1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING. Preparation containing organotin compounds

Transcription

1 Galata Chemicals GmbH urges the recipient of this Safety Data Sheet to study it carefully to become aware of hazards, if any, of the product involved. In the interest of safety you should (1) notify your employees, agents and contractors of the information on this sheet,(2) furnish a copy to each of your customers for the product, and (3) request your customers to inform their employees and customers as well. 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Identification of the substance or preparation: Chemical name: Synonyms: Use of substance/preparation: Preparation containing organotin compounds PVC Stabilizer Company identification: Galata Chemicals GmbH Chemiestraße 22 Lampertheim Germany Manufacturer: Galata Chemicals GmbH Chemiestraße 22 Lampertheim Germany Emergency telephone number: Environmental, Health and (EU) Safety Department: Prepared by Product Safety Department (US) (EU) MSDS@galatachemicals.com 2. HAZARDS IDENTIFICATION Main hazards and effects: Harmful if swowed. Irritating to skin. May cause sensitization by skin contact. Toxic: danger of serious damage to health by prolonged exposure if swowed. Possible risk of harm to the unborn child. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 3. COMPOSITION / INFORMATION ON INGREDIENTS (M)SDS# Page: 1 of 9

2 INGREDIENT % BY WEIGHT HAZARD DANGER SYMBOL(S) Dioctyltin bis(2-ethylhexyl thioglycolate) CAS# EINECS/ELINCS# CAS# EINECS/ELINCS# Dioctyltin mercaptoacetate CAS# EINECS/ELINCS# > 50 R22 R38 R43 R48/25 R53 R63 < 50 R38 R48/22 R63 R50/53 < 10 R48/25 R53 R63 T Xn N T 4. FIRST AID MEASURES Swowing Give medicinal activated charcoal 10 g in 100 ml water at 20 minute intervals (5 x). In case of spontaneous vomiting ensure that vomitus can drain freely to avoid risk of suffocation. Drink water in sm sips. (Diluting effect) Do not induce vomiting. In case of inconsciousness or convulsion no oral administration. Obtain medical attention immediately. Inhalation Remove to fresh air. In case of irritation of respiratory system or mucous membranes or if feeling unwell or after prolonged exposure get medical attention. Skin contact Wash with plenty of water or isopropanol. Do not use other organic solvents. Obtain medical attention if irritation persists. Eye contact Immediately flush eyes with water and continue washing for at least 15 minutes. In case of eye irritation seek medical attention. 5. FIRE-FIGHTING MEASURES Flash point: 114 C Hazardous combustion products If handled as instructed: none Special fire fighting procedures Do not release chemicy contaminated water into drains, soil or surface water. Special protective equipment for firefighters Wear self-contained breathing apparatus. Extinguishing media Suitable: Unsuitable: Water mist. - foam Carbon dioxide. - dry powder (ABC-powder) High volume water jet. (M)SDS# Page: 2 of 9

3 Unusual fire and explosion hazards In case of a fire aside from the major combustion products carbon dioxide and carbon monoxide other harmful gases and vapors may be formed., Especiy the formation of sulfur dioxide must be taken into account. 6. ACCIDENTAL RELEASE MEASURES Personal precautions Do not breath vapors/aerosols., Eliminate sources of ignition., Avoid contact with skin and eyes. Environmental precautions Prevent from entering sewer system, surface water or soil., Disposal: see section 13 Methods for cleaning up Large quantities: Dike spilled product with liquid absorbing material and pump off. Sm quantities: Soak up with liquid absorbing material (sand etc.) and dispose of as instructed. 7. HANDLING AND STORAGE HANDLING Handling precautions Avoid formation of vapors/aerosols., Keep away from sources of ignition - No smoking., Use only in well ventilated areas., On occurence of vapors/aerosols take technical measures for effective exhaust.do not swow., Avoid contact with skin and clothing., Avoid formation of vapors/aerosols., Keep away from heat, sparks and flame., Keep away from sources of ignition - No smoking., Use only in well ventilated areas., On occurence of vapors/aerosols take technical measures for effective exhaust. Other precautions The material is combustible and can form ignitable, explosive air/vapor mixtures., Take precautionary measures against static discharges. STORAGE Storage requirements Keep container tightly closed in a cool, well-ventilated place. Further information on storage Avoid contact with oxidizing agents or strong acids/bases. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE LIMIT VALUES Component Type Value Remark Tin compound, organic (calculated as tin) AGW value, 8-hours average value, skin 8 hours, skin 15 minutes, skin TWA, skin VME (M)SDS# Page: 3 of 9

4 VLE 8 hours, skin 15 minutes, skin 0,3 mg/m3 OEL-TWA, skin OEL-STEL, skin TWA, skin STEL, skin VLA-ED, skin VLA-EC, skin NGV, skin KTV, skin TWA, skin STEL, skin MAC-TWA, skin MAC-STEL, skin TWA, skin STEL, skin PERSONAL PROTECTION Respiratory protection Gas filter type A, if technical measures for exhaust are insufficient. Hand protection / protective gloves (M)SDS# Page: 4 of 9

5 Gauntlet type gloves of nitrile rubber or butyl rubber recommended; for short time contact PVC is suitable. Eye protection Safety glasses. Skin protection Chemical resistant protective clothing., Closed footwear Industrial hygiene measures When using do not eat, drink or smoke., Immediately remove contaminated clothing. ENGINEERING CONTROLS Ventilation General mechanical room ventilation is satisfactory for normal handling and storage operations., If personnel exposure exceeds exposure limits, apply local exhaust ventilation., If the product is used at high temperatures or operations exist which may produce misting, local exhaust ventilation may be required. Further information Provide for sufficient ventilation and/or exhaust. 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Physical state Color Odor Liquid Colorless to straw Characteristic OTHER PROPERTIES Boiling point > 250 C ph 4 Concentration: 200 g/l ( 20 C) Suspension. Density 1,09 g/cm3 at 20 C Method: DIN Solubility in water Solubility in organic solvents Flash point < 0,1 mg/l Soluble 114 C Method: DIN Thermal decomposition >= 250 C Autoignition temperature 280 C Method: DIN Dynamic viscosity mpa.s at 20 C Method: Gardner-Holdt 10. STABILITY AND REACTIVITY (M)SDS# Page: 5 of 9

