SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification. Version: 1.1 Revision Date: 08/16/2018

Transcription

1 1. Identification SAFETY DATA SHEET Material name: UNIVERSAL COLOR PACK STANDARD GRAY-CS Material: Q529 Recommended use and restriction on use Recommended use: Colorant Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information EUCLID CHEMICAL COMPANY REDWOOD ROAD CLEVELAND OH US Contact person: EH&S Department Telephone: Emergency telephone number: (US); (Canada) 2. Hazard(s) identification Hazard Classification Health Hazards Acute toxicity (Inhalation- dust and mist) Carcinogenicity Category 4 Category 1A Unknown toxicity - Health Acute toxicity, oral 0.42 % Acute toxicity, dermal % Acute toxicity, inhalation, vapor % Acute toxicity, inhalation, dust % or mist Environmental Hazards Acute hazards to the aquatic environment Unknown toxicity - Environment Acute hazards to the aquatic environment Chronic hazards to the aquatic environment 15 % % Category 1 Label Elements 1/19

2 Hazard Symbol: Signal Word: Hazard Statement: Danger Harmful if inhaled. May cause cancer. Very toxic to aquatic life. Precautionary Statements Prevention: Response: Storage: Disposal: Hazard(s) not otherwise classified (HNOC): Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Avoid release to the environment. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. Collect spillage. Store locked up. Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. None. 3. Composition/information on ingredients Mixtures Chemical Identity CAS number Content in percent (%)* 2/19

3 Titanium dioxide <50% Diisodecyl phthalate <50% Carbon Black <5% Calcium oxide <5% Aluminum oxide <5% Iron oxide <1% Amorphous silica <1% Zirconium dioxide <1% naphthenic distillate <1% * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. 4. First-aid measures Ingestion: Inhalation: Skin Contact: Eye contact: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. Move to fresh air. Wash skin thoroughly with soap and water. Get medical attention if symptoms occur. Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses. If eye irritation persists: Get medical advice/attention. Most important symptoms/effects, acute and delayed Symptoms: May cause skin and eye irritation. Indication of immediate medical attention and special treatment needed Treatment: Symptoms may be delayed. 5. Fire-fighting measures General Fire Hazards: No unusual fire or explosion hazards noted. Suitable (and unsuitable) extinguishing media Suitable extinguishing media: Unsuitable extinguishing media: Specific hazards arising from the chemical: Use fire-extinguishing media appropriate for surrounding materials. Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters 3/19

4 Special fire fighting procedures: Special protective equipment for fire-fighters: Self-contained breathing apparatus and full protective clothing must be worn in case of fire. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures: Methods and material for containment and cleaning up: Notification Procedures: Environmental Precautions: Dam and absorb spillages with sand, earth or other non-combustible material. Collect spillage in containers, seal securely and deliver for disposal according to local regulations. In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Do not contaminate water sources or sewer. Prevent further leakage or spillage if safe to do so. Avoid release to the environment. 7. Handling and storage Precautions for safe handling: Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities: Store locked up. 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits Chemical Identity Type Exposure Limit Values Source Titanium dioxide 10 mg/m3 US. ACGIH Threshold Limit Values (2011) Titanium dioxide - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) (022006) Titanium dioxide - Respirable 15 millions of US. OSHA Table Z-3 (29 CFR ) (03 particles per 2016) cubic foot of air Titanium dioxide - Total dust. 15 mg/m3 US. OSHA Table Z-3 (29 CFR ) ( ) Titanium dioxide - Respirable 5 mg/m3 US. OSHA Table Z-3 (29 CFR ) ( ) Titanium dioxide - Total dust. 50 millions of particles per cubic foot of air US. OSHA Table Z-3 (29 CFR ) ( ) Carbon Black - Inhalable 3 mg/m3 US. ACGIH Threshold Limit Values (2011) 4/19

