Safety Data Sheet according to Regulation (EC) No 1907/2006

Transcription

1 Safety Data Sheet according to Regulation (EC) No 1907/2006 TEROSON VR 10 Page 1 of 13 SDS No. : Revision: printing date: Replaces version from: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier TEROSON VR 10 Contains: Hydrocarbons, C6-C7, n-alkanes, isoalkanes, 1.2. Relevant identified uses of the substance or mixture and uses advised against Intended use: Surface pretreatment 1.3. Details of the supplier of the safety data sheet Henkel AG & Co. KGaA Henkelstr Düsseldorf Germany Phone: +49 (211) ua-productsafety_za@henkel.com 1.4. Emergency telephone number Classification of the substance or mixture SECTION 2: Hazards identification Classification (CLP): Flammable liquids Category 2 H225 Highly flammable liquid and vapor. Skin irritation Category 2 H315 Causes skin irritation. Specific target organ toxicity - single exposure Category 3 H336 May cause drowsiness or dizziness. Aspiration hazard Category 1 H304 May be fatal if swallowed and enters airways. Chronic hazards to the aquatic environment Category 2 H411 Toxic to aquatic life with long lasting effects.

2 TEROSON VR 10 Page 2 of 13 Classification (DPD): F - Highly flammable R11 Highly flammable. Xn - Harmful R65 Harmful: may cause lung damage if swallowed. Xi - Irritant R38 Irritating to skin. Dangerous for the environment R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness Label elements Label elements (CLP): Hazard pictogram: Signal word: Hazard statement: Precautionary statement: Danger H225 Highly flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H411 Toxic to aquatic life with long lasting effects. P102 Keep out of reach of children. Precautionary statement: Prevention Precautionary statement: Response P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing vapours. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor. P331 Do NOT induce vomiting. P370+P378 In case of fire: Use CO2, dry chemical, or foam for extinction.

3 TEROSON VR 10 Page 3 of 13 Label elements (DPD): F - Highly flammable Xn - Harmful N - Dangerous for the environment Risk phrases: R11 Highly flammable. R38 Irritating to skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R67 Vapours may cause drowsiness and dizziness. Safety phrases: S2 Keep out of the reach of children. S9 Keep container in a well-ventilated place. S16 Keep away from sources of ignition - No smoking. S36/37 Wear suitable protective clothing and gloves. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Contains: Hydrocarbons, C6-C7, n-alkanes, isoalkanes, 2.3. Other hazards Solvents contained in the product evaporate during processing and their vapors can form explosive/highly inflammable air/vapor mixtures. The solvent vapors are heavier than air and may collect in high concentrations at floor level. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Mixtures General chemical description: Surface pretreatment Base substances of preparation: Hydrocarbon mixture, low aromatics SECTION 3: Composition/information on ingredients

4 TEROSON VR 10 Page 4 of 13 Declaration of the ingredients according to CLP (EC) No 1272/2008: Hydrocarbons, C6-C7, n-alkanes, isoalkanes, EC Number REACH-Reg No , content Classification % Flam. Liq. 2 H225 Asp. Tox. 1 H304 Skin Irrit. 2 H315 STOT SE 3 H336 Aquatic Chronic 2 H < 3 % Flam. Liq. 2 H225 Repr. 2 H361f Asp. Tox. 1 H304 STOT RE 2 H373 Skin Irrit. 2 H315 STOT SE 3 H336 Aquatic Chronic 2 H411 For full text of the H - statements and other abbreviations see section 16 "Other information". Substances without classification may have community workplace exposure limits available. Declaration of ingredients according to DPD (EC) No 1999/45: Hydrocarbons, C6-C7, n-alkanes, isoalkanes, EC Number REACH-Reg No , content Classification % F - Highly flammable; R11 Xi - Irritant; R38 Xn - Harmful; R65 R67 N - Dangerous for the environment; R51/ < 3 % F - Highly flammable; R11 Toxic for reproduction - category 3.; R62 Xn - Harmful; R65, R48/20 Xi - Irritant; R38 N - Dangerous for the environment; R51/53 R67 For full text of the R-Phrases indicated by codes see section 16 'Other Information'. Substances without classification may have community workplace exposure limits available. Declaration of ingredients according to Detergent Regulation 648/2004/EC > 30 % aliphatic hydrocarbons 4.1. Description of first aid measures Inhalation: Move to fresh air, consult doctor if complaint persists. Skin contact: IF ON SKIN: Wash with plenty of soap and water. In case of adverse health effects seek medical advice. SECTION 4: First aid measures Eye contact: Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist.

