1.4. Emergency telephone number Country Organisation/Company Address Emergency number Comment

Transcription

1 Date of issue 4/13/2016 Revision date Supersedes Version 3.2 SECTION 1 Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Substance name 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Uses advised against 1.3. Details of the supplier of the safety data sheet Q-Chem Leeuwerweg Wilderen Sint-Truiden T F q-chem@skynet.be 1.4. Emergency telephone number Country Organisation/Company Address Emergency number Comment Ireland National Poisons Information Beaumont Hospital Beaumont Road Dublin Centre Beaumont Hospital SECTION 2 Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixture/Substance SDS EU 2015 According to Regulation (EU) 2015/830 (REACH Annex II) Hazardous to the aquatic environment Acute Hazard, Category 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 H400 H410 Full text of H statements see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) EUH-statements GHS09 Warning H410 - Very toxic to aquatic life with long lasting effects P391 - Collect spillage P501 - Dispose of contents/container to National regulations P102 - Keep out of reach of children P301+P310 - IF SWALLOWED Immediately call a doctor, a POISON CENTER EUH401 - To avoid risks to human health and the environment, comply with the instructions for use 2.3. Other hazards 4/13/2016 EN (English) 1/7

2 SECTION 3 Composition/information on ingredients 3.1. Substance Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] 100 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Full text of H-statements see section Mixture Not applicable SECTION 4 First aid measures 4.1. Description of first aid measures 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5 Firefighting measures 5.1. Extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters SECTION 6 Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel For emergency responders 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7 Handling and storage 7.1. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) SECTION 8 Exposure controls/personal protection 8.1. Control parameters 4/13/2016 EN (English) 2/7

3 8.2. Exposure controls SECTION 9 Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10 Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products SECTION 11 Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) 4/13/2016 EN (English) 3/7

4 Specific target organ toxicity (repeated exposure) Aspiration hazard SECTION 12 Ecological information Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13 Disposal considerations Waste treatment methods SECTION 14 Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number UN-No. (ADR) 3082 UN-No. (IMDG) 3082 UN-No. (IATA) 3082 UN-No. (ADN) 3082 UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) Environmentally hazardous substance, liquid, n.o.s. Transport document description (ADR) UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (diflufenican), 9, III, (E) Transport document description (IMDG) Transport document description (IATA) Transport document description (ADN) Transport document description (RID) Transport hazard class(es) ADR Transport hazard class(es) (ADR) 9 Danger labels (ADR) 9 UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III, MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS UN 3082 Environmentally hazardous substance, liquid, n.o.s., 9, III, ENVIRONMENTALLY HAZARDOUS UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III, ENVIRONMENTALLY HAZARDOUS UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III, ENVIRONMENTALLY HAZARDOUS 4/13/2016 EN (English) 4/7

5 IMDG Transport hazard class(es) (IMDG) 9 Danger labels (IMDG) 9 IATA Transport hazard class(es) (IATA) 9 Hazard labels (IATA) 9 ADN Transport hazard class(es) (ADN) 9 Danger labels (ADN) 9 RID Transport hazard class(es) (RID) 9 Danger labels (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information III III III III III Yes Yes No supplementary information available Special precautions for user - Overland transport Classification code (ADR) M6 Special provisions (ADR) 274, 335, 601 Limited quantities (ADR) 5l Excepted quantities (ADR) E1 Packing instructions (ADR) P001, IBC03, LP01, R001 Special packing provisions (ADR) PP1 Mixed packing provisions (ADR) MP19 4/13/2016 EN (English) 5/7

6 Portable tank and bulk container instructions (ADR) Portable tank and bulk container special provisions (ADR) Tank code (ADR) Vehicle for tank carriage T4 TP1, TP29 LGBV AT Transport category (ADR) 3 Special provisions for carriage - Packages (ADR) Special provisions for carriage - Loading, unloading and handling (ADR) V12 CV13 Hazard identification number (Kemler No.) 90 Orange plates Tunnel restriction code (ADR) E - Transport by sea Special provisions (IMDG) 274, 335 Limited quantities (IMDG) Excepted quantities (IMDG) Packing instructions (IMDG) Special packing provisions (IMDG) IBC packing instructions (IMDG) Tank instructions (IMDG) Tank special provisions (IMDG) EmS-No. (Fire) EmS-No. (Spillage) Stowage category (IMDG) - Air transport PCA Excepted quantities (IATA) PCA Limited quantities (IATA) PCA limited quantity max net quantity (IATA) 5 L E1 P001, LP01 PP1 IBC03 T4 TP2, TP29 F-A S-F A E1 Y964 30kgG PCA packing instructions (IATA) 964 PCA max net quantity (IATA) 450L CAO packing instructions (IATA) 964 CAO max net quantity (IATA) Special provisions (IATA) ERG code (IATA) - Inland waterway transport Classification code (ADN) 450L A97, A158 9L M6 Special provisions (ADN) 274, 335, 61 Limited quantities (ADN) Excepted quantities (ADN) Carriage permitted (ADN) Equipment required (ADN) 5 L E1 T PP Number of blue cones/lights (ADN) 0 - Rail transport Classification code (RID) M6 Special provisions (RID) 274, 335, 601 Limited quantities (RID) Excepted quantities (RID) Packing instructions (RID) Special packing provisions (RID) Mixed packing provisions (RID) Portable tank and bulk container instructions (RID) 5L E1 P001, IBC03, LP01, R001 PP1 MP19 T4 4/13/2016 EN (English) 6/7

7 Portable tank and bulk container special provisions (RID) Tank codes for RID tanks (RID) Transport category (RID) 3 Special provisions for carriage Packages (RID) Special provisions for carriage - Loading, unloading and handling (RID) Colis express (express parcels) (RID) TP1, TP29 LGBV W12 CW13, CW31 CE8 Hazard identification number (RID) Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions is not on the REACH Candidate List National regulations Chemical safety assessment SECTION 16 Other information Full text of H- and EUH-statements Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects EUH401 To avoid risks to human health and the environment, comply with the instructions for use SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 4/13/2016 EN (English) 7/7