RADIAMULS MCT 2106 Safety Data Sheet according to Regulation (EC) No. 453/2010

Transcription

1 Date of issue: 11/07/2013 Revision date: 07/06/2013 Version: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance Trade name : Name : Glycerides, mixed decanoyl and octanoyl EC no. : CAS No. : REACH registration No : C&L notification reference no : Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Use of the substance/mixture Title General overview of professional uses of glycerol fatty estersx General overview of consumer uses of glycerol fatty estersx General overview of industrial uses of glycerol fatty estersx Full text of use descriptors: see section 16 : Industrial use : Food applications Use descriptors SU0, SU1, SU10, SU12, SU20, SU22, PC1, PC9a, PC9b, PC17, PC18, PC21, PC24, PC25, PC31, PC32, PC35, PC39, PROC1, PROC2, PROC3, PROC4, PROC5, PROC7, PROC8a, PROC8b, PROC9, PROC10, PROC11, PROC13, PROC15, PROC17, PROC19, PROC20, PROC21, PROC24, ERC2, ERC8a, ERC8b, ERC8c, ERC8d, ERC8e, ERC8f, ERC9a, ERC9b SU21, PC0, PC1, PC3, PC9a, PC12, PC24, PC28, PC29, PC31, PC35, PC39, ERC2, ERC8a, ERC8b, ERC8c, ERC8d, ERC8e, ERC8f, ERC9a, ERC9b SU0, SU1, SU2a, SU2b, SU3, SU4, SU6b, SU8, SU9, SU10, SU11, SU12, SU14, SU15, SU17, SU20, SU23, PC0, PC1, PC9a, PC12, PC14, PC17, PC18, PC19, PC21, PC24, PC25, PC28, PC29, PC32, PC35, PC39, PROC1, PROC2, PROC3, PROC4, PROC5, PROC6, PROC7, PROC8a, PROC8b, PROC9, PROC10, PROC11, PROC12, PROC13, PROC14, PROC15, PROC17, PROC19, PROC21, PROC24, AC10, ERC1, ERC2, ERC3, ERC4, ERC5, ERC6a, ERC6b, ERC6c, ERC6d, ERC7, ERC8a, ERC8b, ERC8c, ERC8d, ERC10a, ERC10b, ERC11a Uses advised against 1.3. Details of the supplier of the safety data sheet OLEON N.V. Assenedestraat Ertvelde - Belgium T F sds@oleon.com Emergency telephone number Emergency number : /7 EMERGENCY NUMBER (SGS ERS; Oleon contract nr 76858) Country Official advisory body Address Emergency number AUSTRALIA Poisons Information Centre PO Box ACTWODEN GREECE Poisons Information Centre Children's Hospital "Aglaia. Kyriakou" 11527Athens ICELAND Iceland Poisons Information Centre Fossvogi Landspitali University Hospital 108Reykjavik IRELAND (REPUBLIC OF) ISRAEL National Poisons Information Centre Beaumont Hospital Israel Poisons Information Centre Rambam Medical Centre National Poisons Information Service (Belfast Centre) Royal Victoria Hospital National Poisons Information Service (Birmingham Centre) City Hospital National Poisons Information Service (Cardiff Centre) Gwenwyn Ward, Llandough Hospital NPIS Edinburgh (Scottish Poisons Information Bureau) Royal Infirmary of Edinburgh Beaumont Hospital Beaumont Road 9Dublin PO Box Haifa Grosvenor Road BT12 6BABelfast Dudley Road B18 7QHBirmingham Penarth CF64 2XXCardiff 51 Little France Crescent EH16 4SAEdinburgh (UK only), (UK only) (UK only) (UK only) Version: EN (English) 1/8

2 Country Official advisory body Address Emergency number National Poisons Information Service (Newcastle Claremont Place (UK only) Newcastle-upon-Tyne Centre) NE1 4LPNewcastle Regional Drugs and Therapeutics Centre, Wolfson Unit WORLDWIDE SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Guy's & St Thomas' Poisons Unit Medical Toxicology Unit, Guy's & St Thomas' Hospital Trust World directory of poisons centres (Yellow Tox) WHO-OMS Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC or 1999/45/EC Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] No labelling applicable 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances Substance type : UVCB Avonley Road SE14 5ERLondon Website chemical_safety/poisons_ce ntres/en/ Name Product identifier % Classification according to Directive 67/548/EEC Glycerides, mixed decanoyl and octanoyl (Main constituent) (CAS No.) (EC no.) (REACH-no) Not classified Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Glycerides, mixed decanoyl and octanoyl (Main constituent) Full text of R-, H- and EUH-phrases: see section Mixture SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion (CAS No.) (EC no.) (REACH-no) : If you feel unwell, seek medical advice Most important symptoms and effects, both acute and delayed Symptoms/injuries 100 Not classified : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. : Rinse with water. Soap may be used. Take victim to a doctor if irritation persists. : Rinse with water. Take victim to an ophthalmologist if irritation persists. : Rinse mouth with water. Call Poison Information Centre ( Consult a doctor/medical service if you feel unwell. : Unlikely to cause harmful effects Indication of any immediate medical attention and special treatment needed Version: EN (English) 2/8