5 TEROSON VR 10 Page 5 of 13 Ingestion: Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. After ingestion or vomit: danger of product entering the lung Most important symptoms and effects, both acute and delayed ASPIRATION: Coughing, shortness of breath, nausea. Delayed effect: bronchopneumonia or pulmonary oedema SKIN: Redness, inflammation. Vapors may cause drowsiness and dizziness Indication of any immediate medical attention and special treatment needed Do not induce vomiting. Seek medical attention from a specialist. Small amounts of liquid aspirated into the respiratory system during ingestion or from vomiting may cause bronchopneumonia or pulmonary oedema Extinguishing media Suitable extinguishing media: All common extinguishing agents are suitable. SECTION 5: Firefighting measures Extinguishing media which must not be used for safety reasons: Water jet (solvent-containing product) Special hazards arising from the substance or mixture In case of fire toxic gases can be released Advice for firefighters Wear protective equipment. Wear self-contained breathing apparatus. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear protective equipment. Avoid contact with skin and eyes. Keep unprotected persons away. Danger of slipping on spilled product Environmental precautions Do not empty into drains / surface water / ground water. Inform authorities in the event of product spillage to water courses or sewage systems Methods and material for containment and cleaning up Remove with liquid-absorbing material (sand, peat, sawdust). Dispose of contaminated material as waste according to Section Reference to other sections See advice in section Precautions for safe handling Avoid open flames and sources of ignition. Ground/bond container and receiving equipment. Use explosion proof electric equipment. Use only non-sparking tools. Take precautionary measures against static discharge. SECTION 7: Handling and storage

6 TEROSON VR 10 Page 6 of 13 Hygiene measures: Do not eat, drink or smoke while working. Wash hands before work breaks and after finishing work. Take off contaminated clothing and wash before reuse Conditions for safe storage, including any incompatibilities Ensure good ventilation/extraction. Keep away from heat and direct sunlight. Do not store near sources of heat or ignition, or reactive materials. < + 25 C Storage at 5 to 25 C is recommended Specific end use(s) Surface pretreatment SECTION 8: controls/personal protection 8.1. Control parameters Occupational Limits Valid for South Africa Ingredient [Regulated substance] ppm mg/m 3 Value type Short term exposure limit category / Remarks Time Weighted Average (TWA): [N-HEXANE] Regulatory list ZA REL Derived No-Effect Level (DNEL): Name on list Hydrocarbons, C6-C7, n-alkanes, isoalkanes, Hydrocarbons, C6-C7, n-alkanes, isoalkanes, Hydrocarbons, C6-C7, n-alkanes, isoalkanes, Hydrocarbons, C6-C7, n-alkanes, isoalkanes, Hydrocarbons, C6-C7, n-alkanes, isoalkanes, Application Area Route of Health Effect Workers dermal Long term Workers inhalation Long term General dermal Long term population General population General population General population inhalation oral inhalation Long term Long term Long term Workers dermal Long term General population dermal Long term Workers inhalation Long term General population oral Long term Time Value 773 mg/kg 2035 mg/m3 699 mg/kg 608 mg/m3 699 mg/kg 16 mg/m3 11 mg/kg 5,3 mg/kg 75 mg/m3 4 mg/kg Remarks

7 TEROSON VR 10 Page 7 of 13 Biological Indices: None 8.2. controls: Engineering controls: Use only in well ventilated areas. Respiratory protection: In case of aerosol formation, we recommend wearing of appropriate respiratory protection equipment with ABEK P2 filter (EN 14387). This recommendation should be matched to local conditions. Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Goggles which can be tightly sealed. Protective eye equipment should conform to EN166. Skin protection: Wear protective equipment. Protective clothing that covers arms and legs. Protective clothing should conform to EN for liquid splashes or to EN for dusts. Advices to personal protection equipment: Use only personal protection that's CE-labelled according to Directive 89/686/EEC (Europe) or to Regulation No. 819 of 19 August 1994 (Norway). The information provided on personal protective equipment is for guidance purposes only. A full risk assessment should be conducted prior to using this product to determine the appropriate personal protective equipment to suit local conditions. Personal protective equipment should conform to the relevant EN standard. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance liquid thin, liquid colourless Odor of petrol Odour threshold ph Melting point Solidification temperature Initial boiling point (1.013 hpa) Flash point Evaporation rate Flammability Explosive limits Vapour pressure (20 C (68 F)) 85 C (185 F) -15,5 C (4.1 F); DIN Closed cup flash point 85 hpa

