EEC-SAFETY DATA SHEET

Transcription

1 EEC-SAFETY DATA SHEET Esperis S.p.A. Issue: Revision date: March 18, 1999 page:1/5 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Product name: Code: Chemical name: salt. CAS: PIROCTONE OLAMINE PIRO.1 1-Hydroxy-4-methyl-6-(2,2,4-trimethylpentyl)-2(1H)-pyridone -2-amino ethanol EINECS/ELINCS: INCI name: PIROCTONE OLAMINE Manufacturer identification: Name: Street: via A. Binda, 29 Postcode/Location: Milan ITALY Phone: /36/19 Fax: COMPOSITION / INFORMATION ON INGREDIENTS Chemical characterization (preparation): Hazardous ingredients: Name % R-phrases Symb. 1-Hydroxy-4-methyl-6-(2,2,4-trimethylpentyl)- > 99 R37/38, R41, R50/53 X i, N 2(1H)-pyridone -2-amino ethanol salt Additional service: // 3.HAZARD IDENTIFICATION Human health hazards: irritating to respiratory system and skin. Risk of serious damage to eyes. Environmental hazards: very toxic to aquatic organism, may cause long - term adverse effects in the aquatic environment 4. FIRST AID MEASURES General advice: remove the contaminated clothing and keeping in safety. Inhalation: of Skin contact: Eye contact: Ingestion: remove the individual to fresh air, remove any contaminated clothing, in case breathing difficulty, seek medical advice flush with lots of water and soap. Seek a doctor if irritation appear. rinse thoroughly with a lot of water for some minutes with the eye lids held open. Seek a doctor if inflammation persist. Seek a doctor.

2 Esperis S.p.A. Issue: Revision date: March 18, 1999 page: 2/ 5 5.FIRE-FIGHTING MEASURES Suitable extinguishing media: jet. carbon dioxide, dry powder, dry fire extinguisher, spray water Unsuitable extinguishing media: none. Special fire-fighting procedures: in case of insufficient ventilation, wear suitable respiratory equipment Hazardous thermal (de)composition: // Special fire fighting equipment: according to size of fire. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: should be Environmental precautions: Methods of cleaning up/taking up: if necessary use respiratory protection; protective clothing worn i.e. safety glasses or goggles and gloves. do not discharge into the drains / surface waters/groundwater. Avoid dust formation. pink up mechanically. Rinse away rest with water. In the event of such a contamination notify the relevant authority. Wash with a lot of water; use antifoaming agents if there is plentiful foam. 7. HANDLING AND STORAGE Handling: Storage: Other advice: use in a ventilated area. Keep the formation and deposition of dust to a minimum. store product only in closed original packaging. Keep in a cool place and away from heat, light and ignition sources. Take precautionary measures against electrostatic loading-earthing necessary during loading operations. Dust explosion class: ST2. use plastic container. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION General: a good sense of work hygene. Respiratory protection: dust mask. Skin & body protection: normal protective clothes. Hand protection: Eye protection: wear suitable rubber gloves/pvc gloves. recommendable safety-glasses.

3 Esperis S.p.A. Issue: Revision date: March 18, 1999 page: 3 /5 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Colour: Odour: Boiling point C: powder near white to light yellow odourless n.a. Melting point C: C Flash point C: > 100 C DIN Autoignition point C: n.a. Flammability: // Vapor pressure: Explosive properties: Oxidizing properties: about 25 hpa unknown unknown Solubility in water: about 0.5 g/l at 20 C Solubility in solvent: Specific 20 C: soluble in alcohol and organic surfactants // g/ml Refractive 20 C: // Viscosity: ph: ( sol. 1% at 20 C) 10. STABILITY AND REACTIVITY Stability: Conditions to avoid: stable under normal conditions. termic decomposition about 130 C. Materials to avoid: // Hazardous decomposition products: //

4 Esperis S.p.A. Issue: Revision date: March 18, 1999 page: 4/ 5 11.TOXICOLOGICAL INFORMATION Acute oral toxicity: LD 50 (rat): 8100 mg/kg (Method OECD 401) Acute oral toxicity: LD 50 (mouse): 4300 mg/kg (Method OECD 401) Acute dermal toxicity: LD 50 (rabbit): > 2000 mg/kg (Method: OECD 402) Skin irritation: irritating (rabbit) (Method: OECD 404) Eyes irritation: risk of serious damage (Method: OECD 405) Sensitization: non sensitiziting (Method: OECD 406) Ames Test: no mutagenic 12.ECOLOGICAL INFORMATION Degradability: > 80% (Method OECD302B/ISO 9888/CEE C) LC 50, fish: ml/l/96h (Golden orfe) EC 50, bacteria: 141 mg O 2 /g. 13.DISPOSAL CONSIDERATIONS Waste disposal method: in accordance with regulation for special waste, must be taken, after pretreatment, to an authorized special waste incineration plant. Contaminated packaging: product. packaging that cannot be cleaned should be disposed of like the 14.TRANSPORT INFORMATION ONU: 3077 ADR /RID class: 9, III n. danger: 90 label: 9 IATA class: 9 UN Packing Group: III IMDG Class: 9 UN Packing Group: III

5 Esperis S.p.A. Issue: Revision date: March 18, 1999 page:5 / REGULATORY INFORMATION Labelling according to EEC: Symbol X i, N R phrases S phrases R37/38 - Irritating to respiratory system and skin. R41 - Risk of serious damage to eyes. R50/53 - Very toxic to aquatic organism, may cause long-term adverse effects in the aquatic environment. S26 - In case of contact with skin, wash immediately with plenty of water and seek medical advice. S28 - After contact with skin, wash immediately with plenty of water and soap S37/39 - Wear suitable gloves and eye/face protection. S61 - Avoid release to environment. Refer to special instructions / Safety data sheet. 16. OTHER INFORMATION Literature references: // This data sheet is based on current knowledge and is given in good faith but without guarantee of accuracy and no liability for any insufficiency or accuracy in such data whatsoever. It is the user responsibility to satisfy oneself as to the completeness of the information for their own uses. The data sheet does not signify any warranty with regards to the materials, properties or use.