3 SECTION 5: Firefighting measures 5.1. Extinguishing media 5.2. Special hazards arising from the substance or mixture Fire hazard Explosion hazard Reactivity : DIRECT FIRE HAZARD. Combustible. INDIRECT FIRE HAZARD. Heating increases the fire hazard. Temperature above flashpoint: higher fire/explosion hazard. : No direct explosion hazard. : On burning: release of (carbon monoxide - carbon dioxide) Advice for firefighters : SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures For non-emergency personnel For emergency responders 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up : Mark the danger area. Exposure to heat: have neighbourhood close doors and windows. Exposure to fire/heat: consider evacuation. Wash contaminated clothes. : 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Handling temperature : 10 C above melting point 7.2. Conditions for safe storage, including any incompatibilities Prohibitions on mixed storage Storage area Special rules on packaging Packaging materials 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters : KEEP SUBSTANCE AWAY FROM: heat sources. : Keep container in a well-ventilated place. Store at ambient temperature. Keep out of direct sunlight. Meet the legal requirements. : SPECIAL REQUIREMENTS: closing. correctly labelled. meet the legal requirements. : 8.2. Exposure controls Personal protective equipment : Gloves. Protective clothing. Safety glasses. Materials for protective clothing : GIVE GOOD RESISTANCE: nitrile rubber. Version: EN (English) 3/8

4 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance (room temperature) : Liquid. Colour : Colourless to yellow. Odour : Almost odourless. ph Melting point : No supplementary information available Freezing point : ca. -15 C (-30/-10) Boiling point : > 250 C Flash point : ca. 240 C (ASTM D92) Self ignition temperature : > 300 C Decomposition temperature Vapour pressure : No supplementary information available Relative vapour density at 20 C Relative density Density : ca. 946,4 kg/m³ (20 C) Solubility Log Pow : > 5 Viscosity, kinematic : ca. 30 C (26-36) 9.2. VOC content Other properties : < 0,1 % (1999/13/EC; 2004/42/EC) : Oily. Soluble in oils/fats. soluble in most organic solvents. Insoluble in water. SECTION 10: Stability and reactivity Reactivity On burning: release of (carbon monoxide - carbon dioxide) Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity ( ) LD50 oral rat Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard > 5000 mg/kg Non-toxic Version: EN (English) 4/8

5 SECTION 12: Ecological information Toxicity Ecology - general Ecology - air Ecology - water : According to literature: no environmental hazard. : : No bioaccumulation data available Persistence and degradability Bioaccumulative potential ( ) Log Pow > Mobility in soil Results of PBT and vpvb assessment Other adverse effects : SECTION 13: Disposal considerations Waste treatment methods Disposal Regional legislation (waste) Ecology - waste materials EURAL code SECTION 14: Transport information In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA UN number No dangerous good in sense of transport regulations UN proper shipping name Transport hazard class(es) Packing group : Prevent dispersion by covering with dry absorbent,scoop solid spill into closing containers,scoop absorbed substance into closing containers,clean contaminated surfaces with an excess of water and soap solution,wash clothing and equipment after handling : : Do not discharge into drains or the environment. Remove to an authorized waste treatment plant. : No supplementary information available Environmental hazards : Special precautions for user Overland transport Transport regulations (ADR) Transport regulations (RID) State during transport (ADR-RID) Transport by sea Transport regulations (IMDG) Air transport Transport regulations (IATA) Instruction "cargo" (ICAO) Instruction "passenger" (ICAO) Instruction "passenger" - Limited quantities (ICAO) Not subject Not subject : Rail and road transport: not subject to ADR-RID : Not subject : Not subject : : : Version: EN (English) 5/8

6 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions EU Regulation 10/2011 (Annex I) VOC content : FCM 9 - acids, C2-C24, aliphatic, linear, monocarboxylic from natural oils and fats, and their mono-, di- and triglycerol esters (branched fatty acids at naturally occuring levels are included) : < 0,1 % (1999/13/EC; 2004/42/EC) National regulations Chemical inventories : Listed on AICS, DSL, ECL, ECST, ENCS, IECSC, NZIoC, PICCS, TSCA, EC inventories WGK class : nwg (not water endangering) Swiss Ordinance (RS ) Annex 6 : List of additives (part A) Chemical safety assessment The chemical safety assessment has been carried out, an exposure scenario is not applicable (substance is not classified). SECTION 16: Chem. inventories legend SDS changed sections SDS Reason for revision Indication of changes: Training advice : AICS = Australian Inventory of Chemical Substances DSL = Canadian Domestic Sustances List ECL = Korean Existing Chemical List ECST = Existing Chemical Substances Inventory of Taiwan ENCS = Japanese Existing and New Chemicals Substances List IECSC = Inventory of Existing Chemicals Substances in China NZIoC = New Zealand Inventory of Chemicals PICCS = Philippine Inventory of Chemicals and Chemical Substances TSCA = USA Toxic Substances Control Act EC inventories = European Community inventories of chemicals (EINECS/ELINCS/NLP/REACh) : 15 - Regulatory information;16 - : No supplementary information available : : Version: EN (English) 6/8