8 TEROSON VR 10 Page 8 of 13 Relative vapour density: Density (20 C (68 F)) Bulk density Solubility Solubility (qualitative) (20 C (68 F); Solvent: Water) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Viscosity (kinematic) (25 C (77 F); ) Explosive properties Oxidising properties 0,705 g/cm3 Not miscible 0,61 mm2/s 9.2. Other information Flow cup viscosity (23 C (73.4 F); Nozzle: 4 mm DIN EN ISO 2431; QP2017.1, QP1580.0; Running out with flow cups) Ignition temperature max. VOC content: 9 s 250 C (482 F) 705,00 g/l SECTION 10: Stability and reactivity Reactivity Reacts with strong oxidants Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions See section reactivity Conditions to avoid Heat, flames, sparks and other sources of ignition Incompatible materials See section reactivity Hazardous decomposition products No decomposition if used according to specifications Information on toxicological effects SECTION 11: Toxicological information General toxicological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation (EC) No 1272/2008. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. STOT-single exposure: May cause drowsiness or dizziness. Aspiration hazard: May be fatal if swallowed and enters airways. Skin irritation: Causes skin irritation.

9 TEROSON VR 10 Page 9 of 13 Acute oral toxicity: Hydrocarbons, C6-C7, n- alkanes, isoalkanes, Value type Value Route of application Species Method LD50 > mg/kg oral rat OECD Guideline 401 (Acute Oral Toxicity) LD mg/kg oral rat OECD Guideline 401 (Acute Oral Toxicity) Acute inhalative toxicity: Value type Value Route of application Species Method LC50 vapour 24 h rat OECD Guideline 403 (Acute Inhalation Toxicity) Acute dermal toxicity: Hydrocarbons, C6-C7, n- alkanes, isoalkanes, Value type Value Route of application Species Method LD50 > mg/kg dermal rat OECD Guideline 402 (Acute Dermal Toxicity) LD50 > mg/kg dermal rabbit not specified Skin corrosion/irritation: Result Species Method Serious eye damage/irritation: Result Species Method not irritating rabbit not specified Respiratory or skin sensitization: not sensitising Result Test type Species Method Mouse local lymphnod e assay (LLNA) mouse OECD Guideline 429 (Skin Sensitisation: Local Lymph Node Assay) Germ cell mutagenicity: Result Type of study / Route of administration negative bacterial reverse mutation assay (e.g negative Ames test) mammalian cell gene mutation assay Metabolic activation / Species Method with and without OECD Guideline 471 (Bacterial Reverse Mutation with and without negative inhalation: vapour mouse not specified negative inhalation: vapour rat not specified Assay) OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test)

