Material Safety Data Sheet Ampreg 22 Laminating Resin

Transcription

1 Conforms to ANSI Z Standard (United States, Canada).. Material Safety Data Sheet Product and company identification Common name Material uses Supplier/Manufacturer Epoxy resin. Gurit (Canada) inc. Usine de pré-imprégné 75 rue Péladeau Magog, QC JX 5G9 Tel In case of emergency CANUTEC (63) MSDS authored by Kemika XXI Inc /5/ Physical state Hazards identification Routes of entry Potential acute health effects Medical conditions aggravated by overexposure Liquid. (Fluid.) See toxicological information (section ) Odor Characteristic. Color Yellow. Hazard status This material is classified hazardous under OSHA regulations in the United States and the WHMIS Controlled Product Regulation in Canada. Emergency overview WARNING! CAUSES EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. Potential chronic health effects 3. Name Avoid contact with skin and clothing. Wash thoroughly after handling. Dermal contact. Eye contact... Irritating to eyes. Irritating to skin. May cause sensitization by skin contact. No known significant effects or critical hazards. No known significant effects or critical hazards. Carcinogenic effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Mutagenic effects Not available. Teratogenic effects Not available. Repeated skin exposure can produce local skin destruction or dermatitis. Repeated or prolonged contact with spray or mist may produce chronic eye irritation and severe skin irritation. Composition/information on ingredients United States CAS number Reaction product bisphenol A-(epichlorhydrin) Oxirane, mono[(c2-4-alkyloxy)methyl]derivs (2,3-Epoxypropoxy)-2,2-bis[(2,3-epoxypropoxy)methyl]butane Canada Name CAS number % Reaction product bisphenol A-(epichlorhydrin) Oxirane, mono[(c2-4-alkyloxy)methyl]derivs Date of issue 07/5/2006 Page /5 %

2 4. Eye contact contact First aid measures Check for and remove any contact lenses. In case of contact with eyes, rinse immediately with plenty of water. Get medical attention if symptoms occur. Wash with soap and water. Get medical attention if symptoms occur. Notes to physician If inhaled, remove to fresh air. If not breathing, give artificial respiration. Get medical attention if symptoms appear. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention if symptoms appear. No specific antidote. Medical staff must contact Poison Control Center. 5. Fire-fighting measures Flammability of the product Products of combustion Extinguishing media Suitable Not suitable Special exposure hazards Special protective equipment for fire-fighters 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up 7. Handling Storage 8. Handling and storage May be combustible at high temperature. These products are carbon oxides, halogenated compounds, hydrogen chloride. Use an extinguishing agent suitable for the surrounding fire. None known. No specific hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment. Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. If emergency personnel are unavailable, contain spilled material. For small spills, add absorbent (soil may be used in the absence of other suitable materials), scoop up material and place in a sealable, liquid-proof container for disposal. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep container tightly closed. Keep container in a cool, well-ventilated area. Exposure controls/personal protection Consult local authorities for acceptable exposure limits. Engineering measures No special ventilation requirements. Good general ventilation should be sufficient to control airborne levels. If this product contains ingredients with exposure limits, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure below any recommended or statutory limits. Personal protection equipments Safety glasses. Lab coat. Respiratory Hands A respirator is not needed under normal and intended conditions of use. Natural rubber (latex). Date of issue 07/5/2006 Page 2/5