6 Incompatible materials: Oxidizing agents, acids, bases Hazardous combustion products: If handled as instructed: none 11. TOXICOLOGICAL INFORMATION SWOWING Chronic effects In animal studies with repeated oral application of dioctyl tin compounds toxic effects were observed on the immune system. Test results Acute toxicity: SKIN CONTACT Test results Skin irritation: SENSITIZATION Test results: Remark: Effects to be expected according to calculation scheme laid down in EC-Directive 1999/45/EC and amendments and adaptions: LD50 oral: harmful (200 < LD50 <= 2000 mg/kg) Remark: Effects to be expected according to calculation scheme laid down in EC-Directive 1999/45/EC and amendments and adaptions: Irritant Remark: Sensitization: Effects to be expected according to calculation scheme laid down in EC-Directive 1999/45/EC and amendments and adaptions: sensitizing 12. ECOLOGICAL INFORMATION Biodegradation: Remark: Octyltin compounds proved to be not readily biodegradable in degradation tests. Component ecotoxicology Acute toxicity fish: Semi-static LC50 - Zebra fish (Brachydanio rerio) Result: 73 mg/l Exposure time: 96 h Component ecotoxicology Aquatic toxicity to plants: EC50 - Algae Result: 0,71 mg/l Exposure time: 72 h Component ecotoxicology Microorganisms: Component ecotoxicology Bacterial toxicity EC50 - Pseudomonas putida Exposure time: 18 h EC50 - Water flea (Daphnia magna) Result: > 1 mg/l (M)SDS# Page: 6 of 9

7 Acute toxicity to aquatic invertebrates: Exposure time: 48 h 13. DISPOSAL CONSIDERATIONS General: Burn in compliance with operative regulations in a hazardous waste incinerator. Non-cleaned packages Dispose of in the same way as product., Can be reused after cleaning., Dispose of washing solution in the same way as product. 14. TRANSPORT INFORMATION ADR/RID Proper shipping name ENVIRONMENTY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Class 9 () UN No Packing group III Hazard No. 90 Label 9 Technical description contains Octyltin tris(2-ethylhexyl thioglycolate IMDG Classification Proper shipping name: ENVIRONMENTY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Class: 9 UN ID #: UN 3082 Packing group: III Marpol: MARINE POLLUTANT Technical description (contains ICAO/IATA Classification Proper shipping name: ENVIRONMENTY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Class: 9 UN ID #: UN 3082 Packing group: III Technical description (contains 15. REGULATORY INFORMATION EC classification Danger symbol(s) : T N Risk phrases : R22 Harmful if swowed. R38 Irritating to skin. R43 May cause sensitization by skin contact. R48/25 Toxic: danger of serious damage to health by prolonged exposure if swowed. R63 Possible risk of harm to the unborn child. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. (M)SDS# Page: 7 of 9

8 Safety phrases : S24/25 Avoid contact with skin and eyes. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S60 This material and/or its container must be disposed of as hazardous waste. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Contains : Dioctyltin bis(2-ethylhexyl thioglycolate) : : Dioctyltin mercaptoacetate Regulatory data - Germany VBF : Not subjected to VbF WGK : 2, Hazard to water; VwVwS, Annex 4 TA-LUFT : Number: (3.1.7) organic substances class: I CHEMICAL INVENTORY Canada: One or more components of this product are on the NDSL. The ingredients of this mixture are on the EINECS inventory. United States: The ingredients of this product are on the TSCA inventory. Australia: This product is on the AICS inventory. The ingredients of this product are on the IECSC inventory. : The ingredients of this product are not on the ENCS inventory. : One or more ingredients of this product are not on the ECL. 16. OTHER INFORMATION List of R-phrases used in data sheet. See section 15 for classification details. Risk phrases : R22 Harmful if swowed. R38 Irritating to skin. R43 May cause sensitization by skin contact. R48/22 Harmful: danger of serious damage to health by prolonged exposure if swowed. R53 May cause long-term adverse effects in the aquatic environment. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R63 Possible risk of harm to the unborn child. R48/25 Toxic: danger of serious damage to health by prolonged exposure if swowed. FURTHER INFORMATION Where appropriate, use CEN approved personal protection equipment. This Safety Data Sheet conforms to EC Directive 2001/58 and amendments. (M)SDS# Page: 8 of 9

9 STP W/W Standard temperature and pressure Weight/Weight 2010 Galata Chemicals GmbH THE OPINIONS EXPRESSED HEREIN ARE THOSE OF QUALIFIED EXPERTS WITHIN GALATA CHEMICALS GMBH. WE BELIEVE THAT THE INFORMATION CONTAINED HEREIN IS CURRENT AS OF THE DATE OF THIS. SINCE THE USE OF THIS INFORMATION AND OF THESE OPINIONS AND THE CONDITIONS OF USE OF THIS PRODUCT ARE NOT WITHIN THE CONTROL OF GALATA CHEMICALS GMBH, IT IS THE USER'S OBLIGATION TO DETERMINE THE CONDITIONS OF SAFE USE OF THE PRODUCTS. (M)SDS# Page: 9 of 9