5 Carbon Black PEL 3.5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) (022006) Calcium oxide PEL 2 mg/m3 US. ACGIH Threshold Limit Values (2011) 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) (022006) Aluminum oxide - Respirable 1 mg/m3 US. ACGIH Threshold Limit Values (2011) PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) (022006) Aluminum oxide - Total dust. PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Aluminum oxide - Respirable 50 millions of particles per cubic foot of air 15 millions of particles per cubic foot of air Contaminants (29 CFR ) (022006) US. OSHA Table Z-3 (29 CFR ) ( ) US. OSHA Table Z-3 (29 CFR ) ( ) 5 mg/m3 US. OSHA Table Z-3 (29 CFR ) ( ) Aluminum oxide - Total dust. 15 mg/m3 US. OSHA Table Z-3 (29 CFR ) ( ) Iron oxide - Respirable 5 mg/m3 US. ACGIH Threshold Limit Values (2011) Iron oxide - Fume. PEL 10 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) (022006) Iron oxide - Total dust. 15 mg/m3 US. OSHA Table Z-3 (29 CFR ) ( ) Iron oxide - Respirable 50 millions of particles per cubic foot of air US. OSHA Table Z-3 (29 CFR ) ( ) 5 mg/m3 US. OSHA Table Z-3 (29 CFR ) ( ) 15 millions of US. OSHA Table Z-3 (29 CFR ) (03 particles per 2016) cubic foot of air Amorphous silica 20 millions of particles per cubic foot of air US. OSHA Table Z-3 (29 CFR ) (2000) 0.8 mg/m3 US. OSHA Table Z-3 (29 CFR ) (2000) Zirconium dioxide - as Zr STEL 10 mg/m3 US. ACGIH Threshold Limit Values (2011) 5 mg/m3 US. ACGIH Threshold Limit Values (2011) naphthenic distillate - Inhalable naphthenic distillate naphthenic distillate - Mist. PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) (022006) 5 mg/m3 US. ACGIH Threshold Limit Values (032014) PEL PEL 500 ppm 2,000 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) (022006) 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR ) (022006) 5/19

6 Chemical name Type Exposure Limit Values Source Titanium dioxide - Total dust. Titanium dioxide - Respirable 10 mg/m3 Canada. British Columbia OELs. (Occupational 3 mg/m3 Canada. British Columbia OELs. (Occupational Titanium dioxide 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Titanium dioxide - Total dust. 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Diisodecyl phthalate 5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Carbon Black - Inhalable 3 mg/m3 Canada. British Columbia OELs. (Occupational 296/97, as amended) (092011) Carbon Black - Inhalable 3 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (062015) Carbon Black 3.5 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Calcium oxide 2 mg/m3 Canada. British Columbia OELs. (Occupational Calcium oxide 2 mg/m3 Canada. Ontario OELs. (Control of Exposure to Calcium oxide 2 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Aluminum oxide - Respirable. 1 mg/m3 Canada. British Columbia OELs. (Occupational Aluminum oxide - Total dust. 10 mg/m3 Canada. British Columbia OELs. (Occupational 296/97, as amended) (052013) Aluminum oxide - Respirable Aluminum oxide - Respirable Aluminum oxide - Inhalable Aluminum oxide - Respirable Aluminum oxide - Total dust. - as Al naphthenic distillate - Mist. 3 mg/m3 Canada. British Columbia OELs. (Occupational 296/97, as amended) (052013) 1 mg/m3 Canada. Ontario OELs. (Control of Exposure to 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (062015) 3 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (062015) 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor mg/m3 Canada. British Columbia OELs. (Occupational 296/97, as amended) (052013) 1 mg/m3 Canada. British Columbia OELs. (Occupational 296/97, as amended) (052013) 6/19

7 naphthenic distillate - Inhalable naphthenic distillate - Mist. 5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) ( ) 5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (062015) STEL 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor - 7/19

8 Chemical name Type Exposure Limit Values Source Titanium dioxide - Total dust. Titanium dioxide - Respirable 10 mg/m3 Canada. British Columbia OELs. (Occupational 3 mg/m3 Canada. British Columbia OELs. (Occupational Titanium dioxide 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Titanium dioxide - Total dust. 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Diisodecyl phthalate 5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Carbon Black - Inhalable 3 mg/m3 Canada. British Columbia OELs. (Occupational 296/97, as amended) (092011) Carbon Black - Inhalable 3 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (062015) Carbon Black 3.5 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Calcium oxide 2 mg/m3 Canada. British Columbia OELs. (Occupational Calcium oxide 2 mg/m3 Canada. Ontario OELs. (Control of Exposure to Calcium oxide 2 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Aluminum oxide - Respirable. 1 mg/m3 Canada. British Columbia OELs. (Occupational Aluminum oxide - Total dust. 10 mg/m3 Canada. British Columbia OELs. (Occupational 296/97, as amended) (052013) Aluminum oxide - Respirable Aluminum oxide - Respirable Aluminum oxide - Inhalable Aluminum oxide - Respirable Aluminum oxide - Total dust. - as Al 3 mg/m3 Canada. British Columbia OELs. (Occupational 296/97, as amended) (052013) 1 mg/m3 Canada. Ontario OELs. (Control of Exposure to 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (062015) 3 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (062015) 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Iron oxide - Total dust. 10 mg/m3 Canada. British Columbia OELs. (Occupational Iron oxide - Dust. - as Fe 5 mg/m3 Canada. British Columbia OELs. (Occupational 8/19