3 HMIS Code/Personal protective equipment Personal protection in case of a large spill Hygiene measures 9. Physical state Flash point Color Odor B Safety glasses, goggles or face shield. Impervious gloves. Full suit. HAZMAT boots. Wear NIOSH-approved self-contained breathing apparatus or equivalent and full protective gear (Tychem-BR No 9527 from Dupont). Wash hands, forearms and face thoroughly after handling compounds and before eating, smoking and using the lavatory and at the end of the day. Follow good industrial hygiene practice. Physical and chemical properties Auto-ignition temperature Relative density Solubility 0. Liquid. (Fluid.) Closed cup 26 C (258.8 F).(Pensky-Martens.) 460 C (860 F) Yellow. Characteristic. Stability and reactivity Stability and reactivity Incompatibility with various substances Hazardous decomposition products.5 (Water = ) Insoluble in cold water, hot water. The product is stable. Reactive with oxidizing materials, acids and alkalis. These products are halogenated compounds, hydrogen chloride. Hazardous polymerization Will not occur. Conditions of reactivity Slightly flammable in the presence of the following materials or conditions open flames, sparks and static discharge. Non-flammable in the presence of the following materials or conditions heat.. Toxicological information Toxicity data Product/ingredient name Test Result Route Species Reaction product bisphenol A-(epichlorhydrin) Oxirane, mono[(c2-4-alkyloxy)methyl] derivs 400 mg/kg 3600 mg/kg >200 mg/kg >270 mg/kg Oral Oral Dermal Dermal Mouse 700 mg/kg Oral Acute Effects Potential chronic health effects Irritating to eyes. Irritating to skin. May cause sensitization by skin contact. No known significant effects or critical hazards. No known significant effects or critical hazards. Carcinogenic effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Mutagenic effects Not available. Teratogenic effects Not available. Date of issue 07/5/2006 Page 3/5

4 2. Ecological information Environmental precautions Products of degradation Toxicity of the products of biodegradation TOXIC TO AQUATIC ORGANISMS. May cause long-term adverse effects in the aquatic environment. These products are carbon oxides and water, halogenated compounds. The products of degradation are as toxic as the product itself. 3. Disposal considerations Waste disposal The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of spilled material, runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional and local authority requirements. 4. Transport information Regulatory information UN/ IMDG/ IATA DOT/ TDG Not regulated. 5. Regulatory information United States HCS Classification U.S. Federal regulations State regulations Canada WHMIS (Canada) Irritating material Sensitizing material TSCA All components listed. SARA 302/304/3/32 extremely hazardous substances No products were found. SARA 302/304 emergency planning and notification No products were found. SARA 302/304/3/32 hazardous chemicals No products were found. SARA 3/32 MSDS distribution - chemical inventory - hazard identification No products were found. Clean Water Act (CWA) 307 No products were found. Clean Water Act (CWA) 3 No products were found. Clean Air Act (CAA) 2 accidental release prevention No products were found. Clean Air Act (CAA) 2 regulated flammable substances No products were found. Clean Air Act (CAA) 2 regulated toxic substances No products were found. No products were found. California prop. 65 No products were found. Class D-2B Material causing other toxic effects (Toxic). DSL All components listed. This product has been classified in accordance with the hazard criteria of the Canadian CPR and the United States OSHA. This MSDS contains all the information required by the CPR and OSHA, the American National Standard Institute (ANSI) Z400.. International lists This product, (and its ingredients) is (are) listed on national inventories, or is (are) exempted from being listed, Australia (AICS), in Europe (EINECS/ELINCS), in Korea (TCCL), in Japan (METI), in the Philippines (RA6969). Date of issue 07/5/2006 Page 4/5

5 6. Other information Label requirements (U.S.A.) CAUSES EYE AND SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. Hazardous Material Information System (U.S.A.) HMIS RATING Health * Fire hazard Physical Hazard 0 Personal protection B HAZARD RATINGS 4- Extreme 3- Serious 2- Moderate - Slight 0- Minimal See section 8 for more detailed information on personal protection. National Fire Protection Association (U.S.A.) Health 0 Flammability Reactivity Special References Date of issue Version ANSI Z400., MSDS Standard, Manufacturer's Material Safety Data Sheet. - 29CFR Part OSHA MSDS Requirements. - 49CFR Table List of Hazardous Materials, UN#, Proper Shipping Names, PG. - Canada Gazette Part II, Vol. 22, No. 2. Registration SOR/88-64, 3 December 987. Hazardous Products Act "Ingredient Disclosure List" - Canadian Transport of Dangerous Goods, Regulations and Schedules, Clear Language version /5/2006 Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue 07/5/2006 Page 5/5