 1907/2006/EC

Transcription

1 Page 1/8 * SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Article number: Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Processing aid. 1.3 Details of the supplier of the safety data sheet Manufacturer/Supplier: Schill+Seilacher "Struktol" GmbH Moorfleeter Str. 28 D Hamburg Phone: +49 / (0)40 / Fax: +49 / (0)40 / Further information obtainable from: CLP - Documentation msds@struktol.de 1.4 Emergency telephone number: GIZ-Nord Phone: +49 / (0)551 / * SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 GHS07 Skin Irrit. 2 H315 Causes skin irritation. Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xi; Irritant R38: Irritating to skin. Information concerning particular hazards for human and environment: Dust can combine with air to form an explosive mixture. In case of fire, the following can be released: Sulphur dioxide (SO2) The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. Hazard pictograms GHS07 Signal word Warning Hazard statements H315 Causes skin irritation. Precautionary statements P280 Wear protective clothing / eye protection. P264 Wash thoroughly after handling. P302+P352 IF ON SKIN: Wash with plenty of soap and water. (Contd. on page 2)

2 Page 2/8 P332+P313 If skin irritation occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. 2.3 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. (Contd. of page 1) * SECTION 3: Composition/information on ingredients 3.2 Chemical characterisation: Mixtures Description: Preparation of sulphur and organic dispersing agent on fatty acid ester basis. Dangerous components: CAS: EINECS: Reg.nr.: XXXX CAS: EINECS: Reg.nr.: xxxx Modified sulphur. Xi R38 Skin Irrit. 2, H315 Highly refined petroleum (IP346, DMSO- Extrakt < 3 %) Xn R65 Asp. Tox. 1, H304 Additional information: The substance contains less than 3% DMSO extract according to the IP 346. For the wording of the listed risk phrases refer to section % 2.5-<10% * SECTION 4: First aid measures 4.1 Description of first aid measures After inhalation: In case of unconsciousness place patient stably in side position for transportation. After skin contact: Wash off with water and soap. Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. After eye contact: Rinse opened eye for several minutes under running water. 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. For safety reasons unsuitable extinguishing agents: Water with full jet 5.2 Special hazards arising from the substance or mixture In case of fire, the following can be released: (Contd. on page 3)

3 Page 3/8 (Contd. of page 2) Carbon monoxide and carbon dioxide Sulphur dioxide (SO2) 5.3 Advice for firefighters Protective equipment: Do not inhale explosion gases or combustion gases. * SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Wear protective clothing. 6.2 Environmental precautions: The product should not be released into the aquatic environment without preliminary treatments (purification plant). Do not allow to enter sewers/ surface or ground water. 6.3 Methods and material for containment and cleaning up: Pick up mechanically. 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. * SECTION 7: Handling and storage 7.1 Precautions for safe handling The usual precautionary measures are to be adhered to when handling chemicals. Information about fire - and explosion protection: Dust can combine with air to form an explosive mixture. 7.2 Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Not required. Further information about storage conditions: Store in dry conditions. 7.3 Specific end use(s) No further relevant information available. SECTION 8: Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item Control parameters Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists valid during the making were used as basis. 8.2 Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the skin. (Contd. on page 4)

4 Page 4/8 Avoid contact with the eyes and skin. Protection of hands: (Contd. of page 3) Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. Material of gloves In cooperation with the glove manufacturer KCL, we recommend following the gloves: Fluorocarbon rubber (Viton) Nitrile rubber, NBR Butyl rubber, BR The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Value for the permeation: Level 6 For the permanent contact gloves made of the following materials are suitable: Plastic gloves Rubber gloves Eye protection: Not required. Body protection: Protective work clothing * SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties General Information Appearance: Form: Solid Colour: Yellow Odour: Uncharacteristic. Odour threshold: Not determined. ph-value: Not applicable. Change in condition Melting point/melting range: C Boiling point/boiling range: Not determined. Flash point: > 100 C (EN ISO 3679) Flammability (solid, gaseous): Not determined. Ignition temperature: Decomposition temperature: Not determined. Self-igniting: Product is not selfigniting. (Contd. on page 5)