9 Iron oxide - Fume. - as Fe STEL 10 mg/m3 Canada. British Columbia OELs. (Occupational Iron oxide - Respirable 3 mg/m3 Canada. British Columbia OELs. (Occupational 296/97, as amended) ( ) Iron oxide - Fume. - as Fe 5 mg/m3 Canada. British Columbia OELs. (Occupational Iron oxide - Respirable 5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Iron oxide - Total dust. 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Iron oxide - Dust and fume. - as Fe 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Environment) ( ) Amorphous silica - Total 4 mg/m3 Canada. British Columbia OELs. (Occupational Amorphous silica - Respirable. Amorphous silica - Respirable dust. 1.5 mg/m3 Canada. British Columbia OELs. (Occupational 6 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Zirconium dioxide - as Zr STEL 10 mg/m3 Canada. British Columbia OELs. (Occupational 5 mg/m3 Canada. British Columbia OELs. (Occupational Zirconium dioxide - as Zr 5 mg/m3 Canada. Ontario OELs. (Control of Exposure to STEL 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Zirconium dioxide - as Zr 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor - STEL 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - naphthenic distillate - Mist. naphthenic distillate - Inhalable 0.2 mg/m3 Canada. British Columbia OELs. (Occupational 296/97, as amended) (052013) 1 mg/m3 Canada. British Columbia OELs. (Occupational 296/97, as amended) (052013) 5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (062015) 5 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) ( ) 9/19

10 naphthenic distillate - Mist. Crystalline Silica (Quartz)/ Silica Sand - Respirable Crystalline Silica (Quartz)/ Silica Sand - Respirable Crystalline Silica (Quartz)/ Silica Sand - Respirable dust. Appropriate Engineering Controls STEL 10 mg/m3 Canada. Quebec OELs. (Ministry of Labor - 5 mg/m3 Canada. Quebec OELs. (Ministry of Labor mg/m3 Canada. British Columbia OELs. (Occupational 0.10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (062015) 0.1 mg/m3 Canada. Quebec OELs. (Ministry of Labor - Environment) ( ) Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of vapors and mist. Mechanical ventilation or local exhaust ventilation may be required. Individual protection measures, such as personal protective equipment General information: Eye/face protection: Skin Protection Hand Protection: Other: Respiratory Protection: Hygiene measures: Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. Supplementary local exhaust ventilation, closed systems, or respiratory and eye protection may be needed in special circumstances, such as poorly ventilated spaces, heating, evaporation of liquids from large surfaces, spraying of mists, mechanical generation of dusts, drying of solids, etc. Wear safety glasses with side shields (or goggles). Use suitable protective gloves if risk of skin contact. Wear suitable protective clothing. In case of inadequate ventilation use suitable respirator. Seek advice from local supervisor. Observe good industrial hygiene practices. Wash hands before breaks and immediately after handling the product. 9. Physical and chemical properties Appearance Physical state: Form: Color: Odor: Odor threshold: ph: Melting point/freezing point: Initial boiling point and boiling range: liquid Paste Gray Mild 10/19

11 Flash Point: Not applicable Evaporation rate: Slower than Ether Flammability (solid, gas): No Upper/lower limit on flammability or explosive limits Flammability limit - upper (%): Flammability limit - lower (%): Explosive limit - upper (%): Explosive limit - lower (%): Vapor pressure: Vapor density: Vapors are heavier than air and may travel along the floor and in the bottom of containers. Relative density: 1.71 Solubility(ies) Solubility in water: Practically Insoluble Solubility (other): Partition coefficient (n-octanol/water): Auto-ignition temperature: Decomposition temperature: Viscosity: 10. Stability and reactivity Reactivity: Chemical Stability: Possibility of hazardous reactions: Conditions to avoid: Incompatible Materials: Hazardous Decomposition Products: Material is stable under normal conditions. Avoid heat or contamination. Avoid contact with oxidizing agents (e.g. nitric acid, peroxides and chromates). Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors. 11. Toxicological information Information on likely routes of exposure Inhalation: In high concentrations, vapors, fumes or mists may irritate nose, throat and mucus membranes. Skin Contact: Eye contact: May be harmful in contact with skin. Eye contact is possible and should be avoided. 11/19

12 Ingestion: May be ingested by accident. Ingestion may cause irritation and malaise. Symptoms related to the physical, chemical and toxicological characteristics Inhalation: Skin Contact: Eye contact: Ingestion: Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Dermal Inhalation Not classified for acute toxicity based on available data. Not classified for acute toxicity based on available data. ATEmix: 4.24 mg/l Repeated dose toxicity Skin Corrosion/Irritation Serious Eye Damage/Eye Irritation Respiratory or Skin Sensitization Carcinogenicity 12/19

