Safety data sheet according to 1907/2006/EC, Article 31

Transcription

1 Page 1/7 1 Identification of the substance/mixture and of the company/undertaking Product identifier Trade name: SILICONEXP/XC Article number: SP0500/1 Relevant identified uses of the substance or mixture and uses advised against Application of the substance / the preparation Sealant Details of the supplier of the safety data sheet Manufacturer/Supplier: Tape Invent AS Nedre Nøttveit Rådal Norway Further information obtainable from: Tape Invent AS Emergency telephone number: During normal opening times: : Hazards identification Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC Information concerning particular hazards for human and environment: Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. Label elements Labelling according to EU guidelines: The product has been marked in accordance with EU Directives / respective national laws. Risk phrases: Special labelling of certain preparations: Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. 3 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of substances listed below with nonhazardous additions. Dangerous components: CAS: EINECS: trimethoxyvinylsilane Xn R20 R10 Flam. Liq. 3, H226; Acute Tox. 4, H % (Contd. on page 2)

2 Page 2/7 CAS: CAS: EINECS: CAS: EINECS: CAS: ELINCS: CAS: EINECS: Hydrocarbures, C11-C13, isoalcanes, <2% aromatiques Xn R65 R66 Asp. Tox. 1, H304 ethanol F R11 Flam. Liq. 2, H225 N-(3-(trimethoxysilyl)propyl)ethylenediamine Xn R20; Xi R41; Xi R43; N R51/53 Acute Tox. 3, H331; Eye Dam. 1, H318; Aquatic Chronic 2, H411; Skin Sens. 1, H317 a mixture of: dodecyl N-(2,2,6,6-tetramethylpiperidin-4-yl)-ß-alaninate; tetradecyl N-(2,2,6,6-tetramethylpiperidin-4-yl)-ß-alaninate C R34; Xn R22-48/22; N R50/53 STOT RE 2, H373; Skin Corr. 1B, H314; Aquatic Acute 1, H400; Aquatic Chronic 1, H410; Acute Tox. 4, H302 dibutyltin dilaurate T Repr. Cat. 2 R /25; Xn R22-68; Xi R36; N R50/53 Muta. Cat. 3 Acute Tox. 3, H301; Muta. 2, H341; Repr. 1B, H360; STOT RE 1, H372; Aquatic Acute 1, H400; Aquatic Chronic 1, H410; Eye Irrit. 2, H319 Additional information: For the wording of the listed risk phrases refer to section 16. (Contd. of page 1) % % % % % 4 First aid measures Description of first aid measures After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. 5 Firefighting measures Extinguishing media Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: Mouth respiratory protective device. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Not required. Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Pick up mechanically. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. (Contd. on page 3)

3 Page 3/7 See Section 13 for disposal information. (Contd. of page 2) 7 Handling and storage Handling: Precautions for safe handling No special precautions are necessary if used correctly. Ensure good ventilation/exhaustion at the workplace. Information about fire - and explosion protection: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Do not store together with oxidizing and acidic materials. Further information about storage conditions: Protect from heat and direct sunlight. Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: di-''isononyl'' phthalate (10-25%) WEL Long-term value: 5 mg/m³ ethanol ( %) WEL Long-term value: 1920 mg/m³, 1000 ppm dibutyltin dilaurate ( %) WEL Short-term value: 0.2 mg/m³ Long-term value: 0.1 mg/m³ as Sn; Sk Additional Occupational Exposure Limit Values for possible hazards during processing: methanol WEL Short-term value: 333 mg/m³, 250 ppm Long-term value: 266 mg/m³, 200 ppm Sk Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Wash hands before breaks and at the end of work. Do not eat, drink, smoke or sniff while working. Respiratory protection: Not required. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves (Contd. on page 4)

4 Page 4/7 (Contd. of page 3) The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Nitrile rubber, NBR Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Goggles recommended during refilling 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Pasty Colour: Various colours Odour: Characteristic Flash point: > 65 C Ignition temperature: 420 C Danger of explosion: Not determined. Explosion limits: Lower: 0.1 Vol % Upper: 0.2 Vol % Vapour pressure: Not determined. Density at 20 C: 1.44 g/cm³ Solubility in / Miscibility with water: Not miscible or difficult to mix. Viscosity: Dynamic at 20 C: mpas Solvent content: Organic solvents: 4.1 % Other information No further relevant information available. 10 Stability and reactivity Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: Carbon monoxide and carbon dioxide Nitrogen oxides (NOx) silicon dioxide (SiO2) During the crosslinking / polymerization: Methanol (Contd. on page 5)

5 Page 5/7 (Contd. of page 4) 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values relevant for classification: trimethoxyvinylsilane Oral LD mg/kg (rat) Dermal LD mg/kg (rabbit) Inhalative LC50/4 h 16.8 mg/l (rat) dibutyltin dilaurate Oral LD mg/kg (rat) Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitization: No sensitizing effects known. 12 Ecological information Toxicity Acquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behaviour in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Ecotoxical effects: Remark: Harmful to fish Additional ecological information: General notes: Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. European waste catalogue * waste adhesives and sealants containing organic solvents or other dangerous substances Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. (Contd. on page 6)

6 Page 6/7 (Contd. of page 5) 14 Transport information UN-Number A, ADN, IMDG, IATA Void UN proper shipping name A, ADN, IMDG, IATA Void Transport hazard class(es) A, ADN, IMDG, IATA Class Void Packing group A, IMDG, IATA Void Environmental hazards: Marine pollutant: No Special precautions for user Not applicable. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. 15 Regulatory information Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H301 Toxic if swallowed. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H331 Toxic if inhaled. H332 Harmful if inhaled. H341 Suspected of causing genetic defects. H360 May damage fertility or the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. R10 R11 R20 R22 R34 R36 R41 R43 Flammable. Highly flammable. Harmful by inhalation. Harmful if swallowed. Causes burns. Irritating to eyes. Risk of serious damage to eyes. May cause sensitisation by skin contact. (Contd. on page 7)

7 Page 7/7 (Contd. of page 6) R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed. R48/25 Toxic: danger of serious damage to health by prolonged exposure if swallowed. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R60 May impair fertility. R61 May cause harm to the unborn child. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. R68 Possible risk of irreversible effects. Department issuing MSDS: Product safety department Contact: Mr Tor Andre Skeie