5 Page 5/8 (Contd. of page 4) Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Upper: Not determined. Not determined. Vapour pressure: Not applicable. Density at 20 C: 1.9 g/cm³ (DIN 53479) Bulk density at 20 C: kg/m³ (DIN 53644) Relative density Not determined. Vapour density Not applicable. Evaporation rate Not applicable. Solubility in / Miscibility with water: Soluble. Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Kinematic: Solvent content: Not applicable. Not applicable. Organic solvents: 0.0 % 9.2 Other information No further relevant information available. SECTION 10: Stability and reactivity 10.1 Reactivity No further relevant information available Chemical stability Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat Possibility of hazardous reactions No dangerous reactions known Conditions to avoid No further relevant information available Incompatible materials: No further relevant information available Hazardous decomposition products: No dangerous decomposition products known. SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity LD/LC50 values relevant for classification: Modified sulphur. Oral LD50 > 5000 mg/kg (Rat) Dermal LD50 > 2000 mg/kg (Rabbit) Inhalative LC 50/4h 9.23 mg/l (Rat) (Contd. on page 6)

6 Page 6/8 (Contd. of page 5) Highly refined petroleum (IP346, DMSO-Extrakt < 3 %) Oral LD50 > 5000 mg/kg (Rat) Dermal LD50 >5000 mg/kg (Rabbit) Inhalative LC 50/4h >5 mg/l (Rat) Primary irritant effect: Skin corrosion/irritation Causes skin irritation. Serious eye damage/irritation Based on available data, the classification criteria are not met. Respiratory or skin sensitisation Based on available data, the classification criteria are not met. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity Based on available data, the classification criteria are not met. Reproductive toxicity Based on available data, the classification criteria are not met. STOT-single exposure Based on available data, the classification criteria are not met. STOT-repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1 Toxicity Aquatic toxicity: Modified sulphur. LC50/96h 866 mg/l (Fish) EC50/24h > mg/l (Daphnia magna) Type of test Effective concentration Method Assessment Highly refined petroleum (IP346, DMSO-Extrakt < 3 %) NOEC > mg/l (Fish) 12.2 Persistence and degradability No further relevant information available Bioaccumulative potential No further relevant information available Mobility in soil No further relevant information available. Additional ecological information: General notes: Do not allow product to reach ground water, water course or sewage system Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable Other adverse effects No further relevant information available. * SECTION 13: Disposal considerations 13.1 Waste treatment methods Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Disposal must be made according to official regulations. (Contd. on page 7)

7 Page 7/8 (Contd. of page 6) Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. * SECTION 14: Transport information 14.1 UN-Number ADR, ADN, IMDG, IATA Void 14.2 UN proper shipping name ADR, ADN, IMDG, IATA Void 14.3 Transport hazard class(es) ADR, ADN, IMDG, IATA Class Void 14.4 Packing group ADR, IMDG, IATA Void 14.5 Environmental hazards: Not applicable Special precautions for user Not applicable Transport in bulk according to Annex II of Marpol and the IBC Code Not covered in this data sheet. Transport/Additional information: Not dangerous according to the above specifications. UN "Model Regulation": Void * SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Directive 2012/18/EU Named dangerous substances - ANNEX I None of the ingredients is listed. National regulations: Breakdown regulations: Breakdown regulations, Annex II, No.: None of the ingredients is listed Chemical safety assessment: A Chemical Safety Assessment has not been carried out. * SECTION 16: Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H304 May be fatal if swallowed and enters airways. (Contd. on page 8)

8 Page 8/8 H315 Causes skin irritation. R38 Irritating to skin. R65 Harmful: may cause lung damage if swallowed. Department issuing MSDS: CLP - Documentation Abbreviations and acronyms: Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Asp. Tox. 1: Aspiration hazard, Hazard Category 1 * Data compared to the previous version altered. (Contd. of page 7)