13 IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: Titanium dioxide Carbon Black naphthenic distillate Overall evaluation: Possibly carcinogenic to humans. Overall evaluation: Possibly carcinogenic to humans. Overall evaluation: Not classifiable as to carcinogenicity to humans. Overall evaluation: Carcinogenic to humans. US. National Toxicology Program (NTP) Report on Carcinogens: Known To Be Human Carcinogen. naphthenic distillate US. OSHA Specifically Regulated Substances (29 CFR ): No carcinogenic components identified Germ Cell Mutagenicity In vitro In vivo Reproductive toxicity Specific Target Organ Toxicity - Single Exposure Specific Target Organ Toxicity - Repeated Exposure Aspiration Hazard Other effects: 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish 13/19

14 Aquatic Invertebrates Chronic hazards to the aquatic environment: Fish Aquatic Invertebrates Toxicity to Aquatic Plants Persistence and Degradability Biodegradation BOD/COD Ratio Bioaccumulative potential Bioconcentration Factor (BCF) Partition Coefficient n-octanol / water (log Kow) Mobility in soil: Other adverse effects: Very toxic to aquatic organisms. 13. Disposal considerations Disposal instructions: Contaminated Packaging: Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. 14. Transport information TDG: Not Regulated CFR / DOT: Not Regulated 14/19

15 IMDG: Not Regulated 15. Regulatory information US Federal Regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) None present or none present in regulated quantities. US. OSHA Specifically Regulated Substances (29 CFR ) Chemical Identity Crystalline Silica (Quartz)/ Silica Sand OSHA hazard(s) kidney effects lung effects immune system effects Cancer CERCLA Hazardous Substance List (40 CFR 302.4): Chemical Identity Reportable quantity Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate (Acute) Health Hazards Delayed (Chronic) Health Hazard Acute toxicity (any route or exposure) Carcinogenicity SARA 302 Extremely Hazardous Substance None present or none present in regulated quantities. SARA 304 Emergency Release Notification Chemical Identity Reportable quantity Diisodecyl phthalate Diisodecyl phthalate (mixed Is) 15/19

16 SARA 311/312 Hazardous Chemical Chemical Identity Threshold Planning Quantity Titanium dioxide lbs Diisodecyl phthalate lbs Carbon Black lbs Calcium oxide lbs Aluminum oxide lbs Iron oxide lbs Amorphous silica lbs Zirconium dioxide lbs lbs naphthenic distillate SARA 313 (TRI Reporting) Chemical Identity Aluminum oxide Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) None present or none present in regulated quantities. Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) None present or none present in regulated quantities. US State Regulations US. California Proposition 65 WARNING Cancer and Reproductive Harm - US. New Jersey Worker and Community Right-to-Know Act Chemical Identity Titanium dioxide Carbon Black Calcium oxide Aluminum oxide naphthenic distillate US. Massachusetts RTK - Substance List Chemical Identity Titanium dioxide Carbon Black Aluminum oxide Crystalline Silica (Quartz)/ Silica Sand 16/19

17 US. Pennsylvania RTK - Hazardous Substances Chemical Identity Titanium dioxide Diisodecyl phthalate Carbon Black Calcium oxide Aluminum oxide US. Rhode Island RTK Chemical Identity Titanium dioxide Carbon Black Aluminum oxide International regulations Montreal protocol Not applicable Stockholm convention Not applicable Rotterdam convention Not applicable Kyoto protocol Not applicable VOC: Regulatory VOC (less water and exempt solvent) : 1 g/l VOC Method 310 : 0.03 % 17/19

18 Inventory Status: Australia AICS: Canada DSL Inventory List: EINECS, ELINCS or NLP: Japan (ENCS) List: China Inv. Existing Chemical Substances: Korea Existing Chemicals Inv. (KECI): Canada NDSL Inventory: Philippines PICCS: US TSCA Inventory: New Zealand Inventory of Chemicals: Japan ISHL Listing: Japan Pharmacopoeia Listing: Mexico INSQ: Ontario Inventory: Taiwan Chemical Substance Inventory: All components in this product are listed on or exempt from the Inventory. All components in this product are listed on or exempt from the Inventory. 18/19

19 16.Other information, including date of preparation or last revision Version #: 1.1 Further Information: Disclaimer: For Industrial Use Only. Keep out of Reach of Children. The hazard information herein is offered solely for the consideration of the user, subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition. 19/19

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