: PLANT HEALTH technologies Volare DC

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1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Product code : Mixture : : M Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet JR Simplot Company Boise, ID T Emergency telephone number Emergency number : CHEMTREC SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Eye Irrit. 2B H320 Full text of H-phrases: see section Label elements GHS-US labeling Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Warning : H320 - Causes eye irritation : P264 - Wash protective equipment and work clothes thoroughly after handling P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337 + P313 - If eye irritation persists: Get medical advice/attention 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) Paraffin oils (CAS No) Not classified Proprietary Not classified SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 04/23/2015 EN (English US) Page 1

2 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after eye contact : Causes eye irritation Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight. USA ACGIH ACGIH TWA (mg/m³) 5 mg/m³ 8.2. Exposure controls Personal protective equipment Hand protection Eye protection : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. 04/23/2015 EN (English US) 2/6

3 Respiratory protection : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Color Odor Odor threshold ph Relative evaporation rate (butyl acetate=1) Melting point Freezing point : Liquid : Colorless : Odourless Boiling point : C Flash point : > C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapor pressure : 2.6 Relative vapor density at 20 C Relative density Density : sg Solubility : Water: Solubility in water of component(s) of the mixture : : < 0.1 g/100ml Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidizing properties Explosive limits 9.2. SECTION 10: Stability and reactivity Reactivity Chemical stability Stable Possibility of hazardous reactions Hazardous polymerization will not occur Conditions to avoid Heat and sources of ignition. Direct sunlight. Extremely high or low temperatures Incompatible materials Oxidizers. Strong acids. Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity 04/23/2015 EN (English US) 3/6

4 LD50 oral rat LD50 dermal rat LD50 oral rat LD50 dermal rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC group Reproductive toxicity Specific target organ toxicity (single exposure) > 5050 mg/kg > 5050 mg/kg > 5000 mg/kg (Rat) > 2000 mg/kg (Rabbit) : Causes eye irritation. 3 - Not classifiable Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/injuries after eye contact : Based on available data, the classification criteria are not met. : Causes eye irritation. SECTION 12: Ecological information Toxicity Persistence and degradability Persistence and degradability Proprietary Persistence and degradability Persistence and degradability Contains non readily biodegradable component(s) Bioaccumulative potential Bioaccumulative potential Proprietary Bioaccumulative potential Bioaccumulative potential No bioaccumulation data available Mobility in soil Other adverse effects Effect on ozone layer Effect on the global warming : : No known ecological damage caused by this product. : Avoid release to the environment. 04/23/2015 EN (English US) 4/6

5 SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials : Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information : No supplementary information available. ADR Transport document description : Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations All components of this product are listed on the Toxic Substances Control Act (TSCA) inventory except for: Proprietary CAS No C>=30.00% ; C<=35.00% This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR (a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC or 1999/45/EC Not classified National regulations US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer and/or reproductive harm U.S. - New Jersey - Right to Know Hazardous Substance List SECTION 16: : : None. Full text of H-phrases: see section 16: Eye Irrit. 2B Serious eye damage/eye irritation Category 2B H320 Causes eye irritation SDS US (GHS HazCom 2012) 04/23/2015 EN (English US) 5/6

6 Disclaimer: This information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is to the best of our knowledge and belief, accurate and reliable as of the date compiled. However, no representation, warranty or guarantee is made as to its accuracy, reliability or completeness. NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSE, OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE CONCERNING THE INFORMATION HEREIN PROVIDED. It is the user's responsibility to satisfy himself as to the suitability and completeness of such information for his own particular use. We do not accept liability for any loss or damage that may occur from the use of this information nor do we offer warranty against patent infringement. 04/23/2015 EN (English US) 6/6