10 TEROSON VR 10 Page 10 of 13 Carcinogenicity: Result Species Sex Frequenc y of treatment mouse female 2 y 6 h/d; 5 d/w Route of application inhalation: vapour Method OECD Guideline 451 (Carcinogenicity Studies) Reproductive toxicity: Hazardous substances Result / Classification Species NOAEL P = 9000 ppm NOAEL F1 = 3000 ppm NOAEL F2 = 3000 ppm Two generation study inhalation: vapour Species Method 10 w rat OECD Guideline 416 (Two- Generation Reproduction Toxicity Study) Repeated dose toxicity Result NOAEL=586 mg/kg NOAEL=500 ppm Route of application / Frequency of treatment Species Method oral: gavage 90 d5 d/w rat not specified inhalation: vapour 90 d6 h/d; 5 d/w mouse OECD Guideline 413 (Subchronic Inhalation Toxicity: 90-Day) SECTION 12: Ecological information General ecological information: The mixture is classified based on the available hazard information for the ingredients as defined in the classification criteria for mixtures for each hazard class or differentiation in Annex I to Regulation (EC) No 1272/2008. Relevant available health/ecological information for the substances listed under Section 3 is provided in the following. Do not empty into drains, soil or bodies of water Toxicity Ecotoxicity: Toxic to aquatic life with long lasting effects. Hydrocarbons, C6-C7, n- alkanes, isoalkanes, cyclics, <5% n-hexane Hydrocarbons, C6-C7, n- alkanes, isoalkanes, cyclics, <5% n-hexane Value type Value Acute Toxicity Study Species Method EC50 3 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) NOEC 0,17 mg/l chronic Daphnia 21 d Daphnia magna OECD 211 (Daphnia magna, Reproduction Test) LC50 > 1-10 mg/l Fish OECD Guideline 203 (Fish, Acute Toxicity Test) EC50 2,1 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC50 > 1-10 mg/l Algae OECD Guideline 201 (Alga, Growth Inhibition Test) EC 50 > 1-10 mg/l Bacteria OECD Guideline 209 (Activated Sludge, Respiration Inhibition Test)

11 TEROSON VR 10 Page 11 of Persistence and degradability Persistence and degradability: Degradation of surfactants The product does not contain surface-active substances as defined in the EU Detergent Regulation (EC/648/2004). Hydrocarbons, C6-C7, n- alkanes, isoalkanes, cyclics, <5% n-hexane Result Route of application Degradability Method readily biodegradable aerobic 98 % OECD Guideline 301 F (Ready Biodegradability: Manometric Respirometry Test) readily biodegradable, but failing 10-day window aerobic > 60 % not specified Bioaccumulative potential / Mobility in soil LogPow Bioconcentration Species Temperature Method factor (BCF) 4 not specified Results of PBT and vpvb assessment Hydrocarbons, C6-C7, n-alkanes, isoalkanes, PBT/vPvB Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria. Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very Bioaccumulative (vpvb) criteria Other adverse effects No data available. SECTION 13: Disposal considerations Waste treatment methods Product disposal: In consultation with the responsible local authority, must be subjected to special treatment. Waste code The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We will be happy to advise you. Waste code

12 TEROSON VR 10 Page 12 of 13 SECTION 14: Transport information UN number ADR 1268 RID 1268 ADN 1268 IMDG 1268 IATA UN proper shipping name ADR RID ADN IMDG IATA PETROLEUM DISTILLATES, N.O.S. PETROLEUM DISTILLATES, N.O.S. PETROLEUM DISTILLATES, N.O.S. PETROLEUM DISTILLATES, N.O.S. (Petroleum naphtha) Petroleum distillates, n.o.s Transport hazard class(es) ADR 3 RID 3 ADN 3 IMDG 3 IATA Packing group ADR RID ADN IMDG IATA II II II II II Environmental hazards ADR RID ADN IMDG IATA Environmentally Hazardous Environmentally Hazardous Environmentally Hazardous Environmentally Hazardous not applicable Special precautions for user ADR RID ADN IMDG IATA Special provision 640D Tunnelcode: (D/E) Special provision 640D Special provision 640D not applicable not applicable Transport in bulk according to Annex II of Marpol and the IBC Code not applicable SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture VOC content 100 % (VOCV VOC regulation CH) VOC content 3,0 % (2010/75/EU)

13 TEROSON VR 10 Page 13 of 13 VOC Paints and Varnishes (EU): Regulatory Basis: Product (sub)category: Phase I (from ): max. VOC content: Directive 2004/42/EC B(a) Preparatory and cleaning products 850 g/l 705,00 g/l Chemical safety assessment A chemical safety assessment has not been carried out. SECTION 16: Other information The labelling of the product is indicated in Section 2. The full text of all abbreviations indicated by codes in this safety data sheet are as follows: R11 Highly flammable. R38 Irritating to skin. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R62 Possible risk of impaired fertility. R65 Harmful: may cause lung damage if swallowed. R67 Vapours may cause drowsiness and dizziness. H225 Highly flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H361f Suspected of damaging fertility. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. Further information: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. Relevant changes in this safety data sheet are indicated by vertical lines at the left margin in the body of this document. Corresponding text is displayed in a different color on shadowed fields.