7 Full text of R-, H- and EUH-phrases:: AC10 Rubber articles ERC1 Manufacture of substances ERC10a Wide dispersive outdoor use of long-life articles and materials with low release ERC10b Wide dispersive outdoor use of long-life articles and materials with high or intended release (including abrasive processing) ERC11a Wide dispersive indoor use of long-life articles and materials with low release ERC2 Formulation of preparations ERC3 Formulation in materials ERC4 Industrial use of processing aids in processes and products, not becoming part of articles ERC5 Industrial use resulting in inclusion into or onto a matrix ERC6a Industrial use resulting in manufacture of another substance (use of intermediates) ERC6b Industrial use of reactive processing aids ERC6c Industrial use of monomers for manufacture of thermo-plastics ERC6d Industrial use of process regulators for polymerisation processes in production of resins, rubbers, polymers ERC7 Industrial use of substances in closed systems ERC8a Wide dispersive indoor use of processing aids in open systems ERC8b Wide dispersive indoor use of reactive substances in open systems ERC8c Wide dispersive indoor use resulting in inclusion into or onto a matrix ERC8d Wide dispersive outdoor use of processing aids in open systems ERC8e Wide dispersive outdoor use of reactive substances in open systems ERC8f Wide dispersive outdoor use resulting in inclusion into or onto a matrix ERC9a Wide dispersive indoor use of substances in closed systems ERC9b Wide dispersive outdoor use of substances in closed systems PC0 Other (use UCN codes: see last row) PC1 Adhesives, sealants PC12 Fertilizers PC14 Metal surface treatment products, including galvanic and electroplating products PC17 Hydraulic Fluids PC18 Ink and Toners PC19 Intermediate PC21 Laboratory chemicals PC24 Lubricants, Greases and Release Products PC25 Metal Working Fluids PC28 Perfumes, Fragrances PC29 Pharmaceuticals PC3 Air care products PC31 Polishes and Wax Blends PC32 Polymer preparations and compounds PC35 Washing and cleaning products (including solvent based products) PC39 Cosmetics, personal care products PC9a Coatings and paints, thinners, paint removers PC9b Fillers, putties, plasters, modelling clay PROC1 Use in closed process, no likelihood of exposure PROC10 Roller application or brushing PROC11 Non industrial spraying PROC12 Use of blowing agents in manufacture of foam PROC13 Treatment of articles by dipping and pouring PROC14 Production of preparations or articles by tabletting, compression, extrusion, pelletisation PROC15 Use as laboratory reagent PROC17 Lubrication at high energy conditions and in partly open process PROC19 Hand-mixing with intimate contact and only PPE available PROC2 Use in closed, continuous process with occasional controlled exposure PROC20 Heat and pressure transfer fluids in dispersive use but closed systems PROC21 Low energy manipulation of substances bound in materials and/or articles PROC24 High (mechanical) energy work-up of substances bound in materials and/or articles PROC3 Use in closed batch process (synthesis or formulation) PROC4 Use in batch and other process (synthesis) where opportunity for exposure arises PROC5 Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact) PROC6 Calendering operations PROC7 Industrial spraying PROC8a Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non dedicated facilities PROC8b Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC9 Transfer of substance or preparation into small containers (dedicated filling line, including weighing) Version: EN (English) 7/8

8 SU0 SU1 SU10 SU11 SU12 SU14 SU15 SU17 SU20 SU21 SU22 SU23 SU2a SU2b SU3 SU4 SU6b SU8 SU9 Other Agriculture, forestry, fishery Formulation [mixing] of preparations and/or re-packaging (excluding alloys) Manufacture of rubber products Manufacture of plastics products, including compounding and conversion Manufacture of basic metals, including alloys Manufacture of fabricated metal products, except machinery and equipment General manufacturing, e.g. machinery, equipment, vehicles, other transport equipment Health services Consumer uses: Private households (= general public = consumers) Professional uses: Public domain (administration, education, entertainment, services, craftsmen) Electricity, steam, gas water supply and sewage treatment Mining, (including offshore industries) Offshore industries Industrial uses: Uses of substances as such or in preparations* at industrial sites Manufacture of food products Manufacture of pulp, paper and paper products Manufacture of bulk, large scale chemicals (including petroleum products) Manufacture of fine chemicals SDS Oleon Annex II This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product Version: EN (English) 8/8