Azurite natural standard

Transcription

1 Revised edition: Version: 1 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Azurite natural standard Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Coloring agent, pigment Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 H302 Cat.: 4 Classification according to EC Regulation No. 67/548 or No. 1999/45 Harmful (Xn) R22 Acute toxicity (oral), hazard category 4 Harmful if swallowed. Harmful if swallowed. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: GHS07-1 Signal word: Warning Hazard designation: 2

2 Revised edition: Version: 1 H302 Harmful if swallowed. Page 2 Safety designation: P264 P270 Wash thoroughly after handling. Do not eat, drink or smoke when using this product Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Hazardous Ingredients: Cupric carbonate basic (Xn; R22; H302) Copper hydroxide carbonate, 2CuCO3 Cu(OH)2 CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Remove contaminated clothes. Supply fresh air. Wash off immediately with plenty of soap and water and rinse thoroughly. Rinse open eye for several minutes under running water. Should irritation continue, seek medical advice After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with plenty of water and consult physician. Symptoms: No further information available Effects: Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media No further information available. Suitable extinguishing media: Product itself does not burn. 3

3 Revised edition: Version: 1 Use extinguishing media for surrounding fire. Page Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture None known Special hazards: Advice for Firefighters Protective equipment: In case of fire: release of hazardous decomposition products. Wear self-contained respiratory protective device Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal precautions: Environmental Precautions Avoid formation of dust, wear protective clothing. Keep spectators away Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable container for disposal. Rinse spill area. Avoid dust formation. For information for safe handling see Section 7. The usual precautionary measures are to be adhered to when handling chemicals. Provide adequate ventilation Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Wash hands at the end of work. Preventive skin protection recommended. Storage conditions: Requirements for storage areas and containers: Store in tightly sealed containers in a dry and cool room. Keep container tightly closed. Information on fire and explosion protection: Do not store together with: acids. 4

4 Revised edition: Version: 1 Storage class (VCI): Page 4 Product is not flammable. Do not store together with: strong oxidants. Do not store together with: foodstuffs and animal feed Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): TWA-Value: 0.01 mg/m3 air-borne fraction Peak limit category II (2) Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: Wash hands before breaks and after work. Keep away from foodstuffs, beverages and feed. Do not inhale vapor/dust. Remove contaminated clothing. Wash hands after work. Dust mask. Dust mask recommended when very dusty (with particle filter P2/P3; EN 143). Protective gloves Chloroprene rubber (CR), nitrile rubber (NBR), butyl rubber, fluoro carbon rubber (FKM), polyvinyl chloride (PVC). Safety glasses (EN 166) Protective clothing. Environmental precautions: 5

5 Revised edition: Version: 1 9. Physical and Chemical Properties Information on Basic Physical and Chemical Properties Page 5 Form: Color: Odor: Odor threshold: ph-value: Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: powder blue odorless 9 (100 g/l; 20 C) not available not combustible non-combustible no information available no information available not determined Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: 4.0 g/cm3 (20 C) insoluble no information available Decomposition temperature: 200 C Viscosity, dynamic: Explosive properties: Product does not present an explosion hazard. Oxidizing properties: 6

6 Revised edition: Version: 1 Bulk density: ca kg/m Further Information Page Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: No further information. Stable if used according to specifications. Reacts with strong oxidants. Avoid heat, open fire and other ignition sources. approx. 200 C 1350 mg/kg (rat) No information available Irritant effect on eyes: 7

7 Page 7 Revised edition: Version: 1 Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): No information available Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: No toxicity expected. Not very soluble in water. 3, hazardous Avoid subsoil penetration. Prevent product from entering drains. Do not contaminate surface water. 8

8 Revised edition: Version: 1 AOX Value: 13. Disposal Considerations Waste Treatment Methods Page 8 Product: Dispose of according to official national and local regulations. European Waste Code (EWC): Uncleaned packaging: Dispose of according to official local regulations Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: No hazardous goods according to ADR (land transportation). IMDG/IATA: No hazardous goods according to IMDG Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards None Special Precautions for User Not classified as a dangerous good under transport regulations. 9

9 Revised edition: Version: Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Page 9 Not classified as a dangerous good under transport regulations. Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 3, very hazardous for water Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has not yet been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.